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Afwillite

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Ettringer Bellerberg Mt., Ettringen, Mayen, Eifel Mts, Rhineland-Palatinate, Germany
© Stephan Wolfsried

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Formula:
Ca
 
3
[HSiO
 
4
]
 
2
 · 2H
 
2
O
System:MonoclinicColour:Colourless
Lustre:VitreousHardness:3
Name:Named after Alpheus Fuller Williams of the Debeers Consolidated Mines. Dutoitspan mine, South Africa.
This page provides mineralogical data about Afwillite.

Classification of Afwillite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/B.22-30
Nickel-Strunz 10th (pending) edition ID:9.AG.75

9 : SILICATES (Germanates)
A : Nesosilicates
G : Nesosilicates with additional anions; cations in > [6] +- [6] coordination
Dana 8th edition ID:52.4.7.1

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination
Hey's CIM Ref.:14.5.11

14 : Silicates not Containing Aluminum
5 : Silicates of Ca
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Type Occurrence of Afwillite

Type Locality:Dutoitspan Mine, Kimberley, Northern Cape Province, South Africa
Year of Discovery:1925

Physical Properties of Afwillite

Lustre:Vitreous
Colour:Colourless
Streak:White
Hardness (Mohs):3
Cleavage:Perfect

Crystallography of Afwillite

Crystal System:Monoclinic
Cell Parameters:a = 16.27Å, b = 5.63Å, c = 13.23Å
β = 134.9°
Ratio:a:b:c = 2.89 : 1 : 2.35
Unit Cell Volume:V 858.42 ų (Calculated from Unit Cell)

Optical Data of Afwillite

Type:Biaxial (+)
RI values: nα = 1.617 nβ = 1.620 nγ = 1.634
Maximum Birefringence:δ = 0.017

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r < v

Chemical Properties of Afwillite

Formula:
Ca
 
3
[HSiO
 
4
]
 
2
 · 2H
 
2
O
Essential elements:Ca, H, O, Si
All elements listed in formula:Ca, H, O, Si
Common Impurities:Al,Fe,Mg,F

Relationship of Afwillite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.AG.05Abswurmbachite
CuMn
3+
6
O
 
8
(SiO
 
4
)
9.AG.05Braunite
Mn
2+
 
Mn
3+
6
[O
 
8
|SiO
 
4
]
9.AG.05Neltnerite
CaMn
3+
6
[O
 
8
|SiO
 
4
]
9.AG.10Långbanite
(Mn
2+
 
,Ca)
 
4
(Mn
3+
 
,Fe
3+
 
)
 
9
Sb
5+
 
[O
 
8
|SiO
 
4
]
 
2
9.AG.15Malayaite
CaSn[O|SiO
 
4
]
9.AG.15Titanite
CaTi[O|SiO
 
4
]
9.AG.15Vanadomalayaite
CaV
4+
 
[O|SiO
 
4
]
9.AG.20Cerite-(Ce)
(Ce,Ca)
 
9
(Mg,Fe)Si
 
7
(O,OH,F)
 
28
9.AG.20Cerite-(La)
(La,Ce,Ca)
 
9
(Fe,Ca,Mg)(SiO
 
4
)
 
3
[SiO
 
3
(OH)]
 
4
(OH)
 
3
9.AG.25Trimounsite-(Y)
Y
 
2
Ti
 
2
[O
 
5
|SiO
 
4
]
9.AG.25Yftisite-(Y)
(Y,Dy,Er)
 
4
(Ti,Sn)O(SiO
 
4
)
 
2
(F,OH)
 
6
9.AG.30Sitinakite
KNa
 
2
Ti
 
4
Si
 
2
O
 
13
(OH)·2H
 
2
O
9.AG.35Kittatinnyite
Ca
 
2
Mn
 
2
Mn(SiO
 
4
)
 
2
(OH)
 
4
·9H
 
2
O
9.AG.40Natisite
Na
 
2
Ti[O|SiO
 
4
]
9.AG.40Paranatisite
Na
 
2
Ti[O|SiO
 
4
]
9.AG.45Törnebohmite-(Ce)
(Ce,La)
 
2
Al(SiO
 
4
)
 
2
OH
9.AG.45Törnebohmite-(La)
(La,Ce)
 
2
Al(SiO
 
4
)
 
2
OH
9.AG.50Kuliokite-(Y)
Y
 
4
Al(SiO
 
4
)
 
2
(OH)
 
2
F
 
5
9.AG.55Chantalite
CaAl
 
2
[(OH)
 
4
|SiO
 
4
]
9.AG.60Mozartite
CaMn
3+
 
[OH|SiO
 
4
]
9.AG.60Vuagnatite
CaAl[OH|SiO
 
4
]
9.AG.65Hatrurite
Ca
 
3
[O|SiO
 
4
]
9.AG.70Jasmundite
Ca
 
11
[O
 
2
|S|(SiO
 
4
)
 
4
]
9.AG.80Bultfonteinite
Ca
 
2
[F|HSiO
 
4
] · H
 
2
O
9.AG.85Zoltaiite
BaV
4+
2
V
3+
12
Si
 
2
O
 
27
9.AG.90Tranquillityite
(Fe
2+
 
,Ca)
 
8
(Zr,Y)
 
2
Ti
 
3
[O
 
4
|SiO
 
4
]
 
3
Related Minerals - Hey's Index Grouping:
14.5.1Wollastonite
Ca[SiO
 
3
]
14.5.2Wollastonite-7T
14.5.3Wollastonite-2M
CaSiO
 
3
14.5.4Rankinite
Ca
 
3
Si
 
2
O
 
7
14.5.5Kilchoanite
Ca
 
3
Si
 
2
O
 
7
14.5.6Larnite
Ca
 
2
[SiO
 
4
]
14.5.7Bredigite
Ca
 
7
Mg[SiO
 
4
]
 
4
14.5.8Hatrurite
Ca
 
3
[O|SiO
 
4
]
14.5.9Rosenhahnite
HCa
 
3
[Si
 
3
O
 
9
(OH)]
14.5.10Dellaite
Ca
 
6
Si
 
3
O
 
11
(OH)
 
2
14.5.12Xonotlite
Ca
 
6
Si
 
6
O
 
17
(OH)
 
2
14.5.13Foshagite
Ca
 
4
[(OH)
 
2
|Si
 
3
O
 
9
]
14.5.14Hillebrandite
Ca
 
2
[(OH)
 
2
|SiO
 
3
]
14.5.15Jaffeite
Ca
 
6
[(OH)
 
6
|Si
 
2
O
 
7
]
14.5.16Suolunite
Ca
 
2
[H
 
2
Si
 
2
O
 
7
] · H
 
2
O
14.5.17Killalaite
Ca
 
3
[Si
 
2
O
 
7
] · 0.5H
 
2
O
14.5.18Okenite
CaSi
 
2
O
 
5
·2H
 
2
O
14.5.19Riversideite
Ca
 
5
Si
 
6
O
 
16
(OH)
 
2
·2H
 
2
O
14.5.20Trabzonite
Ca
 
4
Si
 
3
O
 
10
·2H
 
2
O
14.5.21Gyrolite
Ca
 
4
(Si
 
6
O
 
15
)(OH)
 
2
·3H
 
2
O
14.5.22Foshallasite
Ca
 
3
[Si
 
2
O
 
7
] · 3H
 
2
O(?)
14.5.23Tobermorite
Ca
 
5
Si
 
6
(O,OH)
 
18
·5H
 
2
O
14.5.24Clinotobermorite
Ca
 
5
[Si
 
3
O
 
8
(OH)
 
2
]2.4H
 
2
O - Ca
 
5
[Si
 
6
O17]·5H
 
2
O
14.5.25Nekoite
Ca
 
3
Si
 
6
O
 
15
·7H
 
2
O
14.5.26Plombièrite
Ca
 
5
Si
 
6
O
 
16
(OH)
 
2
·7H
 
2
O
14.5.27Jennite
Ca
 
9
H
 
2
Si
 
6
O
 
18
(OH)
 
8
·6H
 
2
O

Other Names for Afwillite

German names:
Afwillit
Russian names:
Афвиллит
Spanish names:
Afwillita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Afwillite

Reference List:Mineralogical Magazine (1925): 20, 277-285.

American Mineralogist: 10: 447.

Acta Crystallographica: B32: 475-480.

Internet Links for Afwillite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Afwillite details from Handbook of Mineralogy (PDF)
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    Localities for Afwillite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    France
     
    • Auvergne
      • Puy-de-Dôme
        • Clermont-Ferrand
          • Ceyrat
    		H. Grünhagen and J. Mergoil, Bull. Soc. Franç. Minér. Crist. , 1963, LXXXVI, pp. 149-157.
    Germany
     
    • Bavaria
      • Franconia
        • Maroldsweisach
    		Pöllmann, H. (1991): Die Afwillit-Portlandit Paragenese im Basalt des Zeilbergs bei Maroldsweisach/Unterfranken. Aufschluss, 42, 257-266
    • Rhineland-Palatinate
      • Eifel Mts
        • Daun
          • Hinterweiler
    		Blass, G., Emmerich, F., Graf, HW., Schäfer, Ch., Tschörtner, J., (2006): Minerale der Eifelvulkane, Version 1.0, CD, published by authors
          • Üdersdorf
    		Schüller, W., Betz, V., Die Mineralien vom Emmelberg, Lapis 12/1986
        • Mayen
          • Ettringen
    		Jasmund, K. and Hentschel, G. (1964): Seltene Mineralparagenesen in den Kalksteineinschlüssen der Lava des Ettringer Bellerberges bei Mayen (Eifel), Beitr. Mineral. Petrogr. 10, 296-314; Lapis, 15 (5), 9-36.
        • Mendig
          • Bell
    		Blass, G., Graf, HW., Kolitsch, U., Sebold, D., Über neue Mineralfunde aus der Vulkaneifel, MW 6/2005
    Ireland
     
    • Co. Sligo
      • Killala Bay
    		Min.Mag.(1974) 39, 544-548
    Israel
     
    Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
    www.minsocam.org/msa/Handbook/Afwillite.PDF
    Italy
     
    • Latium
      • Rome Province
    		Caponera, I., Fiori, S., Pucci, R., & Signoretti, E. (2007). I minerali dei Colli Albani. Un aggiornamento sugli ultimi dieci anni di ricerche. Rivista Mineralogica Italiana, 31 (2), 74-91.
      • Viterbo Province
        • Montalto di Castro
          • Pietra Massa Locality
    		Passaglia, E. & Turconi, B. (1982): Silicati ed altri minerali di Montalto di Castro - VT. Rivista Mineralogica Italiana, 4/1982, 97-110.
    • Veneto
      • Vicenza Province
    		Lapis, 15 (12), 27-32+50.
    Japan
     
    • Honshu Island
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi
            • Bitchu-cho (Bicchu-cho)
    New Zealand
     
    • North Island
      • Northland
        • Kaipara
          • Tokatoka
    		Railton, G.L. & Watters, W.A., Minerals of New Zealand, New Zealand Geological Survey Bull. #104 (1990).
    Russia
     
    • Eastern-Siberian Region
      • Krasnoyarsk Territory (Krasnoyarsk Kray; Krasnoyarskii Krai)
        • Evenkia (Evenkiyskiy Autonomous okrug)
          • Nizhnyaya Tunguska River Basin (Lower Tunguska River)
    		No reference listed
    • Northern Caucasus Region
      • Kabardino-Balkarian Republic
        • Verkhnechegemskiy volcanic structure
    		A. E. Zadov data
    South Africa
     
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    		Minerals of South Africa
        • N'Chwaning Mines
    		[Von Bezing, K. L. et al. (1991) - The Kalahari (Afrique du Sud) manganese field : an update, Mineralogical Record, 22 (3), 279-302.]
    Minerals of South Africa
      • Kimberley
    		[Min.Mag.(1925) 20, 277-285; Clark, 1993 - "Hey's Mineral Index, 3rd Edition"]
    UK
     
    • Northern Ireland
      • Co. Antrim
        • Larne
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 590; Strübel, Zimmer: "Lexikon der Minerale", 2nd Ed., 1991.
    • Scotland
      • Strathclyde (Ayrshire)
        • Beith
    		BMS Database
    USA
     
    • California
      • Riverside Co.
        • Crestmore
          • Crestmore quarries
            • Sky Blue Hill
    		No reference listed
    • Missouri
      • Washington Co.
        • Meramec State Park
    		R&M 73:2 pp 98-117
    Mineral and/or Locality
    Google
     
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