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Labuntsovite Group

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A very large group of porous titano- and niobosilicates (monoclinic, pseudo-orthorhombic or orthorhombic).
Seven subgroups are distinguished, each corresponding to different structure types (Chukanov et al., 2002).

One of these is the Nenadkevichite Subgroup which comprises the orthorhombic members.

Classification of Labuntsovite Group

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Relationship of Labuntsovite Group to other Species

Group Members:
Alsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 7H
 
2
O
Burovaite-Ca
(Na,K)
 
4
Ca
 
2
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(OH,O)
 
8
· 12H
 
2
O
Gjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 6H
 
2
O
Gjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 6H
 
2
O
Gjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 6H
 
2
O
Gjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
· 5H
 
2
O
Gutkovaite-Mn
K
 
2
CaMn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 5H
 
2
O
Karupmøllerite-Ca
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 7H
 
2
O
Korobitsynite
Na
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 3-4H
 
2
O
Kuzmenkoite-Mn
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
· 5H
 
2
O
Kuzmenkoite-Zn
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
Labuntsovite-Fe
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
· 10H
 
2
O
Labuntsovite-Mg
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
· 10H
 
2
O
Labuntsovite-Mn
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
· 10-12H
 
2
O
Lemmleinite-Ba
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 5H
 
2
O
Lemmleinite-K
K
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 4H
 
2
O
Lepkhenelmite-Zn
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 7H
 
2
O
Nenadkevichite Subgroup
Neskevaaraite-Fe
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 5-6 H
 
2
O
Organovaite-Mn
K
 
2
Mn(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 6H
 
2
O
Organovaite-Zn
K
 
2
Zn(Nb,Ti)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
· 6H
 
2
O
Parakuzmenkoite-Fe
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
· 14H
 
2
O
Paralabuntsovite-Mg
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· nH
 
2
O
Paratsepinite-Ba
Ba
 
4
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(OH,O)
 
8
· 8H
 
2
O
Paratsepinite-Na
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
(Si
 
4
O
 
12
)
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
Tsepinite-Ca
Ca(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 3H
 
2
O
Tsepinite-K
K
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 3H
 
2
O
Tsepinite-Na
Na
 
2
(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 3H
 
2
O
Tsepinite-Sr
Sr(Ti,Nb)
 
2
(Si
 
4
O
 
12
)(OH,O)
 
2
· 3H
 
2
O
Vuoriyarvite-K
K
 
2
(Nb,Ti)
 
2
(Si
 
4
O
 
12
)(O,OH)
 
2
· 4H
 
2
O

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Labuntsovite Group

Reference List:

- +
Chukanov, Nikita V.; Pekov, Igor V.; Rastsvetaeva, Ramiza K.; Nekrasov, Aleksei N. (1999): Labuntsovite: solid solutions and features of the crystal structure. Canadian Mineralogist 37, 901-910.

Chukanov, Nikita V.; Pekov, Igor V.; Khomyakov, Alexander P. (2002): Recommended nomenclature for labuntsovite-group minerals. European Journal of Mineralogy 14, 165-173. [http://pubsites.uws.edu.au/ima-cnmnc/labuntsovite.pdf]

Armbruster, Th., Krivovichev, S.V., Weber, Th., Gnos, E., Organova, N.N., Yakovenchuk, V.N., Shlyukova, Z.V. (2004): Origin of diffuse superstructure reflections in labuntsovite-group minerals. American Mineralogist, 89, 1655-1666.

Raade, G. (2004): Labuntsovitt-gruppens mineraler. Norsk Bergverksmuseum Skrift 28: 19-22

Internet Links for Labuntsovite Group

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  • Localities for Labuntsovite Group

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Québec
      • Montérégie
        • Lajemmerais RCM
          • Varennes & St-Amable
            • Saint-Amable sill
    [Labuntsovite-Mn] Mineralogical Record: 29: 83.
        • Rouville RCM
          • Mont Saint-Hilaire
    [Labuntsovite-Mn] Henderson, W. (1979), Oriented overgrowth of labuntsovite on elpidite from Mont St.-Hilaire, Quebec, Canada. Mineralogical Record: 10: 970., Horváth, L and Gault, R.A. (1990), The mineralogy of Mont Saint-Hilaire Quebec. Mineralogical Record: 21: 284-359.
    Greenland
     
    • Kitaa (West Greenland) Province
      • Narsaq
        • Ilimaussaq complex
          • Kangerdluarssuq (Kangerdluarssuk; Kangerdluarsuk) Firth
            • Head of Kangerdluarssuq
              • Lilleelv
                • Mellemelv
    [Karupmøllerite-Ca] Pekov, I.V. et al. (2002): Karupmollerite-Ca, (Na,Ca,K)2Ca(Nb,Ti)4(Si4O12)2(O,OH)4.7H2O, a new mineral of the labuntsovite group from the Ilimaussaq alkaline complex, South Greenland, Neues Jahrbuch für Mineralogie, Monatshefte, Vol. 10, 433-444
    Namibia
     
    • Khomas Region
      • Windhoek District
        • Windhoek
          • Aris
    [Labuntsovite-Mn] Petersen, O. V., Niedermayr, G., Pekov, I. V., Balić Žunić, T. and Brandstätter, F. (2004): Tsepinit-Na und Labuntsovit-Mn, seltene Mineralien aus dem Phonolith von Aris, Namibia. Mineralien-Welt, 15 (2), 44-48. (in German)
    Norway
     
    • Oppland
      • Lunner
        • Nordmarka
    [Gjerdingenite-Fe] Raade, G.,Ferraris, G.,Gula.A. & Ivaldi, G.(2002): Gjerdingenite-Fe from Norway, a new mineral species in the labuntsovite group: description, crystal structure and twinning. Canadian Mineralogist 40, 1629-1639
    Russia
     
    • Eastern-Siberian Region
      • Saha Republic (Sakha Republic; Yakutia)
        • Aldan Shield
          • Chara and Tokko Rivers Confluence
    [Labuntsovite-Mn] [Lapis 1993:4 p.13-20]
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
    [Parakuzmenkoite-Fe] Tony Nikischer specimen
    [Kuzmenkoite-Mn] Men'shikov, Y.P., et al (2006), American Mineralogist: 91: 922-928.
              • Astrophyllite Stream
    [Vuoriyarvite-K] Pekov et al (2005) New Data on Minerals Vol 40 pp11-16
    [Labuntsovite-Mn] Pekov et al (2005) New Data on Minerals Vol 40 pp11-16
    [Labuntsovite-Mn] [World of Stones 95:5-6, p64]
    [Lemmleinite-K] Pekov, I.V. & Podlesnyi, A.S. (2004): Kukisvumchorr Deposit: Mineralogy of Alkaline Pegmatites and Hydrotermalites. Mineralogical Almanac, vol. 7, 140 pages + xxiv photo's pages
    [Labuntsovite-Mn] [World of Stones 95:5-6, p64]
    [Vuoriyarvite-K] Pekov, I. et al (2003): New Data on Minerals: 38: 20-33.
    [Vuoriyarvite-K] American Mineralogist, Volume 92, pages 1525-1530, 2007
    [Gutkovaite-Mn] European Journal of Mineralogy: 14: 165-173; Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva: 131(2): 51-57.
    [Labuntsovite-Mn]
    [Labuntsovite-Mn]
    [Lemmleinite-K]
    [Labuntsovite-Mn] Mikhailova, Y.A., Konopleva, N.G., Yakovenchuk, V.N., Ivanyuk, G.Y., Men’shikov, Y.P., and Pakhomovsky, Y.A. (2007): Geology of Ore Deposits 49(7), 590-598.
              • Hackman Valley
    [Tsepinite-Ca] Neues Jahrbuch für Mineralogie, Monatshefte (2003): 10: 461-480.
    [Labuntsovite-Mn] Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
          • Kovdor Massif
    [Labuntsovite-Mn] [World of Stones 95:5-6, p64]
          • Lovozero Massif
    [Korobitsynite] [AmMin 85:1322]
              • Umbozero mine (Umba mine)
    [Korobitsynite]
    [Labuntsovite-Mn] [AmMin 85:1562]; Pekov, I. et al (2003): New Data on Minerals: 38: 20-33.
    [Labuntsovite-Mn] [AmMin 85:1322]
    [Gjerdingenite-Ca] IMA website
    [Kuzmenkoite-Zn] Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva (2002): 131(2): 45-50; Eur. Jour. Min.: 14: 165-173.
            • Kuftn'yun Mt
    [Labuntsovite-Mn] Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
            • Seidozero Lake
    [Tsepinite-Na] Pekov, I. et al (2003): New Data on Minerals: 38: 20-33.
    [Kuzmenkoite-Mn] I.V. Pekov et al.: Zap. Vses. Mineral. Obshch. 133(1):49-59 (2004)
    [Lemmleinite-K] Pavel M. Kartashov analytical data (2011)
    [Kuzmenkoite-Mn]
    [Kuzmenkoite-Mn] Ermolaeva, V.N., Pekov, I.V., Chukanov, N.V., Zadov, A.E. (2007): Geology of Ore Deposits 49(8), 758-775.
          • Turii Cape
    [Labuntsovite-Mn]
    [Labuntsovite-Mn] www.koeln.netsurf.de/~w.steffens/vuori.htm
    [Neskevaaraite-Fe] Lapis 28(12), 47 (2003)
    • Urals Region
      • Southern Urals
        • Chelyabinsk Oblast'
    [Korobitsynite] New Data on Minerals (2004): 39: 50-64
    USA
     
    • Arkansas
      • Hot Spring Co.
        • Magnet Cove
    [Labuntsovite-Mn] Rocks & Min.:64:300-307.
    Henry Barwood - unpublished (2010)
    • Wyoming
      • Sweetwater Co.
        • Green River Formation
    [Paralabuntsovite-Mg] Eur. J. Mineral 14:165–173 (2002)
    [Labuntsovite-Mg] Am Min 46:420-429
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    Updated Mineral Entry: LeakeiteFrom Uwe Kolitsch, 13th Feb 2012 17:52:20