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Stibiconite

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Catorce (Real de Catorce), Mun. de Catorce, San Luis Potosí, Mexico
© 2002 John H. Betts

Show Stibiconite Photos (58)
Formula:
Sb
3+
 
Sb
5+
2
O
 
6
(OH)
System:IsometricColour:White, creamy-white, ...
Hardness:5½ - 7
Name:From Greek "stibi", antimony, plus "konis", powder, alluding to its composition and habit.


Stibiconite Group

Classification of Stibiconite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:4/C.11-50
Nickel-Strunz 10th (pending) edition ID:4.DH.20

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
H : With large (+- medium-sized) cations; sheets of edge-sharing octahedra
Dana 8th edition ID:44.1.1.1

44 : ANTIMONATES
1 : A2X2O6(O,OH,F)
Hey's CIM Ref.:7.13.6

7 : Oxides and Hydroxides
13 : Oxides of As, Sb and Bi
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Type Occurrence of Stibiconite

Type Locality:Brandholz - Goldkronach District, Fichtelgebirge, Franconia, Bavaria, Germany
Year of Discovery:1862

Occurrences of Stibiconite

Geological Setting:Secondary mineral in hydrothermal deposits, mainly replacing stibnite.

Physical Properties of Stibiconite

Lustre:Pearly, Earthy
Diaphaneity (Transparency):Transparent
Colour:White, creamy-white, light to sulphur-yellow, orange, light brown; colourless to cloudy in transmitted light
Hardness (Mohs):5½ - 7
Comment:When compact
Density (measured):3.5 - 5.5 g/cm3

Crystallography of Stibiconite

Crystal System:Isometric
Class (H-M):m3m (4/m 3 2/m) - Hexoctahedral
Space Group:Fd3m {F41/d 3 2/m}
Cell Parameters:a = 10.27Å
Unit Cell Volume:V 1,083.21 ų (Calculated from Unit Cell)
Z:8
Morphology:Massive, compact; botryoidal; in concentric shells
X-Ray Powder Diffraction:
d-spacingIntensity
5.93 (90)
3.09 (70)
2.96 (100)
2.57 (40)
1.81 (80)
1.55 (60)

Optical Data of Stibiconite

Type:Isotropic
RI values: n = 1.621 - 2.047
Maximum Birefringence:δ = 0.000 - Isotropic minerals have no birefringence
Surface Relief:Very High
Type:Isotropic

Chemical Properties of Stibiconite

Formula:
Sb
3+
 
Sb
5+
2
O
 
6
(OH)
Essential elements:H, O, Sb
All elements listed in formula:H, O, Sb

Relationship of Stibiconite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
4.DH.05Brannerite
(U
4+
 
,Ca)(Ti,Fe
3+
 
)
 
2
O
 
6
4.DH.05Orthobrannerite
U
4+
 
U
6+
 
Ti
 
4
O
 
12
(OH)
 
2
4.DH.05Thorutite
(Th,U,Ca)Ti
 
2
(O,OH)
 
6
4.DH.10Kassite
CaTi
 
2
O
 
4
(OH)
 
2
4.DH.10Lucasite-(Ce)
CeTi
 
2
(O,OH)
 
6
4.DH.15Alumotungstite
(W,Al)(O,OH)
 
3
4.DH.15Bariomicrolite
Ba(Ta,Nb)
 
2
(O,OH)
 
7
4.DH.15Bariopyrochlore
(Ba,Sr)
 
2-x
(Nb,Ti)
 
2
(O,OH)
 
7
4.DH.15Betafite
(Ca,U)
 
2
(Ti,Nb)
 
2
O
 
6
(OH)
4.DH.15Bismutomicrolite
(Bi,Ca)(Ta,Nb)
 
2
O
 
6
(OH)
4.DH.15Calciobetafite
(Ca,RE,Th,U)
 
2
(Nb,Ta,Ti)
 
2
O
 
7
4.DH.15Ceriopyrochlore-(Ce)
(Ce,Ca,Y)
 
2
(Nb,Ta)
 
2
O
 
6
(OH,F)
4.DH.15Cesstibtantite
(Cs,Na)SbTa
 
4
O
 
12
4.DH.15Ferritungstite
(W,Fe
3+
 
)(O,OH)
 
3
4.DH.15Jixianite
Pb(W,Fe
3+
 
)
 
2
(O,OH)
 
7
4.DH.15Kalipyrochlore
(K,Sr)
 
2-x
Nb
 
2
O
 
6
(O,OH)·nH
 
2
O
4.DH.15Microlite
(Ca,Na)
 
2
Ta
 
2
O
 
6
(O,OH,F)
4.DH.15Natrobistantite
(Na,Cs)Bi(Ta,Nb,Sb)
 
4
O
 
12
4.DH.15Plumbopyrochlore
(Pb,Ca,Y,U)
 
2-x
(Nb,Ta,Ti)
 
2
O
 
6
(OH,O)
4.DH.15Plumbomicrolite
(Pb,Ca,U)
 
2-x
(Ta,Nb,Sn)
 
2
O
 
6
(O,[])
4.DH.15Plumbobetafite
(Pb,U,Ca)(Ti,Nb)
 
2
O
 
6
(OH,F)
4.DH.15Pyrochlore
(Ca,Na)
 
2
Nb
 
2
O
 
6
(OH,F)
4.DH.15Stibiomicrolite
(Sb,Ca,Na)
 
2
(Ta,Nb)
 
2
O
 
7
4.DH.15Strontiopyrochlore
(Sr,Ce,Ca)
 
2-x
(Nb,Fe)
 
2
(O,OH)
 
7
4.DH.15Stannomicrolite
(Sn,Fe,Mn)
 
2
(Ta,Nb,Sn)
 
2
(O,OH)
 
7
4.DH.15Stibiobetafite
(Sb,Ca)
 
2
(Ti,Nb,Ta)
 
2
(O,OH)
 
7
4.DH.15Uranmicrolite
(U,Ca,Ce)
 
2
(Ta,Nb)
 
2
O
 
6
(OH,F)
4.DH.15Uranpyrochlore
(U,Ca,Ce)
 
2
(Nb,Ta)
 
2
O
 
6
(OH,F)
4.DH.15Yttrobetafite-(Y)
(Y,U,Ce)
 
2
(Ti,Nb,Ta)
 
2
O
 
6
OH
4.DH.15Yttropyrochlore-(Y)
(Y,Ca,U)
 
1-2
(Nb,Ta,Ti)
 
2
(O,OH)
 
7
4.DH.15Fluornatromicrolite
(Na,Ca,Bi)
 
2
Ta
 
2
O
 
6
F
4.DH.15Bismutopyrochlore
(Bi,U,Ca,Pb)
 
1+x
(Nb,Ta)
 
2
O
 
6
(OH)·nH
 
2
O
4.DH.15Thorian Pyrochlore
4.DH.15Elsmoreite
WO
 
3
·0.5H
 
2
O
4.DH.20Bismutostibiconite
Bi(Sb
5+
 
,Fe
3+
 
)
 
2
O
 
7
4.DH.20Bindheimite
Pb
 
2
Sb
 
2
O
 
6
(O,OH)
4.DH.20Monimolite
(Pb,Ca,Fe)
 
3
Sb
 
2
O
 
7
4.DH.20Partzite
Cu
 
2
Sb
 
2
(O,OH)
 
7
4.DH.20Roméite
(Ca,Fe,Mn,Na)
 
2
(Sb,Ti)
 
2
O
 
6
(O,OH,F)
4.DH.20Stetefeldtite
Ag
 
2
Sb
 
2
(O,OH)
 
7
4.DH.25Rosiaite
PbSb
5+
2
O
 
6
4.DH.30Zirconolite
CaZrTi
 
2
O
 
7
4.DH.35Liandratite
U(Nb,Ta)
 
2
O
 
8
4.DH.35Petscheckite
UFe(Nb,Ta)
 
2
O
 
8
4.DH.40Ingersonite
Ca
 
3
MnSb
 
4
O
 
14
4.DH.45Pittongite
Na
 
0.22
(W,Fe
3+
 
)(O,OH)
 
3
 · 0.44H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
7.13.1Arsenolite
As
 
2
O
 
3
7.13.2Claudetite
As
 
2
O
 
3
7.13.3Sénarmontite
Sb
 
2
O
 
3
7.13.4Valentinite
Sb
 
2
O
 
3
7.13.5Cervantite
Sb
3+
 
Sb
5+
 
O
 
4
7.13.7Bahianite
Al
 
5
Sb
 
3
O
 
14
(OH)
 
2
7.13.8Cyanophyllite
(Cu,Al)
 
3
[(OH)
 
6
|Sb
5+
 
(OH)
 
6
]
7.13.9Bismutostibiconite
Bi(Sb
5+
 
,Fe
3+
 
)
 
2
O
 
7
7.13.107.13.11Stibivanite
Sb
 
2
VO
 
5
7.13.12Bismite
Bi
 
2
O
 
3
7.13.13Sillénite
Bi
 
12
SiO
 
20

Other Names for Stibiconite

Synonyms:
ArsenostibiteCumengite (of Kenngott)HydroroméiteStibianiteStibiconise
StibiliteStibioliteVolgerite
Other Languages:
German:Arsenostibit
Hydroromeit
Stibianit
Stibiconit
Stibilit
Stibilith
Stibiolit
Stiblith
Volgerit
Russian:Стибиконит
Spanish:Arsenostibita
Hydroromeita
Stibianita
Stibiconita
Stibilita
Stibiolita
Volgerita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Stibiconite

Reference List:Blum and Delffs (1847), Journal pr. Chem.: 40: 318.

Brush (1862), American Journal of Science: 34: 207.

Natta and Baccaredda (1933) Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 85: 271 (as Hydroroméite).

Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Volume I: Elements, Sulfides, Sulfosalts, Oxides. John Wiley and Sons, Inc., New York. 7th edition, revised and enlarged: 597-598 (as Stibiconite), 1022 (as Hydroroméite).

Fornaseri (1946) Periodico de Mineralogia-Roma: 15: 47 (as Hydroroméite).

American Mineralogist (1952): 37: 982-999.

Anthony, J.W., Bideaux, R.A., Bladh, K.W., and Nichols, M.C. (1997) Handbook of Mineralogy, Volume III. Halides, Hydroxides, Oxides. Mineral Data Publishing, Tucson, AZ, 628pp.: 528.

Internet Links for Stibiconite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Stibiconite in the Natural History Museum (London) online catalogue
  • Stibiconite details from Handbook of Mineralogy (PDF)
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    Localities for Stibiconite

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