Mindat Logo
Home Page Log In Messageboard The Mindat Directory
Register Search Pages Mineral Chatroom The Mindat Store

Phosphoinnelite

This page is currently not sponsored. Click here to sponsor this page.
Big Photo

Kovdor Phlogopite mine (Mica Mine; Slyuda Mine; Kovdorslyuda Shaft), Kovdor Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
© Pavel M. Kartashov

Show Phosphoinnelite Photos (3)



Formula:
Na
 
3
Ba
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(PO
 
4
,SO
 
4
)
 
2
O
 
2
F
System:TriclinicColour:Brown
Hardness:4½ - 5
Name:For its phosphate content and relationship to Innelite


Phosphorous dominant analogue of Innelite

Bafertisite series

Classification of Phosphoinnelite

IMA status:Approved 2005
Strunz 8th edition ID:8/C.25-30
Nickel-Strunz 10th (pending) edition ID:9.BE.40

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
mindat.org URL:http://www.mindat.org/min-27577.html
Please feel free to link to this page.

Type Occurrence of Phosphoinnelite

Type Locality:Kovdor Phlogopite mine (Mica Mine; Slyuda Mine; Kovdorslyuda Shaft), Kovdor Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
General Appearance of Type Material:Lath-like crystals up to 0.2 x 1 x 6 mm in sheaf- and rosette-like aggregates
Geological Setting of type material:Agpaitic pegmatite veins cross-cutting calcite carbonatite in a phlogopite deposit
Associated Minerals at type locality:
PectoliteOrthoclaseMagnesio-arfvedsoniteGolysheviteFluorapatite
CancriniteAegirine-augite

Physical Properties of Phosphoinnelite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Brown
Hardness (Mohs):4½ - 5
Hardness Data:Measured
Cleavage:Perfect
on {010}, good on {100}
Density (measured):3.82 g/cm3

Crystallography of Phosphoinnelite

Crystal System:Triclinic
Cell Parameters:a = 5.38Å, b = 7.1Å, c = 14.76Å
α = 99°, β = 94.94°, γ = 90.14°
Ratio:a:b:c = 0.758 : 1 : 2.079
Unit Cell Volume:V 555 ų
Z:1
X-Ray Powder Diffraction:
d-spacingIntensity
14.5 (100)
2.683 (90)
2.133 (80)
3.455 (40)
2.810 (40)
2.059 (40)

Chemical Properties of Phosphoinnelite

Formula:
Na
 
3
Ba
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(PO
 
4
,SO
 
4
)
 
2
O
 
2
F
Essential elements:Ba, F, Na, O, P, Si, Ti
All elements listed in formula:Ba, F, Na, O, P, S, Si, Ti
Analytical Data:Results from electron microprobe analysis (EPMA)
SiO2 (17.83)
TiO2 (16.88)
Nb2O5 (0.74)
P2O5 (5.93)
Al2O3 (0.27)
Fe2O3 (1.55)
MnO (1.07)
MgO (0.64)
BaO (41.60)
SrO (0.99)
CaO (0.15)
K2O (0.04)
Na2O (6.06)
SO3 (5.29)
F (0.14)

less O = F (0.06)

sum 99.12 wt.-%

Relationship of Phosphoinnelite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.BE.02Wadsleyite
(Mg,Fe
2+
 
)
 
2
(SiO
 
4
)
9.BE.05Hennomartinite
SrMn
3+
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Lawsonite
CaAl
 
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Noelbensonite
BaMn
3+
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.05Itoigawaite
SrAl
 
2
(Si
 
2
O
 
7
)(OH)
 
2
 · H
 
2
O
9.BE.07Ilvaite
CaFe
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.07Manganilvaite
Ca(Mn
2+
 
,Fe
2+
 
)
 
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.10Suolunite
Ca
 
2
(H
 
2
Si
 
2
O
 
7
) · H
 
2
O
9.BE.12Jaffeite
Ca
 
6
(Si
 
2
O
 
7
)(OH)
 
6
9.BE.15Fresnoite
Ba
 
2
Ti(Si
 
2
O
 
7
)O
9.BE.17Baghdadite
Ca
 
3
(Zr,Ti)(Si
 
2
O
 
7
)O
 
2
9.BE.17Burpalite
Na
 
2
CaZr(Si
 
2
O
 
7
)F
 
2
9.BE.17Cuspidine
Ca
 
4
(Si
 
2
O
 
7
)(F,OH)
 
2
9.BE.17Hiortdahlite
(Ca,Na)
 
3
(Zr,Ti)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Janhaugite
(Na,Ca)
 
3
(Mn
2+
 
,Fe
2+
 
)
 
3
(Ti,Zr,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
9.BE.17Låvenite
(Na,Ca)
 
2
(Mn
2+
 
,Fe
2+
 
)(Zr,Ti)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Niocalite
(Ca,Nb)
 
4
(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Normandite
NaCa(Mn,Fe)(Ti,Nb,Zr)(Si
 
2
O
 
7
)OF
9.BE.17Wöhlerite
NaCa
 
2
(Zr,Nb)(Si
 
2
O
 
7
)(O,OH,F)
 
2
9.BE.17Hiortdahlite I
Na
 
4
Ca
 
8
Zr
 
2
(Nb,Mn,Ti,Fe,Mg,Al)
 
2
(Si
 
2
O
 
7
)
 
4
O
 
3
F
 
5
9.BE.17Marianoite
Na
 
2
Ca
 
4
(Nb,Zr)
 
2
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.20Mosandrite
(◻,Ca,Na)
 
3
(Ca,REE)
 
4
Ti(Si
 
2
O
 
7
)
 
2
[H
 
2
O,OH,F]
 
4
 · H
 
2
O
9.BE.20Nacareniobsite-(Ce)
Na
 
3
Ca
 
3
(Ce,La,Nd)Nb(Si
 
2
O
 
7
)
 
2
OF
 
3
9.BE.22Götzenite
Na
 
2
Ca
 
5
Ti(Si
 
2
O
 
7
)
 
2
F
 
4
9.BE.22Hainite
Na
 
4
Ca
 
8
(Ti,Zr,Mn)
 
3
(Si
 
2
O
 
7
)
 
4
F
 
4
9.BE.22Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)(Si
 
2
O
 
7
)OF
9.BE.22Kochite
(Na,Ca)
 
3
Ca
 
2
(Mn,Ca)ZrTi(Si
 
2
O
 
7
)
 
2
(F,O)
 
4
9.BE.23Dovyrenite
Ca
 
6
Zr(Si
 
2
O
 
7
)
 
2
(OH)
 
4
9.BE.25Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(OH,F)
9.BE.25Ericssonite
BaMn
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.25Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(O,OH,F)
9.BE.25Ericssonite-2O
BaMn
2+
2
Fe
3+
 
(Si
 
2
O
 
7
)O(OH)
9.BE.25Seidozerite
Na
 
8
Mn
2+
2
Zr
 
3
Ti
 
3
(Si
 
2
O
 
7
)
 
4
O
 
4
F
 
4
9.BE.25Nabalamprophyllite
Na
 
3
(Ba,Na)
 
2
Ti
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
9.BE.25Grenmarite
(Na,Ca)
 
4
(Mn,Na)(Zr,Mn)
 
2
(Zr,Ti)(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.25Schüllerite
Ba
 
2
Na(Mn,Ca)(Fe
3+
 
,Mg,Fe
2+
 
)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.25Lileyite
Ba
 
2
(Na,Fe,Ca)
 
3
MgTi
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
F
 
2
9.BE.27Murmanite
Na
 
2
Ti
 
2
(Si
 
2
O
 
7
)O
 
2
 · 2H
 
2
O
9.BE.30Epistolite
Na
 
2
(Nb,Ti)
 
2
(Si
 
2
O
 
7
)O
 
2
 · nH
 
2
O
9.BE.32Lomonosovite
Na
 
5
Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)O
 
2
9.BE.35Vuonnemite
Na
 
11
Ti
4+
 
Nb
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
3
(F,OH)
9.BE.37Sobolevite
Na
 
13
Ca
 
2
Mn
 
2
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
4
O
 
3
F
 
3
9.BE.40Innelite
Na
 
2
CaBa
 
4
Ti
 
3
(Si
 
2
O
 
7
)
 
2
(SO
 
4
)
 
2
O
 
4
9.BE.42Yoshimuraite
Ba
 
2
Mn
 
2
Ti(Si
 
2
O
 
7
)(PO
 
4
)O(OH)
9.BE.45Quadruphite
Na
 
14
Ca
 
2
Ti
 
4
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
2
F
9.BE.47Polyphite
Na
 
5
(Na
 
4
Ca
 
2
)Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)
 
3
O
 
2
F
 
2
9.BE.50Bornemanite
Na
 
6
BaTi
 
2
Nb(Si
 
2
O
 
7
)
 
2
(PO
 
4
)O
 
2
(OH)F
9.BE.50Shkatulkaite
Na
 
10
Mn
2+
 
Ti
 
3
Nb
 
3
(Si
 
2
O
 
7
)
 
6
(OH)
 
2
F · 12H
 
2
O
9.BE.55Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(O,OH)
 
2
9.BE.55Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(OH,F)
9.BE.55Bykovaite
(Ba,Na,K)
 
2
(Na,Ti,Mn)
 
4
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(H
 
2
O,F,OH)
 
2
 · 3.5H
 
2
O
9.BE.55Nechelyustovite
(Ba,Sr,K)
 
2
(Na,Ti,Mn)
 
4
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(O,H
 
2
O,F)
 
2
 · 4.5H
 
2
O
9.BE.60Delindeite
(Na,K)
 
2
(Ba,Ca)
 
2
(Ti,Fe,Al)
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
 · 2H
 
2
O
9.BE.65Bussenite
Na
 
2
Ba
 
2
Fe
2+
 
Ti(Si
 
2
O
 
7
)(CO
 
3
)(OH)
 
3
F
9.BE.67Jinshajiangite
BaNaFe
2+
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
9.BE.67Perraultite
BaNaMn
2+
4
Ti
 
2
 (Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
9.BE.67Surkhobite
NaCaBa
 
2
Mn
 
8
Ti
 
4
(Si
 
2
O
 
7
)
 
4
O
 
5
F
 
5
9.BE.70Karnasurtite-(Ce)
(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si
 
2
O
 
7
)(OH)
 
4
 · 3H
 
2
O
9.BE.70Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Fe
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
2+
 
(Ti,Zr)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Chevkinite-(Ce)
(Ce,La,Ca,Th)
 
4
(Fe
2+
 
,Mg)(Fe
2+
 
,Ti,Fe
3+
 
)
 
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Polyakovite-(Ce)
(Ce,Ca)
 
4
(Mg,Fe
2+
 
)(Cr
3+
 
,Fe
3+
 
)
 
2
(Ti,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Rengeite
Sr
 
4
ZrTi
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Matsubaraite
Sr
 
4
Ti
 
5
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Dingdaohengite-(Ce)
(Ce,La)
 
4
Fe
2+
 
(Ti,Fe
2+
 
,Mg,Fe
2+
 
)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Maoniupingite-(Ce)
(Ce,Ca)
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,◻)(Ti,Fe
3+
 
,Fe
2+
 
,Nb)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Perrierite-(La)
(La,Ce,Ca)
 
4
(Fe,Mn
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70UKI-2008-(SiO:SrTiZr)
Sr
 
4
ZrTi
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.70Hezuolinite
(Sr,REE)
 
4
Zr(Ti,Fe
3+
 
)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
9.BE.72Fersmanite
Ca
 
4
(Na,Ca)
 
4
(Ti,Nb)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
F
 
3
9.BE.75Belkovite
Ba
 
3
(Nb,Ti)
 
6
(Si
 
2
O
 
7
)
 
2
O
 
12
9.BE.77Nasonite
Pb
 
6
Ca
 
4
(Si
 
2
O
 
7
)
 
3
Cl
 
2
9.BE.80Kentrolite
Pb
 
2
Mn
3+
2
(Si
 
2
O
 
7
)O
 
2
9.BE.80Melanotekite
Pb
 
2
Fe
3+
2
(Si
 
2
O
 
7
)O
 
2
9.BE.82Tilleyite
Ca
 
5
(Si
 
2
O
 
7
)(CO
 
3
)
 
2
9.BE.85Killalaite
Ca
 
3
(Si
 
2
O
 
7
) · 0.5H
 
2
O
9.BE.87Stavelotite-(La)
(La,Nd,Ca)
 
3
Mn
2+
3
Cu(Mn
3+
 
,Fe
3+
 
,Mn
4+
 
)
 
26
(Si
 
2
O
 
7
)
 
6
O
 
5
9.BE.90Biraite-(Ce)
Ce
 
2
Fe
2+
 
(Si
 
2
O
 
7
)(CO
 
3
)
9.BE.92Cervandonite-(Ce)
(Ce,Nd,La)(Fe
3+
 
,Fe
2+
 
,Ti,Al)
 
3
O
 
2
(Si
 
2
O
 
7
)(As
3+
 
O
 
3
)(OH)
9.BE.95Batisivite
BaV
3+
8
Ti
 
6
(Si
 
2
O
 
7
)O
 
22

Other Names for Phosphoinnelite

Synonyms:
IMA2005-022
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Phosphoinnelite

Reference List:

- +
I. V. Pekov, N. V. Chukanov, I. M. Kulikova & D. L. Belakovsky:(2006): Proceedings of the Russian Mineralogical Society: 135(3):52–60: "Phosphoinnelite, Ba4Na3Ti3Si4O14(PO4,SO4)2(O,F)3, a new mineral from agpaitic pegmatites of Kovdor massif, Kola Peninsula"

Internet Links for Phosphoinnelite

Search Engines:
  • Look for Phosphoinnelite on Google
  • Look for Phosphoinnelite images on Google
    • External Links:
  • Look for Phosphoinnelite on Webmineral
  • Look for Phosphoinnelite on Athena Mineralogy
  • Look for Phosphoinnelite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
    • Mineral Dealers:
  • DAKOTA MATRIX offers Cabinet and Rare Species from Worldwide Localities.
  • Buy minerals from YourMineralCollection
  • webminerals
  • Fine and rare minerals from mintreasure.com
  • Search for - Phosphoinnelite - on e-Rocks Mineral Sales & Auctions
  • Buy RARE Minerals from Rocks of Africa
  • Phosphoinnelite specimens for sale - minfind.com
  • Mineral Classics - Worldwide Collector Quality Minerals and Gems
  • Find Phosphoinnelite on www.crystalclassics.co.uk
  • rare and unusual minerals mainly crystallized
  • Top quality minerals from Kristalle of California
  • Search for minerals at Heliodor
    • Jobs:
  • Mining & Geology Jobs

    • Localities for Phosphoinnelite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Kovdor Massif
    		Zapiski Rossiiskogo Mineralogicheskogo Obshchetstva 135, issue 3, 52-60
    Mineral and/or Locality
    Search Google
     
    Copyright © Jolyon Ralph and Ida Chau 1993-2013. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
    Current server date and time: 27th Mar 2013 19:10:33
    Mineral and Locality Search
    Mineral:
    and/or Locality:
    Options
    Fade toolbar when not in focusFix toolbar to bottom of page
    Hide Social Media Links
    Slideshow frame delay seconds