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Ungemachite

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Chuquicamata Mine, Chuquicamata District, Calama, El Loa Province, Antofagasta Region, Chile
© 2008, J. Weissman

Formula:
K
 
3
Na
 
8
Fe(SO
 
4
)
 
6
(NO
 
3
)
 
2
·6H
 
2
O
System:TrigonalColour:Colourless, pale yellow; ...
Lustre:VitreousHardness:2½
Name:Named after Henri-Léon Ungemach (1880-1936), Belgian crystallographer.


Ungemachite Group

Classification of Ungemachite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:6/D.16-20
Nickel-Strunz 10th (pending) edition ID:7.DG.10

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
G : With large and medium-sized cations; with NO3, CO3, B(OH)4, SiO4 or IO3
Dana 8th edition ID:32.2.3.1

32 : COMPOUND SULFATES
2 : Hydrated Compound Sulfates
Hey's CIM Ref.:25.11.11

25 : Sulphates
11 : Sulphates of Fe and other metals
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Type Occurrence of Ungemachite

Type Locality:Chuquicamata Mine, Chuquicamata District, Calama, El Loa Province, Antofagasta Region, Chile
Place of Conservation of Type Material:Harvard University, Boston, Massachusetts 98282, 98283
Year of Discovery:1936
Geological Setting of type material:Oxidized copper ore body in an arid region.
Associated Minerals at type locality:
MetasideronatriteJarosite

Occurrences of Ungemachite

Geological Setting:Oxidation zone for pyrites in arid environment.

Physical Properties of Ungemachite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:Colourless, pale yellow; colourless in transmitted light.
Hardness (Mohs):2½
Tenacity:Brittle
Cleavage:Perfect
Perfect on {0001}
Fracture:Irregular/Uneven
Density (measured):2.287(3) g/cm3
Density (calculated):2.259 g/cm3

Crystallography of Ungemachite

Crystal System:Trigonal
Class (H-M):3 - Rhombohedral
Space Group:R3
Cell Parameters:a = 10.898(1) Å, c = 24.989(6) Å
Ratio:a:c = 1 : 2.293
Unit Cell Volume:V 2,570.24 ų (Calculated from Unit Cell)
Z:3
Morphology:Crystals thick tabular {0001}.

Optical Data of Ungemachite

Type:Uniaxial (-)
RI values: nω = 1.502() nε = 1.449(2)
Maximum Birefringence:δ = 0.053

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Ungemachite

Formula:
K
 
3
Na
 
8
Fe(SO
 
4
)
 
6
(NO
 
3
)
 
2
·6H
 
2
O
Essential elements:Fe, H, K, N, Na, O, S
All elements listed in formula:Fe, H, K, N, Na, O, S
Empirical Formula:
K
 
3
Na
 
8
Fe
3+
 
(SO
 
4
)
 
6
(NO
 
3
)
 
2
·6H
 
2
O

Relationship of Ungemachite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
7.DG.05Darapskite
Na
 
3
NO
 
3
SO
 
4
·H
 
2
O
7.DG.10Clinoungemachite
(Na, K, Fe, SO
 
4
)
7.DG.10Humberstonite
Na
 
7
K
 
3
Mg
 
2
(SO
 
4
)
 
6
(NO
 
3
)
 
2
·6H
 
2
O
7.DG.15Bentorite
Ca
 
6
(Cr
3+
 
,Al)
 
2
[(OH)
 
4
|SO
 
4
]
 
3
 · 26H
 
2
O
7.DG.15Charlesite
Ca
 
6
(Al,Si)
 
2
[(OH,O)
 
12
|B(OH)
 
4
|(SO
 
4
)
 
2
] · 26H
 
2
O
7.DG.15Ettringite
Ca
 
6
Al
 
2
[(OH)
 
4
|SO
 
4
]
 
3
 · 26H
 
2
O
7.DG.15Jouravskite
Ca
 
6
Mn
3+
2
[(OH)
 
4
|(SO
 
4
,CO
 
3
)]
 
3
 · 26H
 
2
O
7.DG.15Sturmanite
Ca
 
6
(Fe
3+
 
,Al,Mn
3+
 
)
 
2
[(OH)
 
12
|B(OH)
 
4
|(SO
 
4
)
 
2
] · 25H
 
2
O
7.DG.15Thaumasite
Ca
 
3
[CO
 
3
|SO
 
4
|Si(OH)
 
6
] · 12H
 
2
O
7.DG.15Carraraite
Ca
 
3
Ge(OH)
 
6
(SO
 
4
)(CO
 
3
)·12H
 
2
O
7.DG.15Buryatite
Ca
 
3
(Si,Fe,Al)[SO
 
4
][B(OH)
 
4
](OH)
 
5
O•
 
12
H
 
2
O
7.DG.20Rapidcreekite
Ca
 
2
[CO
 
3
|SO
 
4
] · 4H
 
2
O
7.DG.20Korkinoite
Ca, SO
 
4
, H
 
2
O reported
7.DG.25Tatarskite
Ca
 
6
Mg
 
2
(SO
 
4
)
 
2
(CO
 
3
)
 
2
Cl
 
4
(OH)
 
4
·7H
 
2
O
7.DG.30Nakauriite
Cu
 
8
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
4
] · 48H
 
2
O
7.DG.35Chessexite
(Na,K)
 
4
Ca
 
2
(Mg,Zn)
 
3
Al
 
8
[(SO
 
4
)
 
10
|(SiO
 
4
)
 
2
] · 40H
 
2
O
7.DG.40Carlosruizite
K
 
6
(Na,K)
 
4
Na
 
6
Mg
 
10
(SeO
 
4
)
 
12
(IO
 
3
)
 
12
·12H
 
2
O
7.DG.40Fuenzalidaite
K
 
6
(Na,K)
 
4
Na
 
6
Mg
 
10
(SO
 
4
)
 
12
(IO
 
3
)
 
12
·12H
 
2
O
7.DG.45Chelyabinskite
(Ca,Mg)
 
3
[(SO
 
4
,CO
 
3
)
 
2
|Si(OH)
 
6
] · 9H
 
2
O (?)
Related Minerals - Hey's Index Grouping:

- +
25.11.1Natrojarosite
NaFe
 
3
[(OH)
 
3
|SO
 
4
]
 
2
25.11.2Sideronatrite
Na
 
2
Fe(SO
 
4
)
 
2
OH·3H
 
2
O
25.11.3Metasideronatrite
Na
 
4
Fe
 
2
(SO
 
4
)
 
4
(OH)
 
2
·2H
 
2
O
25.11.4Ferrinatrite
Na
 
3
Fe(SO
 
4
)
 
3
·3H
 
2
O
25.11.5Amarillite
NaFe(SO
 
4
)
 
2
·6H
 
2
O
25.11.6Yavapaiite
KFe(SO
 
4
)
 
2
25.11.7Krausite
KFe(SO
 
4
)
 
2
·H
 
2
O
25.11.8Goldichite
KFe(SO
 
4
)
 
2
·4H
 
2
O
25.11.9Jarosite
KFe
3+
 
 
3
[(OH)
 
3
|SO
 
4
]
 
2
25.11.10Voltaite
K
 
2
Fe
2+
5
Fe
3+
3
Al[SO
 
4
]
 
12
 · 18H
 
2
O
25.11.12Metavoltine
Na
 
6
K
 
2
FeFe
 
6
(SO
 
4
)
 
12
O
 
2
·18H
 
2
O
25.11.13Sabieite
NH
 
4
Fe(SO
 
4
)
 
2
25.11.14Ammoniojarosite
(NH
 
4
)Fe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
25.11.15Clairite
(NH
 
4
)
 
2
Fe
 
3
(SO
 
4
)
 
4
(OH)
 
3
·3H
 
2
O
25.11.16Mohrite
(NH
 
4
)
 
2
Fe(SO
 
4
)
 
2
·6H
 
2
O
25.11.17Lonecreekite
(NH
 
4
)Fe
3+
 
[SO
 
4
]
 
2
 · 12H
 
2
O
25.11.18Godovikovite
NH
 
4
(Al,Fe)(SO
 
4
)
 
2
25.11.19Botryogen
MgFe
3+
 
[OH|(SO
 
4
)
 
2
] · 7H
 
2
O
25.11.21Slavíkite
(H
 
3
O
+
 
)
 
3
Mg
 
6
Fe
 
15
(SO
 
4
)
 
21
(OH)
 
18
·99H
 
2
O
25.11.23Sturmanite
Ca
 
6
(Fe
3+
 
,Al,Mn
3+
 
)
 
2
[(OH)
 
12
|B(OH)
 
4
|(SO
 
4
)
 
2
] · 25H
 
2
O
25.11.24Millosevichite
(Al,Fe)
 
2
(SO
 
4
)
 
3
25.11.25Aluminocopiapite
Al
 
2/3
Fe
3+
4
[OH|(SO
 
4
)
 
3
]
 
2
 · 20H
 
2
O
25.11.26Halotrichite
FeAl
 
2
(SO
 
4
)
 
4
·22H
 
2
O
25.11.27Idrizite
(Mg,Fe)(Al,Fe)
 
2
(SO
 
4
)
 
3
(OH)
 
2
·15H
 
2
O or near
25.11.28Lishizhenite
ZnFe
 
2
(SO
 
4
)
 
4
·14H
 
2
O
25.11.29Zincovoltaite
K
 
2
Zn
 
5
Fe
3+
3
Al[SO
 
4
]
 
12
 · 18H
 
2
O

Other Names for Ungemachite

Other Languages:
German:Ungemachit
Russian:Унгемахит
Spanish:Ungemachita

Other Information

Other Information:Readily soluble in dilute HCl.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Ungemachite

Reference List:American Mineralogist (1936): 21/12: part 2, 2.

Peacock, M. A. & Bandy, M. C. (1938): Ungemachite and clino-ungemachite: new minerals from Chile. American Mineralogist: 23: 314-328.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 596.

American Mineralogist (1986): 71: 826-829.

Internet Links for Ungemachite

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    Localities for Ungemachite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • New South Wales
      • Robinson Co.
        • Cobar
          • Cobar
    		http://leme.anu.edu.au/Pubs/Advancesinregolith/Leverett_et_al.pdf
          • Kaloogleguy
    		Leverett, P., McKinnon, A. R., Sharpe, J. L. and Williams, P. A. (2005): Secondary minerals from the central Cobar mines. Australian Journal of Mineralogy, 11, 75-82.
    Chile
     
    • Antofagasta Region
      • El Loa Province
        • Calama
          • Chuquicamata District
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 597; American Mineralogist (1936): 21(12): part 2, p.2; Mineralogical Record: 9: 329.
    Mineral and/or Locality
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