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Zakharovite

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Demix-Varennes quarry, Saint-Amable sill, Varennes & St-Amable, Verchères Co., Québec, Canada
© 2003 DM

Show Zakharovite Photos (5)
Formula:
Na
 
4
Mn
 
5
Si
 
10
O
 
24
(OH)
 
6
·6H
 
2
O
System:TrigonalColour:Yellow
Lustre:Waxy, Pearly, DullHardness:2
Name:Named after E.E. Zakharov (1902-1980) Director of the Moscow Geological Exploration Institute (Russia).


See also Unnamed (Fe analogue of Zakharovite).

Classification of Zakharovite

IMA status:Approved 1981
Strunz 8th edition ID:8/D.02-10
Strunz 9th edition ID:9.CO.05
Nickel-Strunz 10th (pending) edition ID:9.EE.65

9 : SILICATES (Germanates)
E : Phyllosilicates
E : Single tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bands
Dana 8th edition ID:78.1.17.1

78 : Unclassified Silicates
1 : Miscellaneous
Hey's CIM Ref.:14.18.3

14 : Silicates not Containing Aluminum
18 : Silicates of Mn and Na, K, Mg, Ca or Fe
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Type Occurrence of Zakharovite

Co-type Localities:Yukspor Mt, Khibiny Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Karnasurt Mt, Lovozero Massif, Kola Peninsula, Murmanskaja Oblast', Northern Region, Russia
Year of Discovery:1982

Physical Properties of Zakharovite

Lustre:Waxy, Pearly, Dull
Colour:Yellow
Hardness (Mohs):2

Crystallography of Zakharovite

Crystal System:Trigonal
Cell Parameters:a = 14.58Å, c = 37.71Å
Ratio:a:c = 1 : 2.586
Unit Cell Volume:V 6,942.28 ų (Calculated from Unit Cell)

Optical Data of Zakharovite

Type:Uniaxial (-)
RI values: nω = 1.565 nε = 1.535
Maximum Birefringence:δ = 0.030

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low

Chemical Properties of Zakharovite

Formula:
Na
 
4
Mn
 
5
Si
 
10
O
 
24
(OH)
 
6
·6H
 
2
O
Essential elements:H, Mn, Na, O, Si
All elements listed in formula:H, Mn, Na, O, Si
Common Impurities:Fe,Mg,Ca,Sr,K

Relationship of Zakharovite to other Species

Related Minerals - Nickel-Strunz Grouping):
9.EE.05Bementite
Mn
 
5
Si
 
4
O
 
10
(OH)
 
6
9.EE.10Brokenhillite
9.EE.10Pyrosmalite-(Fe)
(Fe,Mn)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Friedelite
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Pyrosmalite-(Mn)
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH,Cl)
 
10
9.EE.10Mcgillite
(Mn,Fe)
 
8
Si
 
6
O
 
15
(OH)
 
8
Cl
 
2
9.EE.15Nelenite
(Mn,Fe)
 
16
Si
 
12
As
 
3
O
 
36
(OH)
 
17
9.EE.15Schallerite
(Mn,Fe)
 
16
Si
 
12
As
 
3
O
 
36
(OH)
 
17
9.EE.20Palygorskite
(Mg,Al)
 
5
(Si,Al)
 
8
O
 
20
(OH)
 
2
·8H
 
2
O
9.EE.20Tuperssuatsiaite
Na
 
2
Fe
 
3
Si
 
8
O
 
20
(OH)
 
2
·4H
 
2
O
9.EE.20Yofortierite
Mn
 
5
Si
 
8
O
 
20
(OH)
 
2
·8-9H
 
2
O
9.EE.25Falcondoite
(Ni,Mg)
 
4
Si
 
6
O
 
15
(OH)
 
2
·6H
 
2
O
9.EE.25Loughlinite
Na
 
2
Mg
 
3
Si
 
6
O
 
16
·8H
 
2
O
9.EE.25Sepiolite
Mg
 
4
Si
 
6
O
 
15
(OH)
 
2
·6H
 
2
O
9.EE.25Kalifersite
(K,Na)
 
5
Fe
3+
7
Si
 
20
O
 
50
(OH)
 
6
·12H
 
2
O
9.EE.30Gyrolite
Ca
 
4
(Si
 
6
O
 
15
)(OH)
 
2
·3H
 
2
O
9.EE.30Orlymanite
Ca
 
4
Mn
 
3
Si
 
8
O
 
20
(OH)
 
6
·2H
 
2
O
9.EE.30Tungusite
Ca
 
4
Fe
 
2
Si
 
6
O
 
15
(OH)
 
6
9.EE.35Fedorite
KNa
 
4
Ca
 
4
[HSi
 
4
O
 
10
]
 
4
 · 6H
 
2
O
9.EE.35Minehillite
(K,Na)
 
2-3
Ca
 
28
Zn
 
4
Al
 
4
Si
 
40
O
 
112
(OH)
 
16
9.EE.35Reyerite
(Na,K)
 
2
Ca
 
14
(Si,Al)
 
24
O
 
58
(OH)
 
8
·6H
 
2
O
9.EE.35Truscottite
(Ca,Mn)
 
14
Si
 
24
O
 
58
(OH)
 
8
·2H
 
2
O
9.EE.35Martinite
(Na,Ca)
 
11
Ca
 
4
(Si,S,B)
 
14
B
 
2
O
 
40
F
 
2
·4H
 
2
O
9.EE.35Lalondeite
(Na,Ca)
 
6
(Ca,Na)
 
3
Si
 
16
O
 
38
(F,OH)
 
2
·3H
 
2
O
9.EE.40Natrosilite
Na
 
2
Si
 
2
O
 
5
9.EE.45Makatite
Na
 
2
Si
 
4
O
 
8
(OH)
 
2
·4H
 
2
O
9.EE.50Varennesite
Na
 
8
Mn
 
2
Si
 
10
O
 
25
(OH,Cl)
 
2
·12H
 
2
O
9.EE.55Raite
(Na,Ca)
 
4
(Mn,Ti,Fe)
 
3
Si
 
8
O
 
16
(OH)
 
12
·5H
 
2
O
9.EE.60Intersilite
Na
 
6
Mn
2+
 
Ti[Si
 
10
O
 
24
(OH)](OH)
 
3
·4H
 
2
O
9.EE.65Shafranovskite
(Na,K)
 
6
(Mn,Fe)
 
3
Si
 
9
O
 
24
·6H
 
2
O
9.EE.70Zeophyllite
Ca
 
4
Si
 
3
O
 
8
(OH,F)
 
4
·2H
 
2
O
Related Minerals - Hey's Index Grouping:
14.18.1Nambulite
(Li,Na)Mn
 
4
Si
 
5
O
 
14
(OH)
14.18.2Natronambulite
(Na,Li)(Mn,Ca)
 
4
Si
 
5
O
 
14
OH
14.18.4Norrishite
KLiMn
2+
2
[(OH)
 
2
|Si
 
4
O
 
10
]
14.18.5Shafranovskite
(Na,K)
 
6
(Mn,Fe)
 
3
Si
 
9
O
 
24
·6H
 
2
O
14.18.6Abswurmbachite
CuMn
3+
6
O
 
8
(SiO
 
4
)
14.18.7Donpeacorite
(Mn
2+
 
,Mg)Mg[SiO
 
3
]
 
2
14.18.8Kanoite
Mn
2+
 
(Mg,Mn
2+
 
)[Si
 
2
O
 
6
]
14.18.9Caryopilite
(Mn,Mg)
 
3
Si
 
2
O
 
5
(OH)
 
4
14.18.10Gonyerite
(Mn,Mg)
 
5
Fe(Si
 
3
Fe)O
 
10
(OH)
 
8
14.18.11 Tirodite
14.18.12Manganhumite
(Mn
2+
 
,Mg)
 
7
[(OH)
 
2
|(SiO
 
4
)
 
3
]
14.18.13Bustamite
(Mn
2+
 
,Ca)[SiO
 
3
]
14.18.14Glaucochroite
CaMn
2+
 
[SiO
 
4
]
14.18.15Truscottite
(Ca,Mn)
 
14
Si
 
24
O
 
58
(OH)
 
8
·2H
 
2
O
14.18.16Santaclaraite
CaMn
 
4
[Si
 
5
O
 
14
OH](OH)·H
 
2
O
14.18.17Ferrobustamite
Ca(Fe
2+
 
,Ca,Mn
2+
 
)[Si
 
2
O
 
6
]
14.18.18Johannsenite
CaMn
2+
 
[Si
 
2
O
 
6
]
14.18.19Neltnerite
CaMn
3+
6
[O
 
8
|SiO
 
4
]
14.18.20Orlymanite
Ca
 
4
Mn
 
3
Si
 
8
O
 
20
(OH)
 
6
·2H
 
2
O
14.18.21Inesite
Ca
 
2
(Mn,Fe)
 
7
Si
 
10
O
 
28
(OH)
 
2
·5H
 
2
O
14.18.22Orientite
Ca
 
2
MnMn
 
2
Si
 
3
O
 
10
(OH)
 
4
14.18.23Ruizite
Ca
 
2
Mn
3+
2
[(OH)
 
2
|H
 
2
Si
 
4
O
 
13
] · 2H
 
2
O
14.18.24Bostwickite
CaMn
 
6
Si
 
3
O
 
16
·7H
 
2
O
14.18.25Kittatinnyite
Ca
 
2
Mn
 
2
Mn(SiO
 
4
)
 
2
(OH)
 
4
·9H
 
2
O
14.18.26Lithiomarsturite
LiCa
 
2
Mn
 
2
Si
 
5
O
 
14
(OH)
14.18.27Sérandite
Na(Mn
2+
 
,Ca)
 
2
[HSi
 
3
O
 
9
]
14.18.28Kvanefjeldite
Na
 
4
(Ca,Mn)(Si
 
3
O
 
7
)
 
2
(OH)
 
2
14.18.29Marsturite
NaCaMn
 
3
Si
 
5
O
 
14
(OH)
14.18.30Raite
(Na,Ca)
 
4
(Mn,Ti,Fe)
 
3
Si
 
8
O
 
16
(OH)
 
12
·5H
 
2
O
14.18.31Richterite
Na[CaNa][Mg
 
5
][(OH)
 
2
|Si
 
8
O
 
22
]
14.18.32Byelorussite-(Ce)
Ba
 
2
NaCe
 
2
MnTi
 
2
Si
 
8
O
 
26
(F,OH) · H
 
2
O
14.18.33Deerite
(Fe,Mn)
 
6
(Fe,Al)
 
3
Si
 
6
O
 
20
(OH)
 
5
14.18.34Calderite
(Mn
2+
 
,Ca)
 
3
(Fe
3+
 
,Al)
 
2
[SiO
 
4
]
 
3
14.18.35Pyroxmangite
MnSiO
 
3
14.18.36Dannemorite
14.18.37Neotocite
(Mn,Fe,Mg)SiO
 
3
·H
 
2
O
14.18.38Babingtonite
Ca
 
2
(Fe,Mn)FeSi
 
5
O
 
14
(OH)
14.18.39Manganbabingtonite
Ca
 
2
(Mn,Fe)FeSi
 
5
O
 
14
(OH)
14.18.40Örebroite
Mn
2+
3
(Fe
3+
 
,Sb
5+
 
)[(O,OH)
 
3
|SiO
 
4
]

Other Names for Zakharovite

Synonyms:
IMA1981-049Unnamed (MSH UK-38)
German names:
Zakharovit
Spanish names:
Zakharovita
Varieties:
Ferroan Zakharovite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Zakharovite

Reference List:Khomyakov, A. P., Kazakova, M. E., Vrublevskaya, Z. V., Zvyagin, B. B. & Piloyan, G. O. (1982): Zakharovite Na4Mn52+Si10O24(OH)6.6H2O as a new hydrosilicate of sodium and manganese. Zapiski Vserossiyskogo Mineralogicheskogo Obshchestva 111(4), 491-495. (in Russian)

American Mineralogist (1983): 68: 1040.

Internet Links for Zakharovite

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    Localities for Zakharovite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Québec
      • Rouville Co.
        • Mont Saint-Hilaire
    		No reference listed
      • Verchères Co.
        • Varennes & St-Amable
          • Saint-Amable sill
    		Mineralogical Record: 27: 306; Mineralogical Record: 29: 83.
    Namibia
     
    • Khomas Region
      • Windhoek District
        • Windhoek
          • Aris
    		[var: Ferroan Zakharovite] Wartha, R., Palfi, A., Niedermayr, G., Brandstätter, F. and Petersen, O. V. (2001): Der Aris-Phonolith-Komplex und seine Mineralien. In Bahmann, U. and A. (Eds.), Namibia – Zauberwelt edler Steine und Kristalle, Bode-Verlag, Haltern, Germany, pp. 172-179. (in German); [http://www.koeln.netsurf.de/~w.steffens/aris.htm]
    Russia
     
    • Northern Region
      • Murmanskaja Oblast'
        • Kola Peninsula
          • Khibiny Massif
    [World of Stones 95:5-6, p64]
    Pekov, I.V. & Podlesnyi, A.S. (2004): Kukisvumchorr Deposit: Mineralogy of Alkaline Pegmatites and Hydrotermalites. Mineralogical Almanac, vol. 7, 140 pages + xxiv photo's pages
    No reference listed
          • Lovozero Massif
    		[World of Stones 95:5-6, p64]
    No reference listed
            • Kedykverpakhk Mt
    		Mineralogical Record: 36(4): 397-416.
    Mineral and/or Locality
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