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Tisinalite

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Big Photo

Umbozero mine (Umbozerskii mine), Alluaiv Mt, Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
© Pavel M. Kartashov

Show Tisinalite Photos (3)



Formula:
Na
 
3
H
 
3
(Mn,Ca,Fe)TiSi
 
6
(O,OH)
 
18
 · 2H
 
2
O
System:TrigonalColour:Yellow-orange
Hardness:5
Member of:Lovozerite Group
Name:The name reflects its titanium (Ti), silicon (Si) and sodium (Na) content.


Lovozerite Group

Classification of Tisinalite

IMA status:Approved 1979
Strunz 8th edition ID:8/E.16-60
Nickel-Strunz 10th (pending) edition ID:9.CJ.15a

9 : SILICATES (Germanates)
C : Cyclosilicates
J : [Si6O18]12- 6-membered single rings (sechser-Einfachringe), without insular complex anions
Dana 8th edition ID:61.1.2a.3

61 : CYCLOSILICATES Six-Membered Rings
1 : Six-Membered Rings with [Si6O18] rings; possible (OH) and Al substitution
Hey's CIM Ref.:14.9.25

14 : Silicates not Containing Aluminum
9 : Silicates of Ti
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Type Occurrence of Tisinalite

Type Locality:Koashva Mt, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1980

Physical Properties of Tisinalite

Lustre:Vitreous
Colour:Yellow-orange
Hardness (Mohs):5

Crystallography of Tisinalite

Crystal System:Trigonal
Cell Parameters:a = 10.14Å, c = 13.08Å
Ratio:a:c = 1 : 1.29
Unit Cell Volume:V 1,164.70 ų (Calculated from Unit Cell)

Optical Data of Tisinalite

Type:Uniaxial (-)
RI values: nω = 1.624 nε = 1.590 - 1.592
Maximum Birefringence:δ = 0.034

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Tisinalite

Formula:
Na
 
3
H
 
3
(Mn,Ca,Fe)TiSi
 
6
(O,OH)
 
18
 · 2H
 
2
O
Essential elements:H, Mn, Na, O, Si, Ti
All elements listed in formula:Ca, Fe, H, Mn, Na, O, Si, Ti
Common Impurities:K

Relationship of Tisinalite to other Species

Member of:Lovozerite Group
Other Members of Group:

- +
Combeite
Na
 
2
Ca
 
2
(Si
 
6
O
 
18
)
 
0.5
Imandrite
Na
 
12
Ca
 
3
Fe
3+
2
(Si
 
6
O
 
18
)
 
2
Kapustinite
Na
 
5
(Na,Mn
2+
 
)
 
<1
Zr(H
 
2
Si
 
6
O
 
18
)
Kazakovite
Na
 
6
Mn
2+
 
Ti(Si
 
6
O
 
18
)
Koashvite
Na
 
6
(Ca,Mn)(Ti,Fe)Si
 
6
O
 
18
 · H
 
2
O
Litvinskite
Na
 
2
(◻,Na,Mn)ZrSi
 
6
O
 
12
(OH,O)
 
6
Lovozerite
Na
 
2
CaZr(H
 
4
Si
 
6
O
 
18
) · H
 
2
O
Zirsinalite
Na
 
6
(Ca,Mn
2+
 
,Fe
2+
 
)Zr(Si
 
6
O
 
18
)
Related Minerals - Nickel-Strunz Grouping):

- +
9.CJ.05Bazzite
Be
 
3
Sc
 
2
(Si
 
6
O
 
18
)
9.CJ.05Beryl
Be
 
3
Al
 
2
(Si
 
6
O
 
18
)
9.CJ.05Indialite
Mg
 
2
Al
 
3
(AlSi
 
5
O
 
18
)
9.CJ.05Stoppaniite
Be
 
3
Fe
3+
2
(Si
 
6
O
 
18
) · H
 
2
O
9.CJ.10Cordierite
(Mg,Fe)
 
2
Al
 
3
(AlSi
 
5
O
 
18
)
9.CJ.10Sekaninaite
(Fe,Mg)
 
2
Al
 
3
(AlSi
 
5
O
 
18
)
9.CJ.15aCombeite
Na
 
2
Ca
 
2
(Si
 
6
O
 
18
)
 
0.5
9.CJ.15bImandrite
Na
 
12
Ca
 
3
Fe
3+
2
(Si
 
6
O
 
18
)
 
2
9.CJ.15aKazakovite
Na
 
6
Mn
2+
 
Ti(Si
 
6
O
 
18
)
9.CJ.15cKoashvite
Na
 
6
(Ca,Mn)(Ti,Fe)Si
 
6
O
 
18
 · H
 
2
O
9.CJ.15aLovozerite
Na
 
2
CaZr(H
 
4
Si
 
6
O
 
18
) · H
 
2
O
9.CJ.15aZirsinalite
Na
 
6
(Ca,Mn
2+
 
,Fe
2+
 
)Zr(Si
 
6
O
 
18
)
9.CJ.15aLitvinskite
Na
 
2
(◻,Na,Mn)ZrSi
 
6
O
 
12
(OH,O)
 
6
9.CJ.15aKapustinite
Na
 
5
(Na,Mn
2+
 
)
 
<1
Zr(H
 
2
Si
 
6
O
 
18
)
9.CJ.25Baratovite
KCa
 
7
(Ti,Zr)
 
2
Li
 
3
Si
 
12
O
 
36
F
 
2
9.CJ.25Katayamalite
KCa
 
7
Ti
 
2
Li
 
3
Si
 
12
O
 
36
(OH)
 
2
9.CJ.25Aleksandrovite
KCa
 
7
Sn
 
2
Li
 
3
Si
 
12
O
 
30
F
 
2
9.CJ.30Dioptase
CuSiO
 
3
 · H
 
2
O
9.CJ.35Kostylevite
K
 
2
Zr(Si
 
3
O
 
9
) · H
 
2
O
9.CJ.40Petarasite
Na
 
5
Zr
 
2
(Si
 
6
O
 
18
)(Cl,OH) · 2H
 
2
O
9.CJ.45Gerenite-(Y)
(Ca,Na)
 
2
(Y,REE)
 
3
Si
 
6
O
 
18
 · 2H
 
2
O
9.CJ.50Odintsovite
K
 
2
Na
 
4
Ca
 
3
Ti
 
2
Be
 
4
Si
 
12
O
 
38
9.CJ.55Mathewrogersite
Pb
 
7
FeAl
 
3
GeSi
 
12
O
 
36
(OH,H
 
2
O)
 
6
9.CJ.60Pezzottaite
Cs(Be
 
2
Li)Al
 
2
(Si
 
6
O
 
18
)
Related Minerals - Hey's Index Grouping:

- +
14.9.1Natisite
Na
 
2
Ti(SiO
 
4
)O
14.9.2Lorenzenite
Na
 
2
Ti
 
2
(Si
 
2
O
 
6
)O
 
3
14.9.3Lintisite
LiNa
 
3
Ti
 
2
(Si
 
2
O
 
6
)
 
2
O
 
2
 · 2H
 
2
O
14.9.4Davanite
K
 
2
TiSi
 
6
O
 
15
14.9.5Kazakovite
Na
 
6
Mn
2+
 
Ti(Si
 
6
O
 
18
)
14.9.6Titanite
CaTi(SiO
 
4
)O
14.9.7Ohmilite
Sr
 
3
(Ti,Fe
3+
 
)(Si
 
4
O
 
12
)(O,OH) · 2-3H
 
2
O
14.9.8Lamprophyllite
(Sr,K,Ba)
 
2
(Na,Ti,Mn
2+
 
,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(O,OH,F)
14.9.9Benitoite
BaTi(Si
 
3
O
 
9
)
14.9.10Batisite
BaNaNaTi
 
2
(Si
 
4
O
 
12
)O
 
2
14.9.11Fresnoite
Ba
 
2
Ti(Si
 
2
O
 
7
)O
14.9.12Joaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(OH,F) · H
 
2
O
14.9.13Orthojoaquinite-(Ce)
NaBa
 
2
Ce
 
2
FeTi
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH) · H
 
2
O
14.9.14Strontiojoaquinite
Sr
 
2
Ba
 
2
(Na,Fe)
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
 · H
 
2
O
14.9.15Bario-orthojoaquinite
(Ba,Sr)
 
4
Fe
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
 · H
 
2
O
14.9.16Strontio-orthojoaquinite
(Na,Fe)
 
2
Sr
 
2
Ba
 
2
Ti
 
2
[Si
 
4
O
 
12
]
 
2
O
 
2
(O,OH)
 
2
 · H
 
2
O
14.9.17Bafertisite
Ba(Fe
3+
 
,Mn
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(O,OH)
 
2
14.9.18Hejtmanite
Ba(Mn
2+
 
,Fe
2+
 
)
 
2
Ti(Si
 
2
O
 
7
)O(OH,F)
14.9.19Delindeite
(Na,K)
 
2
(Ba,Ca)
 
2
(Ti,Fe,Al)
 
3
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
 · 2H
 
2
O
14.9.20Barytolamprophyllite
(Ba,Na)
 
2
(Na,Ti,Fe
3+
 
)
 
4
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O(OH,F)
14.9.21Trimounsite-(Y)
Y
 
2
Ti
 
2
(SiO
 
4
)O
 
5
14.9.22Perrierite-(Ce)
(Ce,Ca,Th)
 
4
(Fe
2+
 
,Mg)Fe
3+
2
(Ti,Fe
3+
 
)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
14.9.23Chevkinite
(Ca,Ce,Th)
 
4
(Fe,Mn)
 
2
(Ti,Fe)
 
3
Si
 
4
O
 
22
14.9.24Strontiochevkinite
(Sr,La,Ce,Ca)
 
4
Fe
2+
 
(Ti,Zr)
 
2
Ti
 
2
(Si
 
2
O
 
7
)
 
2
O
 
8
14.9.26Neptunite
Na
 
2
KLi(Fe
2+
 
,Mn
2+
 
)
 
2
Ti
 
2
(Si
 
8
O
 
24
)
14.9.27Manganoneptunite
Na
 
2
KLi(Mn
2+
 
,Fe
2+
 
)
 
2
Ti
 
2
[Si
 
8
O
 
24
]
14.9.28Kupletskite
(K,Na)
 
3
(Mn,Fe)
 
7
Ti
 
2
Si
 
8
O
 
26
(OH)
 
4
F
14.9.29Astrophyllite
(K,Na)
 
3
(Fe,Mn)
 
7
Ti
 
2
Si
 
8
O
 
24
(O,OH)
 
7
14.9.30Hydroastrophyllite
(H
 
3
O,K,Ca)
 
3
(Fe,Mn)
 
5-65
Ti
 
2
Si
 
8
(O,OH)
 
31
14.9.31Magnesioastrophyllite
(Na,K)
 
4
Mg
 
2
(Fe,Fe,Mn)
 
5
Ti
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
14.9.32Baratovite
KCa
 
7
(Ti,Zr)
 
2
Li
 
3
Si
 
12
O
 
36
F
 
2
14.9.34Aenigmatite
Na
 
2
Fe
2+
5
Ti(Si
 
6
O
 
18
)O
 
2
14.9.35Schorlomite
Ca
 
3
(Ti,Fe
3+
 
)
 
2
((Si,Fe
3+
 
)O
 
4
)
 
3
14.9.36Tinaksite
K
 
2
Na(Ca,Mn
2+
 
)
 
2
Ti[O|Si
 
7
O
 
18
(OH)]
14.9.37Janhaugite
(Na,Ca)
 
3
(Mn
2+
 
,Fe
2+
 
)
 
3
(Ti,Zr,Nb)
 
2
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH,F)
 
2
14.9.38Koashvite
Na
 
6
(Ca,Mn)(Ti,Fe)Si
 
6
O
 
18
 · H
 
2
O

Other Names for Tisinalite

Synonyms:
H-KazakoviteIMA1979-052
Other Languages:
German:Tisinalit
Russian:Тисиналит
Spanish:Tisinalita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Tisinalite

Reference List:

- +
Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva (1980): 109: 223-229.

American Mineralogist (1981): 219-220.

Yamnova, N. A., Yu. K. Egorov-Tismenko, I. V. Pekov, and L. V. Shchegol'kova (2003), Crystal Structure of Tisinalite Na2(Mn,Ca)1 – x(Ti,Zr,Nb,Fe3+)[Si6O8(O,OH)10], Crystallography Reports: 48(4): 551-556.

Internet Links for Tisinalite

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    • Localities for Tisinalite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    		[World of Stones 95:5-6, p64]; Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    Konopleva, N.G., Ivanyuk, G.Y., Pakhomovsky, Y.A., Yakovenchuk, V.N., Men’shikov, Y.P., and Korchak, Y.A. (2008): Geology of Ore Deposits 50(8), 720-731.
    Jiri Spalek specimen.
          • Lovozero Massif
    Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
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