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Woodwardite

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Big Photo

South Caradon Mine, Caradon Hill, St Cleer, Liskeard District, Cornwall, England, UK
© Elmar Lackner

Show Woodwardite Photos (21)



Formula:
Cu
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
( x < 0.5, n < 3x/2)
System:TrigonalColour:Greenish-blue, ...
Member of:Woodwardite Group > Hydrotalcite Supergroup
Name:Named after Samuel Pickworth Woodward (1821-1865), English naturalist and geologist.
This page provides mineralogical data about Woodwardite.

Classification of Woodwardite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:6/D.08-40
Nickel-Strunz 10th (pending) edition ID:7.DD.35

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
D : Sulfates (selenates, etc.) with additional anions, with H2O
D : With only medium-sized cations; sheets of edge-sharing octahedra
Dana 8th edition ID:31.2.2.1

31 : HYDRATED SULFATES CONTAINING HYDROXYL OR HALOGEN
2 : (AB)6(XO4)Zq·xH2O
Hey's CIM Ref.:25.2.21

25 : Sulphates
2 : Sulphates of Cu and Ag
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Type Occurrence of Woodwardite

Type Locality:Cornwall, England, UK
Year of Discovery:1866

Physical Properties of Woodwardite

Diaphaneity (Transparency):Translucent, Opaque
Colour:Greenish-blue, turquoise-blue
Density (measured):2.38 g/cm3

Crystallography of Woodwardite

Crystal System:Trigonal
Cell Parameters:a = 3.06Å, c = 32.8Å
Ratio:a:c = 1 : 10.719
Unit Cell Volume:V 265.98 ų (Calculated from Unit Cell)
Morphology:Occurs as minute, botryoidal concretions with a fine-fibrous structure; spherulitic.
X-Ray Powder Diffraction:
d-spacingIntensity
8.9 (100)
4.47 (90)
2.65 (30)
2.55 (60)
2.28 (50)
1.98 (30)
1.53 (30)

Optical Data of Woodwardite

Type:Biaxial (+)
RI values: nα = 1.552 - 1.571 nβ = 1.555 - 1.574 nγ = 1.565 - 1.576
Maximum Birefringence:δ = 0.013

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:strong

Chemical Properties of Woodwardite

Formula:
Cu
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O


( x < 0.5, n < 3x/2)
Essential elements:Al, Cu, H, O, S
All elements listed in formula:Al, Cu, H, O, S

Relationship of Woodwardite to other Species

Member of:Woodwardite Group > Hydrotalcite Supergroup
Other Members of Group:

- +
Honessite
(Ni
 
1-x
Fe
3+
x
)(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
Zincowoodwardite
Zn
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
7.DD.05Felsőbányaite
Al
 
4
(SO
 
4
)(OH)
 
10
 · 4H
 
2
O
7.DD.10Langite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · 2H
 
2
O
7.DD.10Posnjakite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · H
 
2
O
7.DD.10Wroewolfeite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · 2H
 
2
O
7.DD.15Spangolite
Cu
 
6
Al(SO
 
4
)(OH)
 
12
Cl · 3H
 
2
O
7.DD.20Ktenasite
Zn(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 6H
 
2
O
7.DD.25Christelite
Cu
 
2
Zn
 
3
(SO
 
4
)
 
2
(OH)
 
6
 · 4H
 
2
O
7.DD.30Campigliaite
Mn
2+
 
Cu
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 4H
 
2
O
7.DD.30Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 3H
 
2
O
7.DD.30Orthoserpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 3H
 
2
O
7.DD.30Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 3H
 
2
O
7.DD.30Niedermayrite
CdCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 4H
 
2
O
7.DD.30Edwardsite
Cu
 
3
Cd
 
2
(SO
 
4
)
 
2
(OH)
 
6
·4H
 
2
O
7.DD.35Carrboydite
[(Ni
 
1-x
Al
 
x
)(OH)
 
2
][SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Glaucocerinite
(Zn
 
1-x
Al
 
x
)(OH)
 
2
(SO
 
4
)
 
x/2
 · nH
 
2
O
7.DD.35Honessite
(Ni
 
1-x
Fe
3+
x
)(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Hydrohonessite
(Ni
 
1-x
Fe
3+
x
)(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Motukoreaite
Mg
 
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
 · 6H
 
2
O
7.DD.35Mountkeithite
[(Mg
 
1-x
Fe
3+
x
)(OH)
 
2
][SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Shigaite
Mn
 
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
 · 6H
 
2
O
7.DD.35Wermlandite
Mg
 
7
Al
 
2
(OH)
 
18
[Ca(H
 
2
O)
 
6
][SO
 
4
]
 
2
 · 6H
 
2
O
7.DD.35Zincaluminite
Zn
 
6
Al
 
6
(SO
 
4
)
 
2
(OH)
 
16
 · 5H
 
2
O
7.DD.35Hydrowoodwardite
(Cu
 
1-x
Al
 
x
)(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Zincowoodwardite
Zn
 
1-x
Al
 
x
(OH)
 
2
[SO
 
4
]
 
x/2
 · nH
 
2
O
7.DD.35Natroglaucocerinite
Na
 
x
Zn
 
8-y
Al
 
y
(SO
 
4
)
 
(x+y)/2
(OH)
 
16
 · 6H
 
2
O
7.DD.35Nikischerite
Fe
2+
6
Al
 
3
(OH)
 
18
[Na(H
 
2
O)
 
6
][SO
 
4
]
 
2
 · 6H
 
2
O
7.DD.40Lawsonbauerite
(Mn
2+
 
,Mg)
 
9
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
 · 8H
 
2
O
7.DD.40Torreyite
(Mg,Mn
2+
 
)
 
9
Zn
 
4
(SO
 
4
)
 
2
(OH)
 
22
 · 8H
 
2
O
7.DD.45Mooreite
(Mg,Zn,Mn
2+
 
)
 
15
(SO
 
4
)
 
2
(OH)
 
26
 · 8H
 
2
O
7.DD.50Namuwite
(Zn,Cu)
 
4
(SO
 
4
)(OH)
 
6
 · 4H
 
2
O
7.DD.55Bechererite
(Zn,Cu)
 
6
Zn
 
2
(SO
 
4
,HSiO
 
4
)
 
2
(OH)
 
12
7.DD.60Ramsbeckite
(Cu,Zn)
 
15
(SO
 
4
)
 
4
(OH)
 
22
 · 6H
 
2
O
7.DD.65Vonbezingite
Ca
 
6
Cu
 
3
(SO
 
4
)
 
3
(OH)
 
12
 · 2H
 
2
O
7.DD.70Redgillite
Cu
 
6
(SO
 
4
)(OH)
 
10
 · H
 
2
O
7.DD.75Chalcoalumite
CuAl
 
4
(SO
 
4
)(OH)
 
12
 · 3H
 
2
O
7.DD.75Nickelalumite
(Ni,Cu)Al
 
4
(SO
 
4
,(NO
 
3
)
 
2
)(OH)
 
12
 · 3H
 
2
O
7.DD.75Kyrgyzstanite
ZnAl
 
4
(SO
 
4
)(OH)
 
12
·3H
 
2
O
7.DD.80Guarinoite
(Zn,Co,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
 · 5H
 
2
O
7.DD.80Schulenbergite
(Cu,Zn)
 
7
(SO
 
4
,CO
 
3
)
 
2
(OH)
 
10
 · 3H
 
2
O
7.DD.80Thérèsemagnanite
(Co,Zn,Ni)
 
6
(SO
 
4
)(OH,Cl)
 
10
 · 8H
 
2
O
7.DD.80UM1992-30-SO:CCuHZn
(Zn,Cu)
 
7
(SO
 
4
,CO
 
3
)
 
2
(OH)
 
10
 · 3H
 
2
O
7.DD.85Montetrisaite
Cu
 
6
(SO
 
4
)(OH)
 
10
 · 2H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.2.1Chalcocyanite
CuSO
 
4
25.2.2Bonattite
CuSO
 
4
 · 3H
 
2
O
25.2.3Chalcanthite
CuSO
 
4
 · 5H
 
2
O
25.2.4Boothite
CuSO
 
4
 · 7H
 
2
O
25.2.5Dolerophanite
Cu
 
2
(SO
 
4
)O
25.2.6Antlerite
Cu
 
3
(SO
 
4
)(OH)
 
4
25.2.7Brochantite
Cu
 
4
(SO
 
4
)(OH)
 
6
25.2.8Posnjakite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · H
 
2
O
25.2.9Langite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · 2H
 
2
O
25.2.10Wroewolfeite
Cu
 
4
(SO
 
4
)(OH)
 
6
 · 2H
 
2
O
25.2.11Kröhnkite
Na
 
2
Cu(SO
 
4
)
 
2
 · 2H
 
2
O
25.2.12Natrochalcite
NaCu
 
2
(SO
 
4
)
 
2
(OH) · 2H
 
2
O
25.2.13Piypite
K
 
2
Cu
 
2
(SO
 
4
)
 
2
O
25.2.14Fedotovite
K
 
2
Cu
 
3
(SO
 
4
)
 
3
O
25.2.15Cyanochroite
K
 
2
Cu(SO
 
4
)
 
2
 · 6H
 
2
O
25.2.16Euchlorine
KNaCu
 
3
(SO
 
4
)
 
3
O
25.2.17Devilline
CaCu
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 3H
 
2
O
25.2.18Leightonite
K
 
2
Ca
 
2
Cu(SO
 
4
)
 
4
 · 2H
 
2
O
25.2.19Chalcoalumite
CuAl
 
4
(SO
 
4
)(OH)
 
12
 · 3H
 
2
O
25.2.20Cyanotrichite
Cu
 
4
Al
 
2
(SO
 
4
)(OH)
 
12
 · 2H
 
2
O
25.2.22Campigliaite
Mn
2+
 
Cu
 
4
(SO
 
4
)
 
2
(OH)
 
6
 · 4H
 
2
O
25.2.23Guildite
CuFe
3+
 
(SO
 
4
)
 
2
(OH) · 4H
 
2
O
25.2.24Ransomite
CuFe
 
2
(SO
 
4
)
 
4
 · 6H
 
2
O
25.2.26Klyuchevskite
K
 
3
Cu
 
3
(Fe
3+
 
,Al)(SO
 
4
)
 
4
O
 
2
25.2.27Poitevinite
(Cu,Fe,Zn)SO
 
4
 · H
 
2
O
25.2.28Argentojarosite
AgFe
3+
3
(SO
 
4
)
 
2
(OH)
 
6

Other Names for Woodwardite

Other Languages:
German:Woodwardit
Simplified Chinese:水铜铝矾
Spanish:Woodwardita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Woodwardite

Reference List:

- +
Church (1866) Chemical News and Journal of Industrial Science, London: 13: 85, 113.

Church (1866) Journal of the Chemical Society, London: 19: 130.

Larsen, E.S. (1921) The Microscopic Determination of the Nonopaque Minerals, First edition, USGS Bulletin 679: 98. (langite, no. 3, from Klausen).

Meixner (1940) Zbl. Min.: 238.

Palache, Charles, Harry Berman & Clifford Frondel (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana Yale University 1837-1892, Seventh edition, Volume II: 580.

Mineralogical Magazine (1976): 40: 644.

Neues Jahrbuch für Mineralogie, Monatshefte (1999): 75.

Mills, S.J., Christy, A.G., Genin, J.-M.R., Kameda, T., Colombo, F. (2012): Nomenclature of the hydrotalcite supergroup: natural layered double hydroxides. Mineralogical Magazine, 76, 1289-1336.

Internet Links for Woodwardite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Woodwardite details from Handbook of Mineralogy (PDF)
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    • Localities for Woodwardite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Tasmania
      • Balfour-Temma district
        • Balfour
    		Bottrill & Baker (in prep) Catalogue of minerals of Tasmania
    Austria
     
    • Salzburg
      • Kitzbühel Alps
    		R. Exel: Die Mineralien und Erzlagerstätten Österreichs (1993); U. Kolitsch (PXRD of sample collected by J. Brugger)
    • Tyrol
      • North Tyrol
        • Inn valley
          • Brixlegg - Schwaz area
            • Brixlegg - Rattenberg
              • Geyer - Silberberg District
    		Lapis 19(7/8):13-78 (1994)
    Schnorrer, G. & Poeverlein, R. (2008): Schwaz-Brixlegger Fundstellen. 6. Die Minerale des Gratlspitz bei Brixlegg in Tirol. Aufschluss 59, 7-28.
    France
     
    • Alsace
      • Bas-Rhin
        • Villé Valley
          • Urbeis
    		Aufschluss 1/85
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Badenweiler
    		Lapis, 15 (12),13-20.
    • Lower Saxony
      • Harz
        • Goslar
          • Astfeld
    		No reference listed
    • North Rhine-Westphalia
      • Niederberg area
        • Heiligenhaus
    		Lapis 1988(1), 17-35
      • Sauerland
        • Iserlohn
          • Letmathe
        • Meschede
    		Wittern: "Mineralfundorte in Deutschland", 2001
    • Saxony-Anhalt
      • Harz
        • Wernigerode
          • Hasserode
    		Wittern: "Mineralfundorte in Deutschland", 2001
    • Saxony
      • Erzgebirge
        • Annaberg District
          • Königswalde
    		J. Gröbner und U. Kolitsch (2006): Neufunde aus dem Erzgebirge (II). Mineralien-Welt 17 (3), 22-27.
        • Glashütte
          • Bärenhecke
        • Marienberg District
          • Lauta
    		Hajek, W. (2010): Kristallwelten Marienberg. Weise Verlag, München.
    Lapis 30(7/8):78-80 (2005)
        • Schwarzenberg District
          • Beierfeld
    		[MinRec 30:203]
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamariza)
    		LAPIS 24 (7/8) 1999; Wendel, W. and Markl, G. (1999) Lavrion: Mineralogische Klassiker und Raritäten für Sammler. LAPIS 24 (7/8):34-52
            • Kamariza Mines (Kamareza Mines)
              • Hilarion area
    		Branko Rieck analysis
    Italy
     
    • Aosta Valley
      • Saint-Marcel
    		Piccoli, G.C., Maletto, G., Bosio, P., Lombardo, B. (2007): Minerali del Piemonte e della Valle d'Aosta. Associazione Amici del Museo "F. Eusebio" Alba, Ed., Alba (Cuneo) 607 pp.
    • Sardinia
      • Nuoro Province
        • Gadoni
    		Stara, P., Rizzo, R., Sabelli, C., Ibba, A. (1999): I minerali di Funtana Raminosa. Rivista Mineralogica Italiana, 1/1999, 10-27.
    • Trentino-Alto Adige
      • Bolzano Province (South Tyrol)
        • Isarco Valley (Eisack Valley)
    		Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp. ; Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp.
    Exel, R. (1987): Guida mineralogica del Trentino e del Sudtirolo. Athesia, Bolzano, 204 pp.
        • Vizze Valley (Pfitsch Valley)
          • San Giacomo
            • Vizze pass (Pfitsch pass)
    		Folie, K., P. Gentile, M. Hanke & I. Rocchetti (2010): Mineralien aus der Umgebung des Pfitscher Jochs in Südtirol (II). Mineralien-Welt 21 (4), 42-67.
      • Trento Province
        • Valsugana
          • Roncegno
    		Bortolozzi G., Blass G., Boscardin M., Rocchetti I. and Ferretti P. (2013): La Miniera di Cinquevalli (Valsugana, Trentino-Alto Adige): aggiornamento sulle specie accertate negli ultimi anni. Studi Trent. Sci. Nat., 93, pagg. 149-165.
    • Tuscany
      • Grosseto Province
        • Massa Marittima
    		Sabelli C., Olmi F., Brizzi G., Meli R., 1996. Serrabottini (GR): recenti ritrovamenti nelle antiche discariche. Riv. Mineral. Ital., 19
      • Livorno Province
        • Campiglia Marittima
          • Sassetta
    		Jansen, H. & van den Berg, W. (1998): Slakkenmineralen in Toscane (Italië). Gea, no. 4, 109-117 (in Dutch).
        • Elba Island
          • Capoliveri
    		J. Göske, T. Witzke, H. Pöllmann, S. Stöber (1997) - Neufunde von Sekundarmineralen in der Lagerstatte Calamita/Insel Elba - Der Aufschluss, 48: 305-313.
        • Piombino
    		Cerutti, G. and Preite, D. (1995): Mineralien der etruskischen Schlacken von Baratti, Toskana. Lapis, 20 (4), 13-18; 50 (in German).
    Luigi Chiappino data
    • Veneto
      • Vicenza Province
        • Torrebelvicino
          • Mercanti Valley
            • Monte Trisa Mines
    		Boscardin M., Daleffe A., Rocchetti I., Zordan A. "I minerali nel Vicentino", Museo "G. Zannato", Montecchio Maggiore, (Vicenza), 2011.
    Japan
     
    • Honshu Island
      • Chubu Region
        • Gifu Prefecture
    		Matsubara, S. & Miyawaki, R. (2006) Catalogue of Japanese Minerals (National Science Museum)
      • Kinki Region
        • Hyogo Prefecture
          • Taka-gun
    		Takada & Matsuuchi (1981) Chigaku Kenkyu, 32, 191-199.
    Norway
     
    • Akershus
      • Eidsvoll (Eidsvold)
        • Minnesund
    		Pers. Com. G. Raade 12.07.1990 in Geologisk Museum. Interne notater 1961-1990. Published by Geologisk Museums Venner, Oslo 1991. p 146
    • Aust-Agder
      • Froland
    		Pers. Com. G. Raade 12.07.1990 in Geologisk Museum. Interne notater 1961-1990. Published by Geologisk Museums Venner, Oslo 1991.p 146
    • Rogaland
      • Sauda
    		Pers. Com. G. Raade 12.07.1990 in Geologisk Museum. Interne notater 1961-1990. Published by Geologisk Museums Venner, Oslo 1991. p 146
    UK
     
    • England
    		Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II: 580; Mineralogical Record: 9: 113.
        • Camborne - Redruth - St Day District
          • Camborne
            • Killivose
        • Liskeard District
          • St Cleer
            • Caradon Hill
    		No reference listed
            • Crow's Nest
    		SMLS slide library
        • Mount's Bay District
          • St Hilary
    		No reference listed
        • St Just District
          • St Just
            • Botallack
              • Botallack Mine
    		Golley, P. & Williams, R. (1995): Cornish Mineral Reference Manual. Endsleigh Publications (Truro), 104 pp.
    Golley, P. & Williams, R. (1995): Cornish Mineral Reference Manual. Endsleigh Publications (Truro), 104 pp.
    • Wales
      • Ceredigion (Dyfed; Cardiganshire)
        • Ceulanymaesmawr
          • Talybont
            • Nant-y-Moch Reservoir area
    		BMS Database
      • Gwynedd (Caernarvonshire)
        • Nantlle Vale
    USA
     
    • Arizona
      • Cochise Co.
        • Dragoon Mts
          • Turquoise District (Courtland-Gleeson District)
    		Anthony, J.W., et al (1995), Mineralogy of Arizona, 3rd.ed.: 425.
        • Tombstone Hills
          • Tombstone District
    		Rob Bowell, lab tested
    Rob Bowell, lab tested
    • Colorado
      • Jefferson Co.
        • Ralston Buttes District
    		Minerals of Colorado (1997) E.B. Eckels
    Zambia
     
    • Copperbelt Province
      • Kalulushi District
        • Chambishi
    		No reference listed
    Mineral and/or Locality
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