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Unnamed (Ca-analogue of Humite)

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Formula:
Ca
 
7
(SiO
 
4
)
 
4
F
 
2
System:Orthorhombic
Member of:Humite Group


F-dominant analogue of Chegemite.

Classification of Unnamed (Ca-analogue of Humite)

IMA status:Unnamed - valid
Nickel-Strunz 10th (pending) edition ID:9.AF.50

9 : SILICATES (Germanates)
A : Nesosilicates
F : Nesosilicates with additional anions; cations in [4], [5] and/or only [6] coordination
Dana 8th edition ID:52.3.4.5

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
3 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] coordination only
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Crystallography of Unnamed (Ca-analogue of Humite)

Crystal System:Orthorhombic
Class (H-M):mmm (2/m 2/m 2/m) - Dipyramidal
Cell Parameters:a = 5.0696(1) Å, b = 11.3955(1) Å, c = 23.5571(3) Å
Ratio:a:b:c = 0.445 : 1 : 2.067
Unit Cell Volume:V 1360.92 ų
Z:4
Comment:Space group: Pbnm

Chemical Properties of Unnamed (Ca-analogue of Humite)

Formula:
Ca
 
7
(SiO
 
4
)
 
4
F
 
2
Essential elements:Ca, F, O, Si
All elements listed in formula:Ca, F, O, Si

Relationship of Unnamed (Ca-analogue of Humite) to other Species

Member of:Humite Group
Other Members of Group:

- +
Alleghanyite
Mn
2+
5
(SiO
 
4
)
 
2
(OH)
 
2
Chegemite
Ca
 
7
(SiO
 
4
)
 
3
(OH)
 
2
Chondrodite
(Mg,Fe
2+
 
)
 
5
(SiO
 
4
)
 
2
(F,OH)
 
2
Clinohumite
(Mg,Fe
2+
 
)
 
9
(SiO
 
4
)
 
4
(F,OH)
 
2
Humite
(Mg,Fe
2+
 
)
 
7
(SiO
 
4
)
 
3
(F,OH)
 
2
Hydroxylchondrodite
Mg
 
5
(SiO
 
4
)
 
2
(OH)
 
2
Hydroxylclinohumite
Mg
 
9
(SiO
 
4
)
 
4
(OH,F)
 
2
Jerrygibbsite
Mn
2+
9
(SiO
 
4
)
 
4
(OH)
 
2
Kumtyubeite
Ca
 
5
(SiO
 
4
)
 
2
F
 
2
Leucophoenicite
Mn
2+
7
(SiO
 
4
)
 
3
(OH)
 
2
Manganhumite
(Mn
2+
 
,Mg)
 
7
(SiO
 
4
)
 
3
(OH)
 
2
Norbergite
Mg
 
3
(SiO
 
4
)(F,OH)
 
2
Reinhardbraunsite
Ca
 
5
(SiO
 
4
)
 
2
(OH,F)
 
2
Ribbeite
(Mn
2+
 
,Mg)
 
5
(SiO
 
4
)
 
2
(OH)
 
2
Sonolite
Mn
2+
9
(SiO
 
4
)
 
4
(OH,F)
 
2
Unnamed (F-analogue of Chegemite)
Ca
 
7
(SiO
 
4
)
 
3
(F,OH)
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.AF.05Sillimanite
Al
 
2
(SiO
 
4
)O
9.AF.10Andalusite
Al
 
2
(SiO
 
4
)O
9.AF.10Kanonaite
Mn
3+
 
Al(SiO
 
4
)O
9.AF.15Kyanite
Al
 
2
(SiO
 
4
)O
9.AF.20Mullite
Al
 
4+2x
Si
 
2-2x
O
 
10-x
9.AF.20Krieselite
(Al,Ga)
 
2
(GeO
 
4
)(OH)
 
2
9.AF.23Boromullite
Al
 
9
BSi
 
2
O
 
19
9.AF.25Yoderite
Mg(Al,Fe
3+
 
)
 
3
(SiO
 
4
)
 
2
O(OH)
9.AF.30Magnesiostaurolite
(Mg,Li,Fe
2+
 
)
 
1.5-2
Al
 
9
(SiO
 
4
)
 
4
O
 
6
(OH)
 
2
9.AF.30Staurolite
(Fe
2+
 
,Mg,Zn)
 
1.5-2
Al
 
9
(SiO
 
4
)
 
4
O
 
6
(OH,O)
 
2
9.AF.30Zincostaurolite
(Zn,Li,Fe
2+
 
,Mg)
 
1.5-2
Al
 
9
(SiO
 
4
)
 
4
O
 
6
(OH)
 
2
9.AF.35Topaz
Al
 
2
(SiO
 
4
)(F,OH)
 
2
9.AF.40Norbergite
Mg
 
3
(SiO
 
4
)(F,OH)
 
2
9.AF.45Alleghanyite
Mn
2+
5
(SiO
 
4
)
 
2
(OH)
 
2
9.AF.45Chondrodite
(Mg,Fe
2+
 
)
 
5
(SiO
 
4
)
 
2
(F,OH)
 
2
9.AF.45Reinhardbraunsite
Ca
 
5
(SiO
 
4
)
 
2
(OH,F)
 
2
9.AF.45Kumtyubeite
Ca
 
5
(SiO
 
4
)
 
2
F
 
2
9.AF.45Hydroxylchondrodite
Mg
 
5
(SiO
 
4
)
 
2
(OH)
 
2
9.AF.50Humite
(Mg,Fe
2+
 
)
 
7
(SiO
 
4
)
 
3
(F,OH)
 
2
9.AF.50Manganhumite
(Mn
2+
 
,Mg)
 
7
(SiO
 
4
)
 
3
(OH)
 
2
9.AF.55Clinohumite
(Mg,Fe
2+
 
)
 
9
(SiO
 
4
)
 
4
(F,OH)
 
2
9.AF.55Sonolite
Mn
2+
9
(SiO
 
4
)
 
4
(OH,F)
 
2
9.AF.55Hydroxylclinohumite
Mg
 
9
(SiO
 
4
)
 
4
(OH,F)
 
2
9.AF.60Leucophoenicite
Mn
2+
7
(SiO
 
4
)
 
3
(OH)
 
2
9.AF.65Ribbeite
(Mn
2+
 
,Mg)
 
5
(SiO
 
4
)
 
2
(OH)
 
2
9.AF.70Jerrygibbsite
Mn
2+
9
(SiO
 
4
)
 
4
(OH)
 
2
9.AF.75Franciscanite
Mn
2+
6
(V
5+
 
,☐)
 
2
(SiO
 
4
)
 
2
(O,OH)
 
6
9.AF.75Örebroite
Mn
2+
3
(Fe
3+
 
,Sb
5+
 
)(SiO
 
4
)(O,OH)
 
3
9.AF.75Welinite
Mn
2+
6
(W
6+
 
,Mg)
 
2
(SiO
 
4
)
 
2
(O,OH)
 
6
9.AF.80Ellenbergerite
Mg
 
6
(Mg,Ti,Zr,◻)
 
2
(Al,Mg)
 
6
Si
 
8
O
 
28
(OH)
 
10
9.AF.85Chloritoid
(Fe
2+
 
,Mg,Mn
2+
 
)Al
 
2
(SiO
 
4
)O(OH)
 
2
9.AF.85Magnesiochloritoid
MgAl
 
2
(SiO
 
4
)O(OH)
 
2
9.AF.85Ottrélite
(Mn
2+
 
,Fe
2+
 
,Mg)Al
 
2
(SiO
 
4
)O(OH)
 
2
9.AF.90Poldervaartite
CaCa(HSiO
 
4
)(OH)
9.AF.90Olmiite
CaMn
2+
 
(HSiO
 
4
)(OH)

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Unnamed (Ca-analogue of Humite)

Reference List:

- +
Galuskin, E.V. et al. (2008): New calcium analogues of humite-group minerals: a polysomatic comparison. RMS DPI 2008, 47-48.

Galuskina, I.O., et al. (2009) Kumtyubeite Ca5(SiO4)2F2 - a new calcium mineral of the humite group from Northern Caucasus, Kabardino-Balkaria, Russia. American Mineralogist 94, 1361-1370.

Internet Links for Unnamed (Ca-analogue of Humite)

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    • Localities for Unnamed (Ca-analogue of Humite)

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Caucasus Region
      • Kabardino-Balkarian Republic
        • Verkhnechegemskaya caldera (Upper Chegem caldera)
    		Am.Min. 94,1361(2009)
    Mineral and/or Locality
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