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Parapierrotite

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Formula:
Tl(Sb,As)
 
5
S
 
8
System:MonoclinicColour:Black
Hardness:2½ - 3
Name:Named in polymorphic chemical relation to pierrotite.
Dimorph of:Pierrotite
Isostructural with:Bernardite


Prismatic crystals, also laths and grains

Classification of Parapierrotite

IMA status:Approved
Strunz 8th edition ID:2/E.14-40
Nickel-Strunz 10th (pending) edition ID:2.HC.05f

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
H : Sulfosalts of SnS archetype
C : With only Pb
Dana 8th edition ID:3.8.14.1

3 : SULFOSALTS
8 : 1 < ø < 2
Hey's CIM Ref.:5.5.18

5 : Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)
5 : Sulpharsenites etc. of Tl
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Type Occurrence of Parapierrotite

Type Locality:Allchar (Alsar), Roszdan, Republic of Macedonia
Year of Discovery:1975
Geological Setting of type material: Hydrothermal deposits

Physical Properties of Parapierrotite

Lustre:Sub-Metallic
Diaphaneity (Transparency):Opaque
Colour:Black
Hardness (Mohs):2½ - 3
Hardness (Vickers):VHN100=76
Tenacity:Brittle
Cleavage:None Observed
Density (measured):5.07 g/cm3
Density (calculated):5.04 g/cm3

Crystallography of Parapierrotite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P21/b {P1 1 21/b} {P21/c} {P1 21/c 1} {P21/a}
Cell Parameters:a = 8.02Å, b = 19.35Å, c = 9.03Å
β = 91.97°
Ratio:a:b:c = 0.414 : 1 : 0.467
Unit Cell Volume:V 1,400.51 ų (Calculated from Unit Cell)
Z:4
Morphology:Prismatic crystals to 3 mm
Comment:P21/n
X-Ray Powder Diffraction:
d-spacingIntensity
4.15 (90)
3.93 (60)
3.70 (90)
3.60 (70)
3.49 (100)
2.91 (90)
2.83 (100)
2.36 (90)
Comments:ICDD 29-1330

Optical Data of Parapierrotite

Type:Anisotropic
Reflectivity:
nmR= = 29.1 - 39.7 (540 nm%


Graph shows reflectance levels at different wavelengths (in nm). Peak reflectance is 0%.

Chemical Properties of Parapierrotite

Formula:
Tl(Sb,As)
 
5
S
 
8
Essential elements:S, Sb, Tl
All elements listed in formula:As, S, Sb, Tl

Relationship of Parapierrotite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
2.HC.05bBaumhauerite-2a
Pb
 
11
Ag(As,Sb)
 
18
S
 
36
2.HC.05bBaumhauerite
Pb
 
3
As
 
4
S
 
9
2.HC.05eChabournéite
Tl
 
21-x
Pb
 
2x
(Sb,As)
 
91-x
S
 
147
(x = 0-17.5)
2.HC.05dDufrénoysite
Pb
 
2
As
 
2
S
 
5
2.HC.05aGuettardite
Pb(Sb,As)
 
2
S
 
4
2.HC.05cLiveingite
Pb
 
9
As
 
13
S
 
28
2.HC.05fPierrotite
Tl
 
2
Sb
 
6
As
 
4
S
 
16
2.HC.05dRathite
Pb
 
8
Pb
 
4-x
(Tl
 
2
As
 
2
)
 
x
(Ag
 
2
As
 
2
)As
 
16
S
 
40
2.HC.05aSartorite
PbAs
 
2
S
 
4
2.HC.05aTwinnite
Pb(Sb,As)
 
2
S
 
4
2.HC.05dVeenite
Pb
 
2
(Sb,As)
 
2
S
 
5
2.HC.05gMarumoite
Pb
 
32
As
 
40
S
 
92
2.HC.05eDalnegroite
(Tl
 
4
Pb
 
2
)(As
 
12
Sb
 
8
)S
 
34
2.HC.10aFülöppite
Pb
 
3
Sb
 
8
S
 
15
2.HC.10cHeteromorphite
Pb
 
7
Sb
 
8
S
 
19
2.HC.10bPlagionite
Pb
 
5
Sb
 
8
S
 
17
2.HC.10dRayite
Pb
 
8
(Ag,Tl)
 
2
Sb
 
8
S
 
21
2.HC.10dSemseyite
Pb
 
9
Sb
 
8
S
 
21
2.HC.15Boulangerite
Pb
 
5
Sb
 
4
S
 
11
2.HC.15Falkmanite
Pb
 
5.4
Sb
 
3.6
S
 
11
2.HC.15Plumosite
2.HC.20Robinsonite
Pb
 
4
Sb
 
6
S
 
13
2.HC.25Moëloite
Pb
 
6
Sb
 
6
S
 
14
(S
 
3
)
2.HC.30Dadsonite
Pb
 
23
Sb
 
25
S
 
60
Cl
2.HC.35Owyheeite
Ag
 
3+x
Pb
 
10-2x
Sb
 
11+x
S
 
28
, -0.13 < x > +0.20
2.HC.35Zoubekite
AgPb
 
4
Sb
 
4
S
 
10
2.HC.40Parasterryite
Ag
 
4
Pb
 
20
Sb
 
14
As
 
10
S
 
58
Related Minerals - Hey's Index Grouping:

- +
5.5.1Lorándite
TlAsS
 
2
5.5.2Ellisite
Tl
 
3
AsS
 
3
5.5.3Imhofite
Tl
 
6
CuAs
 
16
S
 
40
5.5.4Simonite
TlHgAs
 
3
S
 
6
5.5.6Christite
TlHgAsS
 
3
5.5.6Routhierite
Tl(Cu,Ag)(Hg,Zn)
 
2
(As,Sb)
 
2
S
 
6
5.5.7Hutchinsonite
(Tl,Pb)
 
2
As
 
5
S
 
9
5.5.8Wallisite
(Cu,Ag)TlPbAs
 
2
S
 
5
5.5.9Bernardite
Tl(As,Sb)
 
5
S
 
8
5.5.10Vrbaite
Tl
 
4
Hg
 
3
Sb
 
2
As
 
8
S
 
20
5.5.11Rebulite
Tl
 
5
Sb
 
5
As
 
8
S
 
22
5.5.12Gillulyite
Tl
 
2
(As,Sb)
 
8
S
 
13
5.5.13Weissbergite
TlSbS
 
2
5.5.14Rohaite
(Tl,Pb,K)
 
2
Cu
 
8.7
Sb
 
2
S
 
4
5.5.15Vaughanite
TlHgSb
 
4
S
 
7
5.5.16Chalcothallite
Tl
 
2
(Cu,Fe)
 
6
SbS
 
4
5.5.17Pierrotite
Tl
 
2
Sb
 
6
As
 
4
S
 
16
5.5.19Criddleite
TlAg
 
2
Au
 
3
Sb
 
10
S
 
10
5.5.20Chabournéite
Tl
 
21-x
Pb
 
2x
(Sb,As)
 
91-x
S
 
147
(x = 0-17.5)

Other Names for Parapierrotite

Synonyms:
IMA1974-059
Other Languages:
German:Parapierrotit
Russian:Парапьерротит
Simplified Chinese:斜硫锑铊矿
Spanish:Parapierrotita

Other Information

Fluorescence in UV light:Not fluorescent
Health Warning:Contains thallium - always wash hands after handling. Avoid inhaling dust when handling or breaking. Never lick or ingest.

References for Parapierrotite

Reference List:

- +
Tschermak's Mineralogisch und Petrographische Mitteilungen (1975) 22:200

American Mineralogist (1976): 61: 504.

P&J 287

Zeitschrift für Kristallographie (1980): 151: 203-216.

Internet Links for Parapierrotite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Parapierrotite details from Handbook of Mineralogy (PDF)
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  • Localities for Parapierrotite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Ontario
      • Thunder Bay District
        • Marathon
    Mineralogical Magazine 1988 52 : 691-697
    Mineralogical Magazine 1988 52 : 691-697
    M. Bonnemaison, J. Delair, F. Tollon, Chron. Rech. Min., N° 486, 1987, pp 81-84.
    France
     
    • Provence-Alpes-Côte d'Azur
      • Hautes-Alpes
        • Valgaudemar
          • Pelvoux Mt.
    Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 1, 1990
    Republic of Macedonia
     
    • Roszdan
    [Tschermaks Min.Petr.(1975) 22, 200-210; Rieck, B. (1993) - Famous mineral localities: Allchar, Macedonia, Mineralogical Record, 24 (6), 437-449]; The Canadian Mineralogist Vol.32, pp. 649-665 (1994)
    Gunnar Farber specimens
    USA
     
    • Utah
      • Tooele Co.
        • Little Valley
    No reference listed
        • Sheeprock Mts
          • Blue Bell District
    U.S. Geological Survey, 2005, Mineral Resources Data System: U.S. Geological Survey, Reston, Virginia.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2011. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 29th Jun 2011 19:07:26
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