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Wherryite

Formula:
Pb
 
4
CuCO
 
3
(SO
 
4
)
 
2
(Cl,OH)
 
2
O
System:MonoclinicColour:Light green, yellow or ...
Lustre:Vitreous
Name:Named after Edgar Theodore Wherry (1885-1982), mineralogist and plant ecologist; President of the Mineralogical Society of America (1923).
This page provides mineralogical data about Wherryite.

Classification of Wherryite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/B.28-25
Nickel-Strunz 10th (pending) edition ID:7.BC.55

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
B : Sulfates (selenates, etc.) with additional anions, without H2O
C : With medium-sized and large cations
Dana 8th edition ID:32.3.3.1

32 : COMPOUND SULFATES
3 : Anhydrous Compound Sulfates containing Hydroxyl or Halogen
Hey's CIM Ref.:12.2.14

12 : Carbonates with other anions
2 : Carbonates with sulphate
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Type Occurrence of Wherryite

Type Locality:Mammoth-Saint Anthony Mine (Mammoth-St Anthony Mine; Mammoth Mine; St. Anthony Mine; Tiger property; Mammoth Gold Mines Ltd. property), St. Anthony deposit, Tiger, Mammoth District, Pinal Co., Arizona, USA
Year of Discovery:1950

Physical Properties of Wherryite

Lustre:Vitreous
Colour:Light green, yellow or bright yellowish-green.
Density (measured):6.45 g/cm3

Crystallography of Wherryite

Crystal System:Monoclinic
Cell Parameters:a = 20.78Å, b = 5.78Å, c = 9.14Å
β = 91.24°
Ratio:a:b:c = 3.595 : 1 : 1.581
Unit Cell Volume:V 1,097.53 ų (Calculated from Unit Cell)
Morphology:Massive; fine-granular.

Optical Data of Wherryite

Type:Biaxial (-)
RI values: nα = 1.942 nβ = 2.010 nγ = 2.024
2V:Measured: 50° , Calculated: 46°
Maximum Birefringence:δ = 0.082

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:relatively weak

Chemical Properties of Wherryite

Formula:
Pb
 
4
CuCO
 
3
(SO
 
4
)
 
2
(Cl,OH)
 
2
O
Essential elements:C, Cl, Cu, O, Pb, S
All elements listed in formula:C, Cl, Cu, H, O, Pb, S

Relationship of Wherryite to other Species

Related Minerals - Nickel-Strunz Grouping):
7.BC.05D'Ansite
Na
 
21
Mg(SO
 
4
)
 
10
Cl
 
3
7.BC.10Alunite
KAl
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Ammonioalunite
(NH
 
4
)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Ammoniojarosite
(NH
 
4
)Fe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Argentojarosite
AgFe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Beaverite
Pb(Fe
3+
 
,Cu,Al)
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Dorallcharite
(Tl,K)Fe
3+
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Huangite
CaAl
 
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.10Hydroniumjarosite
(H
 
3
O)Fe
3+
3
(SO
 
4
)
 
2
(OH)
 
6
7.BC.10Jarosite
KFe
3+
 
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Minamiite
(Na,Ca
 
0.5
,K)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Natroalunite
(Na,K)Al
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Natrojarosite
NaFe
 
3
[(OH)
 
3
|SO
 
4
]
 
2
7.BC.10Osarizawaite
Pb(Al,Cu)
 
3
[(OH,H
 
2
O)
 
3
|SO
 
4
]
 
2
7.BC.10Plumbojarosite
PbFe
3+
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.10Walthierite
BaAl
 
6
[(OH)
 
3
|SO
 
4
]
 
4
7.BC.15Ye'elimite
Ca
 
4
Al
 
6
[O
 
12
|SO
 
4
]
7.BC.20Atlasovite
K(BiO)Cu
 
6
Fe
3+
 
[Cl|O
 
3
|(SO
 
4
)
 
5
]
7.BC.20Nabokoite
KCu
 
7
Te
4+
 
[Cl|O
 
4
|(SO
 
4
)
 
5
]
7.BC.25Chlorothionite
K
 
2
Cu[Cl
 
2
|SO
 
4
]
7.BC.30Euchlorine
KNaCu
 
3
[O|(SO
 
4
)
 
3
]
7.BC.30Fedotovite
K
 
2
Cu
 
3
[O|(SO
 
4
)
 
3
]
7.BC.35Kamchatkite
KCu
 
3
[O|Cl|(SO
 
4
)
 
2
]
7.BC.40Piypite
K
 
2
Cu
 
2
[O|(SO
 
4
)
 
2
]
7.BC.45Klyuchevskite
K
 
3
Cu
 
3
(Fe
3+
 
,Al)[O|(SO
 
4
)
 
2
]
 
2
7.BC.45Alumoklyuchevskite
K
 
3
Cu
 
3
(Al,Fe
3+
 
)[O|(SO
 
4
)
 
2
]
 
2
7.BC.50Caledonite
Cu
 
2
Pb
 
5
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
3
]
7.BC.60Mammothite
Pb
 
6
Cu
 
4
AlSb[(OH)
 
9
|Cl
 
2
|SO
 
4
]
 
2
7.BC.65Linarite
PbCu[(OH)
 
2
|SO
 
4
]
7.BC.65Schmiederite
Pb
 
2
Cu
 
2
[(OH)
 
4
|SeO
 
3
|SeO
 
4
]
7.BC.65Munakataite
Pb
 
2
Cu
 
2
(Se
4+
 
O
 
3
)(SO
 
4
)(OH)
 
4
7.BC.70Chenite
Pb
 
4
Cu[(OH)
 
3
|SO
 
4
]
 
2
7.BC.75Krivovichevite
Pb
 
3
[Al(OH)
 
6
](SO
 
4
)(OH)
7.BC.80Anhydrokainite
KMgClSO
 
4
Related Minerals - Hey's Index Grouping:
12.2.1Burkeite
Na
 
6
CO
 
3
(SO
 
4
)
 
2
12.2.2Hanksite
Na
 
22
K(SO
 
4
)
 
9
(CO
 
3
)
 
2
Cl
12.2.3Tychite
Na
 
6
Mg
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.4Motukoreaite
NaMg
 
19
Al
 
12
(CO
 
3
)
 
6.5
(SO
 
4
)
 
4
(OH)
 
54
·28H
 
2
O
12.2.5Ferrotychite
Na
 
6
(Fe,Mn,Mg)
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.6Nakauriite
Cu
 
8
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
4
] · 48H
 
2
O
12.2.7Carbonatecyanotrichite
Cu
 
4
Al
 
2
[(OH)
 
12
|(CO
 
3
,SO
 
4
)] · 2H
 
2
O
12.2.8Rapidcreekite
Ca
 
2
[CO
 
3
|SO
 
4
] · 4H
 
2
O
12.2.9Tatarskite
Ca
 
6
Mg
 
2
(SO
 
4
)
 
2
(CO
 
3
)
 
2
Cl
 
4
(OH)
 
4
·7H
 
2
O
12.2.10Schulenbergite
(Cu,Zn)
 
7
[(OH)
 
10
|(SO
 
4
,CO
 
3
)
 
2
] · 3H
 
2
O
12.2.11Leadhillite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.12Macphersonite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.13Susannite
Pb
 
4
SO
 
4
(CO
 
3
)
 
2
(OH)
 
2
12.2.15Caledonite
Cu
 
2
Pb
 
5
[(OH)
 
6
|CO
 
3
|(SO
 
4
)
 
3
]
12.2.16Nasledovite
PbMn
 
3
Al
 
4
(CO
 
3
)
 
4
SO
 
4
O
 
5
·5H
 
2
O
12.2.17Jouravskite
Ca
 
6
Mn
3+
2
[(OH)
 
4
|(SO
 
4
,CO
 
3
)]
 
3
· 26H
 
2
O
12.2.18Schröckingerite
NaCa
 
3
(UO
 
2
)[F|(CO
 
3
)
 
3
|SO
 
4
] · 10H
 
2
O
12.2.19Manganotychite
Na
 
6
Mn
 
2
SO
 
4
(CO
 
3
)
 
4
12.2.20Hauckite
Fe
3+
3
(Mg,Mn
2+
 
)
 
24
Zn
 
18
[(OH)
 
81
|(CO
 
3
)
 
2
|(SO
 
4
)
 
4
]
12.2.21Paraotwayite
Ni(OH)
 
2-x
(SO
 
4
,CO
 
3
)
 
0.5x
12.2.22Carrboydite
(Ni,Cu)
 
14
Al
 
9
[(OH)
 
43
|(SO
 
4
,CO
 
3
)
 
6
] · 7H
 
2
O
12.2.23Mountkeithite
(Mg,Ni)
 
11
(Fe
3+
 
,Cr
3+
 
,Al)
 
3
[(OH)
 
24
|(SO
 
4
,CO
 
3
)
 
3.5
] · 11H
 
2
O
12.2.24Camerolaite
Cu
 
4
Al
 
2
[(OH)
 
10
|CO
 
3
|(HSbO
 
4
,SO
 
4
)] · 2H
 
2
O

Other Names for Wherryite

German names:
Wherryit
Russian names:
Уэрриит
Spanish names:
Wherryita

Other Information

Other Information:Slowly soluble in cold HCl or HNO3.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Wherryite

Reference List:Fahey, J.J., Daggett, and Gordon (1950), Wherryite, a new mineral from the Mammoth mine, Arizona, American Mineralogist: 35: 93-98.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 632.

American Mineralogist (1970): 55: 505.

Cooper, M. A. & Hawthorne, F. C. (1994): The crystal structure of wherryite, Pb7Cu2(SO4)4(SiO4)2(OH)2, a mixed sulfate-silicate with [[6]M(TO4)2psi] chains. Canadian Mineralogist: 32: 373-380.

Internet Links for Wherryite

Search Engines:
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  • External Links:
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  • Look for Wherryite on Wikipedia
  • Look for Wherryite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Wherryite in the Natural History Museum (London) online catalogue
  • Mineral Dealers:
  • Wright's Rock Shop - excellent mineral specimens since 1970
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  • Fabre Minerals - search for Wherryite specimens
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    Localities for Wherryite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Austria
     
    • Salzburg
      • Hohe Tauern Mts
        • Rauris valley
          • Hüttwinkl valley
            • Alteck Mt. - Hoher Sonnblick Mt. area
              • Kolm-Saigurn
    A. Strasser: Die MInerale Salzburgs (1989)
    France
     
    • Languedoc-Roussillon
      • Lozère
    Lheur C. (1997), La mine de Vialas en Lozère, 170 p.
    Germany
     
    • Lower Saxony
      • Harz Mts
        • Braunlage
    Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
    USA
     
    • Arizona
      • Maricopa Co.
        • Big Horn Mts
          • Osborn District
            • Tonopah
              • Belmont Mountain
                • Tiger Wash
      • Mohave Co.
        • Artillery Mts
          • Artillery Peak area
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 419.
      • Pinal Co.
        • Mammoth District
          • Tiger
            • St. Anthony deposit
    Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 632; Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 141, 419; Fahey, J.J., et al (1950), Wherryite, a new mineral from the Mammoth mine, AZ, American Mineralogist: 35: 93-98; Bideaux, R.A. (1980), Tiger, AZ, Mineralogical Record: 11: 155-181; Galbraith, F.W. & D.J. Brennan (1959), Minerals of AZ: 67.
        • Silver Reef Mts
          • Casa Grande
    Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 419.
    Mineral and/or Locality
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