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Palladoarsenide

A valid IMA mineral species
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About PalladoarsenideHide

Formula:
Pd2As
Colour:
steel-gray
Lustre:
Metallic
Hardness:
5
Specific Gravity:
10.42 (Calculated)
Crystal System:
Monoclinic
Name:
Named for the composition.
Compare 'UM1974-01-As:PdSb', most likely an antimonian variety.

Also compare UM1975-07-As:PdSn, UM1976-01-As:BiPd, UM1976-03-As:NiPd, UM1974-01-As:PdSb, and very similar palladobismutharsenide.


Unique IdentifiersHide

Mindat ID:
3068
Long-form identifier:
mindat:1:1:3068:3
GUID
(UUID V4):
b231adca-d647-439e-8792-741a827543d5

Classification of PalladoarsenideHide

Approved
First published:
1974
2.AC.25a

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
A : Alloys
C : Alloys of metalloids with PGE
2.4.14.1

2 : SULFIDES
4 : AmBnXp, with (m+n):p = 2:1
3.12.24

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
12 : Sulphides etc. of the platinum metals

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
PdaIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of PalladoarsenideHide

Metallic
Transparency:
Opaque
Colour:
steel-gray
Comment:
in polished section (reflected light?): grayish white with slight rose tint
Hardness:
Hardness:
VHN20=277 - 357 kg/mm2 - Vickers
Tenacity:
Brittle
Cleavage:
Perfect
2 directions
Density:
10.42 g/cm3 (Calculated)

Optical Data of PalladoarsenideHide

Anisotropism:
moderate: dark gray with bluish tint to red-brown (air), dark gray to brownish gray with red tint (oil)
Reflectivity:
WavelengthR1R2
400nm44.2%45.1%
420nm46.8%46.8%
440nm48.4%48.8%
460nm49.4%50.3%
480nm50.2%51.6%
500nm51.2%53.1%
520nm51.9%54.1%
540nm52.5%54.8%
560nm53.3%55.4%
580nm53.9%55.8%
600nm54.6%56.3%
620nm55.4%57.1%
640nm56.0%57.6%
660nm56.6%58.1%
680nm57.1%58.6%
700nm57.8%59.2%

Reflectance graph
Graph shows reflectance levels at different wavelengths (in nm). Top of box is 100%. Peak reflectance is 59.2%.
R1 shown in black, R2 shown in red

Chemical Properties of PalladoarsenideHide

Formula:
Pd2As
Common Impurities:
Pt,Au,Ag,Ni,Cu,Sb,Te

Crystallography of PalladoarsenideHide

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
P2/m
Cell Parameters:
a = 9.25(1) Å, b = 8.47(2) Å, c = 10.44(2) Å
β = 94.0°
Ratio:
a:b:c = 1.092 : 1 : 1.233
Unit Cell V:
815.96 ų (Calculated from Unit Cell)
Z:
18

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
2.14 Å(100)
2.21 Å(90)
2.60 Å(70)
1.955 Å(70)
2.35 Å(60)
2.31 Å(60)
2.13 Å(50)

Geological EnvironmentHide

Paragenetic Mode(s):
Paragenetic ModeEarliest Age (Ga)
Near-surface Processes
26 : Hadean detrital minerals
High-𝑇 alteration and/or metamorphism
33 : Minerals deposited by hydrothermal metal-rich fluids (see also [#12])
Stage 4b: Highly evolved igneous rocks>3.0
37 : Layered igneous intrusions and related PGE minerals

Type Occurrence of PalladoarsenideHide

General Appearance of Type Material:
irregular grains in chalcopyrite, up to 0.4 mm, long & veinlet-like, vermicular, having curving boundaries
Place of Conservation of Type Material:
A.E. Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia
Geological Setting of Type Material:
veins along the footwall of a Cu–Ni sulfide deposit; also within heavy mineral concentrates
Associated Minerals at Type Locality:
Reference:
Begizov, V.D., Meshichankina, V.I., Dubakina, L.S. (1974) Palladoarsenide, Pd2As, a new natural palladium arsenide from the copper-nickel deposits of the Oktyabr deposits. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 103(1): 104-107.

Synonyms of PalladoarsenideHide

Other Language Names for PalladoarsenideHide

Simplified Chinese:æ–œç ·é’ŻçŸż

Common AssociatesHide

Associated Minerals Based on Photo Data:
5 photos of Palladoarsenide associated with Hollingworthite(Rh,Pt,Pd)AsS
5 photos of Palladoarsenide associated with GersdorffiteNiAsS
1 photo of Palladoarsenide associated with CherepanoviteRhAs
1 photo of Palladoarsenide associated with IsoferroplatinumPt3Fe
1 photo of Palladoarsenide associated with Platinum-Group Elements
1 photo of Palladoarsenide associated with PlatinumPt
1 photo of Palladoarsenide associated with Irarsite(Ir,Ru,Rh,Pt)AsS
1 photo of Palladoarsenide associated with TörnroositePd11As2Te2
1 photo of Palladoarsenide associated with SperrylitePtAs2

Related Minerals - Strunz-mindat GroupingHide

2.AC.TörnroositePd11As2Te2Iso. m3m (4/m 3 2/m) : Fd3m
2.AC.05aAtheneitePd2As0.75Hg0.25Hex. 6 m2 : P62m
2.AC.05bVincentitePd3AsMon.
2.AC.10cArsenopalladinitePd8(As,Sb)3Tric. 1 : P1
2.AC.10bMertieitePd8Sb2.5As0.5Trig. 3m (3 2/m) : R3c
2.AC.10aStillwateritePd8As3Trig.
2.AC.15aIsomertieitePd11Sb2As2Iso. m3m (4/m 3 2/m) : Fd3m
2.AC.15bPseudomertieitePd11(Sb,As)4Hex.
2.AC.15aMiessiitePd11Te2Se2Iso. m3m (4/m 3 2/m) : Fd3m
2.AC.20bPalarstanidePd5(Sn,As)2Hex.
2.AC.20aStibiopalladinitePd5Sb2Hex.
2.AC.20cMenshikovitePd3Ni2As3Hex. 6/m : P63/m
2.AC.25eMajakitePdNiAsHex.
2.AC.25fPalladobismutharsenidePd2(As,Bi)Orth.
2.AC.25cPalladodymite(Pd,Rh)2AsOrth. mmm (2/m 2/m 2/m) : Pnma
2.AC.25bRhodarsenide(Rh,Pd)2AsOrth.
2.AC.25dNaldrettitePd2SbOrth. mm2 : Cmc21
2.AC.30UM1999-02-As:NiRh(Rh,Ni)7As4
2.AC.30PolkanoviteRh12As7Hex. 6/m : P63/m
2.AC.35aGenkinitePt4Sb3Tet. 4 2 2
2.AC.35bUngavaitePd4Sb3Tet. 4 2 2 : P41 21 2
2.AC.40PolaritePd(Bi,Pb)Orth. mm2 : Cmc21
2.AC.45aFrooditeα-PdBi2Mon. 2/m : B2/m
2.AC.50NipalarsiteNi8Pd3As4Iso. m3m (4/m 3 2/m)
2.AC.50ViteitePd5InAsTet. 4/mmm (4/m 2/m 2/m) : P4/mmm

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for PalladoarsenideHide

References for PalladoarsenideHide

Reference List:

Localities for PalladoarsenideHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Australia
 
  • Western Australia
    • Coolgardie Shire
Austria
 
  • Styria
    • Leoben District
Bulgaria
 
  • Sofia Province
    • Etropole Municipality
Canada
 
  • Ontario
    • Kenora District
      • Ring of Fire
        • BMA527861 Area
    • Thunder Bay District
      • Coldwell complex
      • Lac des Iles Area
      • O'Neill Township
      • Seagull Lake Area
        • Seagull Lake complex
      • Seeley Lake Area
Finland
 
  • Lapland
    • Penikat complex
    • Portimo complex
    • Rovaniemi
France
 
  • Auvergne-RhĂŽne-Alpes
    • Ain
      • Belley
        • Murs-et-GĂ©lignieux
      • Bourg-en-Bresse
        • Jayat
    • Savoie
      • ChambĂ©ry
        • Marcieux
Greece
 
  • Thessaly
    • Trikala
      • Meteora
India
 
  • Karnataka
    • Davanagere District
      • Shimoga schist belt
Japan
 
  • Hokkaidƍ Prefecture
    • Rumoi Subprefecture
      • Tomamae District
        • Tomamae
Madagascar
 
  • Betsiboka
    • Maevatanana District
      • Morafeno Commune
Norway
 
  • Troms og Finnmark
    • Porsanger
Oman
 
  • Al Buraimi Governorate
    • Northern Oman Ophiolite
Russia
 
  • Krasnoyarsk Krai
    • Taymyrskiy Autonomous Okrug
      • Taimyr Peninsula
        • Putoran Plateau
  • Murmansk Oblast
    • Fedorovo-Pansky massif (Pana layered complex)
    • Monche tundra intrusion
    • Monchegorsk
      • Monchegorsk Cu-Ni Deposit
  • Republic of Karelia
    • Kondopozhsky District
    • Loukhsky District
      • Oulanka plutonic complex
        • Olanga River (Oulanka River)
South Africa
 
  • Limpopo
    • Capricorn District Municipality
      • Blouberg Local Municipality
        • Waterberg project
    • Sekhukhune District Municipality
      • Fetakgomo Tubatse Local Municipality
        • Burgersfort
    • Waterberg District Municipality
      • Mogalakwena Local Municipality
        • Mogalakwena
  • North West
    • Bojanala Platinum District Municipality
      • Rustenburg Local Municipality
        • Rustenburg
          • Royal Bafokeng
USA
 
  • Montana
    • Stillwater County
      • Blakely Creek
  • Pennsylvania
    • Chester County
 
Mineral and/or Locality  
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