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Labuntsovite Group



A very large group of porous titano- and niobosilicates (monoclinic, pseudo-orthorhombic or orthorhombic).
Seven subgroups are distinguished, each corresponding to different structure types (Chukanov et al., 2002).

One of these is the Nenadkevichite Subgroup which comprises the orthorhombic members.

Classification of Labuntsovite Group

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Relationship of Labuntsovite Group to other Species

Minerals in Group:
Alsakharovite-Zn:
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 7H
 
2
O
Burovaite-Ca:
(Na,K)
 
4
Ca
 
2
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(OH,O)
 
8
·12H
 
2
O
Gjerdingenite-Ca:
K
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
Gjerdingenite-Fe:
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
Gjerdingenite-Mn:
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
Gjerdingenite-Na:
K
 
2
Na
 
2
(Nb,Ti)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
Gutkovaite-Mn:
K
 
2
CaMn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
Karupmøllerite-Ca:
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 7H
 
2
O
Korobitsynite:
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3-4H
 
2
O
Kuzmenkoite-Mn:
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
Kuzmenkoite-Zn:
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
Labuntsovite-Fe:
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10H
 
2
O
Labuntsovite-Mg:
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10H
 
2
O
Labuntsovite-Mn:
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 10-12H
 
2
O
Lemmleinite-Ba:
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5H
 
2
O
Lemmleinite-K:
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
Lepkhenelmite-Zn:
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 7H
 
2
O
Nenadkevichite:
(Na,[])
 
8
Nb
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
·8H
 
2
O
Neskevaaraite-Fe:
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 5-6 H
 
2
O
Organovaite-Mn:
K
 
2
Mn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
Organovaite-Zn:
K
 
2
Zn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
· 6H
 
2
O
Parakuzmenkoite-Fe:
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
· 14H
 
2
O
Paralabuntsovite-Mg:
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· n(H
 
2
O)
Paratsepinite-Ba:
Ba
 
4
(Ti,Nb)
 
8
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
4
· 8H
 
2
O
Paratsepinite-Na:
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
Tsepinite-Ca:
Ca(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
Tsepinite-K:
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
Tsepinite-Na:
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
Tsepinite-Sr:
Sr(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
Vuoriyarvite-K:
K
 
2
(Nb,Ti)
 
2
[(O,OH)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Labuntsovite Group

Reference List:Chukanov, Nikita V.; Pekov, Igor V.; Rastsvetaeva, Ramiza K.; Nekrasov, Aleksei N. (1999): Labuntsovite: solid solutions and features of the crystal structure. Can. Mineral. 37, 901-910.

Chukanov, Nikita V.; Pekov, Igor V.; Khomyakov, Alexander P. (2002): Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy 14, 165-173.

Armbruster, Th., Krivovichev, S.V., Weber, Th., Gnos, E., Organova, N.N., Yakovenchuk, V.N., Shlyukova, Z.V. (2004): Origin of diffuse superstructure reflections in labuntsovite-group minerals. American Mineralogist, 89, 1655-1666.

Internet Links for Labuntsovite Group

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    Localities for Labuntsovite Group

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    American Mineralogist, Volume 94, pages 1450–1458, 2009
    Mineral and/or Locality
    Google
     
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 10th Oct 2009 19:11:36