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Gutkovaite-Mn

Big Photo

Maly Mannepakhk Mt (Malyi Mannepakhk Mt), Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
© 2008, JGW

Formula:
K
 
2
CaMn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
System:MonoclinicColour:pale yellowish-pink
Hardness:5
Name:Named after N. N. Gutkova (1896-1960?), Russian mineralogist, who intensively studied the Khibina-Lovozero alkaline complex. She was the first to describe the properties of the Khibiny apatite; discovered primary lovchorrite deposits in the Khibiny massif in 1930; and published the first list of Lovozero species (21) in 1928.


Labuntsovite Group. Gutkovaite Subgroup.

Classification of Gutkovaite-Mn

IMA status:Approved 2002
Strunz 8th edition ID:8/E.07-200
Nickel-Strunz 10th (pending) edition ID:9.CE.30h

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
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Type Occurrence of Gutkovaite-Mn

Type Locality:Maly Mannepakhk Mt (Malyi Mannepakhk Mt), Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Place of Conservation of Type Material:Fersman Mineralogical Museum, Moscow, Russia.
Geological Setting of type material:Pegmatite within nepheline syenite.
Associated Minerals at type locality:
NephelineMicroclineLorenzeniteEudialyteArfvedsonite
AnalcimeAlbiteAegirine

Physical Properties of Gutkovaite-Mn

Lustre:Vitreous
Diaphaneity (Transparency):Transparent, Translucent
Colour:pale yellowish-pink
Streak:White
Hardness (Mohs):5
Hardness Data:Measured
Tenacity:Brittle
Cleavage:None Observed
Fracture:Irregular/Uneven
Density (measured):2.83 g/cm3
Density (calculated):2.79 g/cm3

Crystallography of Gutkovaite-Mn

Crystal System:Monoclinic
Cell Parameters:a = 14.3Å, b = 13.889Å, c = 7.76Å
β = 117.51°
Ratio:a:b:c = 1.03 : 1 : 0.559
Unit Cell Volume:V 1,366.97 ų (Calculated from Unit Cell)
Z:2
Morphology:Prismatic crystals to 0.8 mm in length.
Twinning:Microtwinned on (001) and (_401).
X-Ray Powder Diffraction:
d-spacingIntensity
7.0 (70)
6.33 (50)
3.22 (90)
3.05 (100)
2.57 (50)
Comments:57 mm Debye-Scherrer, FeKα radiation.
Format: d/A (I/%) (hkl)

Optical Data of Gutkovaite-Mn

Type:Biaxial (+)
Dispersion:None observed.
Pleochroism:Non-pleochroic

Chemical Properties of Gutkovaite-Mn

Formula:
K
 
2
CaMn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
All elements listed in formula:Ca, H, K, Mn, Nb, O, Si, Ti

Relationship of Gutkovaite-Mn to other Species

Member of Group:
Labuntsovite Group:
Related Minerals - Nickel-Strunz Grouping):

- +
9.CE.05Papagoite
CaCu[H
 
3
AlSi
 
2
O
 
9
]
9.CE.10Verplanckite
Ba
 
2
(Mn,Fe,Ti)Si
 
2
O
 
6
(O,OH,Cl,F)
 
2
·3H
 
2
O or near
9.CE.15Baotite
Ba
 
4
(Ti,Nb)
 
8
Si
 
4
O
 
28
Cl
9.CE.20Nagashimalite
Ba
 
4
(V,Ti)
 
4
B
 
2
Si
 
8
O
 
27
(O,OH)
 
2
Cl
9.CE.20Taramellite
Ba
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.20Titantaramellite
Ba
 
4
(Ti,Fe
3+
 
,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.25Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
Si
 
8
O
 
26
·H
 
2
O
9.CE.25Byelorussite-(Ce)
Ba
 
2
NaCe
 
2
MnTi
 
2
Si
 
8
O
 
26
(F,OH) · H
 
2
O
9.CE.25Joaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(OH,F) · H
 
2
O
9.CE.25Orthojoaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(O,OH) · H
 
2
O
9.CE.25Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Strontio-orthojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Orthojoaquinite-(La)
Ba
 
2
NaLa
 
2
Fe
2+
 
Ti
 
2
Si
 
8
O
 
26
(O,OH)·H
 
2
O
9.CE.30eLabuntsovite-Mn
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10-12H
 
2
O
9.CE.30aNenadkevichite
(Na,[])
 
8
Nb
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
·8H
 
2
O
9.CE.30dLemmleinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30aKorobitsynite
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3-4H
 
2
O
9.CE.30cKuzmenkoite-Mn
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30bVuoriyarvite-K
K
 
2
(Nb,Ti)
 
2
[(O,OH)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30bTsepinite-Na
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30cKarupmøllerite-Ca
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 7H
 
2
O
9.CE.30eLabuntsovite-Mg
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10H
 
2
O
9.CE.30eLabuntsovite-Fe
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10H
 
2
O
9.CE.30dLemmleinite-Ba
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30cGjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30hNeskevaaraite-Fe
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5-6 H
 
2
O
9.CE.30bTsepinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Ba
Ba
 
4
(Ti,Nb)
 
8
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
4
 · 8H
 
2
O
9.CE.30bTsepinite-Ca
Ca(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30hAlsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7H
 
2
O
9.CE.30cGjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30cLepkhenelmite-Zn
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 7H
 
2
O
9.CE.30bTsepinite-Sr
Sr(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Na
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
9.CE.30fParalabuntsovite-Mg
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· n(H
 
2
O)
9.CE.30cGjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30cGjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30cKuzmenkoite-Zn
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
9.CE.30gOrganovaite-Mn
K
 
2
Mn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30gOrganovaite-Zn
K
 
2
Zn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30gParakuzmenkoite-Fe
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 14H
 
2
O
9.CE.30cBurovaite-Ca
(Na,K)
 
4
Ca
 
2
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(OH,O)
 
8
·12H
 
2
O
9.CE.45Komarovite
(Ca,Mn)Nb
 
2
[O
 
3
|Si
 
2
O
 
7
] · 3.5H
 
2
O
9.CE.45Natrokomarovite
(Na,Ca,H)
 
2
Nb
 
2
Si
 
2
O
 
10
(OH,F)
 
2
·H
 
2
O

Other Names for Gutkovaite-Mn

Synonyms:
IMA2001-038
Other Languages:
Russian:Гутковаит-Mn

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Gutkovaite-Mn

Reference List:- Pekov, I.V., Chukanov, N.V., Rastsvetaeva, R.K., Zadov, A.E., Kononkova, N.N. (2002): Gutkovaite-Mn, CaK2Mn(Ti,Nb)4(Si4O12)2(O,OH)4·5H2O, a new mineral of the labuntsovite group from the Khibiny massif, Kola Peninsula. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva, 131(2), 51-57.

- Chukanov, N,V., Pekov, I.V., Khomyakov, A.P. (2002): Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy, 14, 165-173.

Rozenberg K.A., Rastsvetaeva R.K. (2002), IMA 18th Meeting, Poster Session A12, A12-6.

Rastsvetaeva R.K., Pekov I.V., Nekrasov Yu.V. (2001), Kristallografiya, 46, 415-417 [Crystallogr. Reports, 46, 415-417]

Belokoneva E.L. (2005), Crystallogr. Reports, 50, 13-19.

Jambor, John L., V.A. Kovalenker, & A.C. Roberts (2003), New Mineral Names, American Mineralogist: 88: 931-935.

Kola Science Center of Russian Academy of Sciences - History http://www.kolasc.net.ru/ksc/history.html).

Internet Links for Gutkovaite-Mn

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    Localities for Gutkovaite-Mn

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    		European Journal of Mineralogy: 14: 165-173; Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 131(2): 51-57.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 29th Oct 2009 10:14:56