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Sayrite

Formula:
Pb
 
2
(UO
 
2
)
 
5
O
 
6
(OH)
 
2
·4H
 
2
O
System:MonoclinicColour:Orange
Name:Named after David Sayre (b 1924) , crystallographer, IBM Corporation, USA.
This page provides mineralogical data about Sayrite.

Classification of Sayrite

IMA status:Approved
Strunz 8th edition ID:4/H.07-40
Nickel-Strunz 10th (pending) edition ID:4.GB.50

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
G : Uranyl Hydroxides
B : With additional cations (K, Ca, Ba, Pb, etc.); with mainly UO2(O,OH)5 pentagonal polyhedra
Dana 8th edition ID:5.9.6.1

5 : OXIDES CONTAINING URANIUM OR THORIUM
9 : Miscellaneous
Hey's CIM Ref.:7.16.30

7 : Oxides and Hydroxides
16 : Oxides of U
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Type Occurrence of Sayrite

Type Locality:Shinkolobwe Mine (Kasolo Mine), Shinkolobwe, Central area, Katanga Copper Crescent, Katanga (Shaba), Democratic Republic of Congo (Zaïre)
Year of Discovery:1983

Physical Properties of Sayrite

Colour:Orange

Crystallography of Sayrite

Crystal System:Monoclinic
Cell Parameters:a = 10.7Å, b = 6.96Å, c = 14.53Å
β = 116.81°
Ratio:a:b:c = 1.537 : 1 : 2.088
Unit Cell Volume:V 965.76 ų (Calculated from Unit Cell)

Optical Data of Sayrite

Type:Biaxial (-)
Dispersion:relatively weak

Chemical Properties of Sayrite

Formula:
Pb
 
2
(UO
 
2
)
 
5
O
 
6
(OH)
 
2
·4H
 
2
O
Essential elements:H, O, Pb, U
All elements listed in formula:H, O, Pb, U

Relationship of Sayrite to other Species

Related Minerals - Nickel-Strunz Grouping):
4.GB.05Agrinierite
K
 
2
(Ca,Sr)(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 5H
 
2
O
4.GB.05Compreignacite
K
 
2
(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 7H
 
2
O
4.GB.05Rameauite
K
 
2
Ca(UO
 
2
)
 
6
(OH)
 
16
 · H
 
2
O
4.GB.10Becquerelite
Ca(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 8H
 
2
O
4.GB.10Billietite
Ba(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 4-8H
 
2
O
4.GB.10Protasite
Ba(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
4.GB.15Richetite
PbU
 
4
O
 
13
·4H
 
2
O
4.GB.20Bauranoite
Ba(UO
 
2
)
 
2
(OH)
 
6
 · 1-2H
 
2
O
4.GB.20Calciouranoite
(Ca,Ba,Pb)U
 
2
O
 
7
·5H
 
2
O
4.GB.20Metacalciouranoite
(Ca,Ba,Na
 
2
)U
 
2
O
 
7
·2H
 
2
O
4.GB.25Fourmarierite
PbU
 
4
O
 
13
·4H
 
2
O
4.GB.30Wölsendorfite
(Pb,Ca)U
 
2
O
 
7
·2H
 
2
O
4.GB.35Masuyite
Pb(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
4.GB.40Metavandendriesscheite
PbU
 
7
O
 
22
·nH
 
2
O n < 12
4.GB.40Vandendriesscheite
PbU
 
7
O
 
22
·12H
 
2
O
4.GB.45Vandenbrandeite
Cu(UO
 
2
)(OH)
 
4
4.GB.55Curite
Pb
 
3
(UO
 
2
)
 
8
O
 
8
(OH)
 
6
·2H
 
2
O
4.GB.60Iriginite
UO
 
2
Mo
 
2
O
 
7
·3H
 
2
O
4.GB.65Uranosphaerite
Bi(UO
 
2
)O
 
2
(OH)
4.GB.70Holfertite
Ca
 
x
U
6+
2-x
Ti(O
 
8-x
OH
 
4x
) · 3H
 
2
O
Related Minerals - Hey's Index Grouping:
7.16.1Uraninite
UO
 
2
7.16.2Schoepite
(UO
 
2
)
 
8
O
 
2
(OH)
 
12
 · 12H
 
2
O
7.16.3Paraschoepite
UO
 
3
 · 2H
 
2
O
7.16.4Metaschoepite
UO
 
3
 · 1-2H
 
2
O
7.16.5Metastudtite
UO
 
4
 · 2H
 
2
O
7.16.6Studtite
UO
 
4
 · 4H
 
2
O
7.16.7Ianthinite
U
4+
 
(UO
 
2
)
 
5
O
 
7
 · 10H
 
2
O
7.16.8Compreignacite
K
 
2
(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 7H
 
2
O
7.16.9Vandenbrandeite
Cu(UO
 
2
)(OH)
 
4
7.16.10Roubaultite
Cu
 
2
(UO
 
2
)
 
3
(OH)
 
10
 · 5H
 
2
O
7.16.11Becquerelite
Ca(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 8H
 
2
O
7.16.12Rameauite
K
 
2
Ca(UO
 
2
)
 
6
(OH)
 
16
 · H
 
2
O
7.16.13Agrinierite
K
 
2
(Ca,Sr)(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 5H
 
2
O
7.16.14Protasite
Ba(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
7.16.15Billietite
Ba(UO
 
2
)
 
6
O
 
4
(OH)
 
6
 · 4-8H
 
2
O
7.16.16Bauranoite
Ba(UO
 
2
)
 
2
(OH)
 
6
 · 1-2H
 
2
O
7.16.17Metacalciouranoite
(Ca,Ba,Na
 
2
)U
 
2
O
 
7
·2H
 
2
O
7.16.18Calciouranoite
(Ca,Ba,Pb)U
 
2
O
 
7
·5H
 
2
O
7.16.19Orthobrannerite
UTi
 
4
O
 
12
(OH)
 
2
7.16.20Thorutite
(Th,U,Ca)Ti
 
2
(O,OH)
 
6
7.16.21Davidite-(La)
(La,Ce)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.22Davidite-(Ce)
(Ce,La)(Y,U,Fe)(Ti,Fe)
 
20
(O,OH)
 
38
7.16.23Brannerite
(U
4+
 
,Ca)(Ti,Fe
3+
 
)
 
2
O
 
6
7.16.24Fourmarierite
PbU
 
4
O
 
13
·4H
 
2
O
7.16.25Richetite
PbU
 
4
O
 
13
·4H
 
2
O
7.16.26Curite
Pb
 
3
(UO
 
2
)
 
8
O
 
8
(OH)
 
6
·2H
 
2
O
7.16.27Masuyite
Pb(UO
 
2
)
 
3
O
 
3
(OH)
 
2
 · 3H
 
2
O
7.16.28Vandendriesscheite
PbU
 
7
O
 
22
·12H
 
2
O
7.16.29Metavandendriesscheite
PbU
 
7
O
 
22
·nH
 
2
O n < 12
7.16.31Wölsendorfite
(Pb,Ca)U
 
2
O
 
7
·2H
 
2
O
7.16.32Clarkeite
(Na,Ca,Pb)
 
2
U
 
2
(O,OH)
 
7
7.16.33Uranosphaerite
Bi(UO
 
2
)O
 
2
(OH)

Other Names for Sayrite

Synonyms:
IMA1982-050
German names:
Sayrit
Russian names:
Сэйрит
Spanish names:
Sayrita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Sayrite

Reference List:Piret, P., Deliens, M., Piret-Meunier, J., and Germain, G. (1983) La sayrite, Pb2[(UO2)5O6(OH)2]·4H2O, noveau minéral; propriétés et structure cristalline. Bulletin de la Société française de Minéralogie et de Cristallographie: 106: 299-304.

American Mineralogist (1984): 69: 568.

Burns, P.C. (2005) U 6+ minerals and inorganic compounds: insights into an expanded structural hierarchy of crystal structures. Canadian Mineralogist: 43: 1839-1894.

Internet Links for Sayrite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Sayrite in the Natural History Museum (London) online catalogue
  • Sayrite details from Handbook of Mineralogy (PDF)
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    Localities for Sayrite

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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Democratic Republic of Congo (Zaïre)
     
    • Katanga (Shaba)
      • Katanga Copper Crescent
        • Central area
          • Shinkolobwe
    		Bull.Minéral.(1983) 106, 299-304
    Mineral and/or Locality
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