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Fluorophlogopite

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Big Photo

Roc de Courlande, Chastreix, Monts-Dore massif, Puy-de-Dôme, Auvergne, France
© JM. Johannet

Show Fluorophlogopite Photos (35)



Formula:
KMg
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
System:MonoclinicColour:Pale yellow
Hardness:2 - 3


Mica Group.
The fluorine analogue of Phlogopite and the Mg analogue of Fluorannite.

Classification of Fluorophlogopite

IMA status:Approved 2006
Strunz 8th edition ID:8/H.11-75
Nickel-Strunz 10th (pending) edition ID:9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
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Type Occurrence of Fluorophlogopite

Type Locality:Mt Calvario, Biancavilla, Etna Volcanic Complex, Catania Province, Sicily, Italy

Physical Properties of Fluorophlogopite

Lustre:Vitreous, Resinous
Diaphaneity (Transparency):Transparent
Colour:Pale yellow
Hardness (Mohs):2 - 3
Tenacity:Brittle
Cleavage:Perfect
on {001}
Fracture:Micaceous
Comment:Brittle to malleable
Density (calculated):2.83 g/cm3
Comment:From single crystal data

Crystallography of Fluorophlogopite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Cell Parameters:a = 5.3094(4) Å, b = 9.1933(7) Å, c = 10.1437(4) Å
β = 100.062(3)°
Ratio:a:b:c = 0.578 : 1 : 1.103
Unit Cell Volume:V 487.51 ų (Calculated from Unit Cell)
Z:2
Morphology:Thin lamella
Comment:1M polytype
X-Ray Powder Diffraction:
d-spacingIntensity
9.990 (8)
3.369 (10)
3.324 (10)
3.121 (8)
2.610 (8)
2.426 (8)
1.663 (8)
1.532 (8)

Optical Data of Fluorophlogopite

Type:Biaxial (-)
RI values: nα = 1.543 nβ = 1.568 nγ = 1.569
2V:Measured: 17° (2)
Maximum Birefringence:δ = 0.026

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Pleochroism:Non-pleochroic

Chemical Properties of Fluorophlogopite

Formula:
KMg
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
Essential elements:Al, F, K, Mg, O, Si
All elements listed in formula:Al, F, H, K, Mg, O, Si

Relationship of Fluorophlogopite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.EC.05Minnesotaite
(Fe,Mg)
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.05Talc
Mg
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.05Willemseite
(Ni,Mg)
 
3
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.10Ferripyrophyllite
Fe
3+
2
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.10Pyrophyllite
Al
 
2
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Boromuscovite
KAl
 
2
(BSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Celadonite
K(Mg,Fe
2+
 
)Fe
3+
 
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chernykhite
(Ba,Na)(V
3+
 
,Al,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
9.EC.15Montdorite
(K,Na)
 
2
(Fe
2+
 
,Mn
2+
 
,Mg)
 
5
(Si
 
4
O
 
10
)
 
2
(OH,F)
 
4
9.EC.15Muscovite
KAl
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Nanpingite
CsAl
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.15Paragonite
NaAl
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Roscoelite
K(V
3+
 
,Al)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Tobelite
(NH
 
4
,K)Al
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.15Aluminoceladonite
K(Mg,Fe
2+
 
)Al(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chromphyllite
K(Cr,Al)
 
2
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.15Ferro-aluminoceladonite
K(Fe
2+
 
,Mg)(Al,Fe
3+
 
)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Ferroceladonite
K(Fe
2+
 
,Mg)(Fe
3+
 
,Al)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Chromceladonite
K(Mg,Fe
2+
 
)(Cr,Al)(Si
 
4
O
 
10
)(OH)
 
2
9.EC.15Tainiolite
KLiMg
 
2
(Si
 
4
O
 
10
)F
 
2
9.EC.15Ganterite
(Ba,Na,K)(Al,Mg)
 
2
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Annite
KFe
2+
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Ephesite
LiNaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Hendricksite
K(Zn,Mg,Mn
2+
 
)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Masutomilite
(K,Rb)(Li,Mn
3+
 
,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Norrishite
KLiMn
3+
2
(Si
 
4
O
 
10
)O
 
2
9.EC.20Phlogopite
KMg
 
3
(AlSi
 
3
O
 
10
)(OH,F)
 
2
9.EC.20Polylithionite
KLi
 
2
Al(Si
 
4
O
 
10
)(F,OH)
 
2
9.EC.20Preiswerkite
NaMg
 
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Siderophyllite
KFe
2+
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Tetraferriphlogopite
KMg
 
3
(Fe
3+
 
Si
 
3
O
 
10
)(OH,F)
 
2
9.EC.20Fluorotetraferriphlogopite
KMg
 
3
(Fe
3+
 
Si
 
3
O
 
10
)F
 
2
9.EC.20Wonesite
(Na,K)(Mg,Fe,Al)
 
6
((Al,Si)
 
4
O
 
10
)
 
2
(OH,F)
 
4
9.EC.20Eastonite
KMg
 
2
Al(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.20Tetraferriannite
KFe
2+
3
((Fe
3+
 
,Al)Si
 
3
O
 
10
)(OH)
 
2
9.EC.20Trilithionite
K(Li,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Fluorannite
KFe
2+
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
9.EC.20Shirokshinite
KNaMg
 
2
(Si
 
4
O
 
10
)F
 
2
9.EC.20Shirozulite
K(Mn
2+
 
,Mg)
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Sokolovaite
CsLi
 
2
Al(Si
 
4
O
 
10
)F
 
2
9.EC.20Aspidolite
NaMg
 
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20UM2004-49-SiO:AlCsFHKLi
(Cs,K)(Al,Li)
 
2.6
((Si,Al)
 
4
O
 
10
)(F,OH)
 
2
9.EC.20Suhailite
(NH
 
4
)Fe
2+
3
(AlSi
 
3
O
 
10
)(OH)
 
2
9.EC.20Yangzhumingite
KMg
 
2.5
(Si
 
4
O
 
10
)F
 
2
9.EC.20IMA2009-006
KLi
 
2
Ti(Si
 
4
O
 
10
)OF
9.EC.20Oxyphlogopite
K(Mg,Ti,Fe)
 
3
[(Si,Al)
 
4
O
 
10
](O,F)
 
2
9.EC.25Brammallite
(Na,H
 
3
O)(Al,Mg,Fe)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
9.EC.30Margarite
CaAl
 
2
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.35Anandite
(Ba,K)(Fe
2+
 
,Mg)
 
3
((Si,Al,Fe)
 
4
O
 
10
)(S,OH)
 
2
9.EC.35Bityite
LiCaAl
 
2
(AlBeSi
 
2
O
 
10
)(OH)
 
2
9.EC.35Clintonite
Ca(Mg,Al)
 
3
(Al
 
3
SiO
 
10
)(OH)
 
2
9.EC.35Kinoshitalite
(Ba,K)(Mg,Mn
2+
 
,Al)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH)
 
2
9.EC.35Ferrokinoshitalite
(Ba,K)(Fe
2+
 
,Mg)
 
3
(Al
 
2
Si
 
2
O
 
10
)(OH,F)
 
2
9.EC.35Oxykinoshitalite
(Ba,K)(Mg,Ti,Fe
3+
 
,Fe
2+
 
)
 
3
((Si,Al)
 
4
O
 
10
)(O,OH,F)
 
2
9.EC.35Fluorokinoshitalite
BaMg
 
3
(Al
 
2
Si
 
2
O
 
10
)F
 
2
9.EC.40Beidellite
(Na,Ca
 
0.5
)
 
0.3
Al
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Kurumsakite
(Zn,Ni,Cu)
 
8
Al
 
8
V
5+
2
Si
 
5
O
 
35
 · 27H
 
2
O (?)
9.EC.40Montmorillonite
(Na,Ca)
 
0.33
(Al,Mg)
 
2
(Si
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Nontronite
Na
 
0.3
Fe
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.40Volkonskoite
Ca
 
0.3
(Cr,Mg,Fe)
 
2
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.40Yakhontovite
(Ca,Na)
 
0.5
(Cu,Fe,Mg)
 
2
(Si
 
4
O
 
10
)(OH)
 
2
 · 3H
 
2
O
9.EC.45Hectorite
Na
 
0.3
(Mg,Li)
 
3
(Si
 
4
O
 
10
)(F,OH)
 
2
9.EC.45Saponite
Ca
 
0.25
(Mg,Fe)
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · nH
 
2
O
9.EC.45Sauconite
Na
 
0.3
Zn
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.45Spadaite
MgSiO
 
2
(OH)
 
2
 · H
 
2
O (?)
9.EC.45Stevensite
(Ca,Na)
 
x
Mg
 
3-x
(Si
 
4
O
 
10
)(OH)
 
2
9.EC.45Swinefordite
Li(Al,Li,Mg)
 
4
((Si,Al)
 
4
O
 
10
)
 
2
(OH,F)
 
4
 · nH
 
2
O
9.EC.45Zincsilite
Zn
 
3
(Si
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.45Ferrosaponite
Ca
 
0.3
(Fe
2+
 
,Mg,Fe
3+
 
)
 
3
((Si,Al)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.50Vermiculite
(Mg,Fe,Al)
 
3
((Al,Si)
 
4
O
 
10
)(OH)
 
2
 · 4H
 
2
O
9.EC.55Baileychlore
(Zn,Fe,Al,Mg)
 
6
((Si,Al)
 
4
O
 
10
)(OH)
 
8
9.EC.55Chamosite
(Fe
2+
 
,Mg)
 
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Clinochlore
(Mg,Fe
2+
 
)
 
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Cookeite
LiAl
 
4
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Franklinfurnaceite
Ca
 
2
Fe
3+
 
Mn
2+
3
Mn
3+
 
(Zn
 
2
Si
 
2
O
 
10
)(OH)
 
8
9.EC.55Gonyerite
(Mn
2+
 
,Mg)
 
5
Fe
3+
 
(Fe
3+
 
Si
 
3
O
 
10
)(OH)
 
8
9.EC.55Nimite
(Ni,Mg,Al)
 
6
((Si,Al)
 
4
O
 
10
)(OH)
 
8
9.EC.55Orthochamosite
(Fe
2+
 
,Mg,Fe
3+
 
)
 
5
Al(AlSi
 
3
O
 
10
)(OH,O)
 
8
9.EC.55Pennantite
Mn
2+
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Sudoite
(Mg,Fe
2+
 
)
 
2
Al
 
3
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Donbassite
Al
 
4.33
(AlSi
 
3
O
 
10
)(OH)
 
8
9.EC.55Glagolevite
Na(Mg,Al)
 
6
(AlSi
 
3
O
 
10
)(OH,O)
 
8
9.EC.55Borocookeite
Li
 
1+3x
Al
 
4-x
(BSi
 
3
O
 
10
)(OH)
 
8
9.EC.60Aliettite
Ca
 
0.2
Mg
 
6
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · 4H
 
2
O
9.EC.60Corrensite
(Mg,Fe)
 
9
((Si,Al)
 
8
O
 
20
)(OH)
 
10
 · nH
 
2
O
9.EC.60Dozyite
Mg
 
7
Al
 
2
(Al
 
2
Si
 
4
O
 
15
)(OH)
 
12
9.EC.60Hydrobiotite
K(Mg,Fe
2+
 
)
 
6
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · nH
 
2
O
9.EC.60Karpinskite
(Ni,Mg)
 
2
Si
 
2
O
 
5
(OH)
 
2
 (?)
9.EC.60Kulkeite
Mg
 
8
Al(AlSi
 
7
O
 
20
)(OH)
 
10
9.EC.60Lunijianlaite
Li
 
0.7
Al
 
6.2
(AlSi
 
7
lO
 
20
)(OH,O)
 
10
9.EC.60Rectorite
(Na,Ca)Al
 
4
((Si,Al)
 
8
O
 
20
)(OH)
 
4
 · 2H
 
2
O
9.EC.60Saliotite
(Li,Na)Al
 
3
(AlSi
 
3
O
 
10
)(OH)
 
5
9.EC.60Tosudite
Na
 
0.5
(Al,Mg)
 
6
((Si,Al)
 
8
O
 
18
)(OH)
 
12
 · 5H
 
2
O
9.EC.60Brinrobertsite
Na
 
0.3
Al
 
4
(Si
 
4
O
 
10
)
 
2
(OH)
 
4
 · 3.5 H
 
2
O
9.EC.65Macaulayite
(Fe,Al)
 
24
Si
 
4
O
 
43
(OH)
 
2
9.EC.70Burckhardtite
Pb
 
2
(Fe
3+
 
,Mn
3+
 
)Te
4+
 
(AlSi
 
3
O
 
10
)O
 
2
(OH)
 
2
 · H
 
2
O
9.EC.75Ferrisurite
(Pb,Ca)
 
2.4
Fe
3+
2
(Si
 
4
O
 
10
)(CO
 
3
)
 
1.7
(OH)
 
3
 · nH
 
2
O
9.EC.75Surite
(Pb,Ca)
 
3
(Al,Fe
2+
 
,Mg)
 
2
((Si,Al)
 
4
O
 
10
)(CO
 
3
)
 
2
(OH)
 
2
9.EC.75Niksergievite
(Ba,Ca)
 
2
Al
 
3
(AlSi
 
3
O
 
10
)(CO
 
3
)(OH)
 
6
 · nH
 
2
O
9.EC.80Kegelite
Pb
 
8
Al
 
4
(Si
 
8
O
 
20
)(SO
 
4
)
 
2
(CO
 
3
)
 
4
(OH)
 
8

Other Names for Fluorophlogopite

Synonyms:
FluorphlogopiteIMA2006-011
Other Languages:
German:Fluorophlogopit
Fluorphlogopit
Simplified Chinese:氟金云母

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluorophlogopite

Reference List:

- +
Jinsha Xu and Ganfu Shen (2005): Mineralogical study on fluorophlogopite from the Bayan Obo ore deposit. Acta Mineralogica Sinica 25(3), 213-216 (in Chinese).

Gianfagna, Antonio (2006): Fluorophlogopite from Biancavilla (Mt Etna, Sicily, Italy): crystal chemistry of a new F-dominant analogue of phlogopite. International Mineralogical Association 19th General Meeting, Kobe, Japan, July 23-28, 2006; Conference Abstract Volume, (in press).

Gianfagna, Antonio, Fernando Scordari, Simona Mazziotti-Tagliani, Gennaro Ventruti, and Luisa Ottolini (2007) Fluorophlogopite from Biancavilla (Mt. Etna, Sicily, Italy): Crystal structure and crystal chemistry of a new F-dominant analog of phlogopite. American Mineralogist, Volume 92, pages 1601–1609.

Internet Links for Fluorophlogopite

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  • Look for Fluorophlogopite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
    • Mineral Dealers:
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    • Localities for Fluorophlogopite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • South Australia
      • Olary Province
        • Bimbowrie Station
    		Lottermoser, B.G., and Lu, J. (1997): Mineralogy and Petrology 59, 1-19.
    China
     
    • Inner Mongolia Autonomous Region
      • Baotou League (Baotou Prefecture)
        • Bayan Obo Mining District
          • Bayan Obo
    		Jinsha Xu and Ganfu Shen (2005): Acta Mineralogica Sinica 25(3), 213-216
    France
     
    • Auvergne
      • Puy-de-Dôme
        • Besse-et-Saint-Anastaise
          • Murol
    		P & E Médard collection
        • Mazaye
    		Philippe Rémy collection
        • Monts-Dore massif
          • Chastreix
    		Etienne Médard collection
        • Pontgibaud
          • Saint-Ours-les-Roches
    		Médard P. et al. (2009) La pseudobrookite du Puy de Tunisset (Puy-de-Dôme). Le Cahier des Micromonteurs 105: 3-11.
        • Rochefort-Montagne
          • Le Mont-Dore
    		P & E Médard collection
    P & E Médard collection
    Germany
     
    • Rhineland-Palatinate
      • Eifel
        • Gerolstein
          • Roth
    		Blaß, G. & Schüller, W. (2012): Der Rother Kopf in der Vulkaneifel. Lapis, 37 (3), 20-29.
    A.D. Edgar, Eur. Journ. Mineral. , 1992, 4, pp. 321-330.]
    Italy
     
    • Campania
      • Phlegrean Volcanic Complex
        • Salerno Province
          • Nocera
            • Lavorate
    		Balassone, G., et al. (2002): Re-examination of fluosiderite an unknown mineral from southern Italy: equal to fluorite-rich Chondrodite, European Journal of Mineralogy, Vol. 14, 151-155
    • Latium
      • Viterbo Province
        • Bolsena
    		in the collection of Christof Schäfer
    • Sicily
      • Catania Province
        • Etna Volcanic Complex
          • Biancavilla
    		Antonio Gianfagna, Fernando Scordari, Simona Mazziotti-Tagliani, Gennaro Ventruti, and Luisa Ottolini (2007) Fluorophlogopite from Biancavilla (Mt. Etna, Sicily, Italy): Crystal structure and crystal chemistry of a new F-dominant analog of phlogopite. American Mineralogist, Volume 92, pages 1601–1609. - Sicurella, G., Ciriotti, M.E., Gianfagna, A., Mazziotti-Tagliani, S., Blass, G. (2010): Minerali di Monte Calvario, Biancavilla (Catania, Sicilia). Micro (località), 2/2010, 329-368.
    • Umbria
      • Terni Province
        • San Venanzo
    		Stoppa, F., Sharygin, V.V. and Cundari, A. (1997) New mineral data from the kamafugite-carbonatite association: the melilitolite from Pian di Celle, Italy. Mineralogy and Petrology, 61, 27-45.
    Madagascar
     
    • Tuléar Province (Toliara)
      • Anosy Region (Fort Dauphin Region)
        • Amboasary District
          • Maromby Commune
    		http://www.minsocam.org/msa/special/pig/PIG_articles/Madagascar_txt.pdf
    Romania
     
    • Hunedoara Co.
      • Simeria
    		Bojar, H.-P. & Walter, F. (2006): Fluoro-magnesiohastingsite from Dealul Uroi (Hunedoara county, Romania): Mineral data and crystal structrure of a new amphibole end-member. Eur.J.Mineral. 18, 503-508
    Russia
     
    • Eastern-Siberian Region
      • Saha Republic (Sakha Republic; Yakutia)
        • Aldan Shield
          • Aldan
    		Pavel M. Kartashov data
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Lovozero Massif
    		Pavel M. Kartashov analytical data (2013)
            • Suoluaiv Mt
    		Pavel M. Kartashov analytical data (2010)
    Spain
     
    • Murcia
      • Cartagena
        • La Aljorra
    		J. Viñals http://www.ehu.es/sem/macla_pdf/macla11/Macla11_43.pdf
    Fleet, M.E. (2003): Deer, Howie and Zussman - Rock-forming minerals, Micas, Geological Society London, 2003
        • La Celia
    		P et E Médard collection
    USA
     
    • Arizona
      • Yavapai Co.
        • White Picacho District
          • Independence Gulch
    		Josef Vajdak (2002) Mineral News, 18, #1, 6. (Chet Lemanski specimens)
    • Colorado
      • Clear Creek Co.
        • Dailey District (Jones Pass District)
    		Gunow, Alexander J., Ludington, Steve, and Munoz, J. L., 1980, Fluorine in Micas from the Henderson Molybdenite Deposit, Colorado, Economic Geology, 75:1127-1137.
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
    		RRUFF samples R040039, R040042
        • Hardyston Township
          • Rudeville
    		Volkert, et al. (2005)
    • New York
      • St. Lawrence Co.
        • Balmat-Edwards Zinc District
          • Balmat
    		Petersen, E., Essene, D., Peacor, D. (1982): Fluorine end-member micas and amphiboles, American mineralogist, Vol. 67, 538-544
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