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Papagoite

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Ajo District, Little Ajo Mts, Pima Co., Arizona, USA
© Brent Thorne

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Formula:
CaCu[H
 
3
AlSi
 
2
O
 
9
]
System:MonoclinicColour:Blue
Hardness:5 - 5½
This page provides mineralogical data about Papagoite.

Classification of Papagoite

IMA status:Approved
Strunz 8th edition ID:8/E.06-50
Nickel-Strunz 10th (pending) edition ID:9.CE.05

9 : SILICATES (Germanates)
C : Cyclosilicates
E : [Si4O12]8- 4-membered single rings (vierer-Einfachringe), without insular complex anions
Dana 8th edition ID:60.1.4.1

60 : CYCLOSILICATES Four-Membered Rings
1 : Four-Membered Rings, as Titanosilicates
Hey's CIM Ref.:16.5.7

16 : Silicates Containing Aluminum and other Metals
5 : Aluminosilicates of Cs, NH4 and Cu
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Type Occurrence of Papagoite

Type Locality:New Cornelia Mine (Ajo Mine), Ajo, Ajo District, Little Ajo Mts, Pima Co., Arizona, USA
Year of Discovery:1960

Physical Properties of Papagoite

Colour:Blue
Hardness (Mohs):5 - 5½

Crystallography of Papagoite

Crystal System:Monoclinic
Cell Parameters:a = 12.92Å, b = 11.49Å, c = 4.69Å
β = 100.81°
Ratio:a:b:c = 1.124 : 1 : 0.408
Unit Cell Volume:V 683.88 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Papagoite

Type:Biaxial (-)
RI values: nα = 1.607 nβ = 1.641 nγ = 1.672
2V:Measured: 78° , Calculated: 84°
Maximum Birefringence:δ = 0.065

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v

Chemical Properties of Papagoite

Formula:
CaCu[H
 
3
AlSi
 
2
O
 
9
]
Essential elements:Al, Ca, Cu, H, O, Si
All elements listed in formula:Al, Ca, Cu, H, O, Si
Common Impurities:Ti,Fe,Mn,Mg,H2O

Relationship of Papagoite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.CE.10Verplanckite
Ba
 
2
(Mn,Fe,Ti)Si
 
2
O
 
6
(O,OH,Cl,F)
 
2
·3H
 
2
O or near
9.CE.15Baotite
Ba
 
4
(Ti,Nb)
 
8
Si
 
4
O
 
28
Cl
9.CE.20Nagashimalite
Ba
 
4
(V,Ti)
 
4
B
 
2
Si
 
8
O
 
27
(O,OH)
 
2
Cl
9.CE.20Taramellite
Ba
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.20Titantaramellite
Ba
 
4
(Ti,Fe
3+
 
,Fe
2+
 
,Mg)
 
4
(B
 
2
Si
 
8
O
 
27
)O
 
2
Cl
 
x
9.CE.25Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
Si
 
8
O
 
26
·H
 
2
O
9.CE.25Byelorussite-(Ce)
Ba
 
2
NaCe
 
2
MnTi
 
2
Si
 
8
O
 
26
(F,OH) · H
 
2
O
9.CE.25Joaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(OH,F) · H
 
2
O
9.CE.25Orthojoaquinite-(Ce)
Ba
 
2
NaCe
 
2
FeTi
 
2
Si
 
8
O
 
26
(O,OH) · H
 
2
O
9.CE.25Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Strontio-orthojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
2
·H
 
2
O
9.CE.25Orthojoaquinite-(La)
Ba
 
2
NaLa
 
2
Fe
2+
 
Ti
 
2
Si
 
8
O
 
26
(O,OH)·H
 
2
O
9.CE.30eLabuntsovite-Mn
Na
 
4
K
 
4
(Ba,K)
 
2
Mn
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10-12H
 
2
O
9.CE.30aNenadkevichite
(Na,Ca)(Nb,Ti)Si
 
2
O
 
7
·2H
 
2
O
9.CE.30dLemmleinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30aKorobitsynite
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3-4H
 
2
O
9.CE.30cKuzmenkoite-Mn
K
 
2
Mn
2+
 
(Ti,Nb)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30bVuoriyarvite-K
K
 
2
(Nb,Ti)
 
2
[(O,OH)
 
2
|Si
 
4
O
 
12
] · 4H
 
2
O
9.CE.30bTsepinite-Na
Na
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30cKarupmøllerite-Ca
(Na,Ca,K)
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 7H
 
2
O
9.CE.30eLabuntsovite-Mg
Na
 
4
K
 
4
(Ba,K)
 
2
Mg(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10H
 
2
O
9.CE.30eLabuntsovite-Fe
Na
 
4
K
 
4
(Ba,K)
 
2
Fe
2+
 
(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 10H
 
2
O
9.CE.30dLemmleinite-Ba
Na
 
2
K
 
2
Ba(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30cGjerdingenite-Fe
K
 
2
Fe
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30hNeskevaaraite-Fe
K
 
3
Na
 
2
Fe
2+
 
(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5-6 H
 
2
O
9.CE.30bTsepinite-K
K
 
2
(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Ba
Ba
 
4
(Ti,Nb)
 
8
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
4
 · 8H
 
2
O
9.CE.30bTsepinite-Ca
Ca(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30hAlsakharovite-Zn
NaSrKZn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(O,OH)
 
4
 · 7 H
 
2
O
9.CE.30cGjerdingenite-Mn
K
 
2
Mn
2+
 
(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30cLepkhenelmite-Zn
(Ba,K)
 
2
Zn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 7H
 
2
O
9.CE.30bTsepinite-Sr
Sr(Ti,Nb)
 
2
[(OH,O)
 
2
|Si
 
4
O
 
12
] · 3H
 
2
O
9.CE.30bParatsepinite-Na
(Na,Sr,K,Ca)
 
7
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(O,OH)
 
8
·nH
 
2
O n ~ 8
9.CE.30fParalabuntsovite-Mg
Na
 
8
K
 
8
Mg
 
8
Ti
 
16
(Si
 
4
O
 
12
)
 
8
(O,OH)
 
16
· n(H
 
2
O)
9.CE.30cGjerdingenite-Ca
K
 
2
Ca(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30cGjerdingenite-Na
K
 
2
Na
 
2
(Nb,Ti)
 
4
[(OH,O)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30hGutkovaite-Mn
K
 
2
CaMn(Ti,Nb)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 5H
 
2
O
9.CE.30cKuzmenkoite-Zn
K
 
2
Zn(Ti,Nb)
 
4
(Si
 
4
O
 
12
)
 
2
(OH,O)
 
4
·6-8H
 
2
O
9.CE.30gOrganovaite-Mn
K
 
2
Mn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30gOrganovaite-Zn
K
 
2
Zn(Nb,Ti)
 
4
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
2
 · 6H
 
2
O
9.CE.30gParakuzmenkoite-Fe
(K,Ba)
 
4
Fe(Ti,Nb)
 
8
[(O,OH)
 
2
|Si
 
4
O
 
12
]
 
4
 · 14H
 
2
O
9.CE.30cIMA2008-001
(K,Na,Sr,Ba)
 
4
Ca
 
2
(Ti,Nb)
 
8
[Si
 
4
O
 
12
]
 
4
(OH,O)
 
8
·12H
 
2
O
9.CE.45Komarovite
(Ca,Mn)Nb
 
2
[O
 
3
|Si
 
2
O
 
7
] · 3.5H
 
2
O
9.CE.45Natrokomarovite
(Na,Ca,H)
 
2
Nb
 
2
Si
 
2
O
 
10
(OH,F)
 
2
·H
 
2
O
Related Minerals - Hey's Index Grouping:
16.5.1Pollucite
(Cs,Na)
 
2
[Al
 
2
Si
 
4
O
 
12
] · 2H
 
2
O
16.5.2Nanpingite
CsAl
 
2
[(OH,F)
 
2
|AlSi
 
3
O
 
10
]
16.5.3Buddingtonite
(NH
 
4
)[AlSi
 
3
O
 
8
]
16.5.4Ammonioleucite
(NH
 
4
,K)AlSi
 
2
O
 
6
16.5.5Tobelite
(NH
 
4
,K)Al
 
2
[(OH)
 
2
|AlSi
 
3
O
 
10
]
16.5.6Ajoite
(K,Na)Cu
 
7
[(OH)
 
6
|AlSi
 
9
O
 
24
] · 3H
 
2
O

Other Names for Papagoite

German names:
Papagoit
Russian names:
Папагоит
Spanish names:
Papagoita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Papagoite

Reference List:Hutton, C.O. & A.C. Vlisidis (1960), Papagoite, a new copper-bearing mineral from Ajo, AZ, American Mineralogist: 45: 599-611.

Guillebert, C. & M.T. Le Bihan (1965), Contributions à l'étude structurale des silicates de cuivre: Structure atomique de la papagoite, Bull. Soc. Franc. Min. Crist: 88: 119-121.

Mineralogy and Petrology (1987): 37: 89-96.

Internet Links for Papagoite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Papagoite details from Handbook of Mineralogy (PDF)
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    Localities for Papagoite

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    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Slovakia
     
    • Košice Region
      • Eastern Slovenské Rudohorie Mts
        • Košice
    		Koděra, M. et al., 1986 a 1990 : Topografická mineralógia Slovenska, diel 1- 3, Veda – Vydavateľstvo SAV, Bratislava, 1990, 1 – 1590k
    South Africa
     
    • Limpopo Province
    		[MinRec 22:187]
    Minerals of South Africa
    Minerals of South Africa
    USA
     
    • Arizona
      • Pima Co.
        • Little Ajo Mts
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 109.
            • Ajo
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 319-320; Hutton, C.O. & A.C. Vlisidis (1960), Papagoite, a new copper-bearing mineral from Ajo, AZ, Am.Min.: 45: 599-611; Guillebert, C. & M.T. Le Bihan (1965), Contributions à l'étude structurale des silicates de cuivre: Structure atomique de la papagoite, Bull. Soc. Franc. Min. Crist: 88: 119-121.
    Mineral and/or Locality
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