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Pseudo-autunite

Formula:
(H
 
3
O)
 
4
Ca
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
4
 · 5H
 
2
O (?)
System:OrthorhombicColour:pale yellow, white
Hardness:2 - 3


Fleischer noted that there is no evidence that alkalis or ammonium were looked for, and the hydronium formulation is therefore not proved.

Originally reported from North Karelia, Murmanskaja Oblast', Northern Region, Russia.

Classification of Pseudo-autunite

IMA status:Discredited
Strunz 8th edition ID:7/E.02-180

7 : Phosphates, Arsenates, Vanadates
E : Uranylphosphates and uranylvanadates with [UO2]2+ - [PO4 | AsO4]3- and [UO2]2+ - [V2O8]6-
02 : Meta-autunite group
Dana 8th edition ID:40.2a.1.3

40 : HYDRATED NORMAL PHOSPHATES,ARSENATES AND VANADATES
2a : AB2(XO4)2·xH2O, containing (UO2)2+
Hey's CIM Ref.:19.11.16

19 : Phosphates
11 : Phosphates of U
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Physical Properties of Pseudo-autunite

Colour:pale yellow, white
Streak:white
Hardness (Mohs):2 - 3
Cleavage:Perfect

Crystallography of Pseudo-autunite

Crystal System:Orthorhombic
Cell Parameters:a = 6.94Å, b = 6.94Å, c = 12.85Å
Ratio:a:b:c = 1 : 1 : 1.852
Unit Cell Volume:V 618.90 ų (Calculated from Unit Cell)

Optical Data of Pseudo-autunite

Type:Biaxial (-)
RI values: nα = 1.541 nβ = 1.568 nγ = 1.570
2V:Measured: 32° , Calculated: 30°
Maximum Birefringence:δ = 0.029

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:r > v strong

Chemical Properties of Pseudo-autunite

Formula:
(H
 
3
O)
 
4
Ca
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
4
 · 5H
 
2
O (?)
Essential elements:Ca, F, H, O, P, U
All elements listed in formula:Ca, H, O, P, U

Relationship of Pseudo-autunite to other Species

Member of Group:
Meta-autunite Group:
A(UO
 
2
)
 
2
(XO
 
4
)
 
2
·nH
 
2
O (n = 6, 7 or 8)
Related Minerals - Strunz Grouping):

- +
7/E.02-10Metanováčekite
Mg(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 4-8H
 
2
O
7/E.02-20Bassetite
Fe
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-30Metakahlerite
Fe
2+
 
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-40Lehnerite
Mn
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-50Metakirchheimerite
Co(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-60Metatorbernite
Cu(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-70Metazeunerite
Cu(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-80Metalodèvite
Zn(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 10H
 
2
O
7/E.02-90Meta-autunite
Ca(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6-8H
 
2
O
7/E.02-100Metauranospinite
Ca(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-110Metauranocircite
Ba(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 7H
 
2
O
7/E.02-120Metaheinrichite
Ba(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 8H
 
2
O
7/E.02-125Sodium Meta-autunite
Na
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6-8H
 
2
O
7/E.02-130Natrouranospinite
(Na
 
2
,Ca)(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 5H
 
2
O
7/E.02-140Meta-ankoleite
K
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
7/E.02-150Abernathyite
K
 
2
(UO
 
2
)
 
2
[AsO
 
4
]
 
2
 · 6H
 
2
O
7/E.02-160Uramphite
(NH
 
4
)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
7/E.02-165Uramarsite
(NH
 
4
,H
 
3
O)
 
2
(UO
 
2
)
 
2
[(AsO
 
4
,PO
 
4
)]
 
2
 · 6H
 
2
O
7/E.02-170Chernikovite
(H
 
3
O)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
7/E.02-190Ulrichite
CaCu(UO
 
2
)[PO
 
4
]
 
2
 · 4H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
19.11.1Lermontovite
UPO
 
4
·OH·H
 
2
O
19.11.2Metavanmeersscheite
U
4+
 
(UO
 
2
)
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 2H
 
2
O
19.11.3Vanmeersscheite
U
4+
 
(UO
 
2
)
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 4H
 
2
O
19.11.4Chernikovite
(H
 
3
O)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
19.11.5Vyacheslavite
UPO
 
4
(OH)·nH
 
2
O
19.11.6Metanatroautunite
NaUO
 
2
PO
 
4
·4H
 
2
O
19.11.7Yingjiangite
K
 
2
Ca(UO
 
2
)
 
7
(PO
 
4
)
 
4
(OH)
 
6
 · 6H
 
2
O
19.11.8Meta-ankoleite
K
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
19.11.9Uramphite
(NH
 
4
)
 
2
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 6H
 
2
O
19.11.10Torbernite
Cu(UO
 
2
)
 
2
(PO
 
4
)
 
2
·12H
 
2
O
19.11.11Metatorbernite
Cu(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
19.11.12Saléeite
Mg(UO
 
2
)
 
2
(PO
 
4
)
 
2
·10H
 
2
O
19.11.13Ningyoite
CaU(PO
 
4
)
 
2
·1-2H
 
2
O
19.11.14Meta-autunite
Ca(UO
 
2
)
 
2
[PO
 
4
]
 
2
· 6-8H
 
2
O
19.11.15Autunite
Ca(UO
 
2
)
 
2
(PO
 
4
)
 
2
·11H
 
2
O
19.11.17Phurcalite
Ca
 
2
(UO
 
2
)
 
3
[O|PO
 
4
]
 
2
 · 7H
 
2
O
19.11.18Phosphuranylite
(H
 
3
O)
 
3
KCa(UO
 
2
)
 
7
[O|PO
 
4
]
 
4
 · 8H
 
2
O
19.11.19Ulrichite
CaCu(UO
 
2
)[PO
 
4
]
 
2
 · 4H
 
2
O
19.11.20Bergenite
Ca
 
2
Ba
 
4
[(UO
 
2
)
 
3
O
 
2
(PO
 
4
)
 
2
]
 
3
·16H
 
2
O
19.11.21Metauranocircite
Ba(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 7H
 
2
O
19.11.22Uranocircite
Ba(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 10H
 
2
O
19.11.23Ranunculite
HAlUO
 
2
PO
 
4
(OH)
 
3
·4H
 
2
O
19.11.24Triangulite
Al
 
3
(UO
 
2
)
 
4
(PO
 
4
)
 
4
(OH)
 
5
·5H
 
2
O
19.11.25Mundite
Al(UO
 
2
)
 
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 5.5H
 
2
O
19.11.26Upalite
Al(UO
 
2
)
 
3
(PO
 
4
)
 
2
O(OH)·7H
 
2
O
19.11.27Furongite
Al
 
13
(UO
 
2
)
 
7
(PO
 
4
)
 
13
(OH)
 
14
 · 58H
 
2
O
19.11.28Threadgoldite
Al(UO
 
2
)
 
2
[OH|(PO
 
4
)
 
2
] · 8H
 
2
O
19.11.29Phuralumite
Al
 
2
(UO
 
2
)
 
3
[(OH)
 
2
|(PO
 
4
)
 
3
] · 13H
 
2
O
19.11.30Moreauite
Al
 
3
UO
 
2
(PO
 
4
)
 
3
(OH)
 
2
·13H
 
2
O
19.11.31Sabugalite
HAl(UO
 
2
)
 
4
(PO
 
4
)
 
4
·16H
 
2
O
19.11.32Uranospathite
Al
 
1-x
[]
 
x
)[(UO
 
2
)(PO
 
4
)]
 
2
(H
 
2
O)
 
20+3x
F
 
1-3x
, (0 < x < 0.33)
19.11.33Althupite
AlTh(UO
 
2
)
 
7
[O
 
2
|(OH)
 
5
|(PO
 
4
)
 
4
] · 15H
 
2
O
19.11.34Françoisite-(Nd)
(Nd,Ce,Sm)(UO
 
2
)
 
3
[O|OH|(PO
 
4
)
 
2
] · 6H
 
2
O
19.11.35Kivuite
H
 
2
Th(UO
 
2
)
 
3
[O|OH|(PO
 
4
)
 
2
] · 6H
 
2
O (?)
19.11.36Parsonsite
Pb
 
2
(UO
 
2
)[PO
 
4
]
 
2
 · 2H
 
2
O
19.11.37Dewindtite
Pb(UO
 
2
)
 
3
[OH|PO
 
4
]
 
2
 · 3H
 
2
O
19.11.38Dumontite
Pb
 
2
(UO
 
2
)
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 3H
 
2
O
19.11.39Przhevalskite
Pb
 
2
(UO
 
2
)
 
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 3H
 
2
O
19.11.40Lehnerite
Mn
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
19.11.41Bassetite
Fe
2+
 
(UO
 
2
)
 
2
[PO
 
4
]
 
2
 · 8H
 
2
O
19.11.42Vochtenite
(Fe
2+
 
,Mg)Fe
3+
 
(UO
 
2
)
 
4
[OH|(PO
 
4
)
 
4
] · 12-13H
 
2
O

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Pseudo-autunite

Reference List:American Mineralogist (1965): 50: 1505.

Mineralogiya I Geokhimiya (Mineralogy and Geochemistry), Leningrad University, Sbornik statey: 1: 31-39.

Internet Links for Pseudo-autunite

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    Localities for Pseudo-autunite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
    		Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Mineral and/or Locality
    Google
     
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