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Bendadaite

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Formula:
Fe
2+
 
Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
System:Monoclinic
Member of:Arthurite Group
Name:Named after the type locality, the Bendada phosphate pegmatite, Bendada Quarries, Sabugal, Guarda District, Portugal.
Isostructural with:Whitmoreite


Arthurite Group. The arsenate analogue of Whitmoreite.

The divalent Fe may be partly oxidised.

Classification of Bendadaite

IMA status:Approved 2007
Strunz 9th edition ID:8.DC.15
Nickel-Strunz 10th (pending) edition ID:8.DC.15

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
Dana 8th edition ID:42.11.20.6

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
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Type Occurrence of Bendadaite

Type Locality:Bendada Mines, Bendada, Sabugal, Guarda District, Portugal

Crystallography of Bendadaite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P21/b {P1 1 21/b} {P21/c} {P1 21/c 1} {P21/a}
Cell Parameters:a = 10.239Å, b = 9.713Å, c = 5.552Å
β = 94.11°
Ratio:a:b:c = 1.054 : 1 : 0.572
Unit Cell Volume:V 550.73 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
10.22 (100)
7.036 (80)
4.833 (30)
4.520 (50)
3.490 (20)
2.907 (30)
2.865 (40)

Chemical Properties of Bendadaite

Formula:
Fe
2+
 
Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Essential elements:As, Fe, H, O
All elements listed in formula:As, Fe, H, O

Relationship of Bendadaite to other Species

Member of:Arthurite Group
Other Members of Group:

- +
Arthurite
CuFe
3+
2
(AsO
 
4
,PO
 
4
,SO
 
4
)
 
2
(OH,O)
 
2
· 4H
 
2
O
Cobaltarthurite
(Co,Mg)Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Kunatite
CuFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Whitmoreite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
8.DC.05Nissonite
Cu
 
2
Mg
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 5H
 
2
O
8.DC.07Euchroite
Cu
 
2
(AsO
 
4
)(OH) · 3H
 
2
O
8.DC.10Legrandite
Zn
 
2
(AsO
 
4
)(OH) · H
 
2
O
8.DC.12Strashimirite
Cu
 
8
(AsO
 
4
)
 
4
(OH)
 
4
· 5H
 
2
O
8.DC.15Arthurite
CuFe
3+
2
(AsO
 
4
,PO
 
4
,SO
 
4
)
 
2
(OH,O)
 
2
· 4H
 
2
O
8.DC.15Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15Whitmoreite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15Cobaltarthurite
(Co,Mg)Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15Kunatite
CuFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15UKI-2006-(PO:FeHZn)
ZnFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.15UKI-2006-(PO:AlCuFeH)
Fe
2+
 
Al
 
3
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.17Kleemanite
ZnAl
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 3H
 
2
O
8.DC.20Bermanite
Mn
2+
 
Mn
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.20Coralloite
Mn
2+
 
Mn
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DC.22Kovdorskite
Mg
 
2
(PO
 
4
)(OH) · 3H
 
2
O
8.DC.25Ferristrunzite
Fe
3+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
3
· 5H
 
2
O
8.DC.25Ferrostrunzite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
8.DC.25Metavauxite
Fe
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.25Metavivianite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
8.DC.25Strunzite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
8.DC.27Beraunite
Fe
2+
 
Fe
3+
5
(PO
 
4
)
 
4
(OH)
 
5
· 4H
 
2
O
8.DC.30Gordonite
MgAl
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Laueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Mangangordonite
Mn
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Paravauxite
Fe
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Pseudolaueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Sigloite
Fe
3+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
3
· 7H
 
2
O
8.DC.30Stewartite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Ushkovite
MgFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Ferrolaueite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Kastningite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Maghrebite
MgAl
 
2
(AsO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
8.DC.30Nordgauite
MnAl
 
2
(PO
 
4
)
 
2
(F,OH)
 
2
· 5H
 
2
O
8.DC.32Tinticite
Fe
3+
5.34
(PO
 
4
)
 
3.62
(VO
 
4
)
 
0.38
(OH)
 
4
· 6.7H
 
2
O
8.DC.35Vauxite
Fe
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
8.DC.37Vantasselite
Al
 
4
(PO
 
4
)
 
3
(OH)
 
3
· 9H
 
2
O
8.DC.40Cacoxenite
Fe
3+
24
Al(PO
 
4
)
 
17
O
 
6
(OH)
 
12
· 17H
 
2
O
8.DC.45Gormanite
(Fe
2+
 
,Mg)
 
3
(Al,Fe
3+
 
)
 
4
(PO
 
4
)
 
4
(OH)
 
6
· 2H
 
2
O
8.DC.45Souzalite
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
4
(PO
 
4
)
 
4
(OH)
 
6
· 2H
 
2
O
8.DC.47Kingite
Al
 
3
(PO
 
4
)
 
2
(OH)
 
3
· 9H
 
2
O
8.DC.50Wavellite
Al
 
3
(PO
 
4
)
 
2
(OH,F)
 
3
· 5H
 
2
O
8.DC.50Allanpringite
Fe
3+
3
(PO
 
4
)
 
2
(OH)
 
3
· 5H
 
2
O
8.DC.52Kribergite
Al
 
5
(PO
 
4
)
 
3
(SO
 
4
)(OH)
 
4
· 4H
 
2
O
8.DC.55Mapimite
Zn
 
2
Fe
3+
3
(AsO
 
4
)
 
3
(OH)
 
4
· 10H
 
2
O
8.DC.57Ogdensburgite
Ca
 
2
Fe
3+
4
(Zn,Mn
2+
 
)(AsO
 
4
)
 
4
(OH)
 
6
· 6H
 
2
O
8.DC.60Nevadaite
(Cu
2+
 
,Al,V
3+
 
)
 
6
Al
 
8
(PO
 
4
)
 
8
F
 
8
(OH)
 
2
· 22H
 
2
O
8.DC.60Cloncurryite
(Cu,VO)Al
 
2
(PO
 
4
)
 
2
(F,OH)
 
2
· 4.5-5H
 
2
O

Other Names for Bendadaite

Synonyms:
IMA1998-053a
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Bendadaite

Reference List:

- +
U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486.

Internet Links for Bendadaite

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  • Raman and XRD data at RRUFF project
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  • Localities for Bendadaite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Brazil
     
    • Minas Gerais
      • Doce valley
        • Divino das Laranjeiras
          • Linópolis
    U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486.
    Chile
     
    • Atacama Region
      • Copiapó Province
        • Tierra Amarilla
          • Pampa Larga district
    U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486.
    France
     
    • Limousin
      • Haute-Vienne
        • Razès
          • Chanteloube
            • Vilatte Quarries (La Vilate)
    Meisser, N. (2010): Sur la présence de bendadaite à la Villatte-Haute (Monts d'Amabazac, Haute-Vienne), Le Règne Minéral, 94, 40.
    Italy
     
    • Sardinia
      • Medio Campidano Province
        • Gonnosfanadiga
          • Fenugu Sibiri Mine
    U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486. [Blass, G. (2007) EDX + XRD]; Micro No. 3 (2011) 94-97
    Japan
     
    • Kyushu Region
      • Oita prefecture
        • Saeki city
    Satoshi Matsubara, Ritsuro Miyawaki, Masako Shigeoka, Hidemasa Tajima, Katsuichi Nishida and Yoshiteru Fujiwara (2009): Bendadaite and iron arsenate minerals from the Kiura mine, Oita Prefecture, Japan. 2009 Annual Meeting of Japan Association of Mineralogical Sciences, Abstracts Volume, Abs. R4-06, p. 100.
    Morocco
     
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
        • Tazenakht
          • Bou Azer District (Bou Azzer District)
            • Oumlil
    U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486.
    Portugal
     
    • Guarda District
      • Sabugal
        • Bendada
    U. Kolitsch, D. Atencio, N. V. Chukanov, N. V. Zubkova, L. A. D. Menezes Filho, J. M. V. Coutinho, W. D. Birch, J. Schlüter, D. Pohl, A. R. Kampf, I. M. Steele, G. Favreau, L. Nasdala, S. Möckel, G. Giester and D. Yu. Pushcharovsky (2010): Bendadaite, a new iron arsenate mineral of the arthurite group. Mineral. Mag. 74, 469-486.
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