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Kircherite

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Formula:
Na
 
5
Ca
 
2
K(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
· 0.33H
 
2
O
System:Trigonal
Member of:Cancrinite Group

Classification of Kircherite

IMA status:Approved 2010
Nickel-Strunz 10th (pending) edition ID:9.FB.05

9 : SILICATES (Germanates)
F : Tektosilicates without zeolitic H2O
B : Tektosilicates with additional anions
Dana 8th edition ID:76.2.9.26

76 : TECTOSILICATES Al-Si Framework
2 : Al-Si Framework Feldspathoids and related species
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Type Occurrence of Kircherite

Type Locality:Biachella Valley, Sacrofano, Sacrofano Caldera, Rome Province, Latium, Italy

Crystallography of Kircherite

Crystal System:Trigonal
Class (H-M):3 2 - Trapezohedral
Space Group:R3 2
Space Group Setting:R3 2
Cell Parameters:a = 12.8770(7) Å, c = 95.244(6) Å
Ratio:a:c = 1 : 7.396
Unit Cell Volume:V 13,677.21 ų (Calculated from Unit Cell)
X-Ray Powder Diffraction:
d-spacingIntensity
3.80 (52)
3.72 (100)
3.60 (53)
3.58 (60)
3.55 (24)
3.23 (65)
3.22 (38)
2.65 (100)

Chemical Properties of Kircherite

Formula:
Na
 
5
Ca
 
2
K(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
· 0.33H
 
2
O
Essential elements:Al, Ca, H, K, Na, O, S, Si
All elements listed in formula:Al, Ca, H, K, Na, O, S, Si

Relationship of Kircherite to other Species

Member of:Cancrinite Group
Other Members of Group:

- +
Afghanite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
,CO
 
3
)
 
3
· 0.5H
 
2
O
Alloriite
(Na,Ca,K)
 
26
Ca
 
4
(Al
 
6
Si
 
6
O
 
24
)
 
4
(SO
 
4
)
 
6
Cl
 
6
Biachellaite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
(OH)
 
0.5
· H
 
2
O
Bystrite
(Na,K)
 
7
Ca(Al
 
6
Si
 
6
O
 
24
)(S
 
3
)
 
1.5
· H
 
2
O
Cancrinite
(Na,Ca,☐)
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
,SO
 
4
)
 
2
· 2H
 
2
O
Cancrisilite
Na
 
7
(Al
 
5
Si
 
7
O
 
24
)(CO
 
3
) · 3H
 
2
O
Davyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
)
 
2
Depmeierite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(PO
 
4
,CO
 
3
)
 
1-x
· 3H
 
2
O (x<0.5)
Franzinite
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
· 0.5H
 
2
O
Giuseppettite
(Na,K,Ca)
 
7-8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,Cl)
 
1-2
Hydroxycancrinite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(OH)
 
2
· 2H
 
2
O
Kyanoxalite
Na
 
7
(Al
 
6-x
Si
 
6+x
O
 
24
)(C
 
2
O
 
4
)
 
0.5+x
· 5H
 
2
O (0 < x < 0.5)
Liottite
(Na,K)
 
16
Ca
 
8
(Al
 
6
Si
 
6
O
 
24
)
 
3
(SO
 
4
)
 
5
Cl
 
4
Marinellite
(Na,K)
 
42
Ca
 
6
(Al
 
6
Si
 
6
O
 
24
)
 
6
(SO
 
4
)
 
8
Cl
 
2
· 3H
 
2
O
Microsommite
Na
 
4
K
 
2
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)Cl
 
2
Pitiglianoite
Na
 
6
K
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
) · 2H
 
2
O
Quadridavyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)Cl
 
4
Sacrofanite
(Na,K)
 
98
Ca
 
20
(Al
 
6
Si
 
6
O
 
24
)
 
14
(SO
 
4
)
 
26
Cl
 
2
· 8H
 
2
O
Tounkite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
Cl · H
 
2
O
Vishnevite
(Na,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
) · 2H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
9.FB.05Afghanite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
,CO
 
3
)
 
3
· 0.5H
 
2
O
9.FB.05Bystrite
(Na,K)
 
7
Ca(Al
 
6
Si
 
6
O
 
24
)(S
 
3
)
 
1.5
· H
 
2
O
9.FB.05Cancrinite
(Na,Ca,☐)
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
,SO
 
4
)
 
2
· 2H
 
2
O
9.FB.05Cancrisilite
Na
 
7
(Al
 
5
Si
 
7
O
 
24
)(CO
 
3
) · 3H
 
2
O
9.FB.05Davyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(Cl
 
2
,SO
 
4
)
 
2
9.FB.05Franzinite
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
· 0.5H
 
2
O
9.FB.05Giuseppettite
(Na,K,Ca)
 
7-8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,Cl)
 
1-2
9.FB.05Hydroxycancrinite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(OH)
 
2
· 2H
 
2
O
9.FB.05Liottite
(Na,K)
 
16
Ca
 
8
(Al
 
6
Si
 
6
O
 
24
)
 
3
(SO
 
4
)
 
5
Cl
 
4
9.FB.05Microsommite
Na
 
4
K
 
2
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)Cl
 
2
9.FB.05Pitiglianoite
Na
 
6
K
 
2
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
) · 2H
 
2
O
9.FB.05Quadridavyne
(Na,K)
 
6
Ca
 
2
(Al
 
6
Si
 
6
O
 
24
)Cl
 
4
9.FB.05Sacrofanite
(Na,K)
 
98
Ca
 
20
(Al
 
6
Si
 
6
O
 
24
)
 
14
(SO
 
4
)
 
26
Cl
 
2
· 8H
 
2
O
9.FB.05Tounkite
(Na,Ca,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
 
2
Cl · H
 
2
O
9.FB.05Vishnevite
(Na,K)
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
) · 2H
 
2
O
9.FB.05Marinellite
(Na,K)
 
42
Ca
 
6
(Al
 
6
Si
 
6
O
 
24
)
 
6
(SO
 
4
)
 
8
Cl
 
2
· 3H
 
2
O
9.FB.05Farneseite
(Na,Ca,K)
 
56
(Al
 
6
Si
 
6
O
 
24
)
 
7
(SO
 
4
)
 
12
· 6H
 
2
O
9.FB.05Alloriite
(Na,Ca,K)
 
26
Ca
 
4
(Al
 
6
Si
 
6
O
 
24
)
 
4
(SO
 
4
)
 
6
Cl
 
6
9.FB.05Fantappièite
[Na
 
82.5
Ca
 
33
K
 
16.5
](Si
 
99
Al
 
99
O
 
396
)(SO
 
4
)
 
33
· 4H
 
2
O
9.FB.05Kyanoxalite
Na
 
7
(Al
 
6-x
Si
 
6+x
O
 
24
)(C
 
2
O
 
4
)
 
0.5+x
· 5H
 
2
O (0 < x < 0.5)
9.FB.05Balliranoite
(Na,K)
 
6
Ca
 
2
(Si
 
6
Al
 
6
O
 
24
)Cl
 
2
(CO
 
3
)
9.FB.05Carbobystrite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(CO
 
3
) · 3.5H
 
2
O
9.FB.05Depmeierite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(PO
 
4
,CO
 
3
)
 
1-x
· 3H
 
2
O (x<0.5)
9.FB.10Bicchulite
Ca
 
2
(Al
 
2
SiO
 
6
)(OH)
 
2
9.FB.10Danalite
Fe
2+
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Genthelvite
Zn
 
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Haüyne
(Na,Ca)
 
4-8
(Al
 
6
Si
 
6
(O,S)
 
24
)(SO
 
4
,Cl)
 
1-2
9.FB.10Helvite
Mn
2+
4
(Be
 
3
Si
 
3
O
 
12
)S
9.FB.10Kamaishilite
Ca
 
2
(Al
 
2
SiO
 
6
)(OH)
 
2
9.FB.10Lazurite
(Na,Ca)
 
8
(Al
 
6
Si
 
6
O
 
24
)(S,SO
 
4
,Cl
 
2
)
9.FB.10Nosean
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
)
9.FB.10Sodalite
Na
 
8
(Al
 
6
Si
 
6
O
 
24
)Cl
 
2
9.FB.10Tsaregorodtsevite
(N(CH
 
3
)
 
4
)(AlSi
 
5
O
 
12
)
9.FB.10Tugtupite
Na
 
4
(AlBeSi
 
4
O
 
12
)Cl
9.FB.10Helvine
9.FB.15Marialite
Na
 
4
Al
 
3
Si
 
9
O
 
24
Cl
9.FB.15Meionite
Ca
 
4
Al
 
6
Si
 
6
O
 
24
CO
 
3
9.FB.15Silvialite
(Ca,Na)
 
4
(Al
 
6
Si
 
6
O
 
24
)(SO
 
4
,CO
 
3
)

Other Names for Kircherite

Synonyms:
IMA2009-084
Other Languages:

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Kircherite

Reference List:

- +
Bellatreccia, F., Cámara, F., Della Ventura, G., Gunter, M.E., Cavallo, A., Sebastiani, M. (2009): Kircherite, a new cancrinite-sodalite group mineral from Sacrofano (Rome, Italy). HP-HT Laboratory of Experimental Volcanology and Geophysics, 2009 Annual Report, 2009, Report I 38.

Bellatreccia, F. et al. (2010): Kircherite, a new mineral of the cancrinitesodalite
group with a 36-layer stacking sequence: occurrence and crystal structure. 20th General Meeting of the IMA (IMA2010), Budapest, Hungary, August 21-27, CD of Abstracts, p. 493.

Internet Links for Kircherite

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  • Localities for Kircherite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Italy
     
    • Latium
      • Rome Province
        • Sacrofano Caldera
          • Sacrofano
    Bellatreccia, F., Cámara, F., Della Ventura, G., Gunter, M.E., Cavallo, A., Sebastiani, m. (2009): Kircherite, a new cancrinite-sodalite group mineral from Sacrofano (Rome, Italy). HP-HT Laboratory of Experimental Volcanology and Geophysics, 2009 Annual Report, 2009, Report I 38.
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