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Tripuhyite

A valid IMA mineral species - grandfathered
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About TripuhyiteHide

Formula:
Fe3+Sb5+O4
Colour:
Yellowish brown, lemon-yellow, brown-black
Lustre:
Waxy, Dull, Earthy
Hardness:
6 - 7
Specific Gravity:
5.82
Crystal System:
Tetragonal
Member of:
Name:
Named after its discovery locality, the Tripuhy Mine, Minas Gerais, Brazil.

Unique IdentifiersHide

Mindat ID:
4024
Long-form identifier:
mindat:1:1:4024:8
GUID
(UUID V4):
9cc6db01-a733-4d2a-bd67-4bbe2e3179bf

IMA Classification of TripuhyiteHide

Approved, 'Grandfathered' (first described prior to 1959)
IMA status notes:
Redefined by the IMA
First published:
1897
Approval history:
Redefined IMA02-A: Berlepsch et al. (2003).

Classification of TripuhyiteHide

4.DB.05

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
D : Metal: Oxygen = 1:2 and similar
B : With medium-sized cations; chains of edge-sharing octahedra
44.2.1.3

44 : ANTIMONATES
2 : AX2O6
24.4.3

24 : Antimonates and Antimonites
4 : Antimonates and antimonites of Mn and Fe

Mineral SymbolsHide

As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.

SymbolSourceReference
TpyIMA–CNMNCWarr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43

Physical Properties of TripuhyiteHide

Waxy, Dull, Earthy
Transparency:
Translucent, Opaque
Colour:
Yellowish brown, lemon-yellow, brown-black
Streak:
Canary-yellow to dark brown with a greenish tinge.
Hardness:
6 - 7 on Mohs scale
Density:
5.82 g/cm3 (Measured)    6.70 g/cm3 (Calculated)

Optical Data of TripuhyiteHide

Type:
Uniaxial (+)
RI values:
nω = 2.190(1) nε = 2.330(1)
Max Birefringence:
δ = 0.140
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
Surface Relief:
Very High
Comments:
Biaxial (+), anomalous. α = 2.19(1) β = 2.20(1) γ = 2.33(1) 2V(meas.) = Small.

Chemistry of TripuhyiteHide

Mindat Formula:
Fe3+Sb5+O4

Crystallography of TripuhyiteHide

Crystal System:
Tetragonal
Class (H-M):
4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:
P42/mnm
Setting:
P42/mnm
Cell Parameters:
a = 4.625(4) Å, c = 3.059(5) Å
Ratio:
a:c = 1 : 0.661
Unit Cell V:
65.43 ų (Calculated from Unit Cell)
Z:
1
Morphology:
Fibrous; very fine-grained aggregates; globular.

Crystal StructureHide

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IDSpeciesReferenceLinkYearLocalityPressure (GPa)Temp (K)
0014565TripuhyiteBerlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-462003Tripuhy, Minas Gerais, Brazil0293
0014566TripuhyiteBerlepsch P, Armbruster T, Brugger J, Criddle A J, Graeser S (2003) Tripuhyte, FeSbO4, revisited Mineralogical Magazine 67 31-462003Falotta, Grisons, Switzerland0293
0014926TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type This is the preferred structural model Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
0014927TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
0014928TripuhyiteBasso R, Cabella R, Lucchetti G, Marescotti P, Martinelli A (2003) Structural studies on synthetic and natural Fe-Sb-oxides of MO2 type Neues Jahrbuch fur Mineralogie, Monatshefte 2003 407-4202003Djebel Nador, Algeria0293
CIF Raw Data - click here to close

X-Ray Powder DiffractionHide

Powder Diffraction Data:
d-spacingIntensity
3.28 Å(10)
2.56 Å(9)
2.32 Å(4)
1.72 Å(9)
1.64 Å(5)
1.52 Å(3)
1.47 Å(4)

Geological EnvironmentHide

Type Occurrence of TripuhyiteHide

General Appearance of Type Material:
Microcrystalline aggregates.
Place of Conservation of Type Material:
The Natural History Museum, London, England (86044).
Associated Minerals at Type Locality:
Reference:
Hussak E, Prior G T (1897) On tripuhyite, a new antimonate of iron, from Tripuhy, Brazil. Mineralogical Magazine: 11: 302.

Synonyms of TripuhyiteHide

Other Language Names for TripuhyiteHide

Varieties of TripuhyiteHide

Relationship of Tripuhyite to other SpeciesHide

Member of:
Other Members of this group:
ArgutiteGeO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
CassiteriteSnO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
ParatelluriteTeO2Tet. 4 2 2
PlattneritePbO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
PyrolusiteMn4+O2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
RutileTiO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
StishoviteSiO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
UM2000-35-O:FeNbScTaTi(Sc,Fe2+,Fe3+,Mn)(Ti,Sn,Zr)1.5(Nb,Ta,W)1.33O8

Common AssociatesHide

Associated Minerals Based on Photo Data:
25 photos of Tripuhyite associated with Chert
21 photos of Tripuhyite associated with QuartzSiO2
12 photos of Tripuhyite associated with HematiteFe2O3
12 photos of Tripuhyite associated with ArseniosideriteCa2Fe3+3(AsO4)3O2 · 3H2O
11 photos of Tripuhyite associated with MaxwelliteNaFe3+(AsO4)F
9 photos of Tripuhyite associated with ValentiniteSb2O3
7 photos of Tripuhyite associated with ParapierrotiteTlSb5S8
6 photos of Tripuhyite associated with CabalzariteCaMg2(AsO4)2 · 2H2O
6 photos of Tripuhyite associated with StibiconiteSb3+Sb5+2O6(OH)
6 photos of Tripuhyite associated with SenarmontiteSb2O3

Related Minerals - Strunz-mindat GroupingHide

4.DB.NioboheftetjerniteScNbO4Mon. 2/m : P21/b
4.DB.Shakhdaraite-(Y)ScYNb2O8Mon. 2/m : P2/b
4.DB.Nioboixiolite-(Mn2+)(Nb0.67Mn2+0.33)O2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.Nioboixiolite-([])(Nb0.80.2)4+O2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.05ArgutiteGeO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05CassiteriteSnO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05PlattneritePbO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05PyrolusiteMn4+O2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05RutileTiO2Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.05TugarinoviteMoO2Mon. 2/m : P21/b
4.DB.05Varlamoffite(Sn,Fe)(O,OH)2
4.DB.10ByströmiteMgSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P4/nmm
4.DB.10Tapiolite-(Fe)Fe2+Ta2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10Tapiolite-(Mn)Mn2+Ta2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10OrdoñeziteZnSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.10TredouxiteNiSb2O6Tet. 4/mmm (4/m 2/m 2/m) : P42/mnm
4.DB.15bAkhtenskiteε-Mn4+O2Hex. 6/mmm (6/m 2/m 2/m) : P63/mmc
4.DB.15cNsutite(Mn4+,Mn2+)(O,OH)2Hex.
4.DB.15aParamontroseiteV4+O2Orth. mmm (2/m 2/m 2/m)
4.DB.15aRamsdelliteMn4+O2Orth. mmm (2/m 2/m 2/m)
4.DB.20Scrutinyiteα-PbO2Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.25IshikawaiteU4+Fe2+Nb2O8Mon.
4.DB.25Samarskite-(Y)YFe3+Nb2O8Mon. 2/m : P2/b
4.DB.25SrilankiteZrTi2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.25Yttrocolumbite-(Y)Y(U4+,Fe2+)Nb2O8
4.DB.25Calciosamarskite(Ca,U4+)Fe3+(Nb,Ta,Ti)2O8Orth. mmm (2/m 2/m 2/m)
4.DB.25Samarskite-(Yb)YbFe3+(Nb,Ta)2O8Mon. 2/m : P2/b
4.DB.25Ixiolite-(Fe2+)(Ta0.67Fe2+0.33)O2Orth.
4.DB.25Ixiolite-(Mn2+)(Ta0.67Mn2+0.33)O2Orth.
4.DB.30FerberiteFeWO4Mon. 2/m : P2/b
4.DB.30HübneriteMnWO4Mon. 2/m : P2/b
4.DB.30Sanmartinite(Zn,Fe)WO4Mon. 2/m : P21/b
4.DB.30KrasnoselskiteCoWO4Mon.
4.DB.30HeftetjerniteScTaO4Mon. 2/m : P2/b
4.DB.30HuanzalaiteMgWO4Mon. 2/m : P2/b
4.DB.30 vaWolframite Group
4.DB.30Rossovskyite(Fe3+,Ta)(Nb,Ti)O4Mon. 2/m : P2/b
4.DB.35Columbite-(Fe)Fe2+Nb2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Tantalite-(Fe)Fe2+Ta2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Columbite-(Mn)Mn2+Nb2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Tantalite-(Mn)Mn2+Ta2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.35Columbite-(Mg)(Mg,Fe,Mn)(Nb,Ta)2O6Orth.
4.DB.35Qitianlingite(Fe,Mn)2(Nb,Ta)2WO10Orth. mmm (2/m 2/m 2/m)
4.DB.35Tantalite-(Mg)(Mg,Fe2+)(Ta,Nb)2O6Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.40FerrowodginiteFe2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40LithiotantiteLiTa3O8Mon. 2/m : P21/b
4.DB.40LithiowodginiteLiTa3O8Mon. 2/m : B2/b
4.DB.40TitanowodginiteMn2+TiTa2O8Mon. 2/m : B2/b
4.DB.40WodginiteMn2+Sn4+Ta2O8Mon. 2/m : B2/b
4.DB.40FerrotitanowodginiteFe2+TiTa2O8Mon. 2/m : B2/b
4.DB.40Tantalowodginite(Mn2+0.50.5)TaTa2O8Mon. 2/m : B2/b
4.DB.40WolframowodginiteMn(Mn,Sn,Fe,Ta)(W,Ta,Nb)2O8
4.DB.45TivaniteV3+TiO3(OH)Mon. 2/m : P21/b
4.DB.50Carmichaelite(Ti,Cr,Fe)[O2-x(OH)x]Mon. 2/m : P21/b
4.DB.55AlumotantiteAlTaO4Orth. mmm (2/m 2/m 2/m) : Pbcn
4.DB.60Biehlite((Sb,As)O)2[MoO4]Mon. 2/m : B2/b

Other InformationHide

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

Internet Links for TripuhyiteHide

References for TripuhyiteHide

Reference List:

Localities for TripuhyiteHide

This map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.

Locality ListHide

- This locality has map coordinates listed. - This locality has estimated coordinates. ⓘ - Click for references and further information on this occurrence. ? - Indicates mineral may be doubtful at this locality. - Good crystals or important locality for species. - World class for species or very significant. (TL) - Type Locality for a valid mineral species. (FRL) - First Recorded Locality for everything else (eg varieties). Struck out - Mineral was erroneously reported from this locality. Faded * - Never found at this locality but inferred to have existed at some point in the past (e.g. from pseudomorphs).

All localities listed without proper references should be considered as questionable.
Algeria
 
  • Guelma Province
    • Hammam N'Bails District
      • Djebel Nador
Mineralogical Magazine et al. (1)
Australia
 
  • New South Wales
    • Kennedy Co.
      • Condobolin district
Dr A.R. McKinnon
Leverett +4 other references
    • Robinson Co.
      • Cobar
Gilligan et al. (1995)
Chapman et al. (2005) +1 other reference
    • Sandon Co.
Gilligan et al. (1992)
      • Conningdale
Diemar et al. (2009)
      • Hillgrove
Gilligan et al. (1992)
  • Victoria
    • Yarra Ranges Shire
I.M. Threadgold (1958)
  • Western Australia
    • Ashburton Shire
Nickel et al. (1993)
Min. Record 24 (1993)
Mineralogical Record 24
Min. Record 24 (1993)
Nickel et al. (1993)
Min.Record 24 (1993)
    • City of Karratha
      • Whim Creek
Annual Report of the Western Australian ...
    • Leonora Shire
      • Ten Mile Outcamp
Nickel (1982)
Austria
 
  • Tyrol
    • Kufstein District
      • Brixlegg
Schneider (2010)
Bolivia
 
  • Oruro
    • Cercado Province
      • Caracollo
PXRD by Jaroslav Hyrsl +1 other reference
Brazil
 
  • Minas Gerais
    • Ouro Branco
    • Ouro Preto
      • Ouro Preto
Hussak et al. (1897) +1 other reference
Brugger et al. (1997)
Canada
 
  • Yukon
    • Whitehorse mining district
      • Wheaton River District
        • Carbon Hill
Peatfield (n.d.)
China
 
  • Gansu
    • Gannan
      • Hezuo Co.
Guozhong Chen et al. (2013)
  • Yunnan
    • Pu'er
      • Mojiang County
Bingxi Wang (1983)
Czech Republic
 
  • Central Bohemian Region
    • Kutná Hora District
Brabec (2002)
France
 
  • Auvergne-Rhône-Alpes
    • Ain
      • Belley
        • Murs-et-Gélignieux
Ducluzaux B. (2022)
  • Brittany
    • Finistère
      • Quimper
        • Quimper
C. Lemanski (re-entry of lost Mindat data)
Germany
 
  • Baden-Württemberg
    • Freiburg Region
      • Emmendingen
        • Waldkirch
          • Suggental
Walenta (1992)
      • Ortenaukreis
        • Gengenbach
          • Gengenbach
Wittern (1995)
        • Oberwolfach
Mineralogical Magazine et al. (1)
      • Waldshut
        • Dachsberg
          • Urberg
Lapis 21 (12)
  • Hesse
    • Darmstadt
      • Bergstraße
        • Lautertal (Odenwald)
          • Reichenbach
            • Hohenstein
Lapis (10)
  • Saxony-Anhalt
    • Mansfeld-Südharz
      • Südharz
Gröbner et al. (2011)
Greece
 
  • Attica
    • East Attica
      • Lavreotiki
        • Lavrion mining district
          • Agios Konstantinos (Kamariza)
            • Mercati mines
Gröbner (2001)
          • Plaka
            • Plaka Mines
Rieck et al. (1999)
Hungary
 
  • Heves County
    • Gyöngyös District
      • Gyöngyössolymos
HOM Collection +1 other reference
MAMIT
India
 
  • Madhya Pradesh
    • Jhabua District
Cabella et al. (2003)
Indonesia
 
  • Southeast Sulawesi Province
    • Bombana Regency
Idrus et al. (2017)
Italy
 
  • Friuli Venezia Giulia
    • Udine Province
Bortolozzi et al. (2018)
  • Liguria
    • La Spezia Province
      • Borghetto di Vara
Balestra et al. (2020)
  • Sardinia
    • South Sardinia Province
Fernando Caboni et al. (2024)
      • Gonnosfanadiga
        • Fenugu Sibiri Mine
Brizzi et al. (1994)
  • Tuscany
    • Grosseto Province
      • Manciano
C. Lemanski (6791CL)
      • Massa Marittima
        • Montoccoli-Castellaccia area (Fosso Zanca-Filone di Montoccoli area; Zanca Valley mines)
Bazzoni C. et al. (2011)
      • Scansano
Brizzi G. (1986)
    • Siena Province
      • Chiusdino
European Jour. of Min.: 8:487-492. +1 other reference
Japan
 
  • Gifu Prefecture
    • Shirakawamura
Ito & Hori (1978)
Kyrgyzstan
 
  • Batken Region
    • Kadamjay District
Kolesar et al. (1993)
Luxembourg
 
  • Canton Wiltz
    • Goesdorf
Filella et al. (2009)
New Zealand
 
  • Northland Region
    • Whangarei District
Collection of Rod Martin
  • Otago Region
    • Clutha District
      • Waipori
Robinson (2018)
Robinson (2018)
  • West Coast Region
    • Buller District
      • Reefton
MacKenzie (2014)
North Macedonia
 
  • Kavadarci Municipality
    • Ržanovo
Djordjevic et al. (2021)
  • Lipkovo Municipality
Kolitsch et al. (2018)
Portugal
 
  • Beja
    • Beja
      • Nossa Senhora das Neves
Mateus et al. (2005)
  • Porto
    • Gondomar
      • Melres
Pedro Alves collection and analytical ...
Russia
 
  • Kamchatka Krai
    • Koryak Okrug
      • Karaginsky District
Sidorov +5 other references
Tolstykh et al. (2017) +3 other references
    • Milkovsky District
Sandalov et al. (2023)
        • Great Fissure eruption (Main Fracture)
          • Northern Breakthrough (North Breach)
            • Second scoria cone
Pekov et al. (2020)
  • Krasnoyarsk Krai
    • Enisei Range (Yenisei Ridge; Enisei Ridge)
Sergeev et al. (1997) +1 other reference
  • Tuva
    • Sut-Kholsky District
      • Aldan-Maadyr ore cluster
Kuzhuget et al. (2015)
Slovakia
 
  • Banská Bystrica Region
    • Banská Bystrica District
Lalinská-Voleková B. et al. (in Slovak)
      • Špania Dolina
        • Špania Dolina deposit
Majzlan J. et al. (2018)
  • Bratislava Region
    • Pezinok District
      • Pezinok
Majzlan J. et al. (2011)
  • Košice Region
    • Rožňava District
      • Čučma
Lalinská-Voleková B. et al. (in Slovak)
    • Spišská Nová Ves District
Števko M. et al. (2017)
  • Žilina Region
    • Liptovský Mikuláš District
      • Dúbrava
Lalinská-Voleková B.
Spain
 
  • Andalusia
    • Almería
      • Pechina
        • Baños de Alhamilla
Rewitzer et al. (part2)
  • Castile-La Mancha
    • Guadalajara
      • Pardos
        • Pardos deposit
Borja Sainz de Baranda (2007)
Switzerland
 
  • Grisons
    • Albula Region
      • Surses
        • Tinizong (Tinzen)
Stalder et al. (1998)
    • Viamala Region
      • Ferrera
        • Starlera Valley
Brugger et al. (2002)
  • Ticino
    • Lugano
Schmutz et al. (1986) +1 other reference
Schmutz et al. (1986)
USA
 
  • Nevada
    • Churchill County
      • Lake Mining District
Castor et al. (2004) +1 other reference
    • Eureka County
      • Carlin Trend
        • Maggie Creek Mining Subdistrict
Jensen et al. (1995)
      • Lynn Mining District
        • Elko
Mineralogical Record 26:467
Castor et al. (2004)
    • Humboldt County
      • Opalite Mining District
Mineralogical Magazine et al. (1)
Castor et al. (2004)
    • Lincoln County
Castor et al. (2004)
    • Nye County
      • Paradise Peak Mining District
        • Paradise Peak [summit]
          • Paradise Peak [town]
Castor et al. (2004)
    • Pershing County
Castor et al. (2004)
  • New Mexico
    • Catron County
      • Taylor Creek Mining District
Min.Rec.: 20 (5) +1 other reference
    • Sierra County
Mineralogical Magazine +4 other references
    • Socorro County
      • Bear Mountains Mining District
5th Annual New Mexico Mineral Symposium (1985) +1 other reference
  • Utah
    • Tooele County
      • Lookout Pass Mining District
        • Little Valley
Norman King +1 other reference
 
Mineral and/or Locality  
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