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Whewellite

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William Whewell
Formula:
Ca(C2O4) · H2O
System:
Monoclinic
Colour:
White, yellow, brown, ...
Lustre:
Vitreous, Pearly
Hardness:
2½ - 3
Name:
Named after William Whewell (1794-1866), English naturalist and scientist, Professor of Moral Philosophy and inventor of the system of crystallographic indexing.

The type locality is uncertain, however, the most likely type locality is Cavnic, Romania (Papp, G. (2004) History of minerals, rocks and fossil resins discovered in the Carpathian Region. Hungarian Natural History Museum publ., Studia Naturalia 15, 215p.)
A rare low-temperature primary hydrothermal mineral in carbonate-sulphide veins; also occurs in geodes, or septarian nodules; associated with coal measures and surrounding rocks with organic material; in some uranium deposits. As microscopic crystals in living plant cells and as calculi or as a sediment in the human urinary tract.

NOTE: Cleaning any specimen containing Ca-bearing soluble species with oxalic acid will lead to crystallisation of whewellite or weddellite.

Classification of Whewellite

Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
10.AB.45

10 : ORGANIC COMPOUNDS
A : Salts of organic acids
B : Oxalates
50.1.1.1

50 : ORGANIC COMPOUNDS
1 : Oxalates
31.1.5

31 : Oxalates, Citrates, Mellitates and Acetates
1 : Oxalates
mindat.org URL:
http://www.mindat.org/min-4276.html
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Occurrences of Whewellite

Geological Setting:
In carbonate-sulphide veins, geodes, or septarian nodules; associated with coal measures or in surrounding rock containing organic matter; in some uranium deposits.

Physical Properties of Whewellite

Vitreous, Pearly
Diaphaneity (Transparency):
Transparent, Translucent
Comment:
Lustre pearly on {010} and on some cleavages.
Colour:
White, yellow, brown, colourless; colourless in transmitted light.
Hardness (Mohs):
2½ - 3
Tenacity:
Brittle
Cleavage:
Very Good
On {101} very good; on {010}, imperfect; on {001}, {110}, indistinct.
Fracture:
Conchoidal
Density:
2.21 - 2.23 g/cm3 (Measured)    2.22 g/cm3 (Calculated)

Crystallography of Whewellite

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Cell Parameters:
a = 6.284Å, b = 7.29Å, c = 9.994Å
β = 107.03°
Ratio:
a:b:c = 0.862 : 1 : 1.371
Unit Cell Volume:
V 437.75 ų (Calculated from Unit Cell)
Z:
2
Morphology:
Crystals equant to short prismatic [001], typically distorted with faces commonly irregularly developed, exhibiting forms {001}, {011}, {010}, {110}, {120}, {132}, {101}, plus several additional. Cleavable massive.
Twinning:
Very common on {101} as twin and contact plane, with or without reentrant angles, yielding heart-shaped or prismatic, and of pseudo-orthorhombic appearance.
Comment:
Space Group: P21/n

Crystallographic forms of Whewellite

Crystal Atlas:
Image Loading
Click on an icon to view
Whewellite no.7 - Goldschmidt (1913-1926)
3d models and HTML5 code kindly provided by www.smorf.nl.

Toggle
Edge Lines | Miller Indicies | Axes

Transparency
Opaque | Translucent | Transparent

View
Along a-axis | Along b-axis | Along c-axis | Start rotation | Stop rotation
X-Ray Powder Diffraction:
Image Loading

Radiation - Copper Kα
Data Set:
Data courtesy of RRUFF project at University of Arizona, used with permission.

Optical Data of Whewellite

Type:
Biaxial (+)
RI values:
nα = 1.489 - 1.491 nβ = 1.553 - 1.554 nγ = 1.649 - 1.650
2V:
Measured: 80° to 84°, Calculated: 84°
Max Birefringence:
δ = 0.160
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
Low
Dispersion:
none

Chemical Properties of Whewellite

Formula:
Ca(C2O4) · H2O
Essential elements:
All elements listed in formula:
CAS Registry number:
5794-28-5

CAS Registry numbers are published by the American Chemical Society

Relationship of Whewellite to other Species

10.AB.05HumboldtineFe2+(C2O4) · 2H2O
10.AB.05LindbergiteMn2+(C2O4) · 2H2O
10.AB.10GlushinskiteMg(C2O4) · 2H2O
10.AB.15MoolooiteCu(C2O4) · 0.4H2O
10.AB.20StepanoviteNaMgFe3+(C2O4)3 · 8-9H2O
10.AB.25MinguzziteK3Fe3+(C2O4)3 · 3H2O
10.AB.30WheatleyiteNa2Cu(C2O4)2 · 2H2O
10.AB.35ZhemchuzhnikoviteNaMg(Fe3+,Al)(C2O4)3 · 8H2O
10.AB.40WeddelliteCa(C2O4) · 2H2O
10.AB.50CaoxiteCa(C2O4) · 3H2O
10.AB.55Oxammite(NH4)2(C2O4) · H2O
10.AB.60NatroxalateNa2(C2O4)
10.AB.65Coskrenite-(Ce)(Ce,Nd,La)2(C2O4)(SO4)2 · 12H2O
10.AB.70Levinsonite-(Y)(Y,Nd,La)Al(C2O4)(SO4)2 · 12H2O
10.AB.75Zugshunstite-(Ce)(Ce,Nd,La)Al(C2O4)(SO4)2 · 12H2O
10.AB.80NovgorodovaiteCa2(C2O4)Cl2 · 2H2O
31.1.1Oxammite(NH4)2(C2O4) · H2O
31.1.2MoolooiteCu(C2O4) · 0.4H2O
31.1.3WheatleyiteNa2Cu(C2O4)2 · 2H2O
31.1.4GlushinskiteMg(C2O4) · 2H2O
31.1.6WeddelliteCa(C2O4) · 2H2O
31.1.7HumboldtineFe2+(C2O4) · 2H2O
31.1.8StepanoviteNaMgFe3+(C2O4)3 · 8-9H2O
31.1.9ZhemchuzhnikoviteNaMg(Fe3+,Al)(C2O4)3 · 8H2O
31.1.10MinguzziteK3Fe3+(C2O4)3 · 3H2O

Other Names for Whewellite

Name in Other Languages:

Other Information

Other Information:
Soluble in acids. Insoluble in water.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Whewellite

Reference List:
Brooke, H. T. (1840) Philosophical Magazine and Journal of Science: 16: 449-450 (as Oxalate of Lime).

Shepard C.U. (1844) Treatise on Mineralogy. second edition: 111 (as Oxacalcite).

Brooke, H.J. and Miller, W.H. (1852) Introduction to Mineralogy by Wm. Phillips, London, 1823. New edition by Brooke and Miller. 8vo, London: 623.

Liebig (1853) Annalen der Chemie, Leipzig (Justus Liebig’s): 86: 113 (as Thierschite).

Dana, J.D. (1854) System of Mineralogy, 4th. Edition, New York.

Frenzel (1889) Mineralogische und petrographische Mitteilungen, Vienna: 11: 83 (as Kohlenspath).

Becke (1907) Mineralogische und petrographische Mitteilungen, Vienna: 26: 391.

Slavík (1908) Rozpr. böhm. Ak. Prag: 17, no. 38.

Ježek (1908) Ac. Sc. Bohéme, Bull.: 13: 1.

Ježek (1909) Ac. Sc. Bohéme, Bull.: 14: 1.

Ungemach (1909) Bulletin de la Société française de Minéralogie: 32: 20.

Ježek (1911) Ac. Sc. Bohéme, Bull.: 16: 1.

Kolbeck, Goldschmidt, and Schröder (1918) Beitr. Kr. Min.: 1: 199.

Wherry (1922) Journal of the Washington Academy of Science: 12: 196.

Goldschmidt, V. (1923) Atlas der Krystallformen. 9 volumes, atlas, and text: vol. 9: 70.

Frey (1924) Schweizerische mineralogische und petrographische Mitteilungen, Frauenfeld: 4: 16.

Vassoyevicz and Razumovsky (1928) Mem. soc. russe min.: 57: 275.

Kašpar (1932) Vĕstnik. Král. Čes. Spol. Nauk, Cl. 2, no. 34.

Kašpar (1939) Knihov. Stat. Geol. Úst. Česk. Repub.: 20: 1.

Pobeguin, et al (1943) Comptes rendus de l’Académie des sciences de Paris: 216: 500, 808.

Kalyuzhnyi (1948) Comptes rendus de l’académie des sciences de l’U.R.S.S.: 59: 1631.

Pecora, W.T. and J.H. Kerr (1954) Whewellite from a septarian limestone concretion in marine shale near Havre, Montana. American Mineralogist, 39, 208–214.

Leavens, P.B. (1968) New data on whewellite. American Mineralogist: 53: 455-463.

American Mineralogist (1980): 65: 327-334.

Deganello, S. and O.E. Piro (1981) The crystal structure of calcium oxalate monohydrate (whewellite). Neues Jahrb. Mineral., Monatsh., 81–88.

Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva (1984): 113: 84.

Internet Links for Whewellite

Specimens:
The following Whewellite specimens are currently listed for sale on minfind.com.

Localities for Whewellite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Australia
 
  • New South Wales
    • Durham Co.
      • Muswellbrook
Keith F Compton collection
  • Tasmania
    • Cape Grim district
http://www.crocoite.com/locationbulletins/part1/zeolites.pdf
  • Victoria
    • City of Greater Shepparton
      • Murchison
Louis H. Fuchs, Kenneth J. Jensen & Edward Olsen (1970). Mineralogy and Composition of the Murchison Meteorite. Meteoritics 5, #4, p. 198. (Dec 1970).
  • Western Australia
    • Upper Gascoyne Shire
Moolooite, a Naturally Occurring Hydrated Copper Oxalate; R.M. Clarke and I.R. Williams; Mineralogical Magazine, June 1986, Vol 50, pp 295-298
Austria
 
  • Salzburg
    • Hohe Tauern
      • Habach valley
NIEDERMAYR, G., F. BERNHARD, H.-P. BOJAR, F. BRANDSTÄTTER, H. FINK, J. GRÖBNER, V. M. F. HAMMER, G. KNOBLOCH, U. KOLITSCH, B. LEIKAUF, W. POSTL, M. SABOR, & F. WALTER (2006): Neue Mineralfunde aus Österreich LV. – Carinthia II, 196./116.: 121-157.
Brazil
 
  • Minas Gerais
    • Jequitinhonha valley
      • Itinga
        • Monte Belo
Luiz Alberto Dias Menezes
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • Central Bohemia Region
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101; Duda, Rejl, Slivka: "Mineralien", 1991; Zacek, V., Oplustil, S., Mayova, A. & Meyer, F. R. (1995): Die Mineralien von Kladno in Mittelböhmen, Tschechische Republik. Mineralien-Welt 6 (1), 13-30 (in German).
        • Pchery
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101.
Šarf J.: Nové nálezy v kladenských pelosideritech. Časopis pro mineralogii a geologii, 1979, 24, 3, 324-325.
      • Příbram
        • Dubenec
Litochleb et al. (2005) Bull. Nár. muz. (Praha)
    • Ústí Region
      • Bílina (Bilin)
Bouška, V., Dvořák, Z.: Nerosty severočeské hěndouhelné pánve. Praha: Severočeské doly, a.s., 160 s.
      • Chomutov (Komotau)
Svejkovský, J., Koutecký, D.: Nerosty v pelokarbonátových konkrecích na hnědouhelném lomu Libouš u Chomutova. Minerál, 2008, roč. 16, č. 1, s. 41 - 44.
      • Duchcov (Dux)
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101.
      • Most
RnDr.Zdeněk Dvořák
Finland
 
  • Lapland Region
    • Savukoski
      • Tulppio
Vartiainen, H. 1980 The petrography, mineralogy and petrochemistry of the Sokli carbonative massif, northern Finland. Geological Survey of Finland, Bulletin, 313
France
 
  • Alsace
    • Bas-Rhin
      • Villé Valley
        • Urbeis
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101.
  • Rhône-Alpes
    • Drôme
Martin, R. (1989): "La whewellite de Condorcet (Drôme, France, 1° partie)." Le Cristallier Suisse, 8(7), 301-333.; Anthony, John. W., Bideaux, R., Bladh, K., Nichols, M., Eds., (2001-2005) Handbook of Mineralogy, Mineralogical Society of America.
    • Loire
      • Saint-Just-en-Chevalet
"Les Mineraux, leurs gisements, leurs associations" P. Bariand, F. Cesbron, J. Geffroy, Mineraux et Fossiles 1978
P.-C. Guiollard (2002), L'uranium du Morvan et du Forez, Ed. P.-C. Guiollard, Fichous(64), 95 pp.
J.-J. Périchaud: "Où trouver les minéraux d'Auvergne", Vol. 1, Editions l'Instant Durable (Clermont-Ferrand), 1985, p. 92
Germany
 
  • Lower Saxony
    • Peine
Aufschluss 1986(8+9), 282
  • North Rhine-Westphalia
    • Münsterland
      • Steinfurt
        • Ibbenbüren
Weiss: "Mineralfundstellen, Deutschland West", Weise (Munich), 1990
  • Rhineland-Palatinate
    • Eifel
      • Niederzissen
        • Hannebach
Hentschel, G., Die Mineralien der Eifelvulkane, Weise Verlag, München (2. Auflage), 1987
  • Saxony
    • Dresden
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101; O'Donoghue, 1976 - "Encyclopedia of Minerals & Gemstones", 286.
    • Erzgebirge
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101; Wittern: "Mineralfundorte in Deutschland", 2001
      • Schlema-Hartenstein District
Roger Lang collection
No reference listed
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101; O'Donoghue, 1976 - "Encyclopedia of Minerals & Gemstones", 286.
      • Oelsnitz
Leon Hupperichs Collection
  • Thuringia
    • Gera
      • Ronneburg U deposit
T. Witzke & F. Rüger: Lapis 1998(7/8), 26-64
T. Witzke & F. Rüger: Lapis 1998(7/8), 26-64
Wittern: "Mineralfundorte in Deutschland", 2001
T. Witzke & F. Rüger: Lapis 1998(7/8), 26-64
Greenland
 
  • Kujalleq
    • Narsaq
Soerensen, H. (2001): The Ilimaussaq alkaline complex, South Greenland: status of mineralogical research with new results, Geology of Greenland Survey Bulletin 190, GEUS; Petersen, O.V. (2001): List of all minerals identified in the Ilímaussaq alkaline complex, South Greenland. Geology of Greenland Survey Bulletin. 190, 25-33
Hungary
 
  • Fejér Co.
    • Bicske-Zsámbéki Basin
      • Bicske-Csordakút
  • Heves Co.
    • Mátra Mts
      • Recsk
Zsivny,1925
Weiszburg,1983
Szakáll & Jánosi: Minerals of Hungary, 1995
  • Komárom-Esztergom Co.
    • Gerecse Mts
Szakáll & Jánosi: Minerals of Hungary, 1995
    • Pilisi Basin
      • Dorog
Szakáll-Gatter-Szendrei,2005
Italy
 
  • Emilia-Romagna
    • Modena Province
Dondi, M. & Puggioli, G. (1990): Minerali organici, 1 parte. Rivista Mineralogica Italiana, 4/1990, 189-206.
Kolitsch, U., Lackner, E., Ciriotti, M.E. (2008): Lindbergite: primo ritrovamento italiano a Molinello. Addendum-corrigendum. Micro (UK Report), 2/2008, 77-78
Mexico
 
  • Coahuila
    • Mun. de Cuatrociénegas
      • Cuatro Ciénegas (Cuatrociénegas de Carranza; Venustiano Carranza)
        • Limestone caves
Forti, P. et al. (2006): ACTA CARSOLOGICA 35/1, 79–98.
Romania
 
  • Maramureș Co.
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1101.
Mineralogical Record 28:132-139
Russia
 
  • Eastern-Siberian Region
    • Sakha Republic (Saha Republic; Yakutia)
      • Polar Yakutia
        • Bulun District
          • Lena River Basin
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
Pekov, I. (1998) Minerals First discovered on the territory of the former Soviet Union 369p. Ocean Pictures, Moscow
    • Transbaikalia (Zabaykalye)
      • Chitinskaya Oblast'
        • Krasnokamensk
P.M. Kartashov data
  • Far-Eastern Region
    • Primorskiy Kray
      • Kavalerovo Mining District
        • Dal'negorsk (Dalnegorsk; Tetyukhe; Tjetjuche; Tetjuche)
Min Rec vol 32, pp 7-30 (2001)
  • Krasnodarskiy Kray
    • Apsheronsk area
      • Khadyzhensk
Pavel M. Kartashov data
Slovakia
 
  • Prešov Region
    • Bardejov Co.
Bačo,P.,Pacindová,M., 1993: Whewellit a dawsonit - epigenetická mineralizácia v puklinách pieskovca pri Cígeľke. Min.Slovaca,Bratislava, 4,277-281p
  • Trenčín Region
    • Prievidza Co.
      • Handlová
Števko M., Bačík P., Cagáň P., 2011: Výskyt whewellitu v pelosideritoch uhoľného ložiska Handlová (Slovenská republika). Bull. mineral.-petrolog. Odd. Nár. Muz. (Praha), 19, 1, 27-31.
UK
 
  • England
    • North Yorkshire
      • North Pennines
        • Craven District
          • Ingleton
No reference listed
Ukraine
 
  • Crimea Oblast'
World of Stones v.9
USA
 
  • Arizona
    • Cochise Co.
Rolf Luetcke
  • Florida
    • Polk Co.
      • Central Florida Phosphate District (Bone Valley)
        • Homeland
Marc V. Hurst (2012) Central Florida Phosphate District. Southeastern Geological Society Field Trip Guidebook No. 57
  • Michigan
    • Keweenaw Co.
      • Ahmeek
Mineralogy of Michigan (2004) Heinrich & Robinson
  • Montana
    • Hill Co.
Am Min 39:208-214
  • Ohio
    • Erie Co.
      • Milan
AmMin 51:228
    • Franklin Co.
      • Columbus
Carlson, Ernest H. (1991), Minerals of Ohio. Ohio Department of Natural Resources.
Minerals of Ohio Bull. 69 ODNR
  • Oregon
    • Sherman Co.
Campbell, T. and Roberts, W., 1986, Whewellite from South Dakota and a Review of Other North American Locanities, Mineralogical Record, v 17:131-133.
  • South Dakota
    • Meade Co.
      • Dalzell
Lapis Vol 21, no. 1 (1996)
Handbook of Mineralogy - Anthony, Bideaux, Bladh, Nichols
  • Texas
    • Hudspeth Co.
      • Van Horn Mts
R&M 66:3 pp 196-224
  • Utah
AmMin 45:1257
      • Big Indian District (Big Indian Wash - Lisbon Valley Area)
UGMS Bull 117 Minerals and Mineral Localities of Utah
Mineral and/or Locality  
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