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Pahasapaite

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Tip Top Mine (Tip Top pegmatite), Fourmile, Custer District, Custer Co., South Dakota, USA
© Knut Eldjarn

Show Pahasapaite Photos (3)



Formula:
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
 · 38H
 
2
O
System:IsometricColour:Colourless, light pink, ...
Lustre:VitreousHardness:4½
Member of:Zeolite Group
Name:Named from the Dakota Sioux Indian word 'Pahasapa' for the Black Hills.


Zeolitic structure.

Classification of Pahasapaite

IMA status:Approved
Strunz 8th edition ID:7/C.01-10
Nickel-Strunz 10th (pending) edition ID:8.CA.25

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
A : With small and large/medium cations
Dana 7th edition ID:40.5.7.1
Dana 8th edition ID:40.5.7.1

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
5 : AXO4·xH2O
Hey's CIM Ref.:19.3.9

19 : Phosphates
3 : Phosphates of Be and Mg
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Type Occurrence of Pahasapaite

Type Locality:Tip Top Mine (Tip Top pegmatite), Fourmile, Custer District, Custer Co., South Dakota, USA
Year of Discovery:1987

Physical Properties of Pahasapaite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Colourless, light pink, Yellow
Streak:White
Hardness (Mohs):4½
Cleavage:None Observed
Fracture:Irregular/Uneven
Density (measured):2.28 g/cm3
Density (calculated):2.24 g/cm3

Crystallography of Pahasapaite

Crystal System:Isometric
Class (H-M):2 3 - Tetartoidal
Space Group:I2 3
Cell Parameters:a = 13.781Å
Unit Cell Volume:V 2 ų
Z:1

Optical Data of Pahasapaite

Type:Isotropic

Chemical Properties of Pahasapaite

Formula:
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
 · 38H
 
2
O
Essential elements:Be, Ca, H, Li, O, P
All elements listed in formula:Be, Ca, H, K, Li, O, P

Relationship of Pahasapaite to other Species

Member of:Zeolite Group
Other Members of Group:

- +
Alflarsenite
NaCa
 
2
Be
 
3
Si
 
4
O
 
13
(OH) · 2H
 
2
O
Amicite
K
 
2
Na
 
2
Al
 
4
Si
 
4
O
 
16
 · 5H
 
2
O
Ammonioleucite
(NH
 
4
,K)(AlSi
 
2
O
 
6
)
Analcime
Na
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Barrerite
(Na,K,Ca
 
0.5
)
 
2
[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Bellbergite
(K,Ba,Sr)
 
2
Sr
 
2
Ca
 
2
(Ca,Na)
 
4
[Al
 
3
Si
 
3
O
 
12
]
 
6
 · 30H
 
2
O
Bikitaite
LiAlSi
 
2
O
 
6
 · H
 
2
O
Boggsite
Ca
 
8
Na
 
3
(Si,Al)
 
96
O
 
192
 · 70H
 
2
O
Brewsterite
Brewsterite-Ba
(Ba,Sr)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Brewsterite-Sr
(Sr,Ba,Ca)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Chabazite
Chabazite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-K
(K
 
2
,Ca,Na
 
2
,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Levyne Subgroup
Chabazite-Mg
(Mg
 
0.7
K
 
0.5
Ca
 
0.5
Na
 
0.1
)[Al
 
3
Si
 
9
O
 
24
]·10H
 
2
O
Chabazite-Na
(Na
 
2
,K
 
2
,Ca,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Sr
Sr
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chiavennite
CaMnBe
 
2
Si
 
5
O
 
13
(OH)
 
2
 · 2H
 
2
O
Clinoptilolite-Ca
(Ca,Na,K)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-Na
(Na,K,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Cowlesite
CaAl
 
2
Si
 
3
O
 
10
 · 6H
 
2
O
Dachiardite-Ca
(Ca,Na
 
2
,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Dachiardite-Na
(Na
 
2
,Ca,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Direnzoite
NaK
 
6
MgCa
 
2
(Al
 
13
Si
 
47
O
 
120
) · 36H
 
2
O
Edingtonite
Ba[Al
 
2
Si
 
3
O
 
10
] · 4H
 
2
O
Epistilbite
CaAl
 
2
Si
 
6
O
 
16
 · 5H
 
2
O
Erionite
Erionite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-K
(K
 
2
,Ca,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-Na
(Na
 
2
,K
 
2
,Ca)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Faujasite Subgroup
Faujasite-Ca
(Ca,Na
 
2
,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Mg
(Mg,Na
 
2
,Ca)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Na
(Na
 
2
,Ca,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Ferrierite
Ferrierite-K
(K
 
2
,Na
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Mg
(Mg,Na
 
2
,K
 
2
,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Na
(Na
 
2
,K
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Flörkeite
(K
 
3
Ca
 
2
Na)[Al
 
8
Si
 
8
O
 
32
] · 12H
 
2
O
Garronite
Na
 
2
Ca
 
5
Al
 
12
Si
 
20
O
 
64
 · 27H
 
2
O
Gaultite
Na
 
4
Zn
 
2
Si
 
7
O
 
18
 · 5H
 
2
O
Gismondine
Gismondine-Ba
Ba
 
2
Al
 
4
Si
 
4
O
 
16
 · 4-6H
 
2
O
Gismondine-Ca
CaAl
 
2
Si
 
2
O
 
8
 · 4H
 
2
O
Gmelinite
Gmelinite-Ca
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-K
(K
 
2
,Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-Na
(Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gobbinsite
Na
 
4
(Ca,Mg,K
 
2
)Al
 
6
Si
 
10
O
 
32
 · 12H
 
2
O
Gonnardite
(Na,Ca)
 
2
(Si,Al)
 
5
O
 
10
 · 3H
 
2
O
Goosecreekite
Ca[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Gottardiite
Na
 
3
Mg
 
3
Ca
 
5
Al
 
19
Si
 
117
O
 
272
 · 93H
 
2
O
Harmotome
(Ba
 
0.5
,Ca
 
0.5
,K,Na)
 
5
[Al
 
5
Si
 
11
O
 
32
] · 12H
 
2
O
Heulandite-Ba
(Ba,Ca,K,Na,Sr)
 
5
Al
 
9
Si
 
27
O
 
72
 · 22H
 
2
O
Heulandite-Ca
(Ca,Na)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Na
(Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Sr
(Sr,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Hsianghualite
Ca
 
3
Li
 
2
(Be
 
3
Si
 
3
O
 
12
)F
 
2
Laumontite
CaAl
 
2
Si
 
4
O
 
12
 · 4H
 
2
O
Leucite
K(AlSi
 
2
O
 
6
)
Lévyne
Lévyne-Ca
(Ca,Na
 
2
,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lévyne-Na
(Na
 
2
,Ca,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lovdarite
(Na,K,Ca)
 
4
(Be,Al)
 
2
Si
 
6
O
 
16
 · 4H
 
2
O
Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
 · 32H
 
2
O
Mazzite-Mg
K
 
2
Mg
 
2
Ca
 
1.5
Al
 
9.5
Si
 
26.5
O
 
72
 · 28H
 
2
O or near
Mazzite-Na
Na
 
4
[Al
 
4
Si
 
14
O
 
36
]
 
2
 · 30H
 
2
O
Merlinoite
(K,Na)
 
5
(Ca,Ba)
 
2
Al
 
9
Si
 
23
O
 
64
 · 23H
 
2
O
Mesolite
Na
 
2
Ca
 
2
Si
 
9
Al
 
6
O
 
30
 · 8H
 
2
O
Montesommaite
(K,Na)
 
9
Al
 
9
Si
 
23
O
 
64
 · 10H
 
2
O
Mordenite
(Na
 
2
,Ca,K
 
2
)Al
 
2
Si
 
10
O
 
24
 · 7H
 
2
O
Mutinaite
Na
 
3
Ca
 
4
Si
 
85
Al
 
11
O
 
192
 · 60H
 
2
O
Natrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 2H
 
2
O
Natrolite Subgroup
Offretite
KCaMgAl
 
5
Si
 
13
O
 
36
 · 16H
 
2
O or near
Paranatrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Parthéite
CaAl
 
2
Si
 
2
O
 
8
 · 2H
 
2
O
Paulingite
Paulingite-Ca
(Ca,K
 
2
,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-K
(K
 
2
,Ca,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-Na
(Na
 
2
,K
 
2
,Ca,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Perlialite
K
 
9
Na(Ca,Sr)[Al
 
2
Si
 
4
O
 
12
]
 
6
 · 15H
 
2
O
Phillipsite-Ca
(Ca
 
0.5
,K,Na,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
.
 
 12H2O
Phillipsite-K
(K,Na,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
]
.
 
 12H
 
2
O
Phillipsite-Na
(Na,K,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
] · 12H
 
2
O
Pollucite
(Cs,Na)
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Roggianite
Ca
 
2
Be(OH)
 
2
Al
 
2
Si
 
4
O
 
13
 · 2.5H
 
2
O
Scolecite
CaAl
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Stellerite
Ca[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Stilbite
Stilbite-Ca
NaCa
 
4
[Al
 
9
Si
 
27
O
 
72
] · nH
 
2
O
Stilbite-Na
(Na,Ca,K)
 
6-7
[Al
 
8
Si
 
28
O
 
72
] · nH
 
2
O
Terranovaite
(Na,Ca)
 
8
(Si
 
68
Al
 
12
)O
 
160
 · 29H
 
2
O
Tetranatrolite
Thomsonite-Ca
NaCa
 
2
[Al
 
5
Si
 
5
O
 
20
] · 6H
 
2
O
Thomsonite-Sr
Na(Sr,Ca)
 
2
[Al
 
5
Si
 
5
O
 
20
] · 7H
 
2
O
Tschernichite
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 4-8H
 
2
O
Tschörtnerite
Ca
 
4
(Ca,Sr,K,Ba)
 
3
Cu
 
3
[(OH)
 
2
|Al
 
3
Si
 
3
O
 
12
]
 
4
 · nH
 
2
O
Wairakite
Ca(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Weinebeneite
CaBe
 
3
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
Willhendersonite
KCa[Al
 
3
Si
 
3
O
 
12
] · 5H
 
2
O
Yugawaralite
CaAl
 
2
Si
 
6
O
 
16
 · 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.CA.05Fransoletite
Ca
 
3
Be
 
2
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
 · 4H
 
2
O
8.CA.05Parafransoletite
Ca
 
3
Be
 
2
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
 · 4H
 
2
O
8.CA.10Ehrleite
Ca
 
4
Be
 
3
Zn
 
2
(PO
 
4
)
 
6
 · 9H
 
2
O
8.CA.15Faheyite
(Mn,Mg,Na)Be
 
2
Fe
 
2
(PO
 
4
)
 
4
 · 6H
 
2
O
8.CA.20Gainesite
Na(Na,K)(Be,Li)Zr
 
2
(PO
 
4
)
 
4
 · 1.5-2H
 
2
O
8.CA.20Mccrillisite
NaCs(Be,Li)Zr
 
2
(PO
 
4
)
 
4
 · 1-2H
 
2
O
8.CA.20Selwynite
NaK(Be,Al)Zr
 
2
(PO
 
4
)
 
4
 · 2H
 
2
O
8.CA.30Hopeite
Zn
 
3
(PO
 
4
)
 
2
 · 4H
 
2
O
8.CA.30Arsenohopeite
Zn
 
3
(AsO
 
4
)
 
2
 · 4H
 
2
O
8.CA.35Warikahnite
Zn
 
3
(AsO
 
4
)
 
2
 · 2H
 
2
O
8.CA.40Phosphophyllite
Zn
 
2
Fe(PO
 
4
)
 
2
 · 4H
 
2
O
8.CA.45Parascholzite
CaZn
 
2
(PO
 
4
)
 
2
 · 2H
 
2
O
8.CA.45Scholzite
CaZn
 
2
(PO
 
4
)
 
2
 · 2H
 
2
O
8.CA.50Keyite
Cu
2+
3
Zn
 
4
Cd
 
2
(AsO
 
4
)
 
6
 · 2H
 
2
O
8.CA.55Pushcharovskite
K
 
0.6
Cu
 
18
(AsO
 
4
)(HAsO
 
4
)
 
10
(H
 
2
AsO
 
4
)
 
4
(OH)
 
9.6
·18.6H
 
2
O
8.CA.60Prosperite
CaZn
 
2
(AsO
 
4
)(HAsO
 
4
)(OH)
8.CA.65Gengenbachite
KFe
3+
3
(HPO
 
4
)
 
4
(H
 
2
PO
 
4
)
 
2
 · 6H
 
2
O
8.CA.70Parahopeite
Zn
 
3
(PO
 
4
)
 
2
 · 4H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
19.3.1Moraesite
Be
 
2
(PO
 
4
)(OH) · 4H
 
2
O
19.3.2Beryllonite
NaBePO
 
4
19.3.3Hurlbutite
CaBe
 
2
(PO
 
4
)
 
2
19.3.4Hydroxylherderite
CaBe(PO
 
4
)(OH,F)
19.3.5Glucine
CaBe
 
4
(PO
 
4
)
 
2
(OH)
 
4
 · 0.5H
 
2
O
19.3.6Fransoletite
Ca
 
3
Be
 
2
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
 · 4H
 
2
O
19.3.7Uralolite
Ca
 
2
Be
 
4
(PO
 
4
)
 
3
(OH)
 
3
 · 5H
 
2
O
19.3.10Tiptopite
K
 
2
(Na,Ca)
 
2
Li
 
3
Be
 
6
(PO
 
4
)
 
6
(OH)
 
2
 · H
 
2
O
19.3.11Gainesite
Na(Na,K)(Be,Li)Zr
 
2
(PO
 
4
)
 
4
 · 1.5-2H
 
2
O
19.3.12Roscherite
Ca
 
2
Mn
2+
5
Be
 
4
(PO
 
4
)
 
6
(OH)
 
4
 · 6H
 
2
O
19.3.13Faheyite
(Mn,Mg,Na)Be
 
2
Fe
 
2
(PO
 
4
)
 
4
 · 6H
 
2
O
19.3.14Farringtonite
Mg
 
3
(PO
 
4
)
 
2
19.3.15Holtedahlite
Mg
 
2
(PO
 
4
)(OH)
19.3.16Althausite
Mg
 
2
(PO
 
4
)(OH,F)
19.3.17Newberyite
Mg(HPO
 
4
) · 3H
 
2
O
19.3.18Phosphorrösslerite
Mg(HPO
 
4
) · 7H
 
2
O
19.3.19Bobierrite
Mg
 
3
(PO
 
4
)
 
2
 · 8H
 
2
O
19.3.20Barićite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
 · 8H
 
2
O
19.3.21Panethite
(Na,Ca)
 
2
(Mg,Fe
2+
 
)
 
2
(PO
 
4
)
 
2
19.3.22Dittmarite
(NH
 
4
)Mg(PO
 
4
) · H
 
2
O
19.3.23Struvite
(NH
 
4
)Mg(PO
 
4
) · 6H
 
2
O
19.3.24Hannayite
(NH
 
4
)
 
2
Mg
 
3
H
 
4
(PO
 
4
)
 
4
 · 8H
 
2
O

Other Names for Pahasapaite

Synonyms:
Pahasapite
Other Languages:
German:Pahasapait
Pahasapit
Russian:Пахасапаит
Spanish:Pahasapaita
Pahasapita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Pahasapaite

Reference List:

- +
Neues Jahrbuch für Mineralogie, Monatshefte (1987): 10: 433-440.

Rouse R.C., Peacor D.R., Merlino S.(1989): Crystal structure of pahasapaite, a beryllophosphate mineral with a distorted zeolite rho framework. American Mineralogist: 74: 1195-1202.

Internet Links for Pahasapaite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Pahasapaite details from Handbook of Mineralogy (PDF)
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  • rare and unusual minerals mainly crystallized
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    • Localities for Pahasapaite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    USA
     
    • South Dakota
      • Custer Co.
        • Custer District
          • Fourmile
    		American Mineralogist, Volume 74, pages l195-1202, 1989
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