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Yukonite

Formula:
Ca
 
3
Fe
3+
 
[(OH)
 
3
|(AsO
 
4
)
 
2
] · 5H
 
2
O
Colour:Red-brownHardness:2 - 3
Name:Named after its discovery locality, Daulton Mine, west side of Windy Arm, Tagish Lake, Yukon, Canada.


Easily confused with Arseniosiderite and identifiable only with XRD methods.

Note: The "yukonite" described by Nishikawa et al. (2006) may in fact be identical to the Unnamed (Arseniosiderite-related mineral).

Classification of Yukonite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:7/D.48-40
Nickel-Strunz 10th (pending) edition ID:8.DM.25

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
M : With large and medium-sized cations, (OH, etc.):RO4 > 2:1
Dana 8th edition ID:42.8.6.1

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
8 : (AB)5(XO4)3Zq·xH2O
Hey's CIM Ref.:20.9.12

20 : Arsenates (also arsenates with phosphate, but without other anions)
9 : Arsenates of Fe
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Type Occurrence of Yukonite

Type Locality:Daulton Mine, Windy Arm, Tagish Lake, Carcross, Whitehorse Mining District, Yukon Territory, Canada
Year of Discovery:1913

Physical Properties of Yukonite

Colour:Red-brown
Hardness (Mohs):2 - 3
X-Ray Powder Diffraction:
d-spacingIntensity
14.1 (100)
5.58 (37)
3.25 (57)
2.79 (60)
2.61 (20)
2.33 (3)
2.24 (11)
2.14 (3)
1.76 (9)
1.63 (20)
Comments:XRD pattern richer in lines are also known (U. Kolitsch, unpublished data)

Chemical Properties of Yukonite

Formula:
Ca
 
3
Fe
3+
 
[(OH)
 
3
|(AsO
 
4
)
 
2
] · 5H
 
2
O
Essential elements:As, Ca, Fe, H, O
All elements listed in formula:As, Ca, Fe, H, O

Relationship of Yukonite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DM.05Morinite
Na
 
2
Ca
 
4
Al
 
4
[(F,OH)
 
5
|(PO
 
4
)
 
2
]
 
2
· 3H
 
2
O
8.DM.05Esperanzaite
NaCa
 
2
Al
 
2
[F
 
4
|OH|(AsO
 
4
)
 
2
] · 2H
 
2
O
8.DM.10Clinotyrolite
Ca
 
2
Cu
 
9
[(OH,O)
 
10
|(AsO
 
4
,SO
 
4
)
 
4
] · 10H
 
2
O
8.DM.10Tyrolite
Ca
 
2
Cu
 
9
[(OH)
 
4
|(H
 
2
O)
 
11
|CO
 
3
|(AsO
 
4
)
 
4
] · 0-1H
 
2
O
8.DM.15Betpakdalite
{Mg(H
 
2
O)
 
6
}Ca
 
2
(H
 
2
O)
 
13
[Mo
6+
8
As
5+
2
Fe
3+
3
O
 
36
(OH)](H
 
2
O)
 
4
8.DM.15Melkovite
CaFeH
 
6
(MoO
 
4
)
 
4
PO
 
4
·6H
 
2
O or near·
8.DM.15Natrobetpakdalite
(Na
 
2
,Ca)Fe
 
2
(As
 
2
Mo
 
6
O
 
28
)·15H
 
2
O
8.DM.20Phosphovanadylite
(Ba,Ca,K,Na)x[(V,Al)4P2(O,OH)16]·12(H2O) x~0.66
8.DM.30Uduminelite
Ca
 
3
Al
 
8
(PO
 
4
)
 
2
O
 
12
·2H
 
2
O
8.DM.35Delvauxite
CaFe
 
4
(PO
 
4
,SO
 
4
)
 
2
(OH)
 
8
·4-6H
 
2
O not confirmed·
8.DM.40Santafeite
(Ca,Sr,Na)
 
12
(Mn
2+
 
,Fe
3+
 
,Al,Mg)
 
8
Mn
4+
8
(VO
 
4
)
 
16
(OH,O)
 
20
· 8H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
20.9.1Angelellite
Fe
3+
4
[O
 
3
|(AsO
 
4
)
 
2
]
20.9.2Scorodite
Fe
3+
 
AsO
 
4
·2H
 
2
O
20.9.3Kaňkite
FeAsO
 
4
·3.5H
 
2
O
20.9.4Ferrisymplesite
Fe
3+
3
[(OH)
 
3
|(AsO
 
4
)
 
2
] · 5H
 
2
O
20.9.5Kaatialaite
Fe(H
 
2
AsO
 
4
)
 
3
·5H
 
2
O
20.9.6Symplesite
Fe
2+
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.9.7Parasymplesite
Fe
2+
3
(AsO
 
4
)
 
2
·8H
 
2
O
20.9.8Natropharmacosiderite
(Na,K)Fe
3+
4
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 6-7H
 
2
O
20.9.9Pharmacosiderite
KFe
3+
4
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 6-7H
 
2
O
20.9.10Kolfanite
Ca
 
2
Fe
3+
2
[O
 
2
|(AsO
 
4
)
 
3
] · 2H
 
2
O
20.9.11Arseniosiderite
Ca
 
2
Fe
3+
3
[O
 
2
|(AsO
 
4
)
 
3
] · 3H
 
2
O
20.9.13Dussertite
BaFe
3+
3
[(OH)
 
5
|(AsO
 
4
)
 
2
]
20.9.14Liskeardite
(Al,Fe
3+
 
)
 
3
[(OH)
 
6
|AsO
 
4
] · 5H
 
2
O
20.9.15Mapimite
Zn
 
2
Fe
3+
3
[(OH)
 
4
|(AsO
 
4
)
 
3
] · 10H
 
2
O
20.9.16Ogdensburgite
Ca
 
2
Fe
3+
4
(Zn,Mn
2+
 
)[(OH)
 
3
|(AsO
 
4
)
 
2
]
 
2
· 6H
 
2
O
20.9.17Walentaite
H(Ca,Mn
2+
 
,Fe
2+
 
)Fe
3+
3
[(AsO
 
4
,PO
 
4
)]
 
4
· 7H
 
2
O

Other Names for Yukonite

Other Languages:
German:Yukonit
Spanish:Yukonita
Varieties:
Chromian Yukonite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Yukonite

Reference List:Tyrrell and Graham (1913) Transactions of the Royal Society of Canada: series 3, vol. 7, section IV, 13-18.

Palache, C., Berman, H., & Frondel, C. (1951), The System of Mineralogy of James Dwight Dana and Edward Salisbury Dana, Yale University 1837-1892, Volume II. John Wiley and Sons, Inc., New York, 7th edition, revised and enlarged, 1124 pp.: 953, 954.

Canadian Mineralogist (1970): 8: 13-18.

Mineralogical Magazine (1982): 46: 261-264.

Ross, D. R. & Post, J. E. (1997): New data on yukonite. Powder Diffraction 12 (2), 113-116.

American Mineralogist (1998): 83: 189.

Pieczka, A., Golebiowska, B. and Franus, W. (1998): Yukonite, a rare Ca-Fe arsenate, from Redziny (Sudetes, Poland). Eur. J. Mineral. 10, 1367-1370.

Nishikawa, O., Okrugin, V., Belkova, N., Saji, I., Shiraki, K., Tazaki, K. (2006): Crystal symmetry and chemical composition of yukonite: TEM study of specimens collected from Nalychevskie hot springs, Kamchatka, Russia and from Venus Mine, Yukon Territory, Canada. Mineralogical Magazine: 70: 73-81.

Garavelli, A., Pinto, D., Vurro, F., Mellini, M., Viti, C., Balić-Žunić, T. (2009): Yukonite from “Grotta del Monaca” cave, Sant'Agata di Esaro, Italy: characterization and comparison with cotype material from Daulton mine, Yukon, Canada. Canadian Mineralogist, 47, 39-51.

Internet Links for Yukonite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Yukonite in the Natural History Museum (London) online catalogue
  • Yukonite details from Handbook of Mineralogy (PDF)
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    Localities for Yukonite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • La Rioja
    Las Especies Minerales de La Republica Argentina
    Austria
     
    • Tyrol
      • North Tyrol
        • Inn valley
          • Brixlegg - Schwaz area
            • Brixlegg - Rattenberg
              • Geyer - Silberberg District
                • Silberberg Mt.
    Schnorrer, G. and Poeverlein, R. (2002) Schwaz-Brixlegg-Fundstellen: 2. Die Minerale des Stockerstollens bei Brixlegg in Tirol. Aufschluss, 53, 209-228.
    Canada
     
    • Yukon Territory
      • Whitehorse Mining District
        • Carcross
          • Tagish Lake
    No reference listed
    Tyrrell & Graham (1913), Transactions of the Royal Society of Canada 7, sec. 4: 13-18; Traill (1983), Geol. Soc. of Canada Paper 80-18.
    Sabina (1992), Geol. Soc. of Canada Misc. Report 50: 41.
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Wolfach
          • Oberwolfach
            • Frohnbach valley
    K. Walenta: "Die Mineralien des Schwarzwaldes", Weise (Munich), 1992
            • Rankach valley
    SCHNORRER-KÖHLER, G. (1991): Mineralogische Notizen V. - Aufschluss 42 (3), 155-171; Walenta, K. (1992): Die Mineralien des Schwarzwaldes. Chr. Weise Verlag, München, 336 pp. (in German)
    • Bavaria
      • Franconia
        • Spessart Mts
          • Hösbach
            • Sailauf
              • Hartkoppe Mt.
    see locality page
    • Rhineland-Palatinate
      • Eifel Mts
        • Hillesheim
    Hentschel, G., Die Lavaströme der Graulai: eine neue Fundstelle in der Westeifel, Lapis, Weise Verlag München, 09/1993
    • Saxony-Anhalt
      • Harz Mts
        • Wernigerode
          • Hasserode
    Wittern: "Mineralfundorte in Deutschland", 2001
    Italy
     
    • Calabria
      • Cosenza Province
        • S. Agata di Esaro
    The Canadian Mineralogist; February 2009; v. 47; no. 1; p. 39-51
    Morocco
     
    • Souss-Massa-Draâ Region
      • Ouarzazate Province
        • Tazenakht
          • Bou Azzer District
            • Bou Azzer
    [var: Chromian Yukonite] N. Meisser, J. Brugger (2006): "Bouazzerit und Maghrebit, zwei neue Arsenatmineralien aus dem Revier Bou Azzer, Marokko", Lapis 31(7/8), 69-71
    Norway
     
    • Buskerud
      • Nedre Eiker
        • Krokseter
    P. Andresen, 2005.
    Poland
     
    • Lower Silesia (Dolnośląskie)
      • Rudawy Janowickie Mts
        • Czarnów
          • Rędziny
    Domańska, J.: Rędziny. Otoczak, nr. 29, p. 38-52; Pieczka, A., Golebiowska, B. and Franus, W. (1998): Yukonite, a rare Ca-Fe arsenate, from Redziny (Sudetes, Poland). Eur. J. Mineral. 10, 1367-1370.
    Spain
     
    • Aragón
      • Zaragoza
        • Alpartir
    Calvo, M. (2008). Minerales de Aragón. Prames,Zaragoza. 463 pags.
    • Murcia
      • Mazarrón-Águilas
        • Pastrana
    Jordi Fabre
    MinRec-2003-0708-315
    USA
     
    • Colorado
      • Chaffee Co.
        • Buena Vista
          • Trout Creek Pass pegmatite District
    Minerals of Colorado (1997) Eckels, E. B.
    • Nevada
      • Mineral Co.
        • Fitting District
          • Luning
            • Rhyolite Pass
    Marco Ciriotti collection (analysed only by SEM-EDS, 2005)
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Ogdensburg
            • Sterling Hill
    Dunn(1995):Pt5:685.
    Mineral and/or Locality
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