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Quadruphite

Formula:
Na
 
14
Ca
 
2
Ti
 
4
[O
 
2
|F|(PO
 
4
)
 
2
|Si
 
2
O
 
7
]
 
2
System:TriclinicColour:Light brown
Name:The name is derived from the number of phosphate groups in the formula (QUADR = four) and in allusion to it being a PHosphate.


Epistolite Group.

Classification of Quadruphite

IMA status:Approved
Strunz 8th edition ID:8/C.0-90
Nickel-Strunz 10th (pending) edition ID:9.BE.45

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
Dana 8th edition ID:56.4.1.3

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
4 : Si2O7 Groups and O, OH, F, and H2O with [Si2O7] with other cation groups
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Type Occurrence of Quadruphite

Type Locality:Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1992

Physical Properties of Quadruphite

Lustre:Vitreous, Pearly
Diaphaneity (Transparency):Translucent
Colour:Light brown

Crystallography of Quadruphite

Crystal System:Triclinic
Cell Parameters:a = 5.41Å, b = 7.08Å, c = 20.34Å
α = 86.85°, β = 94.4°, γ = 89.94°
Ratio:a:b:c = 0.764 : 1 : 2.873
Unit Cell Volume:V 775.60 ų (Calculated from Unit Cell)

Chemical Properties of Quadruphite

Formula:
Na
 
14
Ca
 
2
Ti
 
4
[O
 
2
|F|(PO
 
4
)
 
2
|Si
 
2
O
 
7
]
 
2
Essential elements:Ca, F, Mg, Na, O, P, Si, Ti
All elements listed in formula:Ca, F, Na, O, P, Si, Ti
Common Impurities:Sr,Ba,Mn,Fe,Zr,Nb

Relationship of Quadruphite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.BE.02Wadsleyite
(Mg,Fe
2+
 
)
 
2
[SiO
 
4
]
9.BE.05Hennomartinite
SrMn
3+
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Lawsonite
CaAl
 
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Noelbensonite
BaMn
3+
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Itoigawaite
SrAl
 
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.07Ilvaite
CaFe
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.07Manganilvaite
Ca(Mn
2+
 
,Fe
2+
 
)
 
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.10Suolunite
Ca
 
2
[H
 
2
Si
 
2
O
 
7
] · H
 
2
O
9.BE.12Jaffeite
Ca
 
6
[(OH)
 
6
|Si
 
2
O
 
7
]
9.BE.15Fresnoite
Ba
 
2
Ti[O|Si
 
2
O
 
7
]
9.BE.17Baghdadite
Ca
 
3
(Zr,Ti)[O
 
2
|Si
 
2
O
 
7
]
9.BE.17Burpalite
Na
 
2
CaZr[F
 
2
|Si
 
2
O
 
7
]
9.BE.17Cuspidine
Ca
 
4
[(F,OH)
 
2
|Si
 
2
O
 
7
]
9.BE.17Hiortdahlite
(Ca,Na)
 
3
(Zr,Ti)Si
 
2
O
 
7
(O,OH,F)
 
2
9.BE.17Janhaugite
(Na,Ca)
 
3
(Mn,Fe)
 
3
(Ti,Zr,Nb)
 
2
Si
 
4
O
 
15
(OH,F,O)
 
3
9.BE.17Låvenite
(Na,Ca)
 
2
(Mn
2+
 
,Fe
2+
 
)(Zr,Ti)[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Niocalite
(Ca,Nb)
 
4
[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Normandite
NaCa(Mn,Fe)(Ti,Nb,Zr)[(O,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Wöhlerite
NaCa
 
2
(Zr,Nb)[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Hiortdahlite I
(Na
 
3
Ca)Ca
 
8
Zr
 
2
(M
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
4
O
 
3
F
 
5
9.BE.17IMA2005-005a
Na
 
2
Ca
 
4
(Nb,Zr)
 
2
[(O,F)
 
2
|Si
 
2
O
 
7
]
 
2
9.BE.20Mosandrite
(Ca,Na,Ce)
 
12
(Ti,Zr)
 
2
[F
 
4
|(OH)
 
6
|SiO
 
4
|(Si
 
2
O
 
7
)
 
3
]
9.BE.20Nacareniobsite-(Ce)
Na
 
3
Ca
 
3
(Ce,La,Nd)Nb[F
 
3
|O|(Si
 
2
O
 
7
)
 
2
]
9.BE.20Rinkite
Na(Na,Ca)
 
2
(Ca,Ce)
 
4
Ti[F
 
2
|(O,F)
 
2
|(Si
 
2
O
 
7
)
 
2
]
9.BE.22Götzenite
Na
 
2
Ca
 
5
Ti[F
 
4
|(Si
 
2
O
 
7
)
 
2
]
9.BE.22Hainite
Na
 
4
Ca
 
8
(Ti,Zr,Mn)
 
3
[F
 
4
|(Si
 
2
O
 
7
)
 
2
]
 
2
9.BE.22Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)[O|F|Si
 
2
O
 
7
]
9.BE.22Kochite
(Na,Ca)
 
3
Ca
 
2
(Mn,Ca)ZrTi[(F,O)
 
4
|(Si
 
2
O
 
7
)
 
2
]
9.BE.23Dovyrenite
Ca
 
6
Zr(Si
 
2
O
 
7
)
 
2
(OH)
 
4
9.BE.25Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
[O|(OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Ericssonite
BaMn
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.25Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
[O|(O,OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Orthoericssonite
BaMn
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.25Seidozerite
Na
 
8
Zr
 
3
Ti
 
3
Mn
2+
2
[O|F|Si
 
2
O
 
7
]
 
4
9.BE.25Nabalamprophyllite
Na
 
3
(Ba,Na)
 
2
Ti
 
3
[O|(OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Grenmarite
(Zr,Mn)
 
2
(Zr,Ti)(Mn,Na)(Na,Ca)
 
4
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.27Murmanite
Na
 
2
(Ti,Nb)
 
2
Si
 
2
O
 
9
·nH
 
2
O
9.BE.30Epistolite
Na
 
2
(Nb,Ti)
 
2
[O
 
2
|Si
 
2
O
 
7
] · nH
 
2
O
9.BE.32Lomonosovite
Na
 
5
Ti
 
2
[O
 
2
|PO
 
4
|Si
 
2
O
 
7
]
9.BE.35Vuonnemite
Na
 
11
Ti
4+
 
Nb
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
3
(F,OH)
9.BE.37Sobolevite
Na
 
12
Ca(NaCaMn)Ti
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
4
O
 
3
F
 
3
9.BE.40Innelite
Na
 
2
(Ba,K)
 
4
(Mg,Ca,Fe)Ti
 
3
Si
 
4
O
 
18
(OH,F)
 
1.5
SO
 
4
9.BE.40Phosphoinnelite
Ba
 
4
Na
 
3
Ti
 
3
[(O,F)
 
3
|(PO
 
4
,SO
 
4
)
 
2
|Si
 
4
O
 
14
]
9.BE.42Yoshimuraite
Ba
 
2
Mn
 
2
TiOSi
 
2
O
 
7
(PO
 
4
)(OH)
9.BE.47Polyphite
Na
 
5
(Na
 
4
Ca
 
2
)Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)
 
3
O
 
2
F
 
2
9.BE.50Bornemanite
BaNa
 
4
Ti
 
2
NbSi
 
4
O
 
17
(F,OH)·Na
 
3
PO
 
4
9.BE.50Shkatulkaite
Na
 
10
Mn
2+
 
Ti
 
3
Nb
 
3
[(OH)
 
2
|F|(Si
 
2
O
 
7
)
 
6
] · 12H
 
2
O
9.BE.50Shkatulkalite
9.BE.50Bykovaite
BaNa(Na,Ti)
 
4
[(OH,F)
 
2
|(Ti,Nb)
 
2
Si
 
4
O
 
14
(O,OH)
 
3
] · 3H
 
2
O
9.BE.55Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti[O|(O,OH)
 
2
|Si
 
2
O
 
7
]
9.BE.55Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti[O|(OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.55Nechelyustovite
(Ba,Na)
 
2
{(Na,Ti,Mn)
 
4
[(Ti,Nb)
 
2
(OH)
 
3
Si
 
4
O
 
14
](OH,O,F)
 
2
} · 3H
 
2
O
9.BE.60Delindeite
(Na,K)
 
2.7
(Ba,Ca)
 
4
(Ti,Fe,Al)
 
6
Si
 
8
O
 
26
(OH)
 
14
9.BE.65Bussenite
Na
 
2
Ba
 
2
FeTiSi
 
2
O
 
7
(CO
 
3
)(OH)
 
3
F
9.BE.67Jinshajiangite
(Na,Ca)(Ba,K)(Fe,Mn)
 
4
Ti
 
2
Si
 
4
O
 
16
(F,O,OH)
 
2-3
9.BE.67Perraultite
(Na,Ca)(Ba,K)(Mn,Fe)
 
4
(Ti,Nb)
 
2
Si
 
4
O
 
16
(OH,F,O)
 
3
9.BE.67Surkhobite
(Ba,K)
 
2
CaNaMn
 
8
Ti
 
4
(Si
 
2
O
 
7
)
 
4
O
 
4
(F,OH,O)
 
6
9.BE.70Karnasurtite-(Ce)
(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si,P)
 
2
O
 
7
(OH)
 
4
·3H
 
2
O
9.BE.70Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Mg,Fe
2+
 
)
 
2
(Ti,Fe
3+
 
)
 
3
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
3+
 
(Ti,Zr)
 
2
Ti
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Chevkinite-(Ce)
(Ce,La,Ca,Na,Th)
 
4
(Fe
2+
 
,Mg)(Fe
3+
 
,Ti,Fe
2+
 
)
 
2
(Ti,Fe
3+
 
,Nb)
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Polyakovite-(Ce)
(Ce,Ca)
 
4
(Mg,Fe
2+
 
)(Cr
3+
 
,Fe
3+
 
)
 
2
(Ti,Nb)
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Rengeite
Sr
 
4
ZrTi
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Matsubaraite
Sr
 
4
Ti
 
5
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Dingdaohengite-(Ce)
Ce
 
4
Fe
2+
 
Ti
 
2
Ti
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Maoniupingite-(Ce)
(REE,Ca)
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,[])(Ti,Fe
3+
 
,Fe
2+
 
,Nb)
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Perrierite-(La)
(La,Ce, Ca)
 
4
(Fe,Mn
2+
 
,Mg)(Ti,Fe)
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.72Fersmanite
(Ca,Na)
 
4
(Ti,Nb)
 
2
Si
 
2
O
 
11
(F,OH)
 
2
9.BE.75Belkovite
Ba
 
3
(Nb,Ti)
 
6
[O
 
6
|Si
 
2
O
 
7
]
 
2
9.BE.77Nasonite
Pb
 
6
Ca
 
4
[Cl
 
2
|(Si
 
2
O
 
7
)
 
3
]
9.BE.80Kentrolite
Pb
 
2
Mn
3+
2
[O
 
2
|Si
 
2
O
 
7
]
9.BE.80Melanotekite
Pb
 
2
Fe
3+
2
[O
 
2
|Si
 
2
O
 
7
]
9.BE.82Tilleyite
Ca
 
5
[(CO
 
3
)
 
2
|Si
 
2
O
 
7
]
9.BE.85Killalaite
Ca
 
3
[Si
 
2
O
 
7
] · 0.5H
 
2
O
9.BE.87Stavelotite-(La)
(La,Nd,Ca)
 
3
Mn
2+
3
Cu(Mn
3+
 
,Fe
3+
 
,Mn
4+
 
)
 
26
[O
 
5
|Si
 
2
O
 
7
]
 
6
9.BE.90Biraite-(Ce)
Ce
 
2
Fe
2+
 
[CO
 
3
|Si
 
2
O
 
7
]

Other Names for Quadruphite

German names:
Quadruphit
Russian names:
Квадруфит
Spanish names:
Quadruphita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Quadruphite

Reference List:Mineralogicheskiy Zhurnal (1987): 9(3): 28.

Khomyakov, A.P., Nechelyustov, G.N., Sokolova, EV., and Dorokhova, G.I. (1992) Quadruphite Na14CaMgTi4[Si2O7]2[PO4]4O4F2 and polyphite Na17Ca3Mg(Ti,Mn)4[Si2O7]2[PO4]6O2F6 - new minerals of the lomonosovite family. Zapiski Vserossiskogo Mineralogicheskogo Obshchetstva (1992): 121(1): 105-112 (in Russian).


New Minerals (1997), New Minerals 1990-1994.

Canadian Mineralogist (2001): 39: 1275.

Sokolova, E., Hawthorne, F.C., Khomyakov, A.P. (2005): Polyphite and sobolevite: revision of their crystal structures. Canadian Mineralogist: 43: 1527-1544.

Internet Links for Quadruphite

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    Localities for Quadruphite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
    		ZVMO,(1992) 121, n1, 105-112; www.koeln.netsurf.de/~w.steffens/lovo.htm
    Mineral and/or Locality
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