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Tilleyite

Big Photo

Commercial quarry, Sky Blue Hill, Crestmore quarries, Crestmore, Riverside Co., California, USA
© Caltech

Show Tilleyite Photos (6)
Formula:
Ca
 
5
[(CO
 
3
)
 
2
|Si
 
2
O
 
7
]
System:MonoclinicColour:Colourless, white
Name:Named after Cecil Edgar Tilley (1894-1973), Professor of Petrology, University of Cambridge (England).
This page provides mineralogical data about Tilleyite.

Classification of Tilleyite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/C.09-20
Nickel-Strunz 10th (pending) edition ID:9.BE.82

9 : SILICATES (Germanates)
B : Sorosilicates
E : Si2O7 groups, with additional anions; cations in octahedral [6] and greater coordination
Dana 8th edition ID:56.2.9.1

56 : SOROSILICATES Si2O7 Groups, With Additional O, OH, F and H2O
2 : Si2O7 Groups and O, OH, F, and H2O with cations in [4] and/or >[4] coordination
Hey's CIM Ref.:17.4.1

17 : Silicates Containing other Anions
4 : Silicates with carbonates
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Type Occurrence of Tilleyite

Type Locality:Crestmore quarries, Crestmore, Riverside Co., California, USA
Year of Discovery:1933

Physical Properties of Tilleyite

Lustre:Vitreous
Colour:Colourless, white

Crystallography of Tilleyite

Crystal System:Monoclinic
Cell Parameters:a = 15.1Å, b = 10.24Å, c = 7.57Å
β = 105.17°
Ratio:a:b:c = 1.475 : 1 : 0.739
Unit Cell Volume:V 1,129.72 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Horizontal Axis: ° to ° Vertical Axis: % Source Data: Filtered Data: Peaks:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Tilleyite

Type:Biaxial (+)
RI values: nα = 1.612 - 1.617 nβ = 1.632 - 1.635 nγ = 1.652 - 1.654
2V:Measured: 85° to 90°, Calculated: 88° to 90°
Maximum Birefringence:δ = 0.040

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v

Chemical Properties of Tilleyite

Formula:
Ca
 
5
[(CO
 
3
)
 
2
|Si
 
2
O
 
7
]
Essential elements:C, Ca, O, Si
All elements listed in formula:C, Ca, O, Si

Relationship of Tilleyite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.BE.02Wadsleyite
(Mg,Fe
2+
 
)
 
2
[SiO
 
4
]
9.BE.05Hennomartinite
SrMn
3+
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Lawsonite
CaAl
 
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Noelbensonite
BaMn
3+
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.05Itoigawaite
SrAl
 
2
[(OH)
 
2
|Si
 
2
O
 
7
] · H
 
2
O
9.BE.07Ilvaite
CaFe
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.07Manganilvaite
Ca(Mn
2+
 
,Fe
2+
 
)
 
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.10Suolunite
Ca
 
2
[H
 
2
Si
 
2
O
 
7
] · H
 
2
O
9.BE.12Jaffeite
Ca
 
6
[(OH)
 
6
|Si
 
2
O
 
7
]
9.BE.15Fresnoite
Ba
 
2
Ti[O|Si
 
2
O
 
7
]
9.BE.17Baghdadite
Ca
 
3
(Zr,Ti)[O
 
2
|Si
 
2
O
 
7
]
9.BE.17Burpalite
Na
 
2
CaZr[F
 
2
|Si
 
2
O
 
7
]
9.BE.17Cuspidine
Ca
 
4
[(F,OH)
 
2
|Si
 
2
O
 
7
]
9.BE.17Hiortdahlite
(Ca,Na)
 
3
(Zr,Ti)Si
 
2
O
 
7
(O,OH,F)
 
2
9.BE.17Janhaugite
(Na,Ca)
 
3
(Mn,Fe)
 
3
(Ti,Zr,Nb)
 
2
Si
 
4
O
 
15
(OH,F,O)
 
3
9.BE.17Låvenite
(Na,Ca)
 
2
(Mn
2+
 
,Fe
2+
 
)(Zr,Ti)[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Niocalite
(Ca,Nb)
 
4
[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Normandite
NaCa(Mn,Fe)(Ti,Nb,Zr)[(O,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Wöhlerite
NaCa
 
2
(Zr,Nb)[(O,OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.17Hiortdahlite I
(Na
 
3
Ca)Ca
 
8
Zr
 
2
(M
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
4
O
 
3
F
 
5
9.BE.17IMA2005-005a
Na
 
2
Ca
 
4
(Nb,Zr)
 
2
[(O,F)
 
2
|Si
 
2
O
 
7
]
 
2
9.BE.20Mosandrite
(Ca,Na,Ce)
 
12
(Ti,Zr)
 
2
[F
 
4
|(OH)
 
6
|SiO
 
4
|(Si
 
2
O
 
7
)
 
3
]
9.BE.20Nacareniobsite-(Ce)
Na
 
3
Ca
 
3
(Ce,La,Nd)Nb[F
 
3
|O|(Si
 
2
O
 
7
)
 
2
]
9.BE.20Rinkite
Na(Na,Ca)
 
2
(Ca,Ce)
 
4
Ti[F
 
2
|(O,F)
 
2
|(Si
 
2
O
 
7
)
 
2
]
9.BE.22Götzenite
Na
 
2
Ca
 
5
Ti[F
 
4
|(Si
 
2
O
 
7
)
 
2
]
9.BE.22Hainite
Na
 
4
Ca
 
8
(Ti,Zr,Mn)
 
3
[F
 
4
|(Si
 
2
O
 
7
)
 
2
]
 
2
9.BE.22Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)[O|F|Si
 
2
O
 
7
]
9.BE.22Kochite
(Na,Ca)
 
3
Ca
 
2
(Mn,Ca)ZrTi[(F,O)
 
4
|(Si
 
2
O
 
7
)
 
2
]
9.BE.23Dovyrenite
Ca
 
6
Zr(Si
 
2
O
 
7
)
 
2
(OH)
 
4
9.BE.25Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
[O|(OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Ericssonite
BaMn
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.25Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
[O|(O,OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Orthoericssonite
BaMn
2+
2
Fe
3+
 
[O|OH|Si
 
2
O
 
7
]
9.BE.25Seidozerite
Na
 
8
Zr
 
3
Ti
 
3
Mn
2+
2
[O|F|Si
 
2
O
 
7
]
 
4
9.BE.25Nabalamprophyllite
Na
 
3
(Ba,Na)
 
2
Ti
 
3
[O|(OH,F)|Si
 
2
O
 
7
]
 
2
9.BE.25Grenmarite
(Zr,Mn)
 
2
(Zr,Ti)(Mn,Na)(Na,Ca)
 
4
(Si
 
2
O
 
7
)
 
2
(O,F)
 
4
9.BE.27Murmanite
Na
 
2
(Ti,Nb)
 
2
Si
 
2
O
 
9
·nH
 
2
O
9.BE.30Epistolite
Na
 
2
(Nb,Ti)
 
2
[O
 
2
|Si
 
2
O
 
7
] · nH
 
2
O
9.BE.32Lomonosovite
Na
 
5
Ti
 
2
[O
 
2
|PO
 
4
|Si
 
2
O
 
7
]
9.BE.35Vuonnemite
Na
 
11
Ti
4+
 
Nb
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
2
O
 
3
(F,OH)
9.BE.37Sobolevite
Na
 
12
Ca(NaCaMn)Ti
 
2
(Si
 
2
O
 
7
)
 
2
(PO
 
4
)
 
4
O
 
3
F
 
3
9.BE.40Innelite
Na
 
2
(Ba,K)
 
4
(Mg,Ca,Fe)Ti
 
3
Si
 
4
O
 
18
(OH,F)
 
1.5
SO
 
4
9.BE.40Phosphoinnelite
Ba
 
4
Na
 
3
Ti
 
3
[(O,F)
 
3
|(PO
 
4
,SO
 
4
)
 
2
|Si
 
4
O
 
14
]
9.BE.42Yoshimuraite
Ba
 
2
Mn
 
2
TiOSi
 
2
O
 
7
(PO
 
4
)(OH)
9.BE.45Quadruphite
Na
 
14
Ca
 
2
Ti
 
4
[O
 
2
|F|(PO
 
4
)
 
2
|Si
 
2
O
 
7
]
 
2
9.BE.47Polyphite
Na
 
5
(Na
 
4
Ca
 
2
)Ti
 
2
(Si
 
2
O
 
7
)(PO
 
4
)
 
3
O
 
2
F
 
2
9.BE.50Bornemanite
BaNa
 
4
Ti
 
2
NbSi
 
4
O
 
17
(F,OH)·Na
 
3
PO
 
4
9.BE.50Shkatulkaite
Na
 
10
Mn
2+
 
Ti
 
3
Nb
 
3
[(OH)
 
2
|F|(Si
 
2
O
 
7
)
 
6
] · 12H
 
2
O
9.BE.50Shkatulkalite
9.BE.50Bykovaite
BaNa(Na,Ti)
 
4
[(OH,F)
 
2
|(Ti,Nb)
 
2
Si
 
4
O
 
14
(O,OH)
 
3
] · 3H
 
2
O
9.BE.55Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti[O|(O,OH)
 
2
|Si
 
2
O
 
7
]
9.BE.55Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti[O|(OH,F)
 
2
|Si
 
2
O
 
7
]
9.BE.55Nechelyustovite
(Ba,Na)
 
2
{(Na,Ti,Mn)
 
4
[(Ti,Nb)
 
2
(OH)
 
3
Si
 
4
O
 
14
](OH,O,F)
 
2
} · 3H
 
2
O
9.BE.60Delindeite
(Na,K)
 
2.7
(Ba,Ca)
 
4
(Ti,Fe,Al)
 
6
Si
 
8
O
 
26
(OH)
 
14
9.BE.65Bussenite
Na
 
2
Ba
 
2
FeTiSi
 
2
O
 
7
(CO
 
3
)(OH)
 
3
F
9.BE.67Jinshajiangite
(Na,Ca)(Ba,K)(Fe,Mn)
 
4
Ti
 
2
Si
 
4
O
 
16
(F,O,OH)
 
2-3
9.BE.67Perraultite
(Na,Ca)(Ba,K)(Mn,Fe)
 
4
(Ti,Nb)
 
2
Si
 
4
O
 
16
(OH,F,O)
 
3
9.BE.67Surkhobite
(Ba,K)
 
2
CaNaMn
 
8
Ti
 
4
(Si
 
2
O
 
7
)
 
4
O
 
4
(F,OH,O)
 
6
9.BE.70Karnasurtite-(Ce)
(Ce,La,Th)(Ti,Nb)(Al,Fe)(Si,P)
 
2
O
 
7
(OH)
 
4
·3H
 
2
O
9.BE.70Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Mg,Fe
2+
 
)
 
2
(Ti,Fe
3+
 
)
 
3
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
3+
 
(Ti,Zr)
 
2
Ti
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Chevkinite-(Ce)
(Ce,La,Ca,Na,Th)
 
4
(Fe
2+
 
,Mg)(Fe
3+
 
,Ti,Fe
2+
 
)
 
2
(Ti,Fe
3+
 
,Nb)
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Polyakovite-(Ce)
(Ce,Ca)
 
4
(Mg,Fe
2+
 
)(Cr
3+
 
,Fe
3+
 
)
 
2
(Ti,Nb)
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Rengeite
Sr
 
4
ZrTi
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Matsubaraite
Sr
 
4
Ti
 
5
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Dingdaohengite-(Ce)
Ce
 
4
Fe
2+
 
Ti
 
2
Ti
 
2
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Maoniupingite-(Ce)
(REE,Ca)
 
4
(Fe
3+
 
,Ti,Fe
2+
 
,[])(Ti,Fe
3+
 
,Fe
2+
 
,Nb)
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.70Perrierite-(La)
(La,Ce, Ca)
 
4
(Fe,Mn
2+
 
,Mg)(Ti,Fe)
 
4
[O
 
4
|Si
 
2
O
 
7
]
 
2
9.BE.72Fersmanite
(Ca,Na)
 
4
(Ti,Nb)
 
2
Si
 
2
O
 
11
(F,OH)
 
2
9.BE.75Belkovite
Ba
 
3
(Nb,Ti)
 
6
[O
 
6
|Si
 
2
O
 
7
]
 
2
9.BE.77Nasonite
Pb
 
6
Ca
 
4
[Cl
 
2
|(Si
 
2
O
 
7
)
 
3
]
9.BE.80Kentrolite
Pb
 
2
Mn
3+
2
[O
 
2
|Si
 
2
O
 
7
]
9.BE.80Melanotekite
Pb
 
2
Fe
3+
2
[O
 
2
|Si
 
2
O
 
7
]
9.BE.85Killalaite
Ca
 
3
[Si
 
2
O
 
7
] · 0.5H
 
2
O
9.BE.87Stavelotite-(La)
(La,Nd,Ca)
 
3
Mn
2+
3
Cu(Mn
3+
 
,Fe
3+
 
,Mn
4+
 
)
 
26
[O
 
5
|Si
 
2
O
 
7
]
 
6
9.BE.90Biraite-(Ce)
Ce
 
2
Fe
2+
 
[CO
 
3
|Si
 
2
O
 
7
]
Related Minerals - Hey's Index Grouping:
17.4.2Spurrite
Ca
 
5
[CO
 
3
|(SiO
 
4
)
 
2
]
17.4.3Paraspurrite
Ca
 
5
[CO
 
3
|(SiO
 
4
)
 
2
]
17.4.4Scawtite
Ca
 
7
Si
 
6
(CO
 
3
)O
 
18
·2H
 
2
O
17.4.5Fukalite
Ca
 
4
[CO
 
3
|(HSiO
 
4
)
 
2
]
17.4.6Meionite
Ca
 
4
[CO
 
3
|(Al
 
2
Si
 
2
O
 
8
)
 
3
]
17.4.7Cancrinite
Na
 
6
Ca
 
2
[(CO
 
3
)
 
2
|Al
 
6
Si
 
6
O
 
24
] · 2H
 
2
O
17.4.8Carletonite
KNa
 
4
Ca
 
4
Si
 
8
O
 
18
(CO
 
3
)
 
4
(OH,F)·H
 
2
O
17.4.9Iimoriite-(Y)
Y
 
2
[CO
 
3
|SiO
 
4
]
17.4.10Kainosite-(Y)
Ca
 
2
(Y,Ce)
 
2
Si
 
4
O
 
12
CO
 
3
·H
 
2
O
17.4.11Caysichite-(Y)
Y
 
2
(Ca,Gd)
 
2
Si
 
4
O
 
10
(CO
 
3
)
 
3
·4H
 
2
O
17.4.12Lepersonnite-(Gd)
CaO(Gd,Dy)
 
2
O
 
3
·24UO
 
3
·8CO
 
2
·4SiO
 
2
·60H
 
2
O
17.4.13Ashburtonite
Pb
 
4
Cu
 
4
[(OH)
 
3
|Cl|(HCO
 
3
)
 
4
|Si
 
4
O
 
12
] · H
 
2
O
17.4.14Surite
Pb(Pb,Ca)(CO
 
3
)
 
2
(Al,Fe,Mg)
 
2
(Si,Al)
 
4
O
 
10
(OH)
 
2
17.4.15Tundrite-(Ce)
Na
 
2
Ce
 
2
TiO
 
2
(SiO
 
4
)(CO
 
3
)
 
2
17.4.16Tundrite-(Nd)
Na
 
3
(Nd,La)
 
4
(Ti,Nb)
 
2
(SiO
 
4
)
 
2
(CO
 
3
)
 
3
O
 
4
(OH)·2H
 
2
O

Other Names for Tilleyite

German names:
Tilleyit
Russian names:
Тиллеит
Spanish names:
Tilleyita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Tilleyite

Reference List:Larsen E.S., Dunham K.C. (1933), Tilleyite, a new mineral from the contact zone at Crestmore, California, American Mineralogist: 18: 469-473.

Harker, R. I. (1959), Synthesis and stability of tilleyite, Ca5Si2O7(CO3)2: American Journal of Science: 257: 656-667.

Louisnathan, S.J. & J.V. Smith (1970), Crystal structure of tilleyite: refinement and coordination: Zeitschrift für Kristallographie: 132: 288-306.

Grice, J.D. (2005) The structure of spurrite, tilleyite and scawtite, and relationships to other slicate-carbonate minerals. Canadian Mineralogist: 43: 1489-1500.

Internet Links for Tilleyite

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  • Look for Tilleyite on Wikipedia
  • Look for Tilleyite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Tilleyite in the Natural History Museum (London) online catalogue
  • Tilleyite details from Handbook of Mineralogy (PDF)
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    Localities for Tilleyite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Japan
     
    • Honshu Island
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi
            • Bitchu-cho (Bicchu-cho)
    		P.M. Kartashov data
      • Tohoku Region
        • Iwate Prefecture
    		Dr. Matsuo Nambu ore collection (curated at Geological Survey of Japan)
          • Kamaishi City
    		Anthony, Bideaux, Bladh, Nichols: "Handbook of Mineralogy", Vol. 1, 1990
    Norway
     
    • Telemark
      • Skien
    		Jamtveit B., Dahlgren S. and Austrheim H., (1997): "High-grade contact metamorphism of calcareous rocks from the Oslo Rift, Southern Norway".
    Romania
     
    • Hunedoara Co.
      • Hunedoara
    		Canadian Mineralogist: 39: 1435-1453.
    Russia
     
    • Eastern-Siberian Region
      • Krasnoyarsk Territory (Krasnoyarsk Kray; Krasnoyarskii Krai)
        • Evenkia (Evenkiyskiy Autonomous okrug)
          • Nizhnyaya Tunguska River Basin (Lower Tunguska River)
    		No reference listed
    USA
     
    • California
      • Riverside Co.
        • Crestmore
    		[Amer.Min.(1933) 18, 469-473; micromounts@yahoogroups.com]
            • Sky Blue Hill
    		AmMin 26:352-381
    • New Mexico
      • Sierra Co.
    		Minerals of New Mexico 3rd ed.
    • Texas
      • Brewster Co.
        • Christmas Mts
    		Rocks & Minerals (1991): 66:3: 196-224.
      • Culberson Co.
        • Apache Peak area
    		Rocks & Minerals: 66(3): 196-224.
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