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Overite

Big Photo

Little Green Monster Variscite Mine, Clay Canyon, Fairfield, Oquirrh Mts, Utah Co., Utah, USA
© Van King

Show Overite Photos (3)
Formula:
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
System:OrthorhombicColour:Light apple-green to ...
Hardness:3½ - 4
Name:After Mr. Edwin J. Over (1903-1963) American mineral collector, Colorado Springs, Colorado, USA, who worked with Arthur Montgomery at the Fairfield locality and who discovered the first material.


Overite Group.

A secondary phosphate mineral found in altered phosphate nodules in sediments and in granitic pegmatites.

Classification of Overite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/D.28-10
Strunz 9th edition ID:8.DH.20
Nickel-Strunz 10th (pending) edition ID:8.DH.20

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Dana 8th edition ID:42.11.1.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Hey's CIM Ref.:19.8.11

19 : Phosphates
8 : Phosphates of Al and other metals
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Type Occurrence of Overite

Type Locality:Clay Canyon, Fairfield, Oquirrh Mts, Utah Co., Utah, USA
Place of Conservation of Type Material:Harvard University, Cambridge, Massachusetts, USA: #95482. U.S. National Museum of Natural History, Washington, D.C., USA: #R7898.
Year of Discovery:1938
Geological Setting of type material:Altered phosphate nodules in sedimentary rocks.
Associated Minerals at type locality:
VarisciteApatite

Occurrences of Overite

Geological Setting:Complex granitic pegmatite.

Physical Properties of Overite

Lustre:Vitreous
Diaphaneity (Transparency):Translucent
Colour:Light apple-green to colourless; colourless in transmitted light.
Hardness (Mohs):3½ - 4
Cleavage:Perfect
On {010}, perfect; on {100}, poor.
Density (measured):2.53 g/cm3
Density (calculated):2.51 g/cm3

Crystallography of Overite

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:Pbca {P21/b 21/c 21/a}
Cell Parameters:a = 14.723Å, b = 18.746Å, c = 7.107Å
Ratio:a:b:c = 0.785 : 1 : 0.379
Unit Cell Volume:V 1,961.51 ų (Calculated from Unit Cell)
Z:8
Morphology:Crystals platy to lathlike, flattened on {010} and elongated along [001]. Forms exhibited include {010}, {100}, {110}, {121}, and {021}. Commonly forms subparallel aggregates; massive.

Optical Data of Overite

Type:Biaxial (-)
RI values: nα = 1.568 nβ = 1.574 nγ = 1.580
2V:Measured: 75° , Calculated: 88°
Maximum Birefringence:δ = 0.012

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:r > v strong

Chemical Properties of Overite

Formula:
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
Essential elements:Al, Ca, H, Mg, O, P
All elements listed in formula:Al, Ca, H, Mg, O, P

Relationship of Overite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DH.05Minyulite
KAl
 
2
[(OH,F)|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.10Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.15Jahnsite-(CaMnFe)
CaMn
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMg)
CaMn
2+
 
(Mg,Fe
2+
 
)
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMn)
CaMn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Keckite
CaMnMn
2+
2
Fe
3+
3
(PO
 
4
)
 
4
(OH)
 
3
(H
 
2
O)
 
7
8.DH.15Rittmannite
(Mn
2+
 
,Ca)Mn
2+
 
(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
(Al,Fe
3+
 
)
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaFeMg)
Ca(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaMnMg)
CaMn
2+
 
Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(MnFeMg)
(Mn
2+
 
,Ca)(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(MnMnMn)
Mn
2+
 
Mn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
](OH)
 
2
 · 8H
 
2
O
8.DH.15Kaluginite
(Mn
2+
 
,Ca)MgFe
3+
 
[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.15Jahnsite-(CaFeFe)
CaFe
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
·8H
 
2
O
8.DH.15Jahnsite-(NaFeMg)
NaFe
3+
 
Mg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(NaMnMg)
NaMnMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMgMg)
CaMgMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Manganosegelerite
(Mn
2+
 
,Ca)(Mn
2+
 
,Fe
2+
 
,Mg)Fe
3+
 
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DH.20Segelerite
Ca
 
2
 Mg
 
2
 Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Wilhelmvierlingite
CaMnFe
3+
 
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.20Juonniite
CaMgSc(PO
 
4
)
 
2
(OH)·4H
 
2
O
8.DH.25Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
8.DH.25Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.30Arseniosiderite
Ca
 
2
Fe
3+
3
[O
 
2
|(AsO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Kolfanite
Ca
 
2
Fe
3+
2
[O
 
2
|(AsO
 
4
)
 
3
] · 2H
 
2
O
8.DH.30Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Pararobertsite
Ca
 
2
Mn
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Robertsite
Ca
 
3
Mn
3+
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.30Sailaufite
(Ca,Na,[])
 
2
Mn
3+
3
[O
 
2
|CO
 
3
|(AsO
 
4
)
 
2
] · 3H
 
2
O
8.DH.35Mantienneite
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
8.DH.35Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
 · 15H
 
2
O
8.DH.35Benyacarite
(H
 
2
O,K)
 
2
(Mn
2+
 
,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti)
 
2
Ti[(O,F)
 
2
|(PO
 
4
)
 
4
] · 14H
 
2
O
8.DH.40Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.45Mahnertite
NaCu
 
3
(AsO
 
4
)
 
2
Cl · 5H
 
2
O
8.DH.50Andyrobertsite
KCdCu
 
5
[H
 
2
AsO
 
4
|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.50Calcioandyrobertsite
KCaCu
 
5
[H
 
2
AsO
 
4
|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.55Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
 · 26H
 
2
O
8.DH.60Bouazzerite
Bi
 
6
(Mg,Co)
 
11
Fe
3+
14
(AsO
 
4
)
 
18
O
 
12
(OH)
 
4
(H
 
2
O)
 
86
Related Minerals - Hey's Index Grouping:

- +
19.8.1Montebrasite
LiAl[(OH,F)|PO
 
4
]
19.8.2Brazilianite
NaAl
 
3
[(OH)
 
2
|PO
 
4
]
 
2
19.8.3Wardite
NaAl
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 2H
 
2
O
19.8.4Tancoite
LiNa
 
2
Al[OH|HPO
 
4
|PO
 
4
]
19.8.5Bertossaite
(Li,Na)
 
2
(Ca,Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH,F)|PO
 
4
]
 
4
19.8.6Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.8.7Taranakite
(K,NH
 
4
)Al
 
3
(PO
 
4
)
 
3
OH·9H
 
2
O
19.8.8Francoanellite
K
 
3
Al
 
5
[(HPO
 
4
)
 
3
|PO
 
4
]
 
2
 · 12H
 
2
O
19.8.9Gordonite
MgAl
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.8.10Aldermanite
Mg
 
5
Al
 
12
[(OH)
 
11
|(PO
 
4
)
 
4
]
 
2
 · 32H
 
2
O
19.8.12Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
19.8.14Foggite
CaAl[(OH)
 
2
|PO
 
4
] · H
 
2
O
19.8.15Gatumbaite
CaAl
 
2
[OH|PO
 
4
]
 
2
 · H
 
2
O
19.8.16Crandallite
CaAl
 
3
[(OH)
 
5
|(PO
 
4
)
 
2
] · H
 
2
O
19.8.17Matulaite
CaAl
 
18
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
4
 · 28H
 
2
O
19.8.19Lehiite
19.8.20Millisite
(Na,K)CaAl
 
6
[(OH)
 
9
|(PO
 
4
)
 
4
] · 3H
 
2
O
19.8.21Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
 · 26H
 
2
O
19.8.22Kleemanite
ZnAl
 
2
[OH|PO
 
4
]
 
2
 · 3H
 
2
O
19.8.23Mantienneite
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
19.8.24Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
 · 15H
 
2
O

Other Names for Overite

Other Languages:
German:Overit
Russian:Оверит
Spanish:Overita

Other Information

Other Information:Readily soluble in hot nitric acid.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Overite

Reference List:Larsen, E.S. (1940) American Mineralogist: 25: 315.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 979-980.

Moore, P.B. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist (1974): 59: 48-59.

Moore, P.B. and T. Araki (1977) Overite, segelerite, and jahnsite: a study in combinatorial polymorphism. American Mineralogist: 62: 692-702.

Internet Links for Overite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Overite in the Natural History Museum (London) online catalogue
  • Overite details from Handbook of Mineralogy (PDF)
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    Localities for Overite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Western Australia
    		Min.Mag. 39, 577(1974)
    Portugal
     
    • Viseu District
      • Mangualde
    USA
     
    • Utah
      • Utah Co.
        • Oquirrh Mts
          • Fairfield
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 980; UGMS Bull 117 Minerals and Mineral Localities of Utah.
    Rocks & Minerals (1970): 45(11): 667-674.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 7th Nov 2009 04:39:57