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Unnamed (Pb13O8(OH)6(NO3)4)

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Big Photo

Altemann Rock, Sehringen, Badenweiler Pb mining District, Badenweiler, Black Forest, Baden-Württemberg, Germany
© Stephan Wolfsried




Formula:
Pb
 
13
O
 
8
(OH)
 
6
(NO
 
3
)
 
4
System:Trigonal


Anthropogenic lead oxide hydroxide nitrate (formed on late medieval mine dumps due to the use of nitrate explosives).
Forms pseudo-octahedral colourless, white to pale yellowish crystals.
Often associated with Unnamed (Pb2(OH)3(NO3)).

According to Kolitsch and Tillmanns (2003), this phase is identical with "Pb6O3(OH)4(NO3)2" and "Pb3(OH)5(NO3)" reported in the literature.


Classification of Unnamed (Pb13O8(OH)6(NO3)4)

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Crystallography of Unnamed (Pb13O8(OH)6(NO3)4)

Crystal System:Trigonal
Class (H-M):3 - Rhombohedral
Space Group:R3
Cell Parameters:a = 10.263(1) Å, c = 25.454(5) Å
Ratio:a:c = 1 : 2.48
Unit Cell Volume:V 2321.9 ų
Comment:Data from Kolitsch & Tillmanns (2003); Li et al. (2001) give a = 10.283(1), c = 25.471(4) Å, V = 2331.6(5) Å3).

Chemical Properties of Unnamed (Pb13O8(OH)6(NO3)4)

Formula:
Pb
 
13
O
 
8
(OH)
 
6
(NO
 
3
)
 
4
Essential elements:H, N, O, Pb
All elements listed in formula:H, N, O, Pb

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Unnamed (Pb13O8(OH)6(NO3)4)

Reference List:

- +
Walenta, K. (1998) Neue Mineralfunde aus dem Schwarzwald. 7. Folge, 2. Teil. Lapis, 23 (12), 43-48. (in German)

Li, Y., Krivovichev, S.V. and Burns, P.C. (2001) Crystal chemistry of lead oxide hydroxide nitrates. II. The crystal structure of Pb13O8(OH)6(NO3)4. Journal of Solid State Chemistry, 158, 74-77.

U. Kolitsch and E. Tillmanns (2003): The crystal structure of anthropogenic Pb2(OH)3(NO3), and a review of Pb-(O,OH) clusters and lead nitrates. Mineral. Mag. 67, 79-93.

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    • Localities for Unnamed (Pb13O8(OH)6(NO3)4)

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Badenweiler
          • Badenweiler Pb mining District
            • Sehringen
    		Walenta, K. (1998) Neue Mineralfunde aus dem Schwarzwald. 7. Folge, 2. Teil. Lapis, 23 (12), 43-48. (in German); U. Kolitsch and E. Tillmanns (2003): The crystal structure of anthropogenic Pb2(OH)3(NO3), and a review of Pb-(O,OH) clusters and lead nitrates. Mineral. Mag. 67, 79-93.
    • North Rhine-Westphalia
      • Sauerland
        • Sundern
          • Bönkhausen
    		U. Kolitsch and E. Tillmanns (2003): The crystal structure of anthropogenic Pb2(OH)3(NO3), and a review of Pb-(O,OH) clusters and lead nitrates. Mineral. Mag. 67, 79-93.
    • Rhineland-Palatinate
      • Eifel Mts
        • Prüm
          • Bleialf
            • Neue Hoffnung Mine
    		Graf, H.-W. (1991) Die Grube "Neue Hoffnung" zu Bleialf/Eifel. Lapis, 16 (2), 13-18. (in German); U. Kolitsch and E. Tillmanns (2003): The crystal structure of anthropogenic Pb2(OH)3(NO3), and a review of Pb-(O,OH) clusters and lead nitrates. Mineral. Mag. 67, 79-93.
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