Overite
A valid IMA mineral species - grandfathered
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About Overite
Formula:
CaMgAl(PO4)2(OH) · 4H2O
Colour:
Light apple-green to colourless; colourless in transmitted light.
Lustre:
Vitreous
Hardness:
3½ - 4
Specific Gravity:
2.53
Crystal System:
Orthorhombic
Member of:
Name:
After Mr. Edwin J. Over (1903-1963) American mineral collector, Colorado Springs, Colorado, USA, who worked with Arthur Montgomery at the Fairfield locality and who discovered the first material.
Overite Group.
A secondary phosphate mineral found in altered phosphate nodules in sediments and in granitic pegmatites.
A secondary phosphate mineral found in altered phosphate nodules in sediments and in granitic pegmatites.
Unique Identifiers
Mindat ID:
3048
Long-form identifier:
mindat:1:1:3048:5
GUID
(UUID V4):
(UUID V4):
12656320-4583-461e-822c-868071832736
IMA Classification of Overite
Approved, 'Grandfathered' (first described prior to 1959)
First published:
1940
Classification of Overite
8.DH.20
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
42.11.1.1
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
19.8.11
19 : Phosphates
8 : Phosphates of Al and other metals
19 : Phosphates
8 : Phosphates of Al and other metals
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
Symbol | Source | Reference |
---|---|---|
Ove | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Overite
Vitreous
Transparency:
Translucent
Colour:
Light apple-green to colourless; colourless in transmitted light.
Hardness:
3½ - 4 on Mohs scale
Cleavage:
Perfect
On {010}, perfect; on {100}, poor.
On {010}, perfect; on {100}, poor.
Density:
2.53 g/cm3 (Measured) 2.51 g/cm3 (Calculated)
Optical Data of Overite
Type:
Biaxial (-)
RI values:
nα = 1.568 nβ = 1.574 nγ = 1.580
2V:
Measured: 75° , Calculated: 88°
Max Birefringence:
δ = 0.012
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
r > v strong
Chemistry of Overite
Mindat Formula:
CaMgAl(PO4)2(OH) · 4H2O
Crystallography of Overite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Pbca
Cell Parameters:
a = 14.723(14) Å, b = 18.746(16) Å, c = 7.107(4) Å
Ratio:
a:b:c = 0.785 : 1 : 0.379
Unit Cell V:
1,961.51 ų (Calculated from Unit Cell)
Z:
8
Morphology:
Crystals platy to lathlike, flattened on {010} and elongated along [001]. Forms exhibited include {010}, {100}, {110}, {121}, and {021}. Commonly forms subparallel aggregates; massive.
Crystal Structure
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2x2x2 | 3x3x3 | 4x4x4
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Data courtesy of the American Mineralogist Crystal Structure Database. Click on an AMCSD ID to view structure
ID | Species | Reference | Link | Year | Locality | Pressure (GPa) | Temp (K) |
---|---|---|---|---|---|---|---|
0000582 | Overite | Moore P B, Araki T (1977) Overite, segelerite, and jahnsite: a study in combinatorial polymorphism American Mineralogist 62 692-702 | 1977 | 0 | 293 |
CIF Raw Data - click here to close
X-Ray Powder Diffraction
Powder Diffraction Data:
d-spacing | Intensity |
---|---|
2.832 Å | (100) |
9.4 Å | (80) |
5.29 Å | (60) |
2.889 Å | (60) |
3.70 Å | (50) |
1.975 Å | (50) |
3.42 Å | (40) |
Comments:
Fairfield, Utah, USA. ICDD 16-157.
Geological Environment
Paragenetic Mode(s):
Paragenetic Mode | Earliest Age (Ga) |
---|---|
Near-surface Processes | |
21 : Chemically precipitated carbonate, phosphate, iron formations | |
22 : Hydration and low-𝑇 subsurface aqueous alteration (see also #23) |
Geological Setting:
Complex granitic pegmatite.
Type Occurrence of Overite
General Appearance of Type Material:
Pale green to colorless vitreous crystals in cavities in the variscite nodules.
Place of Conservation of Type Material:
Harvard University, Cambridge, Massachusetts, USA: #95482. U.S. National Museum of Natural History, Washington, D.C., USA: #R7898.
Geological Setting of Type Material:
Altered phosphate nodules in sedimentary rocks.
Associated Minerals at Type Locality:
Reference:
Larsen, E.S. (1940) Overite and montgomeryite: two new minerals from Fairfield, Utah. American Mineralogist: 25: 315-326.
Other Language Names for Overite
Relationship of Overite to other Species
Member of:
Other Members of this group:
Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O | Orth. mmm (2/m 2/m 2/m) : Pcca |
Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O | Orth. mmm (2/m 2/m 2/m) : Pbca |
Common Associates
Associated Minerals Based on Photo Data:
5 photos of Overite associated with Crandallite | CaAl3(PO4)(PO3OH)(OH)6 |
3 photos of Overite associated with Variscite | AlPO4 · 2H2O |
1 photo of Overite associated with Gordonite | MgAl2(PO4)2(OH)2 · 8H2O |
1 photo of Overite associated with Whitlockite | Ca9Mg(PO4)6(PO3OH) |
1 photo of Overite associated with Groatite | NaCaMn2(PO4)[PO3(OH)]2 |
1 photo of Overite associated with Cacoxenite | Fe3+24AlO6(PO4)17(OH)12 · 75H2O |
1 photo of Overite associated with Wardite | NaAl3(PO4)2(OH)4 · 2H2O |
Related Minerals - Strunz-mindat Grouping
8.DH. | Ferroberaunite | Fe2+Fe3+5(PO4)4(OH)5 · 6H2O |
8.DH. | Rowleyite | [Na(NH4,K)9Cl4][V5+,4+2(P,As)O8]6 · n[H2O,Na,NH4,K,Cl] |
8.DH. | Ammoniotinsleyite | (NH4)Al2(PO4)2(OH) · 2H2O |
8.DH. | Thebaite-(NH4) | (NH4)3Al(C2O4)(PO3OH)2(H2O) |
8.DH. | Dendoraite-(NH4) | (NH4)2NaAl(C2O4)(PO3OH)2(H2O)2 |
8.DH. | Whiteite-(MnMnMn) | Mn2+Mn2+Mn2+2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Whiteite-(CaMnFe) | CaMnFe2Al2(PO4)4(OH)2 · 8H2O |
8.DH. | Hochleitnerite | Mn2Ti3(PO4)4O2(H2O)2 · 14H2O |
8.DH. | Regerite | KFe6(PO4)4(OH)7(H2O)6 · 4H2O |
8.DH.05 | Minyulite | KAl2(PO4)2F · 4H2O |
8.DH.10 | Leucophosphite | KFe3+2(PO4)2(OH) · 2H2O |
8.DH.10 | Spheniscidite | (NH4,K)(Fe3+,Al)2(PO4)2(OH) · 2H2O |
8.DH.10 | Tinsleyite | KAl2(PO4)2(OH) · 2H2O |
8.DH.15 | Jahnsite-(CaMnFe) | {Ca}{Mn2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMg) | {Ca}{Mn2+}{(Mg,Fe2+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnMn) | {Ca}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Keckite | CaMn2+(Fe3+Mn2+)Fe3+2(PO4)4(OH)3 · 7H2O |
8.DH.15 | Rittmannite | {(Mn2+,Ca)}{Mn2+}{(Fe2+,Mn2+,Mg)2}{(Al,Fe3+)2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaFeMg) | {Ca}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMg) | {Ca}{Mn2+}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnFeMg) | {(Mn2+,Ca)}{(Fe2+,Mn2+)}{Mg2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMn) | {Mn2+}{Mn2+}{Mn2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Kaluginite | (Mn2+,Ca)MgFe3+(PO4)2(OH) · 4H2O |
8.DH.15 | Jahnsite-(CaFeFe) | {Ca}{Fe2+}{Fe2+2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaFeMg) | NaFe3+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMg) | {(Na,Ca)}{(Mn2+,Fe3+)}{(Mg,Fe3+)2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMgMg) | {Ca}{Mg}{Mg2}{Fe3+2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMnMn) | {Ca}{Mn2+}{Mn2}{Al2}(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(MnMnMg) | MnMnMg2Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnMg) | Mn2+Mn2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaFeMg) | CaFe2+Mg2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnFe) | Mn2+Mn2+Fe2+2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Whiteite-(CaMgMg) | CaMg3Al2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(MnMnZn) | Mn2+Mn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(NaMnMn) | NaMn2+(Mn2+Fe3+)Σ2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.15 | Jahnsite-(CaMnZn) | CaMn2+Zn2Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Lun'okite | (Mn,Ca)(Mg,Fe,Mn)Al(PO4)2OH · 4H2O |
8.DH.20 | Manganosegelerite | (Mn2+,Ca)(Mn2+,Fe2+,Mg)Fe3+(PO4)2(OH) · 4H2O |
8.DH.20 | Segelerite | Ca2 Mg2 Fe3+2(PO4)4(OH)2 · 8H2O |
8.DH.20 | Wilhelmvierlingite | CaMnFe3+(PO4)2(OH) · 2H2O |
8.DH.20 | Juonniite | CaMgSc(PO4)2(OH) · 4H2O |
8.DH.25 | Calcioferrite | Ca2Fe3+2(PO4)3(OH) · 7H2O |
8.DH.25 | Kingsmountite | Ca3MnFeAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Montgomeryite | Ca4MgAl4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Zodacite | Ca4Mn2+Fe3+4(PO4)6(OH)4 · 12H2O |
8.DH.25 | Fanfaniite | Ca4MnAl4(PO4)6(OH)4 · 12H2O |
8.DH.30 | Arseniosiderite | Ca2Fe3+3(AsO4)3O2 · 3H2O |
8.DH.30 | Kolfanite | Ca2Fe3+3O2(AsO4)3 · 2H2O |
8.DH.30 | Mitridatite | Ca2Fe3+3(PO4)3O2 · 3H2O |
8.DH.30 | Pararobertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Robertsite | Ca2Mn3+3(PO4)3O2 · 3H2O |
8.DH.30 | Sailaufite | (Ca,Na,◻)2Mn3+3(AsO4)2(CO3)O2 · 3H2O |
8.DH.35 | Mantienneite | KMg2Al2Ti(PO4)4(OH)3 · 15H2O |
8.DH.35 | Paulkerrite | K(Mg,Mn2+)2(Fe3+,Al,Ti,Mg)2Ti(PO4)4(OH)3 · 15H2O |
8.DH.35 | Benyacarite | (H2O)2Mn2Ti2Fe3+(PO4)4(OF)(H2O)10 · 4H2O |
8.DH.35 | Hydroxylbenyacarite | (H2O)2Mn2(Ti2Fe)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH.35 | Macraeite | K(H2O)Mn2(Fe2Ti)(PO4)4[O(OH)](H2O)10 · 4H2O |
8.DH.40 | Xanthoxenite | Ca4Fe3+2(PO4)4(OH)2 · 3H2O |
8.DH.45 | Mahnertite | NaCu3(AsO4)2Cl · 5H2O |
8.DH.50 | Andyrobertsite | KCdCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.50 | Calcioandyrobertsite | KCaCu5(AsO4)4(H2AsO4) · 2H2O |
8.DH.55 | Englishite | K3Na2Ca10Al15(PO4)21(OH)7 · 26H2O |
8.DH.60 | Bouazzerite | Bi6(Mg,Co)11Fe3+14(AsO4)18(OH)4O12 · 86H2O |
8.DH.65 | Galliskiite | Ca4Al2(PO4)2F8 · 5H2O |
8.DH.70 | Joteite | Ca2CuAl(AsO4)[AsO3(OH)]2(OH)2 · 5H2O |
8.DH.75 | Kampelite | Ba6Mg3Sc8(PO4)12(OH)6 · 7H2O |
8.DH.80 | Kapundaite | NaCaFe4(PO4)4(OH)3 · 5H2O |
8.DH.85 | Vaniniite | Ca2Mn2+3Mn3+2O2(AsO4)4 · 2H2O |
Other Information
Notes:
Readily soluble in hot nitric acid.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Overite
mindat.org URL:
https://www.mindat.org/min-3048.html
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References for Overite
Reference List:
Larsen, Esper S., Shannon, Earl V. (1930) The minerals of the phosphate nodules from near Fairfield, Utah. American Mineralogist, 15 (8) 307-337 (as number 8)
Larsen, Esper S., 3d, (1940) Overite and montgomeryite: two new minerals from Fairfield, Utah. American Mineralogist, 25 (5) 315-326
Moore, Paul Brian, Ito, J. (1974) I. Jahnsite, segelerite, and robertsite, three new transition metal phosphate species. II. Redefinition of overite, an isotype of segelerite. III. Isotypy of robertsite, mitridatite, and arseniosiderite. American Mineralogist, 59 (1-2) 48-59
Localities for Overite
Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
Struck out - Mineral was erroneously reported from this locality.
Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).
All localities listed without proper references should be considered as questionable.
All localities listed without proper references should be considered as questionable.
Australia | |
| Mineralogical Magazine 39 (1974) |
Canada | |
| 153-155. +2 other references |
Portugal | |
| Canadian Mineralogist 47 et al. (2009) |
Russia | |
| Local geolofist S.V.Kolesnichenko data |
USA | |
| Kampf et al. (2016) |
| Collected by Paul Adams. EDS and XRD ... |
| Palache et al. (1951) +1 other reference |
Rocks & Minerals (1970) +1 other reference |
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Little Green Monster Variscite Mine, Clay Canyon, Fairfield, Sunshine Mining District, Utah County, Utah, USA