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Allendeite

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Formula:
Sc
 
4
Zr
 
3
O
 
12
System:Trigonal
Name:Named for Puebilito de Allende, Chihuahua, Mexico, where the Allende meteorite fell in 1969


Well-known as a synthetic compound.
Crystal structure is derived from the fluorite structure type.

Classification of Allendeite

IMA status:Approved 2007
Dana 8th edition ID:4.6.8.

4 : SIMPLE OXIDES
6 : Miscellaneous
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Type Occurrence of Allendeite

Type Locality:Allende meteorite (Pueblito de Allende meteorite; Qutrixpileo meteorite [NHM cat.]), Pueblito de Allende, Chihuahua, Mexico

Crystallography of Allendeite

Crystal System:Trigonal
Class (H-M):3 - Rhombohedral
Space Group:R3
Cell Parameters:a = 9.396Å, c = 8.72Å
Ratio:a:c = 1 : 0.928
Unit Cell Volume:V 666.70 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
4.698 (5)
2.900 (100)
2.513 (18)
1.779 (27)
1.776 (32)
1.515 (19)
1.450 (4)
1.152 (4)
(

Chemical Properties of Allendeite

Formula:
Sc
 
4
Zr
 
3
O
 
12
Essential elements:O, Sc, Zr
All elements listed in formula:O, Sc, Zr

Other Names for Allendeite

Synonyms:
IMA2007-027
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Allendeite

Reference List:

- +
Collongues, Robert; Qucyroux, Francine; Jorba, Monique Perez y; Gilles, Jean Claude (1965): Structure and properties of the compounds of rare earth oxides with oxides of the Group IV elements. Bulletin de la Societe Chimique de France 1965, 1141-1149.

Thornber, M. R.; Bevan, D. J. M.; Graham, J. (1968): Mixed oxides of the type MO2(fluorite)-M2O3. III. Crystal structures of the intermediate phases Zr5Sc2O13 and Zr3Sc4O12. Acta Crystallographica, B24, 1183-1190.

Rossell, H. J. (1976): Crystal structures of some fluorite-related M7O12 compounds. Journal of Solid State Chemistry 19, 103-111.

Magunov, R. L.; Shklyar, G. L.; Katridi, V. F. (1989): The phase diagrams of the zirconia (hafnia)-scandium sesquioxide systems. Izvestiya Akademii Nauk SSSR, Neorganicheskie Materialy 25, 1224-1226.

Red'ko, V. P.; Lopato, L. M. (1991): Crystal structure of rare earth zirconates M4Zr3O12 and hafnates M4Hf3O12 (M = rare earth). Neorganicheskie Materialy 27, 1905-1910.

Bevan, D. J. M.; Mohyla, J.; Wallwork, Kia S.; Rossell, H. J.; Schweda, Eberhard (2002): Structural principles for anion-deficient, fluorite-related superstructures in the zirconia-scandia system. Zeitschrift für Anorganische und Allgemeine Chemie 628, 1180-1186.

Stanek, C. R.; Jiang, C.; Uberuaga, B. P.; Sickafus, K. E.; Cleave, A. R.; Grimes, R. W. (2009): Predicted structure and stability of A4B3O12 delta-phase compositions. Physical Review B: Condensed Matter and Materials Physics 80, 174101/1-174101/11.

Ma, C., J.R.Beckett & G.R.Rossman (2009): Allendeite and hexamolybdenum: two new ultra-refractory minerals in Allende and two missing links. 40th Lunar and Planetary Science Conference and Abstracts, 1402 (2009)

Internet Links for Allendeite

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  • Localities for Allendeite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Mexico
     
    • Chihuahua
      • Pueblito de Allende
    IMA website - October 2007 approvals
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    Copyright © Jolyon Ralph and Ida Chau 1993-2011. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them. Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. Mindat does not offer minerals for sale. If you would like to add information to improve the quality of our database, then click here to register.
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