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Paralaurionite

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Formula:
PbCl(OH)
System:MonoclinicColour:Colourless, white, ...
Hardness:3
Member of:Matlockite Group
Name:From the Greek for "near", para-, and laurionite, in allusion to its polymorphic relationship to that species.
Dimorph of:Laurionite

Classification of Paralaurionite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:3/D.0-20
Nickel-Strunz 10th (pending) edition ID:3.DC.05

3 : HALIDES
D : Oxyhalides, hydroxyhalides and related double halides
C : With Pb (As,Sb,Bi), without Cu
Dana 8th edition ID:10.2.3.1

10 : OXYHALIDES AND HYDROXYHALIDES
2 : A(O,OH)Xq
Hey's CIM Ref.:8.8.8

8 : Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and Fluosilicates
8 : Halides of Pb
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Type Occurrence of Paralaurionite

Type Locality:Lavrion District slag localities, Lavrion (Laurion; Laurium) District, Attikí (Attica; Attika) Prefecture, Greece
Year of Discovery:1899

Physical Properties of Paralaurionite

Lustre:Sub-Adamantine
Diaphaneity (Transparency):Transparent
Colour:Colourless, white, yellow, violet, green
Hardness (Mohs):3
Cleavage:Perfect
On {001}.
Density (measured):6.15 g/cm3
Density (calculated):6.28 g/cm3

Crystallography of Paralaurionite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Space Group Setting:C1 2/m 1
Cell Parameters:a = 10.865(4) Å, b = 4.006(2) Å, c = 7.233(3) Å
β = 117.24(4)°
Ratio:a:b:c = 2.712 : 1 : 1.806
Unit Cell Volume:V 279.90 ų (Calculated from Unit Cell)
Morphology:Crystals thin tabular {100} or lath-like by elongation [001]. The terminations of the plates or laths are rectangular or wedge-shaped as a result of development of pyramidal faces at the corners.
Twinning:Twin plane {100}, very common, as symmetrical contact twins with composition face (100), simulating orthorhombic holohedry.
Comment:OD structure.
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Paralaurionite

Type:Biaxial (-)
RI values: nα = 2.050 nβ = 2.150 nγ = 2.200
Maximum Birefringence:δ = 0.150

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r < v strong
Pleochroism:Visible
Comments:Violet-tinted crystals are pleochroic with absorption Y is greater than X, Z.
Comments:Plates on {100} exhibit abnormal interference figures due to twinning.

Chemical Properties of Paralaurionite

Formula:
PbCl(OH)
Essential elements:Cl, H, O, Pb
All elements listed in formula:Cl, H, O, Pb

Relationship of Paralaurionite to other Species

Member of:Matlockite Group
Other Members of Group:

- +
Bismoclite
(BiO)Cl
Daubréeite
(BiO)(OH,Cl)
Laurionite
PbCl(OH)
Matlockite
PbFCl
Rorisite
CaFCl
Zavaritskite
(BiO)F
Related Minerals - Nickel-Strunz Grouping):

- +
3.DC.05Laurionite
PbCl(OH)
3.DC.10Fiedlerite
Pb
 
3
FCl
 
4
(OH) · H
 
2
O
3.DC.15Penfieldite
Pb
 
2
Cl
 
3
(OH)
3.DC.20Laurelite
Pb
 
7
F
 
12
Cl
 
2
3.DC.25Bismoclite
(BiO)Cl
3.DC.25Daubréeite
(BiO)(OH,Cl)
3.DC.25Matlockite
PbFCl
3.DC.25Rorisite
CaFCl
3.DC.25Zavaritskite
(BiO)F
3.DC.25Zhangpeishanite
BaFCl
3.DC.30Nadorite
PbSbClO
 
2
3.DC.30Perite
PbBiClO
 
2
3.DC.35Aravaipaite
Pb
 
3
F
 
3
[AlF
 
6
] · H
 
2
O
3.DC.37Calcioaravaipaite
PbCa
 
2
(F,OH)
 
3
[AlF
 
6
] · H
 
2
O
3.DC.40Thorikosite
Pb
 
3
Cl
 
2
(OH)(SbO
 
3
,AsO
 
3
)
3.DC.45Mereheadite
Pb
 
47
Cl
 
25
(OH)
 
13
O
 
24
(CO
 
3
)(BO
 
3
)
 
2
3.DC.50Blixite
Pb
 
2
(O,OH)
 
2
Cl
3.DC.55Pinalite
Pb
 
3
WO
 
5
Cl
 
2
3.DC.60Symesite
Pb
 
10
Cl
 
4
O
 
7
(SO
 
4
) · H
 
2
O
3.DC.65Ecdemite
Pb
 
6
Cl
 
4
(As
 
2
O
 
7
)
3.DC.65Heliophyllite
Pb
 
6
Cl
 
4
(As
 
2
O
 
7
)
3.DC.70Mendipite
Pb
 
3
Cl
 
2
O
 
2
3.DC.75Damaraite
Pb
 
3
Cl(OH)O
 
2
3.DC.80Onoratoite
Sb
 
8
Cl
 
2
O
 
11
3.DC.85Cotunnite
PbCl
 
2
3.DC.90Pseudocotunnite
K
 
2
PbCl
 
4
3.DC.95Barstowite
Pb
 
4
Cl
 
6
(CO
 
3
) · H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
8.8.1Abhurite
Sn
 
21
Cl
 
16
(OH)
 
14
O
 
6
8.8.2Matlockite
PbFCl
8.8.3Laurelite
Pb
 
7
F
 
12
Cl
 
2
8.8.4Cotunnite
PbCl
 
2
8.8.5Mendipite
Pb
 
3
Cl
 
2
O
 
2
8.8.6Damaraite
Pb
 
3
Cl(OH)O
 
2
8.8.7Laurionite
PbCl(OH)
8.8.9Penfieldite
Pb
 
2
Cl
 
3
(OH)
8.8.10Fiedlerite
Pb
 
3
FCl
 
4
(OH) · H
 
2
O
8.8.11Blixite
Pb
 
2
(O,OH)
 
2
Cl
8.8.12Pseudocotunnite
K
 
2
PbCl
 
4
8.8.13Diaboleite
Pb
 
2
CuCl
 
2
(OH)
 
4
8.8.14Pseudoboleite
Pb
 
31
Cu
 
24
Cl
 
62
(OH)
 
48
8.8.15Chloroxiphite
Pb
 
3
CuO
 
2
Cl
 
2
(OH)
 
2
8.8.17Bideauxite
Pb
 
2
AgCl
 
3
(F,OH)
 
2
8.8.18Boleite
KPb
 
26
Ag
 
9
Cu
 
24
(OH)
 
48
Cl
 
62
8.8.19Aravaipaite
Pb
 
3
F
 
3
[AlF
 
6
] · H
 
2
O
8.8.20Yedlinite
Pb
 
6
Cr
3+
 
Cl
 
6
(O,OH,H
 
2
O)
 
8
8.8.21Kolarite
PbTeCl
 
2
8.8.22Hematophanite
Pb
 
4
Fe
 
3
O
 
8
(OH,Cl)

Other Names for Paralaurionite

Synonyms:
Laurionite-2M
Other Languages:
German:Paralaurionit
Rafaëlit (of Arzruni and Thaddéeff)
Russian:Паралаурионит
Spanish:Paralaurionita

Other Information

Other Information:Soluble in nitric acid.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Paralaurionite

Reference List:

- +
Arzruni and Thaddéeff (1899) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 31: 229 (as Rafaëlit).

Smith (1899) Mineralogical Magazine: 12: 102, 183.

Ktenas (1910) Bulletin de la Société française de Minéralogie: 33: 173.

Russell (1927) Mineralogical Magazine: 21: 221.

Palache, C. (1934) Mineralogical Magazine: 23: 578.

Palache, Charles, Harry Berman & Clifford Frondel (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume II: Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged: 64-66.

Mineralogical Magazine: 29: 341.

Merlino S., Pasero M., Perchiazzi N. (1993): Crystal structure of paralaurionite and its OD relationships with laurionite. Mineralogical Magazine 57, 323-328.

Internet Links for Paralaurionite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Paralaurionite details from Handbook of Mineralogy (PDF)
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  • Localities for Paralaurionite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Western Australia
      • Pilbara Region
        • Ashburton Shire
          • Ashburton Downs
    Min. Record 24,203-218(1993)
    Austria
     
    • Carinthia
      • Friesach - Hüttenberg area
        • Hüttenberg
          • Waitschach
    U. Kolitsch and H. Pristacz (2009): An orthorhombic dimorph of barstowite, Pb4Cl6(CO3)•H2O, from slags at Maria Waitschach, Austria, and Lavrion, Greece. Poster, Joint MinPet 2009 and 4th MSCC, Budapest, Hungary, September 7-11; abstract in Mitt. Österr. Mineral. Ges. 155, 83.
    Chile
     
    • Antofagasta Region
      • Antofagasta Province
    Econ Geol (1991) 86:1222-1237
        • Sierra Gorda District
          • Caracoles
    M. Dini specimens
    Arzruni and Thaddéeff (1899) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 31: 229; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 65, 317.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Central Bohemia Region
        • Příbram
    [Der Aufschluss 1996:6 p.267-287]
    France
     
    • Brittany
      • Côtes-d'Armor
        • Callac
          • Carnoët
            • Menez-Plom
    P. Le Roch collection
      • Finistère
        • Poullaouen
    Germain C., Leydet J-C., Saget Ph. (1990), Les minéraux de néoformation de Huelgoat (Finistère), Le Cahier des Micromonteurs, n°3, 3-16
    Germany
     
    • Lower Saxony
      • Harz Mts
        • Goslar
          • Astfeld
    No reference listed
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
    Gelaude, Piet, van Kalmthout, Piet and Rewitzer, Christian, Laurion: The Minerals in the Ancient Slags. Mineralogical Magazine (1899): 12: 108; Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 65.
          • Agios Nikolaos [St Nicholas] area
    No reference listed
          • Lavrion (Laurion; Laurium)
    No reference listed
          • Oxygon area
    No reference listed
          • Panormos area
    No reference listed
          • Passa Limani area
    Gelaude, Piet, van Kalmthout, Piet, and Rewitzer, Christian (1996) Laurion: The Minerals of the Ancient Slags, Janssen Print, Nijmegen, The Netherlands
          • Sounion area
    Collection of Elmar Lackner
    Gelaude, Piet, van Kalmthout, Piet and Rewitzer, Christian, (1996) Laurion: The Minerals in the Ancient Slags, Janssen Print, Nijmegen, The Netherlands
          • Thorikos area
    Gelaude, Piet, van Kalmthout, Piet and Rewitzer, Christian (1996) Laurion: The Minerals in the Ancient Slags, Janssen Print, Nijmegen, The Netherlands
          • Tourkolimanon area
    No reference listed
          • Vrissaki area
    Gelaude, Piet, van Kalmthout, Piet, and Rewitzer, Christian (1996) Laurion: The Minerals in the Ancient Slags, Janssen Print, Nijmegen, The Netherlands
    Italy
     
    • Liguria
      • Genova Province
        • Genova
          • Varenna Valley
    Rivista Mineralogica Italiana, 2 (Avril/Juin), 175-188.
    • Piedmont
      • Vercelli Province
        • Sesia Valley
    Luigi Chiappino data
    • Tuscany
      • Livorno Province
        • Campiglia Marittima
    http://www.comune.pisa.it/apsn/Articoli/Scorie/Capattoli.htm
        • Piombino
    Lapis, 20 (4), 13-18+50.
    Luigi Chiappino data
    Morocco
     
    • Meknès-Tafilalet Region
      • Khénifra Province
        • Midelt
          • Upper Moulouya lead district
    Jébrak, M., Marcoux, E., Masloubi, M., and Zaharaoui, M. (1998): Mineralium Deposita 33, 406-415.
    • Oriental Region
      • Oujda-Angad Province
        • Touissit District
          • Touissit
    Van King
    South Africa
     
    • Gauteng Province
    Minerals of South Africa
    UK
     
    • England
      • Cornwall
        • Mount's Bay District
          • Porthleven
    Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 65.
        • St Agnes District
          • Crantock
    BMS Newsletter 79, March 2010 (http://britishmicromountsociety.homestead.com/Gannell-Smelter.html)
        • Wadebridge District
          • Area West of Wadebridge
            • Padstow
    No reference listed
      • Somerset
        • Cranmore
    Turner, R.W. and Rumsey, M.S. (2010): Mineral Relationships in the Mendip Hills. Journal of the Russell Society, vol 13, pp 3-46; Turner, R.W., (2006) A Mechanism for the formation of the Mineralised Mn Deposits at Merehead Quarry, Cranmore, Somerset, England. Min. Mag. vol. 70, no. 6, pp 629 - 653
        • Holwell
    BMS Database
        • Westbury on Trym
    BMS Database
    • Scotland
      • Dumfries & Galloway (Dumfries-shire)
        • Wanlockhead
    BMS Database
    USA
     
    • Arizona
      • Maricopa Co.
        • Big Horn Mts
          • Osborn District
            • Tonopah
              • Belmont Mountain
    Collected by and in the collection of Joe Ruiz. Analyzed by the University of Arizona.
      • Pinal Co.
        • Mammoth District
          • Tiger
            • St. Anthony deposit
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 141; Fahey, J.J., et al (1950), Wherryite, a new mineral from the Mammoth mine, AZ, Am.Min.: 35: 93-98; Bideaux, R.A. (1980), Tiger, AZ, Min.Rec.: 11: 155-181; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 67.
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 320; Bideaux, R.A. (1980), Tiger, Arizona, Min.Rec.: 11: 155-181; Palache, C. (1950), Paralaurionite, Min.Mag.: 29: 341-345; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 44.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2011. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
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