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Shafranovskite

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Formula:
(Na,K)
 
6
(Mn,Fe)
 
3
Si
 
9
O
 
24
· 6H
 
2
O
System:TrigonalColour:Dark green to olive-green
Hardness:2 - 3
Name:Named after Ilarion Ilarionovich Shafranovsky (b. 1907), Russian, Professor of mineralogy and crystallography.
This page provides mineralogical data about Shafranovskite.

Classification of Shafranovskite

IMA status:Approved
Strunz 8th edition ID:8/D.16-20
Nickel-Strunz 10th (pending) edition ID:9.EE.65

9 : SILICATES (Germanates)
E : Phyllosilicates
E : Single tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bands
Dana 8th edition ID:78.3.2.1

78 : Unclassified Silicates
3 :
Hey's CIM Ref.:14.18.5

14 : Silicates not Containing Aluminum
18 : Silicates of Mn and Na, K, Mg, Ca or Fe
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Type Occurrence of Shafranovskite

Co-type Localities:Rasvumchorr Mt, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Yubileinaya (Yubileinoye; Jubilejnaja) pegmatite, Karnasurt Mt, Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1982
Geological Setting of type material:A sodalite-nepheline-aegirine-microcline vein in urtite

Physical Properties of Shafranovskite

Lustre:Vitreous
Diaphaneity (Transparency):Translucent
Comment:Vitreous to tarnished
Colour:Dark green to olive-green
Comment:Alters to greenish yellow, then to ochre-yellow
Streak:Green to yellow
Hardness (Mohs):2 - 3
Cleavage:Perfect
on (0001)

Crystallography of Shafranovskite

Crystal System:Trigonal
Cell Parameters:a = 14.58Å, c = 21.01Å
Ratio:a:c = 1 : 1.441
Unit Cell Volume:V 3,867.87 ų (Calculated from Unit Cell)
Morphology:Aggregates (up to 5mm in diameter of olive-green equant grains (up to 0.,1 mm)

Optical Data of Shafranovskite

Type:Uniaxial (-)
RI values: nω = 1.587 nε = 1.570
Maximum Birefringence:δ = 0.017

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low

Chemical Properties of Shafranovskite

Formula:
(Na,K)
 
6
(Mn,Fe)
 
3
Si
 
9
O
 
24
· 6H
 
2
O
Essential elements:H, Mn, Na, O, Si
All elements listed in formula:Fe, H, K, Mn, Na, O, Si
Common Impurities:Ti,Al,Mg,Ca

Relationship of Shafranovskite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.EE.05Bementite
Mn
 
5
Si
 
4
O
 
10
(OH)
 
6
9.EE.10Brokenhillite
Mn
 
8
Si
 
6
O
 
15
(OH)
 
10
9.EE.10Pyrosmalite-(Fe)
(Fe,Mn)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Friedelite
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Pyrosmalite-(Mn)
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Mcgillite
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH)
 
8
Cl
 
2
9.EE.15Nelenite
(Mn,Fe)
 
16
(Si
 
12
O
 
30
)(OH)
 
14
[As
3+
3
O
 
6
(OH)
 
3
]
9.EE.15Schallerite
(Mn,Fe)
 
16
Si
 
12
As
 
3
O
 
36
(OH)
 
17
9.EE.20Palygorskite
(Mg,Al)
 
5
(Si,Al)
 
8
O
 
20
(OH)
 
2
· 8H
 
2
O
9.EE.20Tuperssuatsiaite
Na
 
2
Fe
 
3
Si
 
8
O
 
20
(OH)
 
2
· 4H
 
2
O
9.EE.20Yofortierite
Mn
 
5
Si
 
8
O
 
20
(OH)
 
2
· 8-9H
 
2
O
9.EE.25Falcondoite
(Ni,Mg)
 
4
Si
 
6
O
 
15
(OH)
 
2
· 6H
 
2
O
9.EE.25Loughlinite
Na
 
2
Mg
 
3
Si
 
6
O
 
16
· 8H
 
2
O
9.EE.25Sepiolite
Mg
 
4
(Si
 
6
O
 
15
)(OH)
 
2
· 6H
 
2
O
9.EE.25Kalifersite
(K,Na)
 
5
Fe
3+
7
Si
 
20
O
 
50
(OH)
 
6
· 12H
 
2
O
9.EE.30Gyrolite
Ca
 
4
(Si
 
6
O
 
15
)(OH)
 
2
· 3H
 
2
O
9.EE.30Orlymanite
Ca
 
4
Mn
 
3
Si
 
8
O
 
20
(OH)
 
6
· 2H
 
2
O
9.EE.30Tungusite
Ca
 
4
Fe
 
2
Si
 
6
O
 
15
(OH)
 
6
9.EE.35Reyerite
(Na,K)
 
2
Ca
 
14
(Si,Al)
 
24
O
 
58
(OH)
 
8
· 6H
 
2
O
9.EE.35Truscottite
(Ca,Mn)
 
14
Si
 
24
O
 
58
(OH)
 
8
· 2H
 
2
O
9.EE.40Natrosilite
Na
 
2
Si
 
2
O
 
5
9.EE.45Makatite
Na
 
2
Si
 
4
O
 
8
(OH)
 
2
· 4H
 
2
O
9.EE.50Varennesite
Na
 
8
Mn
 
2
Si
 
10
O
 
25
(OH,Cl)
 
2
· 12H
 
2
O
9.EE.55Raite
Na
 
4
Mn
2+
3
Ti
 
0.25
Si
 
8
O
 
20
(OH)
 
2
· 10H
 
2
O
9.EE.60Intersilite
Na
 
6
Mn
2+
 
Ti[Si
 
10
O
 
24
(OH)](OH)
 
3
· 4H
 
2
O
9.EE.65Zakharovite
Na
 
4
Mn
 
5
Si
 
10
O
 
24
(OH)
 
6
· 6H
 
2
O
9.EE.70Zeophyllite
Ca
 
4
Si
 
3
O
 
8
(OH,F)
 
4
· 2H
 
2
O
9.EE.75Minehillite
(K,Na)
 
2-3
Ca
 
28
Zn
 
4
Al
 
4
Si
 
40
O
 
112
(OH)
 
16
9.EE.80Fedorite
(Na,K)
 
2-3
(Ca
 
4
Na
 
3
)Si
 
16
O
 
38
F
 
2
· 3.5H
 
2
O
9.EE.80Martinite
(Na,Ca)
 
11
Ca
 
4
(Si,S,B)
 
14
B
 
2
O
 
40
F
 
2
·4H
 
2
O
9.EE.85Lalondeite
(Na,Ca)
 
6
(Ca,Na)
 
3
Si
 
16
O
 
38
(F,OH)
 
2
·3H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
14.18.1Nambulite
(Li,Na)Mn
 
4
Si
 
5
O
 
14
(OH)
14.18.2Natronambulite
(Na,Li)(Mn,Ca)
 
4
Si
 
5
O
 
14
OH
14.18.3Zakharovite
Na
 
4
Mn
 
5
Si
 
10
O
 
24
(OH)
 
6
· 6H
 
2
O
14.18.4Norrishite
KLiMn
3+
2
(Si
 
4
O
 
10
)O
 
2
14.18.6Abswurmbachite
CuMn
3+
6
(SiO
 
4
)O
 
8
14.18.7Donpeacorite
(Mn
2+
 
,Mg)Mg[SiO
 
3
]
 
2
14.18.8Kanoite
Mn
2+
 
(Mg,Mn
2+
 
)Si
 
2
O
 
6
14.18.9Caryopilite
(Mn,Mg)
 
3
(Si
 
2
O
 
5
)(OH)
 
4
14.18.10Gonyerite
(Mn
2+
 
,Mg)
 
5
Fe
3+
 
(Fe
3+
 
Si
 
3
O
 
10
)(OH)
 
8
14.18.11 Tirodite
14.18.12Manganhumite
(Mn
2+
 
,Mg)
 
7
(SiO
 
4
)
 
3
(OH)
 
2
14.18.13Bustamite
CaMn
2+
 
(Si
 
2
O
 
6
)
14.18.14Glaucochroite
CaMn
2+
 
SiO
 
4
14.18.15Truscottite
(Ca,Mn)
 
14
Si
 
24
O
 
58
(OH)
 
8
· 2H
 
2
O
14.18.16Santaclaraite
CaMn
 
4
[Si
 
5
O
 
14
OH](OH) · H
 
2
O
14.18.17Ferrobustamite
Ca(Fe
2+
 
,Ca,Mn
2+
 
)(Si
 
2
O
 
6
)
14.18.18Johannsenite
CaMn
2+
 
Si
 
2
O
 
6
14.18.19Neltnerite
CaMn
3+
6
(SiO
 
4
)O
 
8
14.18.20Orlymanite
Ca
 
4
Mn
 
3
Si
 
8
O
 
20
(OH)
 
6
· 2H
 
2
O
14.18.21Inesite
Ca
 
2
(Mn,Fe)
 
7
Si
 
10
O
 
28
(OH)
 
2
· 5H
 
2
O
14.18.22Orientite
Ca
 
2
Mn
2+
 
Mn
3+
2
(Si
 
3
O
 
10
)(OH)
 
4
14.18.23Ruizite
Ca
 
2
Mn
3+
2
[(OH)
 
2
|H
 
2
Si
 
4
O
 
13
] · 2H
 
2
O
14.18.24Bostwickite
CaMn
 
6
Si
 
3
O
 
16
· 7H
 
2
O
14.18.25Kittatinnyite
Ca
 
2
Mn
 
2
Mn(SiO
 
4
)
 
2
(OH)
 
4
· 9H
 
2
O
14.18.26Lithiomarsturite
LiCa
 
2
Mn
 
2
Si
 
5
O
 
14
(OH)
14.18.27Sérandite
Na(Mn
2+
 
,Ca)
 
2
(HSi
 
3
O
 
9
)
14.18.28Kvanefjeldite
Na
 
4
(Ca,Mn)(Si
 
3
O
 
7
)
 
2
(OH)
 
2
14.18.29Marsturite
NaCaMn
 
3
Si
 
5
O
 
14
(OH)
14.18.30Raite
Na
 
4
Mn
2+
3
Ti
 
0.25
Si
 
8
O
 
20
(OH)
 
2
· 10H
 
2
O
14.18.31Richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
14.18.32Byelorussite-(Ce)
NaBa
 
2
Ce
 
2
MnTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(F,OH) · H
 
2
O
14.18.33Deerite
(Fe,Mn)
 
6
(Fe,Al)
 
3
[Si
 
6
O
 
17
]O
 
3
(OH)
 
5
14.18.34Calderite
(Mn
2+
 
,Ca)
 
3
(Fe
3+
 
,Al)
 
2
(SiO
 
4
)
 
3
14.18.35Pyroxmangite
MnSiO
 
3
14.18.36Dannemorite
14.18.37Neotocite
(Mn,Fe,Mg)SiO
 
3
· H
 
2
O
14.18.38Babingtonite
Ca
 
2
(Fe,Mn)FeSi
 
5
O
 
14
(OH)
14.18.39Manganbabingtonite
Ca
 
2
(Mn,Fe)FeSi
 
5
O
 
14
(OH)
14.18.40Örebroite
Mn
2+
3
(Fe
3+
 
,Sb
5+
 
)(SiO
 
4
)(O,OH)
 
3

Other Names for Shafranovskite

Synonyms:
IMA1981-048
Other Languages:
German:Shafranovskit
Russian:Шафрановскит
Spanish:Shafranovskita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Shafranovskite

Reference List:

- +
American Mineralogist (1983): 68: 644.

Krivovichev, S.V., Yakovenchuk, V.N., Armbruster, Th., Pakhomovsky, Y.A., Weber, H.-P., Depmeier, W. (2004): Synchrotron X-ray diffraction study of the structure of shafranovskite, K2Na3(Mn,Fe,Na)4 [Si9(O,OH)27](OH)2·nH2O, a rare manganese phyllosilicate from the Kola peninsula, Russia. The American Mineralogist, 89, 1816-1821.

-

Internet Links for Shafranovskite

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  • Localities for Shafranovskite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
          • Lovozero Massif
            • Karnasurt Mt
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
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