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Okhotskite

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Big Photo

Kokuriki mine, Kitami City, Okhotsk Subprefecture (Abashiri Province), Hokkaido, Japan
© 2008, JGW




Formula:
Ca
 
2
(Mn
2+
 
,Mg)(Mn
3+
 
,Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
System:Monoclinic
Member of:Pumpellyite Group
Name:For the Sea of Okhotsk.


Pumpellyite Group.
Forms a solid solution series with pumpellyite-(Al).

Classification of Okhotskite

IMA status:Approved 1985
Strunz 8th edition ID:8/C.24-80
Nickel-Strunz 10th (pending) edition ID:9.BG.20

9 : SILICATES (Germanates)
B : Sorosilicates
G : Sorosilicates with mixed SiO4 and Si2O7 groups; cations in octahedral [6] and greater coordination
Hey's CIM Ref.:16.16.23

16 : Silicates Containing Aluminum and other Metals
16 : Aluminosilicates of Mn
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Type Occurrence of Okhotskite

Type Locality:Kokuriki mine, Kitami City, Okhotsk Subprefecture (Abashiri Province), Hokkaido, Japan
Year of Discovery:1985

Crystallography of Okhotskite

Crystal System:Monoclinic
Cell Parameters:a = 8.88Å, b = 6Å, c = 19.53Å
β = 97.08°
Ratio:a:b:c = 1.48 : 1 : 3.255
Unit Cell Volume:V 1,032.62 ų (Calculated from Unit Cell)

Optical Data of Okhotskite

Type:Biaxial
RI values: nα = 1.782 nβ = 1.820 nγ = 1.827
Maximum Birefringence:δ = 0.045

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:extreme

Chemical Properties of Okhotskite

Formula:
Ca
 
2
(Mn
2+
 
,Mg)(Mn
3+
 
,Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Essential elements:Ca, H, Mn, O, Si
All elements listed in formula:Al, Ca, Fe, H, Mg, Mn, O, Si
Common Impurities:Ti,Na,K

Relationship of Okhotskite to other Species

Member of:Pumpellyite Group
Other Members of Group:

- +
Julgoldite-(Fe2+)
Ca
 
2
(Fe
2+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Julgoldite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
Julgoldite-(Mg)
Ca
 
2
(Mg,Fe
2+
 
)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Poppiite
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
Pumpellyite-(Al)
Ca
 
2
(Al,Fe
2+
 
,Mg)Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
Pumpellyite-(Fe2+)
Ca
 
2
Fe
2+
 
Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Pumpellyite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
Pumpellyite-(Mg)
Ca
 
2
MgAl
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
Shuiskite
Ca
 
2
(Mg,Al)(Cr,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · 2H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.BG.05bAllanite-(Ce)
{CaCe}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(La)
{CaLa}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(Y)
{CaY}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05aClinozoisite
{Ca
 
2
}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bDissakisite-(Ce)
{CaCe}{Al
 
2
Mg}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dollaseite-(Ce)
{CaCe}{MgAlMg}(Si
 
2
O
 
7
)(SiO
 
4
)(OH)F
9.BG.05aEpidote
{Ca
 
2
}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Epidote-(Pb)
{CaPb}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Khristovite-(Ce)
{CaCe}{MgAlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)(OH)F
9.BG.05Mukhinite
{Ca
 
2
}{Al
 
2
V
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Piemontite
{Ca
 
2
}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Piemontite-(Sr)
{CaSr}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bManganiandrosite-(La)
{Mn
2+
 
La}{Mn
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Tawmawite
{Ca
 
2
}{(Al,Fe
3+
 
,Cr)
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Manganipiemontite-(Sr)
{CaSr}{Mn
3+
 
AlMn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bFerriallanite-(Ce)
{CaCe}{Fe
3+
 
AlFe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Clinozoisite-(Sr)
{CaSr}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Manganiandrosite-(Ce)
{(Mn
2+
 
,Ca)(Ce,REE)}{Mn
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Dissakisite-(La)
{CaLa}{Al
 
2
Mg}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Vanadoandrosite-(Ce)
{Mn
2+
 
Ce}{V
3+
 
AlMn
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Uedaite-(Ce)
{Mn
2+
 
Ce}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05Epidote-(Sr)
{CaSr}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bAllanite-(Nd)
{CaNd}{Al
 
2
Fe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bFerriallanite-(La)
{CaLa}{Fe
3+
 
AlFe
2+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.05bÅskagenite-(Nd)
{Mn
2+
 
Nd}{Al
 
2
Fe
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O
 
2
9.BG.10Zoisite
{Ca
 
2
}{Al
 
3
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
9.BG.15Macfallite
Ca
 
2
(Mn
3+
 
,Al)
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
9.BG.15Sursassite
Mn
2+
2
Al
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
9.BG.20Julgoldite-(Fe2+)
Ca
 
2
(Fe
2+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
9.BG.20Pumpellyite-(Fe2+)
Ca
 
2
Fe
2+
 
Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
9.BG.20Pumpellyite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg,Fe
2+
 
)(Al,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
9.BG.20Pumpellyite-(Mg)
Ca
 
2
MgAl
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
9.BG.20Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
9.BG.20Shuiskite
Ca
 
2
(Mg,Al)(Cr,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · 2H
 
2
O
9.BG.20Julgoldite-(Fe3+)
Ca
 
2
(Fe
3+
 
,Mg)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
9.BG.20Pumpellyite-(Al)
Ca
 
2
(Al,Fe
2+
 
,Mg)Al
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
9.BG.20Poppiite
Ca
 
2
(V
3+
 
,Fe
3+
 
,Mg)(V
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH,O)
 
2
 · H
 
2
O
9.BG.20Julgoldite-(Mg)
Ca
 
2
(Mg,Fe
2+
 
)(Fe
3+
 
,Al)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
9.BG.25Ganomalite
Pb
 
9
Ca
 
5
Mn(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)O
9.BG.30Rustumite
Ca
 
10
(Si
 
2
O
 
7
)
 
2
(SiO
 
4
)(OH)
 
2
Cl
 
2
9.BG.35Vesuvianite
(Ca,Na,☐)
 
19
(Al,Mg,Fe
3+
 
)
 
13
(☐,B,Al,Fe
3+
 
)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(OH,F,O)
 
10
9.BG.35Wiluite
Ca
 
19
(Al,Mg)
 
13
(B,☐,Al)
 
5
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
(O,OH)
 
10
9.BG.35Manganvesuvianite
Ca
 
19
Mn
3+
 
(Al,Mn
3+
 
,Fe
3+
 
)
 
10
(Mg,Mn
2+
 
)
 
2
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(OH)
 
9
9.BG.35Fluorvesuvianite
Ca
 
19
(Al,Mg,Fe
2+
 
)
 
13
(Si
 
2
O
 
7
)
 
4
(SiO
 
4
)
 
10
O(F,OH)
 
9
9.BG.40Vyuntspakhkite-(Y)
(Y,Yb)
 
4
Al
 
2.5-1.5
(Si,Al)
 
1.5-2.5
(SiO
 
4
)
 
4
O(OH)
 
7
9.BG.45Dellaite
Ca
 
6
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
9.BG.50Gatelite-(Ce)
CaCe
 
3
Al
 
2
(Al,Mg)(Mg,Fe
2+
 
,Al)(Si
 
2
O
 
7
)(SiO
 
4
)
 
3
(O,F)(OH,O)
 
2
9.BG.55Västmanlandite-(Ce)
Ca(Ce,La)
 
3
Al
 
2
Mg
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)
 
3
(OH)
 
2
F
Related Minerals - Hey's Index Grouping:

- +
16.16.1Kanonaite
Mn
3+
 
Al(SiO
 
4
)O
16.16.2Spessartine
Mn
2+
3
Al
 
2
(SiO
 
4
)
 
3
16.16.3Davreuxite
MnAl
 
6
Si
 
4
O
 
17
(OH)
 
2
16.16.4Sursassite
Mn
2+
2
Al
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
16.16.5Carpholite
Mn
2+
 
Al
 
2
(Si
 
2
O
 
6
)(OH)
 
4
16.16.6Kellyite
Mn
2+
2
Al(AlSiO
 
5
)(OH)
 
4
16.16.7Pennantite
Mn
2+
5
Al(AlSi
 
3
O
 
10
)(OH)
 
8
16.16.8Akatoreite
(Mn
2+
 
,Fe
2+
 
)
 
9
Al
 
2
(HSi
 
4
O
 
13
)
 
2
(OH)
 
6
16.16.9Ganophyllite
(K,Na,Ca)
 
2
Mn
 
8
(Si,Al)
 
12
(O,OH)
 
32
 · 8H
 
2
O
16.16.10Mangano-arfvedsonite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
)]Si
 
8
O
 
22
(OH)
 
2
16.16.11Masutomilite
(K,Rb)(Li,Mn
3+
 
,Al)
 
3
(AlSi
 
3
O
 
10
)(F,OH)
 
2
16.16.13Howieite
Na(Fe,Mn)
 
10
(Fe,Al)
 
2
Si
 
12
O
 
31
(OH)
 
13
16.16.14Eggletonite
(Na,K,Ca)
 
2
(Mn,Fe)
 
8
(Si,Al)
 
12
O
 
29
(OH)
 
7
 · 11H
 
2
O
16.16.15Bannisterite
Ca
 
0.5
(K,Na)
 
0.5
(Mn,Fe,Zn)
 
10
(Si,Al)
 
16
O
 
38
(OH)
 
8
 · 5.5H
 
2
O
16.16.16Taneyamalite
(Na,Ca)(Mn,Mg,Fe)
 
12
Si
 
12
(O,OH)
 
44
16.16.17Zussmanite
K(Fe,Mg,Mn)
 
13
(Si,Al)
 
18
O
 
42
(OH)
 
14
16.16.18Coombsite
K(Mn,Fe,Mg)
 
13
(Si,Al)
 
18
O
 
42
(OH)
 
14
16.16.19Henritermierite
Ca
 
3
(Mn
3+
 
,Al)
 
2
(SiO
 
4
)
 
2
(OH)
 
4
16.16.20Macfallite
Ca
 
2
(Mn
3+
 
,Al)
 
3
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
3
16.16.21Ottrélite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
(SiO
 
4
)O(OH)
 
2
16.16.22Piemontite
{Ca
 
2
}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)
16.16.24Pumpellyite-(Mn2+)
Ca
 
2
(Mn
2+
 
,Mg)(Al,Mn
3+
 
,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)(SiO
 
4
)(OH)
 
2
 · H
 
2
O
16.16.25Piemontite-(Sr)
{CaSr}{Al
 
2
Mn
3+
 
}(Si
 
2
O
 
7
)(SiO
 
4
)O(OH)

Other Names for Okhotskite

Synonyms:
IMA1985-010aOkhotskite-(Mn2+)
Other Languages:
German:Okhotskit
Spanish:Okhotskita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Okhotskite

Reference List:

- +
Togari, K. & Akasaka, M. (1987): Okhotskite, a new mineral, a manganese ion(3+)-dominant member of the pumpellyite group, from the Kokuriki mine, Hokkaido, Japan. Mineralogical Magazine 51, 611-614.

American Mineralogist (1988): 73: 1495-1496.

Dasgupta, Somnath; Chakraborti, Sanjib; Sengupta, Pulak; Bhattacharya, P. K.; Banerjee, H.; Roy, Supriya; Fukuoka, M. (1991): Manganese-rich minerals of the pumpellyite group from the Precambrian Sausar Group, India. American Mineralogist 76, 241-245.

Kimura, Yoshio; Akasaka, Masahide; Sakakibara, Masayuki; Shinno, Isamu; Togari, Kenji (1995): Distribution of Fe3+ and Mn3+ in okhotskite. Shimane Daigaku Chishitsugaku Kenkyu Hokoku 14, 43-54. (in Japanese)

Akasaka, M., Suzuki, Y. & Watanabe, H. (2003): Hydrothermal synthesis of pumpellyite-okhotskite series minerals. Mineralogy and Petrology 77, 25-37.

Internet Links for Okhotskite

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    • Localities for Okhotskite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Hokkaido
      • Okhotsk Subprefecture (Abashiri Province)
        • Kitami City
    		Min.Mag.(1987) 51, 611-614
    • Shikoku Island
      • Kochi Prefecture
    		Journal of Mineralogical and Petrological Sciences 103,400-406(2008)
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