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Sigloite

Big Photo

Potosí Department, Bolivia
© 2005 - MMI

Show Sigloite Photos (3)
Formula:
Fe
3+
 
Al
 
2
[(OH)
 
3
|(PO
 
4
)
 
2
] · 7H
 
2
O
System:TriclinicColour:Light brown, straw-yellow
Hardness:3
Name:Named after its discovery locality, the Siglo Veinte Mine (Siglo XX Mine), Llallagua, Bustillos Province, Potosí Department, Bolivia.


Paravauxite Group.

Classification of Sigloite

IMA status:Approved
Strunz 8th edition ID:7/D.10-40
Nickel-Strunz 10th (pending) edition ID:8.DC.30

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
Dana 8th edition ID:42.11.14.3

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Hey's CIM Ref.:19.14.26

19 : Phosphates
14 : Phosphates of Fe and other metals
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Type Occurrence of Sigloite

Type Locality:Siglo Veinte Mine (Siglo XX Mine; Llallagua Mine; Catavi), Llallagua, Bustillos Province, Potosí Department, Bolivia
Year of Discovery:1962

Physical Properties of Sigloite

Colour:Light brown, straw-yellow
Hardness (Mohs):3

Crystallography of Sigloite

Crystal System:Triclinic
Cell Parameters:a = 5.26Å, b = 10.52Å, c = 7.06Å
α = 106.97°, β = 111.5°, γ = 69.5°
Ratio:a:b:c = 0.5 : 1 : 0.671
Unit Cell Volume:V 334.42 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Sigloite

Type:Biaxial (+)
RI values: nα = 1.563 nβ = 1.586 nγ = 1.619
2V:Measured: 76° , Calculated: 82°
Maximum Birefringence:δ = 0.056

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:strong

Chemical Properties of Sigloite

Formula:
Fe
3+
 
Al
 
2
[(OH)
 
3
|(PO
 
4
)
 
2
] · 7H
 
2
O
Essential elements:Al, Fe, H, O, P
All elements listed in formula:Al, Fe, H, O, P

Relationship of Sigloite to other Species

Related Minerals - Nickel-Strunz Grouping):
8.DC.IMA 2007-057
CuFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.05Nissonite
Cu
 
2
Mg
 
2
[OH|PO
 
4
]
 
2
 · 5H
 
2
O
8.DC.07Euchroite
Cu
 
2
[OH|AsO
 
4
] · 3H
 
2
O
8.DC.10Legrandite
Zn
 
2
[OH|AsO
 
4
] · H
 
2
O
8.DC.12Strashimirite
Cu
 
8
[OH|AsO
 
4
]
 
4
 · 5H
 
2
O
8.DC.15Arthurite
CuFe
3+
2
[(OH,O)|(AsO
 
4
,PO
 
4
,SO
 
4
)]
 
2
 · 4H
 
2
O
8.DC.15Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.15Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Whitmoreite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Cobaltarthurite
(Co,Mg)Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Bendadaite
Fe
2+
 
Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.17Kleemanite
ZnAl
 
2
[OH|PO
 
4
]
 
2
 · 3H
 
2
O
8.DC.20Bermanite
Mn
2+
 
Mn
3+
2
[OH|PO
 
4
]
 
2
 · 4H
 
2
O
8.DC.22Kovdorskite
Mg
 
2
(PO
 
4
)(OH)·3H
 
2
O
8.DC.25Ferristrunzite
Fe
3+
3
[OH|PO
 
4
]
 
2
 · 5(H
 
2
O,OH)
8.DC.25Ferrostrunzite
Fe
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.25Metavauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.25Strunzite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.27Beraunite
Fe
2+
 
Fe
3+
5
[(OH)
 
5
|(PO
 
4
)
 
4
] · 4H
 
2
O
8.DC.30Gordonite
MgAl
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Laueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Mangangordonite
Mn
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Paravauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Pseudolaueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Stewartite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Ushkovite
MgFe
3+
2
[PO
 
4
]
 
2
(OH)
 
2
 · 8H
 
2
O
8.DC.30Ferrolaueite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
 · 8H
 
2
O
8.DC.30Kastningite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Maghrebite
MgAl
 
2
[OH|AsO
 
4
]
 
2
 · 8H
 
2
O
8.DC.32Tinticite
Fe
3+
4
[OH|PO
 
4
]
 
3
 · 5H
 
2
O
8.DC.35Vauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.37Vantasselite
Al
 
4
[OH|PO
 
4
]
 
3
 · 9H
 
2
O
8.DC.40Cacoxenite
Fe
3+
24
Al[(OH)
 
12
|O
 
6
|(PO
 
4
)
 
17
] · 17H
 
2
O
8.DC.45Gormanite
(Fe
2+
 
,Mg)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
8.DC.45Souzalite
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
8.DC.47Kingite
Al
 
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 9H
 
2
O
8.DC.50Wavellite
Al
 
3
[(OH,F)
 
3
|(PO
 
4
)
 
2
] · 5H
 
2
O
8.DC.50Allanpringite
Fe
3+
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 5H
 
2
O
8.DC.52Kribergite
Al
 
5
[(OH)
 
4
|SO
 
4
|(PO
 
4
)
 
3
] · 4H
 
2
O
8.DC.55Mapimite
Zn
 
2
Fe
3+
3
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 10H
 
2
O
8.DC.57Ogdensburgite
Ca
 
2
Fe
3+
4
(Zn,Mn
2+
 
)[(OH)
 
3
|(AsO
 
4
)
 
2
]
 
2
 · 6H
 
2
O
8.DC.60Nevadaite
(Cu
2+
 
,Al,V
3+
 
)
 
6
Al
 
8
(PO
 
4
)
 
8
F
 
8
(OH)
 
2
(H
 
2
O)
 
22
8.DC.60Cloncurryite
(Cu,VO)Al
 
2
[(F,OH)|PO
 
4
]
 
2
 · 4.5-5H
 
2
O
Related Minerals - Hey's Index Grouping:
19.14.1Cyrilovite
NaFe
3+
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 2H
 
2
O
19.14.2Kidwellite
NaFe
3+
9
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
2
 · 5H
 
2
O
19.14.3Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
19.14.4Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
19.14.5Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
19.14.6Natrodufrénite
NaFe
2+
 
(Fe
3+
 
,Al)
 
5
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.7Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.14.8Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.14.9Burangaite
(Na,Ca
 
0.5
)(Fe
2+
 
,Mg)Al
 
5
[(OH,O)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.10Satterlyite
(Fe
2+
 
,Mg,Fe
3+
 
)
 
2
[(OH,O)|PO
 
4
]
19.14.11Ushkovite
MgFe
3+
2
[PO
 
4
]
 
2
(OH)
 
2
 · 8H
 
2
O
19.14.12Garyansellite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
(OH,O)·1.5H
 
2
O
19.14.13Thadeuite
Ca(Mg,Fe
2+
 
)
 
3
[(OH,F)|PO
 
4
]
 
2
19.14.14Anapaite
Ca
 
2
Fe
2+
 
[PO
 
4
]
 
2
 · 4H
 
2
O
19.14.15Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
19.14.16Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
19.14.17Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
19.14.18Mélonjosephite
CaFe
2+
 
Fe
3+
 
[OH|(PO
 
4
)
 
2
]
19.14.19Delvauxite
CaFe
 
4
(PO
 
4
,SO
 
4
)
 
2
(OH)
 
8
·4-6H
 
2
O not confirmed·
19.14.20Collinsite
Ca
 
2
(Mg,Fe
2+
 
)[PO
 
4
]
 
2
 · 2H
 
2
O
19.14.21Segelerite
Ca
 
2
 Mg
 
2
 Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
19.14.22Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
19.14.23Vauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
19.14.24Metavauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.14.25Paravauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.14.27Cacoxenite
Fe
3+
24
Al[(OH)
 
12
|O
 
6
|(PO
 
4
)
 
17
] · 17H
 
2
O
19.14.28Koninckite
Fe
3+
 
[PO
 
4
] · 3H
 
2
O
19.14.29Lazulite
(Mg,Fe
2+
 
)Al
 
2
[OH|PO
 
4
]
 
2
19.14.30Scorzalite
(Fe
2+
 
,Mg)Al
 
2
[OH|PO
 
4
]
 
2
19.14.31Souzalite
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.32Gormanite
(Fe
2+
 
,Mg)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.33Zaïrite
Bi(Fe
3+
 
,Al)
 
3
[(OH)
 
6
|(PO
 
4
)
 
2
]

Other Names for Sigloite

Synonyms:
Hydrated ParavauxiteHydroparavauxite
German names:
Sigloit
Russian names:
Сиглоит
Spanish names:
Sigloita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Sigloite

Reference List:American Mineralogist (1962): 47: 1-8.

Mineralogy and Petrology (1988): 38: 201-211.

American Mineralogist (1989): 74: 1404.

Internet Links for Sigloite

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  • Look for Sigloite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Sigloite in the Natural History Museum (London) online catalogue
  • Sigloite details from Handbook of Mineralogy (PDF)
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    Localities for Sigloite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Bolivia
     
    • Potosí Department
      • Bustillos Province
        • Llallagua
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 973; American Mineralogist (1962): 47: 1-8; Mineralogical Record: 32: 474.
    USA
     
    • Arkansas
      • Polk Co.
        • Shady
    		Josef Vajdak (2002) Mineral News, 18, #1, 6.
    Mineral and/or Locality
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