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Woodhouseite

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Formula:
CaAl3(PO4)(SO4)(OH)6
System:
Trigonal
Colour:
White, flesh-pink, ...
Hardness:
Name:
Named after Professor Charles Douglas Woodhouse (1888-1975), American Mineralogist and mineral collector, University of California, Santa Barbara, California, USA.
The Ca analogue of svanbergite.

A secondary mineral found where sulphatic argillic wall rock alteration occurred in hydrothermal and disseminated ore deposits; rare in cave deposits.

Classification of Woodhouseite

Approved
8.BL.05

8 : PHOSPHATES, ARSENATES, VANADATES
B : Phosphates, etc., with additional anions, without H2O
L : With medium-sized and large cations, (OH, etc.):RO4 = 3:1
43.4.1.8

43 : COMPOUND PHOSPHATES, ETC.
4 : Anhydrous Compound Phosphates, etc·, Containing Hydroxyl or Halogen
22.3.7

22 : Phosphates, Arsenates or Vanadates with other Anions
3 : Phosphates, arsenates or vanadates with sulphates
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Type Occurrence of Woodhouseite

Year of Discovery:
1937
Geological Setting of Type Material:
Quartz veins in an andalusite deposit.
Associated Minerals at Type Locality:

Occurrences of Woodhouseite

Geological Setting:
Altered wall rock in hydrothermal and disseminated ore deposits; cave deposits.

Physical Properties of Woodhouseite

Vitreous, Pearly
Diaphaneity (Transparency):
Transparent, Translucent
Comment:
Lustre pearly on {0001}.
Colour:
White, flesh-pink, colourless
Hardness (Mohs):
Cleavage:
Very Good
On {0001}, excellent.
Density:
3.01 g/cm3 (Measured)    3 g/cm3 (Calculated)

Crystallography of Woodhouseite

Crystal System:
Trigonal
Class (H-M):
3m (3 2/m) - Hexagonal Scalenohedral
Space Group:
R3m
Cell Parameters:
a = 6.993Å, c = 16.386Å
Ratio:
a:c = 1 : 2.343
Unit Cell Volume:
V 693.95 ų (Calculated from Unit Cell)
Z:
3
Morphology:
Crystals small, pseudocubic rhombohedral {1012}; tabular at times {0001}, with curved and striated faces.
Comment:
Pseudocubic

Optical Data of Woodhouseite

Type:
Uniaxial (+)
RI values:
nω = 1.636 nε = 1.647
Max Birefringence:
δ = 0.011
Image shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:
Moderate
Comments:
May exhibit anomalous biaxial sectors. Basal sections of larger crystals exhibit six radial biaxial sectors. May exhibit zonal banding.

Chemical Properties of Woodhouseite

Formula:
CaAl3(PO4)(SO4)(OH)6
Essential elements:
All elements listed in formula:

Relationship of Woodhouseite to other Species

Series:
Forms a series with Svanbergite (see here)
Other Members of Group:
BeudantitePbFe3(AsO4)(SO4)(OH)6
CorkitePbFe3(PO4)(SO4)(OH)6
GallobeudantitePbGa3(AsO4)(SO4)(OH)6
HidalgoitePbAl3(AsO4)(SO4)(OH)6
HinsdalitePbAl3(PO4)(SO4)(OH)6
KemmlitziteSrAl3(AsO4)(SO4)(OH)6
SvanbergiteSrAl3(PO4)(SO4)(OH)6
WeileriteBaAl3(AsO4)(SO4)(OH)6
8.BL.05BeudantitePbFe3(AsO4)(SO4)(OH)6
8.BL.05CorkitePbFe3(PO4)(SO4)(OH)6
8.BL.05HidalgoitePbAl3(AsO4)(SO4)(OH)6
8.BL.05HinsdalitePbAl3(PO4)(SO4)(OH)6
8.BL.05KemmlitziteSrAl3(AsO4)(SO4)(OH)6
8.BL.05SvanbergiteSrAl3(PO4)(SO4)(OH)6
8.BL.05GallobeudantitePbGa3(AsO4)(SO4)(OH)6
8.BL.10ArsenogoyaziteSrAl3(AsO4)2(OH)5 · H2O
8.BL.10ArsenogorceixiteBaAl3(AsO4)2(OH)5 · H2O
8.BL.10ArsenocrandalliteCaAl3(AsO4)2(OH)5 · H2O
8.BL.10BenauiteSrFe33+(HPO4,PO4)2(OH)6
8.BL.10CrandalliteCaAl3(PO4)2(OH)5 · H2O
8.BL.10DussertiteBaFe33+(AsO4)2(OH)5
8.BL.10EylettersiteTh0.75Al3(PO4)2(OH)6
8.BL.10GorceixiteBaAl3(PO4)2(OH)5 · H2O
8.BL.10GoyaziteSrAl3(PO4)2(OH)5 · H2O
8.BL.10KintoreitePbFe3(PO4)(PO3OH)(OH)6
8.BL.10PhilipsbornitePbAl3(AsO4)2(OH)5 · H2O
8.BL.10PlumbogummitePbAl3(PO4)2(OH)5 · H2O
8.BL.10SegnititePbFe33+(AsO4)2(OH,H2O)6
8.BL.10SpringcreekiteBaV33+(PO4)2(OH,H2O)6
8.BL.13Arsenoflorencite-(La)LaAl3(AsO4)2(OH)6
8.BL.13Arsenoflorencite-(Nd)NdAl3(AsO4)2(OH)6
8.BL.13Arsenoflorencite-(Ce)CeAl3(AsO4)2(OH)6
8.BL.13Florencite-(Ce)CeAl3(PO4)2(OH)6
8.BL.13Florencite-(La)LaAl3(PO4)2(OH)6
8.BL.13Florencite-(Nd)(Nd,La,Ce)Al3(PO4)2(OH)6
8.BL.13WaylanditeBiAl3(PO4)2(OH)6
8.BL.13ZaïriteBiFe33+(PO4)2(OH)6
8.BL.13ArsenowaylanditeBiAl3(AsO4)2(OH)6
8.BL.13Graulichite-(Ce)CeFe33+(AsO4)2(OH)6
8.BL.13Florencite-(Sm)(Sm,Nd)Al3(PO4)2(OH)6
8.BL.15ViitaniemiiteNa(Ca,Mn2+)Al(PO4)(F,OH)3
8.BL.25PattersonitePbFe33+(PO4)2(OH)5 · H2O
22.3.1ParnauiteCu9(AsO4)2(SO4)(OH)10 · 7H2O
22.3.2ArdealiteCa2(HPO4)(SO4) · 4H2O
22.3.3Machatschkiite(Ca,Na)6(AsO4)(HAsO4)3(PO4,SO4) · 15H2O
22.3.4ClinotyroliteCa2Cu9(AsO4,SO4)4(OH,O)10 · 10H2O
22.3.5PeisleyiteNa3Al16(PO4)10(SO4)2(OH)17•20H2O
22.3.6ChalcophylliteCu18Al2(SO4)3(AsO4)3(OH)27 · 33H2O
22.3.8Schlossmacherite(H3O)Al3(SO4)2(OH)6
22.3.9SvanbergiteSrAl3(PO4)(SO4)(OH)6
22.3.10KemmlitziteSrAl3(AsO4)(SO4)(OH)6
22.3.11SanjuaniteAl2(PO4)(SO4)(OH) · 9H2O
22.3.12KribergiteAl5(PO4)3(SO4)(OH)4 · 4H2O
22.3.13HotsoniteAl11(SO4)3(PO4)2(OH)21 · 16H2O
22.3.14WeileriteBaAl3(AsO4)(SO4)(OH)6
22.3.15TsumebitePb2Cu(PO4)(SO4)(OH)
22.3.16ArsentsumebitePb2Cu(AsO4)(SO4)(OH)
22.3.17HinsdalitePbAl3(PO4)(SO4)(OH)6
22.3.18HidalgoitePbAl3(AsO4)(SO4)(OH)6
22.3.19Orpheite
22.3.20CoconinoiteFe23+Al2(UO2)2(PO4)4(SO4)(OH)2 · 20H2O
22.3.21Sasaite(Al,Fe3+)14(PO4)11(SO4)(OH)7 · 83H2O
22.3.22Tristramite(Ca,U,Fe)(PO4,SO4) · 2H2O
22.3.23CorkitePbFe3(PO4)(SO4)(OH)6
22.3.24BeudantitePbFe3(AsO4)(SO4)(OH)6
22.3.25DiadochiteFe23+(PO4)(SO4)(OH) · 5H2O
22.3.26SarmientiteFe23+(AsO4)(SO4)(OH) · 5H2O
22.3.27BukovskýiteFe23+(AsO4)(SO4)(OH) · 9H2O
22.3.28ZýkaiteFe43+(AsO4)3(SO4)(OH) · 15H2O
22.3.29TooeleiteFe63+(As3+O3)4(SO4)(OH)4 · 4H2O
22.3.30Pitticite(Fe, SO4, AsO4, H2O) ?
22.3.31Xiangjiangite(Fe3+,Al)(UO2)4(PO4)2(SO4)2(OH) · 22H2O

Other Names for Woodhouseite

Name in Other Languages:
Simplified Chinese:磷钙铝矾
Spanish:Woodhouseita

Other Information

Other Information:
Soluble in acids only after driving off the water in a closed tube.
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Woodhouseite

Reference List:
Lemmon, D. W.; Rautenberg, A. (1937): Woodhouseite, a new mineral of the beudantite group. American Mineralogist: 22: 939-948.

Lemmon, D.M. (1938), Woodhouseite, a new mineral of the beudantite group, Pacific Mineralogist: 5(2): 6.

Pabst, Adolf (1947), Some computations on Svanbergite, Woodhouseite and Alunite: American Mineralogist: 32: 16-30.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 1006-1007.

Kato, T. (1971) The crystal structures of goyazite and woodhouseite. Neues Jahrbuch für Mineralogie, Monatshefte, 241–247.

Mineralogical Record (1981): 12: 106.

Kato, T. (1977) Further refinement of the woodhouseite structure. Neues Jahrbuch für Mineralogie, Monatshefte (1977): 54-58.

Sato, E., Nakai, I., Miyawaki, R. & Matsubara, S. (2009): Crystal structures of alunite family minerals: beaverite, corkite, alunite, natroalunite, jarosite, svanbergite, and woodhouseite. Neues Jahrbuch für Mineralogie Abhandlungen 185, 313-322.

Internet Links for Woodhouseite

Specimens:
The following Woodhouseite specimens are currently listed for sale on minfind.com.

Localities for Woodhouseite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Argentina
 
  • Catamarca
    • Andalgalá Department
FRANCHINI, Marta et al. Alterationand mineralization along the central section of the Agua Rica deposit(27º26'S-66º16'O), Catamarca. Rev. Asoc. Geol. Argent. [online]. 2009, vol.64, n.3, pp. 391-408
Australia
 
  • South Australia
    • Eyre Peninsula
      • Middleback Range
        • Iron Knob
[MinRec 12:106]
  • Tasmania
    • Queenstown district
      • Mount Lyell Mines
Bottrill RS & Baker, WE (in prep) Catalogue of Minerals of Tasmania. Mineral Resources Tasmania
AGSO Research Newsletter May 2000
Austria
 
  • Salzburg
    • Hohe Tauern
      • Untersulzbach valley
R. Exel: Die Mineralien und Ezlagerstätten Österreichs (1993)
        • Leutachkopf - Stocker Alp area
A. Strasser: Die Minerale Salzburgs (1989)
Belgium
 
  • Liège Province
    • Visé
1./ A.M. Fransolet, J Jedwab and R. Van Tassel, 1974, Inventaire minéralogique de Richelles, Belgique, Annales de la Société Géologique de Belgique, Tome 27, pp. 23-26.
Bolivia
 
  • Potosí Department
    • Nor Chichas Province
      • Atocha-Quechisla District
        • Cerro Tazna
Alfredo Petrov collection (PXRD by Jaroslav Hyrsl)
Brazil
 
  • Bahia
    • Brumado (Bom Jesus dos Meiras)
      • Serra das Éguas
Barbosa et al, "Minerals of the Brumado Magnesite Deposits, Serra das Eguas, Bahia, Brazil", Rocks and Minerals, January 2000
Bulgaria
 
  • Pazardzhik Oblast (Pazardjik Oblast)
    • Panagyurishte (Panagurishte) Obshtina
      • Popintsi
Hikov, C. A. (2004)
  • Sofiya Town Oblast (Grad Sofia Oblast)
    • Bankya Obshtina
      • Bankya
HIKOV, A., VELINOVA, N., GEORGIEVA, S., & KUNOV, A. ALUMINIUM-PHOSPHATE-SULPHATE (APS) MINERALS IN BULGARIA: CHARACTERISTICS AND POSSIBILITY FOR PRESERVATION.
Canada
 
  • New Brunswick
    • Gloucester Co.
      • Bathurst Parish
        • Bathurst Mining Camp
Sabina (1967) GSC Paper 66-51, 118
  • Ontario
    • Cochrane District
      • South of Ridge Lake Area
SAGE, R.P. (1981) Geology of the Martison carbonatite complex. Ontario Geological Survey Open File Report 5420, 99p.
Chile
 
  • Atacama Region
    • Chañaral Province
      • Diego de Almagro
        • Potrerillos
Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.
      • El Salvador district
Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.
Economic Geology; January 2005; v. 100; no. 1; p. 131-148
China
 
  • Guangxi Zhuang Autonomous Region
Xunyi Wang (1982): Acta Mineralogica Sinica 2(2), 154-156
      • Yangshuo Co.
Anthony, J.W. et al.: Handbook of Mineralogy
  • Henan Province
    • Nanyang Prefecture
      • Tongbai Co.
Keqin Wang, Mingkai Li, Guozhi Yan, and Huimin Feng (1994): Geology and Prospecting 30(6), 37-42
      • Wancheng District
Keqin Wang, Mingkai Li, Guozhi Yan, and Huimin Feng (1994): Geology and Prospecting 30(6), 37-42
  • Hubei Province
    • Shiyan Prefecture
      • Zhushan Co.
Zhenrong Shi (2008): Jiangsu Geology 32(2), 109-112
  • Jiangsu Province
    • Lianyungang Prefecture
      • Donghai Co.
Zhang, R.Y., Liou, J.G., and Shu, J.F. (2002): American Mineralogist 87, 445-453.
    • Suqian Prefecture
      • Shuyang Co.
Keqin Wang, Mingkai Li, Guozhi Yan, and Huimin Feng (1994): Geology and Prospecting 30(6), 37-42; Zhang, R.Y., Liou, J.G., and Shu, J.F. (2002): American Mineralogist 87, 445-453
  • Shaanxi Province
    • Ankang Prefecture
      • Baihe Co.
Zhenrong Shi and Keqin Cai (2008): Acta Petrologica et Mineralogica 27(2), 164-170.
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • Liberec Region
Scharm, B.: Přehled minerálů nalezených v oblasti uranových koncentrací v severočeské křídě. Bulletin mineralogicko-petrografického oddělení Národního muzea v Praze, 1995, roč. 3, s. 169-172.
Greece
 
  • Thraki Department (Thrace; Thracia)
    • Komotini Prefecture (Rodopi; Rhodope)
Voudouris, P. C., & Melfos, V. (2013). Aluminum-phosphate-sulfate (APS) minerals in the sericitic-advanced argillic alteration zone of the Melitena porphyry-epithermal Mo-Cu Au Re prospect, western Thrace, Greece. Neues Jahrbuch für Mineralogie-Abhandlungen: Journal of Mineralogy and Geochemistry, 190(1), 11-27.
    • Xánthi Prefecture
      • Kassiteres-Sapes area
Michael, C. (2004). Epithermal systems and gold mineralization in western Thrace (North Greece). Bull Geol Soc Greece, 36, 416-423.
Hungary
 
  • Fejér Co.
    • Velencei Mts
      • Nadap
Mineral Species of Hungary, 2005
Indonesia
 
  • Sulawesi Island (Celebes Island)
    • Sulawesi Utara Province (North Sulawesi Province)
DILL, H.G., FRICKE, A., HENNING, K.-H.and GEBERT, H. (1995) An APS mineralization in the kaolin deposit Desa Toraget from northern Sulawesi, Indonesia.- Journal of Southeast Asian Earth Siences, 11: 289-293
Italy
 
  • Lombardy
    • Sondrio Province
      • Valchiavenna
        • Spluga Valley (San Giacomo Valley)
          • Madesimo
Demartin, F., Gramaccioli, C.M., Pilati, T., Sciesa, E. (1996): Sigismundite, (Ba,K,Pb)Na3(Ca,Sr)(Fe,Mg,Mn)14Al(OH)2(PO4)12, a new Ba-rich member of the arrojadite group from Spluga Valley, Italy. Canadian Mineralogist, 34, 827-834.
Japan
 
  • Honshu Island
    • Kanto Region
      • Gunma Prefecture
Aoki (1985) Sanko-Gakkai Kou'en-Youshi, 16; Matsubara et al (1998) Mineralogical Journal, 20, 1-8.; Mineralogical Journal Vol. 20 (1998) , No. 1 pp 1-8
Kyrgyzstan
 
  • Osh Oblast
    • Alai Range (Alay Range)
      • Fergana Valley
        • Fergana
Karpenko, V.Yu. et al. Zapiski RMO 138(1)83(2009)
Norway
 
  • Telemark
    • Bamble (Bamle)
Morton, R. D. (1961): Contributions to the mineralogy of Norway. No.9). On the occurrence of two rare phospates in the Ødegården Apatite mines, Bamble, South Norway. Norsk Geologisk Tidsskrift 41: 233-246; Neumann (1985, p. 108).
Romania
 
  • Alba Co.
    • Apuseni District
Singer, D.A., Berger, V.I., and Moring, B.C. (2008): US Geological Survey Open-File Report 2008-1155.; Mineralium Deposita (2004) 39:173-188
Russia
 
  • Eastern-Siberian Region
    • Transbaikalia (Zabaykalye)
      • Buriatia Republic (Buryatia)
        • Dzhida Basin
American Mineralogist (2001) 86:200
Spain
 
  • Andalusia
    • Almería
      • Níjar
A. Arribas, F. Hernández, M. A. Fernández Périz, J. Gröbner, G. Leal (2005): Rodalquilar - El oro del capo del ágata. BOCAMINA 15, 12-88.
Sweden
 
  • Västergötland
    • Tidaholm
USA (TL)
 
  • California
    • Mono Co.
      • White Mts
        • White Mountain Peak
Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 1007; Lemmon, Dwight Moulton (1937), Woodhouseite, a new mineral of the beudantite group American Mineralogist: 22: 939-948; Gross, E.B. and Parwel, A. (1968) Rutile mineralization at the White Mountain andalusite deposit, California. Arkiv för Mineralogie och Geologi 4, No. 29: 493-497; Wise, W. S. (1977): Mineralogy of the Champion mine White Mountains, California. Mineralogical Record 8, 480, 483-485; Pemberton, H. Earl (1983), Minerals of California; Van Nostrand Reinholt Press: 305, 307, 309; Mineralogical Record (1987): 18: 360; Mineralogical Record (1988): 19: 331.
  • Colorado
    • Boulder Co.
Minerals of Colorado (1997) E.B. Eckels
    • Conejos Co.
Minerals of Colorado (1997) Eckels, E. B.
    • Rio Grande Co.
Minerals of Colorado (1997) Eckels, E. B.
Minerals of Colorado (1997) E.B. Eckels
  • Georgia
    • Lincoln Co.
Barwood,Henry.,(1999)Phosphate Minerals at Graves Mountain,Georgia;Graves Mountain and Magruder Mine,Southeastern Geological Society Guidebook No.38,April 23-25,1999
  • Montana
    • Granite Co.
      • Philipsburg District (Flint Creek District)
Gobla, M.J. (2012) Montana mineral locality index. Rocks & Minerals, 87, #3, 208-240.
  • New Mexico
    • Grant Co.
      • Burro Mountains District
        • Tyrone Area
Northrop, Minerals of New Mexico, 3rd Rev. Ed., 1996
  • Pennsylvania
    • Centre Co.
      • State College
        • Skytop
U.S. Geological Survey/ U.S. Department of the Interior
  • Virginia
    • Buckingham Co.
      • Farmville District
        • Sprouses Corner
Minerals of Virginia 1990 by R. V. Dietrich
Mineral and/or Locality  
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