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Flörkeite

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Big Photo

Caspar quarry, Bellerberg volcano, Ettringen, Mayen, Eifel, Rhineland-Palatinate, Germany
© y vessely

Show Flörkeite Photos (13)



Formula:
(K
 
3
Ca
 
2
Na)[Al
 
8
Si
 
8
O
 
32
] · 12H
 
2
O
System:Triclinic
Member of:Zeolite Group


Zeolite Group.

A distinctly triclinic zeolite, closely related to phillipsite (monoclinic). The triclinic distortion is caused by Al-Si ordering in the crystal structure.

Classification of Flörkeite

IMA status:Approved 2008
Nickel-Strunz 10th (pending) edition ID:9.GC.10

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
C : Chains of doubly-connected 4-membered rings
Dana 8th edition ID:77.1.10.5

77 : TECTOSILICATES Zeolites
1 : Zeolite group - True zeolites
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Type Occurrence of Flörkeite

Type Locality:Caspar quarry, Bellerberg volcano, Ettringen, Mayen, Eifel, Rhineland-Palatinate, Germany

Crystallography of Flörkeite

Crystal System:Triclinic
Class (H-M):1 - Pinacoidal
Space Group:P1
Cell Parameters:a = 19.965Å, b = 14.271Å, c = 8.704Å
α = 88.37°, β = 125.08°, γ = 89.57°
Ratio:a:b:c = 1.399 : 1 : 0.61
Unit Cell Volume:V 2,027.78 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
4.965 (45)
4.065 (35)
3.235 (100)
3.162 (80)
3.135 (80)
2.736 (60)
2.712 (40)
2.665 (40)

Chemical Properties of Flörkeite

Formula:
(K
 
3
Ca
 
2
Na)[Al
 
8
Si
 
8
O
 
32
] · 12H
 
2
O
Essential elements:Al, Ca, H, K, Na, O, Si
All elements listed in formula:Al, Ca, H, K, Na, O, Si

Relationship of Flörkeite to other Species

Member of:Zeolite Group
Other Members of Group:

- +
Alflarsenite
NaCa
 
2
Be
 
3
Si
 
4
O
 
13
(OH) · 2H
 
2
O
Amicite
K
 
2
Na
 
2
Al
 
4
Si
 
4
O
 
16
 · 5H
 
2
O
Ammonioleucite
(NH
 
4
,K)(AlSi
 
2
O
 
6
)
Analcime
Na
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Barrerite
(Na,K,Ca
 
0.5
)
 
2
[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Bellbergite
(K,Ba,Sr)
 
2
Sr
 
2
Ca
 
2
(Ca,Na)
 
4
[Al
 
3
Si
 
3
O
 
12
]
 
6
 · 30H
 
2
O
Bikitaite
LiAlSi
 
2
O
 
6
 · H
 
2
O
Boggsite
Ca
 
8
Na
 
3
(Si,Al)
 
96
O
 
192
 · 70H
 
2
O
Brewsterite
Brewsterite-Ba
(Ba,Sr)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Brewsterite-Sr
(Sr,Ba,Ca)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Chabazite
Chabazite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-K
(K
 
2
,Ca,Na
 
2
,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Levyne Subgroup
Chabazite-Mg
(Mg
 
0.7
K
 
0.5
Ca
 
0.5
Na
 
0.1
)[Al
 
3
Si
 
9
O
 
24
]·10H
 
2
O
Chabazite-Na
(Na
 
2
,K
 
2
,Ca,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Sr
Sr
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chiavennite
CaMnBe
 
2
Si
 
5
O
 
13
(OH)
 
2
 · 2H
 
2
O
Clinoptilolite-Ca
(Ca,Na,K)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-Na
(Na,K,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Cowlesite
CaAl
 
2
Si
 
3
O
 
10
 · 6H
 
2
O
Dachiardite-Ca
(Ca,Na
 
2
,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Dachiardite-Na
(Na
 
2
,Ca,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Direnzoite
NaK
 
6
MgCa
 
2
(Al
 
13
Si
 
47
O
 
120
) · 36H
 
2
O
Edingtonite
Ba[Al
 
2
Si
 
3
O
 
10
] · 4H
 
2
O
Epistilbite
CaAl
 
2
Si
 
6
O
 
16
 · 5H
 
2
O
Erionite
Erionite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-K
(K
 
2
,Ca,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-Na
(Na
 
2
,K
 
2
,Ca)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Faujasite Subgroup
Faujasite-Ca
(Ca,Na
 
2
,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Mg
(Mg,Na
 
2
,Ca)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Na
(Na
 
2
,Ca,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Ferrierite
Ferrierite-K
(K
 
2
,Na
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Mg
(Mg,Na
 
2
,K
 
2
,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Na
(Na
 
2
,K
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Garronite
Na
 
2
Ca
 
5
Al
 
12
Si
 
20
O
 
64
 · 27H
 
2
O
Gaultite
Na
 
4
Zn
 
2
Si
 
7
O
 
18
 · 5H
 
2
O
Gismondine
Gismondine-Ba
Ba
 
2
Al
 
4
Si
 
4
O
 
16
 · 4-6H
 
2
O
Gismondine-Ca
CaAl
 
2
Si
 
2
O
 
8
 · 4H
 
2
O
Gmelinite
Gmelinite-Ca
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-K
(K
 
2
,Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-Na
(Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gobbinsite
Na
 
4
(Ca,Mg,K
 
2
)Al
 
6
Si
 
10
O
 
32
 · 12H
 
2
O
Gonnardite
(Na,Ca)
 
2
(Si,Al)
 
5
O
 
10
 · 3H
 
2
O
Goosecreekite
Ca[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Gottardiite
Na
 
3
Mg
 
3
Ca
 
5
Al
 
19
Si
 
117
O
 
272
 · 93H
 
2
O
Harmotome
(Ba
 
0.5
,Ca
 
0.5
,K,Na)
 
5
[Al
 
5
Si
 
11
O
 
32
] · 12H
 
2
O
Heulandite-Ba
(Ba,Ca,K,Na,Sr)
 
5
Al
 
9
Si
 
27
O
 
72
 · 22H
 
2
O
Heulandite-Ca
(Ca,Na)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Na
(Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Sr
(Sr,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Hsianghualite
Ca
 
3
Li
 
2
(Be
 
3
Si
 
3
O
 
12
)F
 
2
IMA2012-039
Ca
 
1-2
Fe[(Si,Al,Be)
 
5
Be
 
2
O
 
13
(OH)
 
2
]•2H
 
2
O
Laumontite
CaAl
 
2
Si
 
4
O
 
12
 · 4H
 
2
O
Leucite
K(AlSi
 
2
O
 
6
)
Lévyne
Lévyne-Ca
(Ca,Na
 
2
,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lévyne-Na
(Na
 
2
,Ca,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lovdarite
(Na,K,Ca)
 
4
(Be,Al)
 
2
Si
 
6
O
 
16
 · 4H
 
2
O
Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
 · 32H
 
2
O
Mazzite-Mg
K
 
2
Mg
 
2
Ca
 
1.5
Al
 
9.5
Si
 
26.5
O
 
72
 · 28H
 
2
O or near
Mazzite-Na
Na
 
4
[Al
 
4
Si
 
14
O
 
36
]
 
2
 · 30H
 
2
O
Merlinoite
(K,Na)
 
5
(Ca,Ba)
 
2
Al
 
9
Si
 
23
O
 
64
 · 23H
 
2
O
Mesolite
Na
 
2
Ca
 
2
Si
 
9
Al
 
6
O
 
30
 · 8H
 
2
O
Montesommaite
(K,Na)
 
9
Al
 
9
Si
 
23
O
 
64
 · 10H
 
2
O
Mordenite
(Na
 
2
,Ca,K
 
2
)Al
 
2
Si
 
10
O
 
24
 · 7H
 
2
O
Mutinaite
Na
 
3
Ca
 
4
Si
 
85
Al
 
11
O
 
192
 · 60H
 
2
O
Nabesite
Na
 
2
BeSi
 
4
O
 
10
 · 4H
 
2
O
Natrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 2H
 
2
O
Natrolite Subgroup
Offretite
KCaMgAl
 
5
Si
 
13
O
 
36
 · 16H
 
2
O or near
Pahasapaite
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
 · 38H
 
2
O
Paranatrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Parthéite
CaAl
 
2
Si
 
2
O
 
8
 · 2H
 
2
O
Paulingite
Paulingite-Ca
(Ca,K
 
2
,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-K
(K
 
2
,Ca,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-Na
(Na
 
2
,K
 
2
,Ca,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Perlialite
K
 
9
Na(Ca,Sr)[Al
 
2
Si
 
4
O
 
12
]
 
6
 · 15H
 
2
O
Phillipsite-Ca
(Ca
 
0.5
,K,Na,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
.
 
 12H2O
Phillipsite-K
(K,Na,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
]
.
 
 12H
 
2
O
Phillipsite-Na
(Na,K,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
] · 12H
 
2
O
Pollucite
(Cs,Na)
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Roggianite
Ca
 
2
Be(OH)
 
2
Al
 
2
Si
 
4
O
 
13
 · 2.5H
 
2
O
Scolecite
CaAl
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Stellerite
Ca[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Stilbite
Stilbite-Ca
NaCa
 
4
[Al
 
9
Si
 
27
O
 
72
] · nH
 
2
O
Stilbite-Na
(Na,Ca,K)
 
6-7
[Al
 
8
Si
 
28
O
 
72
] · nH
 
2
O
Terranovaite
(Na,Ca)
 
8
(Si
 
68
Al
 
12
)O
 
160
 · 29H
 
2
O
Tetranatrolite
Thomsonite-Ca
NaCa
 
2
[Al
 
5
Si
 
5
O
 
20
] · 6H
 
2
O
Thomsonite-Sr
Na(Sr,Ca)
 
2
[Al
 
5
Si
 
5
O
 
20
] · 7H
 
2
O
Tschernichite
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 4-8H
 
2
O
Tschörtnerite
Ca
 
4
(Ca,Sr,K,Ba)
 
3
Cu
 
3
[(OH)
 
2
|Al
 
3
Si
 
3
O
 
12
]
 
4
 · nH
 
2
O
Wairakite
Ca(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Weinebeneite
CaBe
 
3
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
Willhendersonite
KCa[Al
 
3
Si
 
3
O
 
12
] · 5H
 
2
O
Yugawaralite
CaAl
 
2
Si
 
6
O
 
16
 · 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.GC.05Amicite
K
 
2
Na
 
2
Al
 
4
Si
 
4
O
 
16
 · 5H
 
2
O
9.GC.05Garronite
Na
 
2
Ca
 
5
Al
 
12
Si
 
20
O
 
64
 · 27H
 
2
O
9.GC.05Gismondine-Ca
CaAl
 
2
Si
 
2
O
 
8
 · 4H
 
2
O
9.GC.05Gobbinsite
Na
 
4
(Ca,Mg,K
 
2
)Al
 
6
Si
 
10
O
 
32
 · 12H
 
2
O
9.GC.10Harmotome
(Ba
 
0.5
,Ca
 
0.5
,K,Na)
 
5
[Al
 
5
Si
 
11
O
 
32
] · 12H
 
2
O
9.GC.10Phillipsite-Ca
(Ca
 
0.5
,K,Na,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
.
 
 12H2O
9.GC.10Phillipsite-K
(K,Na,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
]
.
 
 12H
 
2
O
9.GC.10Phillipsite-Na
(Na,K,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
] · 12H
 
2
O
9.GC.15Merlinoite
(K,Na)
 
5
(Ca,Ba)
 
2
Al
 
9
Si
 
23
O
 
64
 · 23H
 
2
O
9.GC.20Mazzite-Mg
K
 
2
Mg
 
2
Ca
 
1.5
Al
 
9.5
Si
 
26.5
O
 
72
 · 28H
 
2
O or near
9.GC.20Mazzite-Na
Na
 
4
[Al
 
4
Si
 
14
O
 
36
]
 
2
 · 30H
 
2
O
9.GC.25Perlialite
K
 
9
Na(Ca,Sr)[Al
 
2
Si
 
4
O
 
12
]
 
6
 · 15H
 
2
O
9.GC.30Boggsite
Ca
 
8
Na
 
3
(Si,Al)
 
96
O
 
192
 · 70H
 
2
O
9.GC.35Paulingite-Ca
(Ca,K
 
2
,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
9.GC.35Paulingite-K
(K
 
2
,Ca,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O

Other Names for Flörkeite

Synonyms:
IMA2008-036Unnamed (Triclinic "phillipsite")
Other Languages:
German:Flörkeit

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Flörkeite

Reference List:

- +
Kolitsch, U. & Blass, G. (2005): Triclinic "phillipsite" in a Ca-rich xenolith from the Bellerberg, Eifel, Germany: reduction of symmetry due to nearly complete Al-Si ordering - evidence for an unusual cooling history? Mitt. Österr. Mineral. Ges. 151, 66.

C. Lengauer, U. Kolitsch, E. Tillmanns (2008): More data on (Na,K,Ca)6[Al8Si8O32]•12H2O, a new triclinic phillipsite-type zeolite from the Bellerberg volcano, Eifel, Germany. Annual Meeting of the DMG, Berlin, Germany, September 14-17, 2008; CD with abstracts, Abs. no. 348.

G. Blass, H.-W. Graf, U. Kolitsch and D. Sebold (2009): The new finds from the volcanic Eifel (II). Mineralien-Welt 20 (2), 38-49. (in German)

C. L. Lengauer, U. Kolitsch, E. Tillmanns (2009): Flörkeite, K3Ca2Na[Al8Si8O32]•12H2O, a new phillipsite-type zeolite from the Bellerberg, East Eifel volcanic area, Germany. Eur. J. Mineral. 21, 901-913.

Ternes, B. (2010): Flörkeit - ein neuer Zeolith und seine Begleiter am Bellerberg-Vulkan. Lapis, 35 (10), 28-29 (in German).

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    • Localities for Flörkeite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Germany
     
    • Rhineland-Palatinate
      • Eifel
        • Mayen
          • Ettringen
            • Bellerberg volcano
    		 C. L. Lengauer, U. Kolitsch, E. Tillmanns (2009): Flörkeite, K3Ca2Na[Al8Si8O32].12H2O, a new phillipsite-type zeolite from the Bellerberg, East Eifel volcanic area, Germany. Eur. J. Mineral. 21, 901-913;.
              • Southern lava flow
                • Mayener Feld
    		in the collection of Christof Schäfer
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    Current server date and time: 27th Apr 2013 00:16:53
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