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Violarite

Formula:
Fe
2+
 
Ni
3+
2
S
 
4
System:IsometricColour:Violet gray, copper red, ...
Lustre:MetallicHardness:4½ - 5½
Name:From Latin "violaris", of violets, alluding to the color of the mineral, especially if viewed with a reflected-light microscope.

Classification of Violarite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:2/D.01-70
Nickel-Strunz 10th (pending) edition ID:2.DA.05

2 : SULFIDES and SULFOSALTS (sulfides, selenides, tellurides; arsenides, antimonides, bismuthides; sulfarsenites, sulfantimonites, sulfbismuthites, etc.)
D : Metal Sulfides, M: S = 3 :4 and 2:3
A : M:S = 3:4
Dana 8th edition ID:2.10.1.8

2 : SULFIDES
10 : AmBnXp, with (m+n):p = 3:4
Hey's CIM Ref.:3.11.8

3 : Sulphides, Selenides, Tellurides, Arsenides and Bismuthides (except the arsenides, antimonides and bismuthides of Cu, Ag and Au, which are included in Section 1)
11 : Sulphides etc. of Ni
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Type Occurrence of Violarite

Type Locality:Vermilion Mine, Denison Township, Sudbury District, Ontario, Canada
Year of Discovery:1924

Physical Properties of Violarite

Lustre:Metallic
Diaphaneity (Transparency):Opaque
Colour:Violet gray, copper red, light gray, or steel gray
Streak:Black
Hardness (Mohs):4½ - 5½
Cleavage:Perfect
Perfect

Crystallography of Violarite

Crystal System:Isometric
Cell Parameters:a = 9.46Å
Unit Cell Volume:V 846.59 ų (Calculated from Unit Cell)

Optical Data of Violarite

Type:Isotropic

Chemical Properties of Violarite

Formula:
Fe
2+
 
Ni
3+
2
S
 
4
Essential elements:Fe, Ni, S
All elements listed in formula:Fe, Ni, S
Common Impurities:Co,Cu

Relationship of Violarite to other Species

Series:Forms a series with Polydymite (see here)
Forms a series with Greigite (see here)
Forms a series with Siegenite (see here)
Related to:
  • Thiospinel Group
  • Related Minerals - Nickel-Strunz Grouping):

    - +
    2.DA.05Bornhardtite
    Co
    2+
     
    Co
    3+
    2
    Se
     
    4
    2.DA.05Carrollite
    Cu(Co,Ni)
     
    2
    S
     
    4
    2.DA.05Cuproiridsite
    (Cu,Fe)Ir
     
    2
    S
     
    4
    2.DA.05Cuprorhodsite
    (Cu,Fe)Rh
     
    2
    S
     
    4
    2.DA.05Daubréelite
    Fe
    2+
     
    Cr
    3+
    2
    S
     
    4
    2.DA.05Fletcherite
    Cu(Ni,Co)
     
    2
    S
     
    4
    2.DA.05Florensovite
    (Cu,Zn)Cr
     
    1.5
    Sb
     
    0.5
    S
     
    4
    2.DA.05Greigite
    Fe
    2+
     
    Fe
    3+
    2
    S
     
    4
    2.DA.05Indite
    FeIn
     
    2
    S
     
    4
    2.DA.05Kalininite
    ZnCr
     
    2
    S
     
    4
    2.DA.05Linnaeite
    Co
    2+
     
    Co
    3+
    2
    S
     
    4
    2.DA.05Malanite
    Cu(Pt
    3+
     
    ,Ir
    3+
     
    )
     
    2
    S
     
    4
    2.DA.05Polydymite
    Ni
    2+
     
    Ni
    3+
    2
    S
     
    4
    2.DA.05Siegenite
    from CoNi
     
    2
    S
     
    4
    to NiCo
     
    2
    S
     
    4
    2.DA.05Trüstedtite
    Ni
     
    3
    Se
     
    4
    2.DA.05Tyrrellite
    Cu(Co
    3+
     
    ,Ni
    3+
     
    )
     
    2
    Se
     
    4
    2.DA.05Xingzhongite
    (Pb,Cu,Fe)(Ir,Pt,Rh)
     
    2
    S
     
    4
    2.DA.05Ferrorhodsite
    (Fe,Cu)(Rh,Ir,Pt)
     
    2
    S
     
    4
    2.DA.05Cadmoindite
    CdIn
     
    2
    S
     
    4
    2.DA.10Rhodostannite
    Cu
     
    2
    FeSn
     
    3
    S
     
    8
    2.DA.10Toyohaite
    Ag
     
    2
    FeSn
     
    3
    S
     
    8
    2.DA.15Brezinaite
    Cr
     
    3
    S
     
    4
    2.DA.15Heideite
    (Fe,Cr)
     
    1.15
    (Ti,Fe)
     
    2
    S
     
    4
    2.Da.15Wilkmanite
    Ni
     
    3
    Se
     
    4
    2.DA.20Inaglyite
    Cu
     
    3
    Pb(Ir,Pt)
     
    8
    S
     
    16
    2.DA.20Konderite
    Cu
     
    3
    Pb(Rh,Pt,Ir)
     
    8
    S
     
    16
    2.DA.25Kingstonite
    (Rh,Ir,Pt)
     
    3
    S
     
    4
    Related Minerals - Hey's Index Grouping:

    - +
    3.11.1Heazlewoodite
    Ni
     
    3
    S
     
    2
    3.11.2Godlevskite
    (Ni,Fe)
     
    9
    S
     
    8
    3.11.3Millerite
    NiS
    3.11.4Polydymite
    Ni
    2+
     
    Ni
    3+
    2
    S
     
    4
    3.11.5Vaesite
    NiS
     
    2
    3.11.6Shandite
    Ni
     
    3
    Pb
     
    2
    S
     
    2
    3.11.7Donharrisite
    Ni
     
    8
    Hg
     
    3
    S
     
    9
    3.11.9Pentlandite
    (Fe,Ni)
     
    9
    S
     
    8
    3.11.10Bravoite
    (Fe,Ni)S
     
    2
    3.11.11Siegenite
    from CoNi
     
    2
    S
     
    4
    to NiCo
     
    2
    S
     
    4
    3.11.12Fletcherite
    Cu(Ni,Co)
     
    2
    S
     
    4
    3.11.13Villamanínite
    (Cu,Ni,Co,Fe)S
     
    2
    3.11.14Mäkinenite
    γ-NiSe
    3.11.15Sederholmite
    NiSe beta-NiSe
    3.11.16Trüstedtite
    Ni
     
    3
    Se
     
    4
    3.11.17Wilkmanite
    Ni
     
    3
    Se
     
    4
    3.11.18Kullerudite
    NiSe
     
    2
    3.11.19Penroseite
    (Ni,Co,Cu)Se
     
    2
    3.11.20Tyrrellite
    Cu(Co
    3+
     
    ,Ni
    3+
     
    )
     
    2
    Se
     
    4
    3.11.21Imgreite
    NiTe (?)
    3.11.22Melonite
    NiTe
     
    2
    3.11.23Kitkaite
    NiTeSe
    3.11.24Dienerite
    3.11.25Orcelite
    Ni
     
    5-x
    As
     
    2
    3.11.26Maucherite
    Ni
     
    11
    As
     
    8
    3.11.27Nickeline
    NiAs
    3.11.28Rammelsbergite
    NiAs
     
    2
    3.11.29Pararammelsbergite
    NiAs
     
    2
    3.11.30Nickelskutterudite
    NiAs
     
    2-3
    3.11.31Oregonite
    Ni
     
    2
    FeAs
     
    2
    3.11.32Westerveldite
    (Fe,Ni,Co)As
    3.11.33Langisite
    (Co,Ni)As ratio Co:Ni = 5:1
    3.11.34Gersdorffite
    NiAsS
    3.11.35Jolliffeite
    NiAsSe
    3.11.36Breithauptite
    NiSb
    3.11.38Ullmannite
    NiSbS
    3.11.39Willyamite
    (Co,Ni)SbS

    Other Names for Violarite

    Other Languages:
    German:Violarit
    Russian:Виоларит
    Spanish:Violarita

    Other Information

    Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

    References for Violarite

    Reference List:Clarke and Catlett (1889), American Journal of Science: 37: 372.

    Lindgren and Davy (1924), Economic Geology: 19: 309.

    Short, Maxwell Naylor & E.V. Shannon (1930), Violarite and other rare nickel sulfides: American Mineralogist: 15: 1-22.

    Palache, Charles, Harry Berman & Clifford Frondel (1944), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume I: 262-265.

    Berry, L.G. and R.M. Thompson (1962) X-ray powder data for the ore minerals. Geological Society of America Mem. 85: 77-78.

    Canadian Mineralogist (1969): 6: 629-643.

    Misra, K.C. and M.E. Fleet (1974), Chemical composition and stability of violarite: Economic Geology: 69: 391-403.

    Dunn, J.G., & V.L. Howes (1996): The oxidation of violarite: Thermochimica Acta: 282/283: 305-316.

    Grguric, B.A. (2002), Hypogene violarite of exsolution origin from Mount Keith, Western Australia: field evidence for a stable pentlandite-violarite tie line: Mineralogical Magazine: 66: 313-326.

    Tenailleau, Christophe, Allan Pring, Barbara Tschmann, Joël Brugger, Ben Grguric, and Andrew Putnis (2006), Transformation of pentlandite to violarite under mild hydrothermal conditions: American Mineralogist: 91: 706-709.

    Internet Links for Violarite

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  • External Links:
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  • Look for Violarite on Wikipedia
  • Look for Violarite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Violarite in the Natural History Museum (London) online catalogue
  • Violarite details from Handbook of Mineralogy (PDF)
  • Mineral Dealers:
  • Rare and Unusual minerals at Mineralogical Research Company
  • Wright's Rock Shop - excellent mineral specimens since 1970
  • Search for Violarite at Thames Valley Minerals
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    Localities for Violarite

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