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Ferro-fluoro-pedrizite

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Formula:
{Na}{Li
 
2
}{Fe
 
2
Al
 
2
Li}(Al
 
2
Si
 
6
O
 
22
)F
 
2
The pedrizite group minerals are lithium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu and
CLi > 0,5 apfu

Ferro-fluoro-pedrizite is defined with
A position: Na dominant
C2+ position: Fe dominant
C3+ position: Al dominant
W position: F dominant
System:MonoclinicColour:Crystals are pale ...
Member of:Pedrizite Group > Lithium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Name:This mineral was originally described as Fluoro-sodic-ferropedrizite (IMA 2008-070) by Oberti et.al (2009), and has been renamed ferro-fluoro-pedrizite in the new amphibole nomenclature.
This page provides mineralogical data about Ferro-fluoro-pedrizite.

Classification of Ferro-fluoro-pedrizite

IMA status:Renamed approved 2012
Explanation of status:This mineral was originally described as Fluoro-sodic-ferropedrizite (IMA 2008-070) by Oberti et.al (2009), and has been renamed ferro-fluoro-pedrizite in the new amphibole nomenclature.
Nickel-Strunz 10th (pending) edition ID:9.DE.05

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
Dana 8th edition ID:66.1.9.8

66 : INOSILICATES Double-Width,Unbranched Chains,(W=2)
1 : Amphiboles - Mg-Fe-Mn-Li subgroup
mindat.org URL:http://www.mindat.org/min-39337.html
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Type Occurrence of Ferro-fluoro-pedrizite

Type Locality:Sutlug River, Tuva Republic, Eastern-Siberian Region, Russia
General Appearance of Type Material:It occurs as prismatic to acicular crystals, ranging in length from 0.1-3 cm and widths of up to 50 μm. Crystals occur in parallel to sub-parallel aggregates up to 5 mm across
Geological Setting of type material:It occurs at the endogenic contact of a Li-pegmatite with country rocks near to a diabase dyke and formed by reaction of the pegmatitic melt with the country rock

Physical Properties of Ferro-fluoro-pedrizite

Colour:Crystals are pale bluish-grey
Streak:greyish-white streak
Comment:Mohs hardness of ∼6
Cleavage:Perfect
perfect {110} cleavage
Fracture:Splintery
Density (calculated):3.116 g/cm3

Crystallography of Ferro-fluoro-pedrizite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:B2/m {B1 1 2/m} {C2/m} {C1 2/m 1}
Cell Parameters:a = 9.3720(4) Å, b = 17.6312(8) Å, c = 5.2732(3) Å
β = 102.247(4)°
Ratio:a:b:c = 0.532 : 1 : 0.299
Unit Cell Volume:V 851.51 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
8.146 (100)
4.430 (70)
3.383 (40)
3.008 (80)
2.876 (30)
2.686 (90)
2.485 (60)
2.199 (30)

Chemical Properties of Ferro-fluoro-pedrizite

Formula:
{Na}{Li
 
2
}{Fe
 
2
Al
 
2
Li}(Al
 
2
Si
 
6
O
 
22
)F
 
2


The pedrizite group minerals are lithium amphiboles defined with:
A(Na+K+2Ca)> 0.5 apfu and
CLi > 0,5 apfu

Ferro-fluoro-pedrizite is defined with
A position: Na dominant
C2+ position: Fe dominant
C3+ position: Al dominant
W position: F dominant
Essential elements:Al, F, Fe, Li, Na, O, Si
All elements listed in formula:Al, F, Fe, Li, Na, O, Si
Empirical Formula:
A
 
(Na
 
0.68
)
B
 
(Li
 
1.92
Na
 
0.05
Ca
 
0.03
)
C
 
(Mg
 
1.10
Zn
 
0.02
Al
 
1.97
Ti
 
0.01
Li
 
0.66
)
T
 
(Si
 
7.98
Al
 
0.02
)O
W
22
(F
 
1.03
OH
 
0.97
) ·

Relationship of Ferro-fluoro-pedrizite to other Species

Member of:Pedrizite Group > Lithium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Other Members of Group:

- +
Ferri-fluoro-pedrizite
NaLi
 
2
(LiMg
 
2
Fe
3+
2
)(Si
 
8
O
 
22
)F
 
2
Ferri-pedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
Ferro-ferri-fluoro-pedrizite
NaLi
 
2
(LiFe
2+
2
Fe
3+
2
)(Si
 
8
O
 
22
)F
 
2
Ferro-ferri-pedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
Ferro-pedrizite
NaLi
 
2
(LiFe
2+
2
Al
 
2
)Si
 
8
O
 
22
(OH)
 
2
Fluoro-pedrizite
NaLi
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
Pedrizite
NaLi
 
2
(LiMg
 
2
Al
 
2
)(Si
 
8
O
 
22
)(OH)
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.DE.05Anthophyllite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Cummingtonite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Clino-holmquistite Group
☐{Li
 
2
}{Z
2+
3
Z
3+
2
}(Si
 
8
O
 
22
)((OH),F,Cl)
 
2
9.DE.05Grunerite
☐{Fe
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganocummingtonite
☐{Mn
2+
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganogrunerite
☐{Mn
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Permanganogrunerite
☐{Mn
2+
2
}{Mn
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Ferri-fluoro-leakeite
{Na}{Na
 
2
}{Mg
 
2
Fe
3+
2
Li}(Si
 
8
O
 
22
)F
 
2
9.DE.10Actinolite
☐{Ca
 
2
}{(Mg,Fe
2+
 
)
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferri-tschermakite
☐{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Ferro-Actinolite
☐{Ca
 
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferro-hornblende
☐{Ca
 
2
}{Fe
2+
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Ferro-tschermakite
☐{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Joesmithite
{Pb}{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Be
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Magnesio-hornblende
☐{Ca
 
2
}{Mg
 
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Tschermakite
☐(Ca
 
2
)(Mg
 
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Cannilloite
Ca(Ca
 
2
)(Mg
 
4
Al)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.10Fluor-cannilloite
{Ca}{Ca
 
2
}{Mg
 
4
Al}(Al
 
3
Si
 
5
O
 
22
)(F,OH)
 
2
9.DE.10Parvo-manganotremolite
☐{CaMn
2+
 
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Fluoro-tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)F
 
2
9.DE.10Potassic-fluoro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-edenite
{Na}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-kaersutite
{Na}{Ca
 
2
}{Fe
2+
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Ferro-pargasite
{Na}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Hastingsite
{Na}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Kaersutite
{Na}{Ca
 
2
}{Mg
 
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Magnesio-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Sadanagaite
{Na}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Fluoro-edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-ferro-ferri-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Fe
3+
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-sadanagaite
{K}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Magnesio-fluoro-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Potassic- fluoro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-chloro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Fluoro-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Parvo-mangano-edenite
{Na}{CaMn
2+
 
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Potassic-chloro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-ferro-chloro-edenite
{K}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-magnesio-hastingsite
{K}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-pargasite
{K}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Chromio-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Cr
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-taramite
Na(CaNa)(Fe
2+
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Barroisite
☐{CaNa}{Mg
 
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-barroisite
☐(CaNa)(Fe
2+
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-winchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-barroisite
☐(CaNa)(Mg
 
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-taramite
Na(CaNa)(Fe
2+
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-katophorite
NaCaNaFe
2+
4
(Fe
3+
 
)[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferro-barroisite
☐{CaNa}{Fe
2+
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-richterite
{Na}{CaNa}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-winchite
☐{CaNa}{Fe
2+
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-katophorite
{Na}{CaNa}{Fe
2+
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferri-taramite
Na(CaNa)(Mg
 
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Magnesiotaramite
{Na}{CaNa}{Mg
 
3
AlFe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Winchite
☐{CaNa}{Mg
 
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Fluoro-richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Katophorite
{Na}{CaNa}{Mg
 
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Potassic-fluoro-richterite
{K}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Potassic-richterite
K[CaNa][Mg
 
5
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-ghoseite
☐[Mn
2+
 
Na][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-winchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Fluoro-taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Eckermannite
NaNa
 
2
(Mg
 
4
Al}Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-eckermannite
NaNa
 
2
(Fe
2+
 
,
 
4
Al)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-glaucophane
◻[Na
 
2
][Fe
2+
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Glaucophane
◻[Na
 
2
][Mg
 
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-mangani-leakeite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-arfvedsonite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
)]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Magnesio-riebeckite
◻{Na
 
2
}{Mg
 
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-arfvedsonite
{Na}{Na
 
2
}{Mg
 
4
Fe
3+
 
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Riebeckite
◻[Na
 
2
][Fe
2+
3
Fe
3+
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-mangani-ungarettiite
NaNa
 
2
(Mn
2+
2
Mn
3+
3
)(Si
 
8
O
 
22
)O
 
2
9.DE.25Ferro-ferri-nybøite
NaNa
 
2
[(Fe
2+
3
,Mg)Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Clino-ferro-ferri-holmquistite
◻{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Ferri-nybøite
NaNa
 
2
(Mg
 
3
Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Ferro-ferri-leakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-ferri-fluoro-leakeite
Na(Na
 
2
)(Fe
2+
2
Fe
3+
2
Li)(Si
 
8
O
 
22
)(F)
 
2
9.DE.25Sodic-ferri-clinoferroholmquistite
☐{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-fluoro-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
](F,OH)
 
2
9.DE.25Ferri-pedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-ferri-leakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.25Mangani-dellaventuraite
{Na}{Na
 
2
}{MgMn
3+
2
LiTi
4+
 
}Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-pedrizite
NaLi
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Potassic-arfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-obertiite
Na(Na
 
2
)(Mg
 
3
Fe
3+
 
Ti)(Si
 
8
O
 
22
)O
 
2
9.DE.25Potassic-magnesio-fluoro-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
][(F,OH)
 
2
]
9.DE.25Ferro-ferri-pedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Pedrizite
NaLi
 
2
(LiMg
 
2
Al
 
2
)(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Ferro-pedrizite
NaLi
 
2
(LiFe
2+
2
Al
 
2
)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-leakeite
NaNa
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Ferro-ferri-obertiite
NaNa
 
2
(Fe
2+
3
Fe
3+
 
Ti)Si
 
8
O
 
22
O
 
2

Other Names for Ferro-fluoro-pedrizite

Synonyms:
Fluoro-sodic-ferropedriziteIMA2008-070
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ferro-fluoro-pedrizite

Reference List:

- +
Oberti, R., Boiocchi, M., Ball, N.A., Hawthorne, F.C. (2009): Fluoro-sodic-ferropedrizite, NaLi2(Fe2+Al2Li)Si8O22F2, a new mineral of the amphibole group from the Sutlug River, Tuva Republic, Russia: description and crystal structure. Mineralogical Magazine, 73, 487-494.

Frank C. Hawthorne, Roberta Oberti, George E. Harlow, Walter V. Maresch, Robert F. Martin, John C. Schumacer, Mark D. Welch (2012): Nomenclature of the amphibole supergroup, American Mineralogist, Volume 97, pages 2031–2048

Internet Links for Ferro-fluoro-pedrizite

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    • Localities for Ferro-fluoro-pedrizite

    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Eastern-Siberian Region
      • Tuva Republic
    		Mineralogical Magazine 73,487(2009)
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