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Sigloite

Big Photo

Potosí Department, Bolivia
© 2005 - MMI

Show Sigloite Photos (6)
Formula:
Fe
3+
 
Al
 
2
[(OH)
 
3
|(PO
 
4
)
 
2
] · 7H
 
2
O
System:TriclinicColour:Light brown, straw-yellow
Hardness:3
Name:Named after its discovery locality, the Siglo Veinte Mine (Siglo XX Mine), Llallagua, Bustillos Province, Potosí Department, Bolivia.


Paravauxite Group.

Classification of Sigloite

IMA status:Approved
Strunz 8th edition ID:7/D.10-40
Nickel-Strunz 10th (pending) edition ID:8.DC.30

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
C : With only medium-sized cations, (OH, etc.):RO4 = 1:1 and < 2:1
Dana 8th edition ID:42.11.14.3

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
Hey's CIM Ref.:19.14.26

19 : Phosphates
14 : Phosphates of Fe and other metals
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Type Occurrence of Sigloite

Type Locality:Siglo Veinte Mine (Siglo XX Mine; Llallagua Mine; Catavi), Llallagua, Rafael Bustillo Province, Potosí Department, Bolivia
Year of Discovery:1962

Physical Properties of Sigloite

Colour:Light brown, straw-yellow
Hardness (Mohs):3

Crystallography of Sigloite

Crystal System:Triclinic
Cell Parameters:a = 5.26Å, b = 10.52Å, c = 7.06Å
α = 106.97°, β = 111.5°, γ = 69.5°
Ratio:a:b:c = 0.5 : 1 : 0.671
Unit Cell Volume:V 334.42 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Sigloite

Type:Biaxial (+)
RI values: nα = 1.563 nβ = 1.586 nγ = 1.619
2V:Measured: 76° , Calculated: 82°
Maximum Birefringence:δ = 0.056

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:strong

Chemical Properties of Sigloite

Formula:
Fe
3+
 
Al
 
2
[(OH)
 
3
|(PO
 
4
)
 
2
] · 7H
 
2
O
Essential elements:Al, Fe, H, O, P
All elements listed in formula:Al, Fe, H, O, P

Relationship of Sigloite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DC.05Nissonite
Cu
 
2
Mg
 
2
[OH|PO
 
4
]
 
2
 · 5H
 
2
O
8.DC.07Euchroite
Cu
 
2
[OH|AsO
 
4
] · 3H
 
2
O
8.DC.10Legrandite
Zn
 
2
[OH|AsO
 
4
] · H
 
2
O
8.DC.12Strashimirite
Cu
 
8
[OH|AsO
 
4
]
 
4
 · 5H
 
2
O
8.DC.15Arthurite
CuFe
3+
2
[(OH,O)|(AsO
 
4
,PO
 
4
,SO
 
4
)]
 
2
 · 4H
 
2
O
8.DC.15Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.15Ojuelaite
ZnFe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Whitmoreite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Cobaltarthurite
(Co,Mg)Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Bendadaite
Fe
2+
 
Fe
3+
2
(AsO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DC.15Kunatite
CuFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.15UKI-2006-(PO:FeHZn)
ZnFe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.15UKI-2006-(PO:AlCuFeH)
Fe
2+
 
Al
 
3
(PO
 
4
)
 
2
(OH)
 
2
·4H
 
2
O
8.DC.17Kleemanite
ZnAl
 
2
[OH|PO
 
4
]
 
2
 · 3H
 
2
O
8.DC.20Bermanite
Mn
2+
 
(H
 
2
O)
 
4
[Mn
3+
2
(OH)
 
2
(PO
 
4
)
 
2
]
8.DC.22Kovdorskite
Mg
 
2
(PO
 
4
)(OH)·3H
 
2
O
8.DC.25Ferristrunzite
Fe
3+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
3
 · 5H
 
2
O
8.DC.25Ferrostrunzite
Fe
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.25Metavauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.25Strunzite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.27Beraunite
Fe
2+
 
Fe
3+
5
[(OH)
 
5
|(PO
 
4
)
 
4
] · 4H
 
2
O
8.DC.30Gordonite
MgAl
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Laueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Mangangordonite
Mn
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Paravauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Pseudolaueite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Stewartite
Mn
2+
 
Fe
3+
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Ushkovite
MgFe
3+
2
[PO
 
4
]
 
2
(OH)
 
2
 · 8H
 
2
O
8.DC.30Ferrolaueite
Fe
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
 · 8H
 
2
O
8.DC.30Kastningite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
8.DC.30Maghrebite
MgAl
 
2
[OH|AsO
 
4
]
 
2
 · 8H
 
2
O
8.DC.32Tinticite
Fe
3+
5.34
(PO
 
4
)
 
3.62
(VO
 
4
)
 
0.38
(OH)
 
4
·6.7H
 
2
O
8.DC.35Vauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
8.DC.37Vantasselite
Al
 
4
[OH|PO
 
4
]
 
3
 · 9H
 
2
O
8.DC.40Cacoxenite
Fe
3+
24
Al[(OH)
 
12
|O
 
6
|(PO
 
4
)
 
17
] · 17H
 
2
O
8.DC.45Gormanite
(Fe
2+
 
,Mg)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
8.DC.45Souzalite
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
8.DC.47Kingite
Al
 
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 9H
 
2
O
8.DC.50Wavellite
Al
 
3
[(OH,F)
 
3
|(PO
 
4
)
 
2
] · 5H
 
2
O
8.DC.50Allanpringite
Fe
3+
3
[(OH)
 
3
|(PO
 
4
)
 
2
] · 5H
 
2
O
8.DC.52Kribergite
Al
 
5
[(OH)
 
4
|SO
 
4
|(PO
 
4
)
 
3
] · 4H
 
2
O
8.DC.55Mapimite
Zn
 
2
Fe
3+
3
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 10H
 
2
O
8.DC.57Ogdensburgite
Ca
 
2
Fe
3+
4
(Zn,Mn
2+
 
)[(OH)
 
3
|(AsO
 
4
)
 
2
]
 
2
 · 6H
 
2
O
8.DC.60Nevadaite
(Cu
2+
 
,Al,V
3+
 
)
 
6
Al
 
8
(PO
 
4
)
 
8
F
 
8
(OH)
 
2
(H
 
2
O)
 
22
8.DC.60Cloncurryite
(Cu,VO)Al
 
2
[(F,OH)|PO
 
4
]
 
2
 · 4.5-5H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
19.14.1Cyrilovite
NaFe
3+
3
[(OH)
 
2
|PO
 
4
]
 
2
 · 2H
 
2
O
19.14.2Kidwellite
NaFe
3+
9
[(OH)
 
5
|(PO
 
4
)
 
3
]
 
2
 · 5H
 
2
O
19.14.3Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
19.14.4Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
19.14.5Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
19.14.6Natrodufrénite
NaFe
2+
 
(Fe
3+
 
,Al)
 
5
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.7Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.14.8Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
19.14.9Burangaite
(Na,Ca
 
0.5
)(Fe
2+
 
,Mg)Al
 
5
[(OH,O)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.10Satterlyite
(Fe
2+
 
,Mg,Fe
3+
 
)
 
2
[(OH,O)|PO
 
4
]
19.14.11Ushkovite
MgFe
3+
2
[PO
 
4
]
 
2
(OH)
 
2
 · 8H
 
2
O
19.14.12Garyansellite
(Mg,Fe)
 
3
(PO
 
4
)
 
2
(OH,O)·1.5H
 
2
O
19.14.13Thadeuite
Ca(Mg,Fe
2+
 
)
 
3
[(OH,F)|PO
 
4
]
 
2
19.14.14Anapaite
Ca
 
2
Fe
2+
 
[PO
 
4
]
 
2
 · 4H
 
2
O
19.14.15Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
19.14.16Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
19.14.17Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
19.14.18Mélonjosephite
CaFe
2+
 
Fe
3+
 
[OH|(PO
 
4
)
 
2
]
19.14.19Delvauxite
CaFe
 
4
(PO
 
4
,SO
 
4
)
 
2
(OH)
 
8
·4-6H
 
2
O not confirmed·
19.14.20Collinsite
Ca
 
2
(Mg,Fe
2+
 
)[PO
 
4
]
 
2
 · 2H
 
2
O
19.14.21Segelerite
Ca
 
2
 Mg
 
2
 Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
19.14.22Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
19.14.23Vauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 6H
 
2
O
19.14.24Metavauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.14.25Paravauxite
Fe
2+
 
Al
 
2
[OH|PO
 
4
]
 
2
 · 8H
 
2
O
19.14.27Cacoxenite
Fe
3+
24
Al[(OH)
 
12
|O
 
6
|(PO
 
4
)
 
17
] · 17H
 
2
O
19.14.28Koninckite
Fe
3+
 
[PO
 
4
] · 3H
 
2
O
19.14.29Lazulite
(Mg,Fe
2+
 
)Al
 
2
[OH|PO
 
4
]
 
2
19.14.30Scorzalite
(Fe
2+
 
,Mg)Al
 
2
[OH|PO
 
4
]
 
2
19.14.31Souzalite
(Mg,Fe
2+
 
)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.32Gormanite
(Fe
2+
 
,Mg)
 
3
(Al,Fe
3+
 
)
 
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 2H
 
2
O
19.14.33Zaïrite
Bi(Fe
3+
 
,Al)
 
3
[(OH)
 
6
|(PO
 
4
)
 
2
]

Other Names for Sigloite

Synonyms:
Hydrated ParavauxiteHydroparavauxite
Other Languages:
German:Sigloit
Russian:Сиглоит
Spanish:Sigloita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Sigloite

Reference List:American Mineralogist (1962): 47: 1-8.

Mineralogy and Petrology (1988): 38: 201-211.

American Mineralogist (1989): 74: 1404.

Internet Links for Sigloite

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  • Look for Sigloite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Sigloite in the Natural History Museum (London) online catalogue
  • Sigloite details from Handbook of Mineralogy (PDF)
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    Localities for Sigloite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Bolivia
     
    • Potosí Department
      • Rafael Bustillo Province
        • Llallagua
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 973; American Mineralogist (1962): 47: 1-8; Mineralogical Record: 32: 474.
    USA
     
    • Arkansas
      • Polk Co.
        • Shady
    		Josef Vajdak (2002) Mineral News, 18, #1, 6.
    Mineral and/or Locality
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    Copyright © Jolyon Ralph and Ida Chau 1993-2009. Site Map. Locality, mineral & photograph data are the copyright of the individuals who submitted them.Further information contact the Site hosted & developed by Jolyon Ralph. Mindat.org is an online information resource dedicated to providing free mineralogical information to all. Mindat relies on the contributions of hundreds of members and supporters. If you would like to add information to improve the quality of our database, then click here to register. Current server date and time: 13th Oct 2009 05:37:47