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Nenadkevichite

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Poudrette quarry (Demix quarry; Uni-Mix quarry; Desourdy quarry; Carrière Mont Saint-Hilaire), Mont Saint-Hilaire, Rouville RCM, Montérégie, Québec, Canada
© Stephan Wolfsried

Show Nenadkevichite Photos (93)



Formula:
(Na,◻)
 
8
Nb
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 8H
 
2
O
System:OrthorhombicColour:Rose-pink, very light ...
Hardness:5
Member of:Nenadkevichite Subgroup > Labuntsovite Group
Name:After Konstantin Avtonomovich Nenadkevich [May 21 or June 2, 1880 Kashevka, now Kovel' Raion, Volyn' Oblast, Russia - June 19, 19633 Moscow, Russia] Russian mineralogist and geochemist, A.E. Fersman Mineralogical Museum, Moscow, Russia.


Labuntsovite Group, Nenadkevichite Subgroup.

Classification of Nenadkevichite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/E.07-90
Nickel-Strunz 10th (pending) edition ID:9.CE.30a

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Dana 8th edition ID:60.1.3.1

60 : CYCLOSILICATES Four-Membered Rings
1 : Four-Membered Rings, as Titanosilicates
Hey's CIM Ref.:17.8.8

17 : Silicates Containing other Anions
8 : Silicates with niobate or tantalate
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Type Occurrence of Nenadkevichite

Type Locality:Natrolite Stock (Pegmatite No. 61), Karnasurt Mt, Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1955
Geological Setting of type material:Natrolite-albite-rich pegmatite in nepheline syenite in a differentiated alkalic massif.
Associated Minerals at type locality:
Microcline

Physical Properties of Nenadkevichite

Lustre:Vitreous, Dull
Diaphaneity (Transparency):Transparent, Translucent, Opaque
Colour:Rose-pink, very light pink, light yellow, brown; dark brown due to inclusions
Streak:White, very light rose-pink
Hardness (Mohs):5
Tenacity:Brittle
Cleavage:Poor/Indistinct
On {001}
Fracture:Irregular/Uneven
Density (measured):2.78 - 2.885 g/cm3
Density (calculated):2.7 g/cm3

Crystallography of Nenadkevichite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:Pbam {P21/b 21/a 2/m}
Cell Parameters:a = 7.408Å, b = 14.198Å, c = 7.148Å
Ratio:a:b:c = 0.522 : 1 : 0.503
Unit Cell Volume:V 751.82 ų (Calculated from Unit Cell)
Z:4
Morphology:Crystals equant or bladed pseudohexagonal prisms. Foliated segregations and lamellar mases.
X-Ray Powder Diffraction:
d-spacingIntensity
3.20 (100)
3.10 (100)
1.427 (100)
1.289 (90)
2.49 (80)
2.58 (70)
1.705 (70)
Comments:Lovozero massif material.

Optical Data of Nenadkevichite

Type:Biaxial (+)
RI values: nα = 1.633 - 1.659 nβ = 1.642 - 1.686 nγ = 1.738 - 1.785
2V:Measured: 31° to 45°, Calculated: 36° to 58°
Maximum Birefringence:δ = 0.105 - 0.126

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v strong
Pleochroism:Weak
Comments:X = colourless
Y = Light yellow
Z = Light rose-pink

Chemical Properties of Nenadkevichite

Formula:
(Na,◻)
 
8
Nb
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 8H
 
2
O
Idealised Formula:
(Na,Ca)(Nb,Ti)Si
 
2
O
 
7
 · 2H
 
2
O
Essential elements:H, Na, Nb, O, Si
All elements listed in formula:H, Na, Nb, O, Si
Common Impurities:Al,TR,Fe,Mn,Mg,Ba

Relationship of Nenadkevichite to other Species

Member of:Nenadkevichite Subgroup > Labuntsovite Group
Other Members of Group:

- +
Alsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7H
 
2
O
Burovaite-Ca
(Na,K)
 
4
Ca
 
2
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(OH,O)
 
8
 · 12H
 
2
O
Gjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
Gjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
Gjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
Gjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
 · 5H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.CE.05Papagoite
CaCu[H
 
3
AlSi
 
2
O
 
9
]
9.CE.10Verplanckite
Ba
 
2
(Mn,Fe,Ti)Si
 
2
O
 
6
(O,OH,Cl,F)
 
2
 · 3H
 
2
O or near
9.CE.15Baotite
Ba
 
4
(Ti,Nb)
 
8
Si
 
4
O
 
28
Cl
9.CE.20Nagashimalite
Ba
 
4
(V,Ti)
 
4
B
 
2
Si
 
8
O
 
27
(O,OH)
 
2
Cl
9.CE.20Taramellite
Ba
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.20Titantaramellite
Ba
 
4
(Ti,Fe
3+
 
,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.25Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
 · H
 
2
O
9.CE.25Byelorussite-(Ce)
NaBa
 
2
Ce
 
2
MnTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(F,OH) · H
 
2
O
9.CE.25Joaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(OH,F) · H
 
2
O
9.CE.25Orthojoaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH) · H
 
2
O
9.CE.25Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
 · H
 
2
O
9.CE.25Strontio-orthojoaquinite
(Na,Fe)
 
2
Sr
 
2
Ba
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
 · H
 
2
O
9.CE.25Orthojoaquinite-(La)
NaBa
 
2
La
 
2
Fe
2+
 
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH) · H
 
2
O
9.CE.30eLabuntsovite-Mn
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
 · 10-12H
 
2
O
9.CE.30dLemmleinite-K
K
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 4H
 
2
O
9.CE.30aKorobitsynite
Na
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 3-4H
 
2
O
9.CE.30cKuzmenkoite-Mn
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
 · 5H
 
2
O
9.CE.30bVuoriyarvite-K
K
 
2
(Nb,Ti)
 
2
(Si
 
4
O
 
12
)(O,OH)
 
2
 · 4H
 
2
O
9.CE.30bTsepinite-Na
Na
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 3H
 
2
O
9.CE.30cKarupmøllerite-Ca
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7H
 
2
O
9.CE.30eLabuntsovite-Mg
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
 · 10H
 
2
O
9.CE.30eLabuntsovite-Fe
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
 · 10H
 
2
O
9.CE.30dLemmleinite-Ba
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 5H
 
2
O
9.CE.30cGjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
9.CE.30hNeskevaaraite-Fe
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 5-6 H
 
2
O
9.CE.30bTsepinite-K
K
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 3H
 
2
O
9.CE.30bParatsepinite-Ba
Ba
 
4
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(OH,O)
 
8
 · 8H
 
2
O
9.CE.30bTsepinite-Ca
Ca(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 3H
 
2
O
9.CE.30hAlsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7H
 
2
O
9.CE.30cGjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
9.CE.30cLepkhenelmite-Zn
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7H
 
2
O
9.CE.30bTsepinite-Sr
Sr(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
 · 3H
 
2
O
9.CE.30bParatsepinite-Na
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
9.CE.30fParalabuntsovite-Mg
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· nH
 
2
O
9.CE.30cGjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
9.CE.30cGjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
 · 5H
 
2
O
9.CE.30hGutkovaite-Mn
K
 
2
CaMn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 5H
 
2
O
9.CE.30cKuzmenkoite-Zn
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
9.CE.30gOrganovaite-Mn
K
 
2
Mn(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
9.CE.30gOrganovaite-Zn
K
 
2
Zn(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 6H
 
2
O
9.CE.30gParakuzmenkoite-Fe
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
 · 14H
 
2
O
9.CE.30cBurovaite-Ca
(Na,K)
 
4
Ca
 
2
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(OH,O)
 
8
 · 12H
 
2
O
9.CE.45Komarovite
(Ca,Mn)Nb
 
2
[O
 
3
|Si
 
2
O
 
7
] · 3.5H
 
2
O
9.CE.45Natrokomarovite
(Na,Ca,H)
 
2
Nb
 
2
Si
 
2
O
 
10
(OH,F)
 
2
 · H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
17.8.1Epistolite
Na
 
2
(Nb,Ti)
 
2
(Si
 
2
O
 
7
)O
 
2
 · nH
 
2
O
17.8.2Murmanite
Na
 
2
Ti
 
2
(Si
 
2
O
 
7
)O
 
2
 · 2H
 
2
O
17.8.3Perraultite
BaNaMn
2+
4
Ti
 
2
 (Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
17.8.4Niocalite
(Ca,Nb)
 
4
(Si
 
2
O
 
7
)(O,OH,F)
 
2
17.8.5Mongolite
Ca
 
4
Nb
 
6
Si
 
5
O
 
24
(OH)
 
10
 · nH
 
2
O
17.8.6Fersmanite
Ca
 
4
(Na,Ca)
 
4
(Ti,Nb)
 
4
(Si
 
2
O
 
7
)
 
2
O
 
8
F
 
3
17.8.7Nacareniobsite-(Ce)
Na
 
3
Ca
 
3
(Ce,La,Nd)Nb(Si
 
2
O
 
7
)
 
2
OF
 
3
17.8.9Natrokomarovite
(Na,Ca,H)
 
2
Nb
 
2
Si
 
2
O
 
10
(OH,F)
 
2
 · H
 
2
O
17.8.10Wöhlerite
NaCa
 
2
(Zr,Nb)(Si
 
2
O
 
7
)(O,OH,F)
 
2
17.8.11Belkovite
Ba
 
3
(Nb,Ti)
 
6
(Si
 
2
O
 
7
)
 
2
O
 
12
17.8.12Baotite
Ba
 
4
(Ti,Nb)
 
8
Si
 
4
O
 
28
Cl
17.8.13Shcherbakovite
(K,Ba)KNa(Ti,Nb)
 
2
(Si
 
4
O
 
12
)O
 
2
17.8.14Ilímaussite-(Ce)
(Na,K)
 
7-8
(Ba,K)
 
10
Ce
 
5
(Nb,Ti)
 
6
(Si
 
3
O
 
9
)
 
4
(Si
 
9
O
 
18
)O
 
6
(O,OH)
 
24
17.8.15Komarovite
(Ca,Mn)Nb
 
2
[O
 
3
|Si
 
2
O
 
7
] · 3.5H
 
2
O
17.8.16Manganbelyankinite
(Mn,Ca)(Ti,Nb)
 
5
O
 
12
 · 9H
 
2
O
17.8.17Niobophyllite
(K,Na)
 
3
(Fe,Mn)
 
6
(Nb,Ti)
 
2
Si
 
8
(O,OH,F)
 
31
17.8.18Caesium-Kupletskite

Other Names for Nenadkevichite

Other Languages:
German:Nenadkevichit
Russian:Ненадкевичит
Spanish:Nenadkevichita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Nenadkevichite

Reference List:

- +
Kuz'menko, M.V., and Kazakova, M.E. (1955) Nenadkevichite - anew mineral.Doklady Akademii Nauk SSSR: 100: 1159-1160 (in Russian).

American Mineralogist (1955): 40: 1154 (abstract).

Vlasov, K.A., editor (1966) Mineralogy of rare elements, volume II: 547-549.

Perrault, G., Boucher, C., and Vicat, J. (1973) Structure cristalline du nenadkevichite (Na,K)2-x(Nb,Ti)(O,OH)Si2O6·2H2O. Acta Crystallographica: B29: 1432-1438 (in French with English abstracts).

Mandarino, J.A. and Anderson, V. (1989) Monteregian Treasures Cambridge University Press: 155.

Canadian Mineralogist (1999): 901-910.

European Journal of Mineralogist (2002): 14: 165-173.

Internet Links for Nenadkevichite

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    • Localities for Nenadkevichite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Québec
      • Montérégie
        • Lajemmerais RCM
          • Varennes & St-Amable
            • Saint-Amable sill
    		Horváth, L., Pfenninger-Horváth, E., Gault, R. A., & Tarassoff, P. (1998): Mineralogy of the Saint-Amable Sill, Varennes and Saint-Amable, Québec. Mineralogical Record, 29: 83-118.
        • Rouville RCM
          • Mont Saint-Hilaire
    		Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359., AmMin 40:1154(1955)
    China
     
    • Liaoning Province (Manchuria; Dongbei Region)
      • Dandong Prefecture
        • Fengcheng Co.
          • Saima complex
    		Saima Deposit Research Group, Beijing Institute of Uranium Geology (1978): Scientia Sinica 11(3), 365-389
    Greenland
     
    • Kitaa Province (West Greenland)
      • Narsaq
    		Soerensen, H. (2001): The Ilimaussaq alkaline complex, South Greenland: status of mineralogical research with new results, Geology of Greenland Survey Bulletin 190, GEUS
    Namibia
     
    • Khomas Region
      • Windhoek District
        • Aris
    		Uwe Kolitsch (single-crystal X-ray diffraction); Petersen et al.: Mineralienwelt 15(2): 44-48 (2004)
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
            • Kukisvumchorr Mt
    		Lapis 28(12), 46-47 (2003)
    Pekov, I. et al (2003): New Data on Minerals: 38: 20-33.
    http://maurice.strahlen.org/kola/khibiny.htm
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
          • Lovozero Massif
    		Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
              • Umbozero mine (Umba mine)
            • Karnasurt Mt
    		I. Pekov (1998) Minerals First Discovered on the Territory of the former Soviey Union
    [World of Stones 95:5-6, p64]
        • Northern Karelia
          • Vuoriyarvi alkaline-ultrabasic massif
    		Lapis 28(12), 47 (2003)
    • Urals Region
      • Southern Urals
        • Chelyabinsk Oblast'
    		New Data on Minerals (2004): 39: 50-64
    USA
     
    • Arkansas
      • Hot Spring Co.
        • Magnet Cove
    		Henry Barwood - unpublished (2010)
    • Virginia
    		Minerals of Virginia 1990 by R. V. Dietrich
    Minerals of Virginia 1990 by R. V. Dietrich
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