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Zeolite Group

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Big Photo

Chabazite
Teviot Brook, Boonah Shire, Queensland, Australia
© viccloete

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A group name for a large number of framework alumosilicates (and, rarely, beryllosilicates, zincosilicates, beryllophosphates) which are built of corner-linked tetrahedra and contain exchangeable cations; several of these minerals have important technical applications.
Several subgroups are distinguished (e.g., Natrolite Subgroup).

The current IMA-approved nomenclature is reported in Coombs et al. (1997).


Note: Tvedalite may also belong to the Zeolite Group (presently uncertain since the crystal structure of the mineral has not been determined yet).

Other minerals often found associated with zeolites include:
Apophyllite, calcite, cavansite, prehnite, epidote, quartz, pyrite, clay minerals etc.

Classification of Zeolite Group

IMA status:Approved 1997
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Relationship of Zeolite Group to other Species

Group Members:
Amicite
K
 
2
Na
 
2
Al
 
4
Si
 
4
O
 
16
 · 5H
 
2
O
Ammonioleucite
(NH
 
4
,K)(AlSi
 
2
O
 
6
)
Analcime
Na
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Barrerite
(Na,K,Ca
 
0.5
)
 
2
[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Bellbergite
(K,Ba,Sr)
 
2
Sr
 
2
Ca
 
2
(Ca,Na)
 
4
[Al
 
3
Si
 
3
O
 
12
]
 
6
 · 30H
 
2
O
Bikitaite
LiAlSi
 
2
O
 
6
 · H
 
2
O
Boggsite
Ca
 
8
Na
 
3
(Si,Al)
 
96
O
 
192
 · 70H
 
2
O
Brewsterite
Brewsterite-Ba
(Ba,Sr)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Brewsterite-Sr
(Sr,Ba,Ca)[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Chabazite
Chabazite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-K
(K
 
2
,Ca,Na
 
2
,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Levyne Subgroup
Chabazite-Mg
(Mg
 
0.7
K
 
0.5
Ca
 
0.5
Na
 
0.1
)[Al
 
3
Si
 
9
O
 
24
]·10H
 
2
O
Chabazite-Na
(Na
 
2
,K
 
2
,Ca,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chabazite-Sr
Sr
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
 · 12H
 
2
O
Chiavennite
CaMnBe
 
2
Si
 
5
O
 
13
(OH)
 
2
 · 2H
 
2
O
Clinoptilolite-Ca
(Ca,Na,K)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Clinoptilolite-Na
(Na,K,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Cowlesite
CaAl
 
2
Si
 
3
O
 
10
 · 6H
 
2
O
Dachiardite-Ca
(Ca,Na
 
2
,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Dachiardite-Na
(Na
 
2
,Ca,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
 · 25H
 
2
O
Direnzoite
NaK
 
6
MgCa
 
2
(Al
 
13
Si
 
47
O
 
120
) · 36H
 
2
O
Edingtonite
Ba[Al
 
2
Si
 
3
O
 
10
] · 4H
 
2
O
Epistilbite
CaAl
 
2
Si
 
6
O
 
16
 · 5H
 
2
O
Erionite
Erionite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-K
(K
 
2
,Ca,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Erionite-Na
(Na
 
2
,K
 
2
,Ca)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Faujasite Subgroup
Faujasite-Ca
(Ca,Na
 
2
,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Mg
(Mg,Na
 
2
,Ca)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Faujasite-Na
(Na
 
2
,Ca,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
Ferrierite
Ferrierite-K
(K
 
2
,Na
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Mg
(Mg,Na
 
2
,K
 
2
,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Ferrierite-Na
(Na
 
2
,K
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
] · 18H
 
2
O
Flörkeite
(K
 
3
Ca
 
2
Na)[Al
 
8
Si
 
8
O
 
32
] · 12H
 
2
O
Garronite
Na
 
2
Ca
 
5
Al
 
12
Si
 
20
O
 
64
 · 27H
 
2
O
Gaultite
Na
 
4
Zn
 
2
Si
 
7
O
 
18
 · 5H
 
2
O
Gismondine
Gismondine-Ba
Ba
 
2
Al
 
4
Si
 
4
O
 
16
 · 4-6H
 
2
O
Gismondine-Ca
CaAl
 
2
Si
 
2
O
 
8
 · 4H
 
2
O
Gmelinite
Gmelinite-Ca
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-K
(K
 
2
,Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gmelinite-Na
(Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Gobbinsite
Na
 
4
(Ca,Mg,K
 
2
)Al
 
6
Si
 
10
O
 
32
 · 12H
 
2
O
Gonnardite
(Na,Ca)
 
2
(Si,Al)
 
5
O
 
10
 · 3H
 
2
O
Goosecreekite
Ca[Al
 
2
Si
 
6
O
 
16
] · 5H
 
2
O
Gottardiite
Na
 
3
Mg
 
3
Ca
 
5
Al
 
19
Si
 
117
O
 
272
 · 93H
 
2
O
Harmotome
(Ba
 
0.5
,Ca
 
0.5
,K,Na)
 
5
[Al
 
5
Si
 
11
O
 
32
] · 12H
 
2
O
Heulandite-Ba
(Ba,Ca,K,Na,Sr)
 
5
Al
 
9
Si
 
27
O
 
72
 · 22H
 
2
O
Heulandite-Ca
(Ca,Na)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-K
(K,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Na
(Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Heulandite-Sr
(Sr,Na,Ca)
 
2-3
Al
 
3
(Al,Si)
 
2
Si
 
13
O
 
36
 · 12H
 
2
O
Hsianghualite
Ca
 
3
Li
 
2
(Be
 
3
Si
 
3
O
 
12
)F
 
2
Laumontite
CaAl
 
2
Si
 
4
O
 
12
 · 4H
 
2
O
Leucite
K(AlSi
 
2
O
 
6
)
Lévyne
Lévyne-Ca
(Ca,Na
 
2
,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lévyne-Na
(Na
 
2
,Ca,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
Lovdarite
(Na,K,Ca)
 
4
(Be,Al)
 
2
Si
 
6
O
 
16
 · 4H
 
2
O
Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
 · 32H
 
2
O
Mazzite-Mg
K
 
2
Mg
 
2
Ca
 
1.5
Al
 
9.5
Si
 
26.5
O
 
72
 · 28H
 
2
O or near
Mazzite-Na
Na
 
4
[Al
 
4
Si
 
14
O
 
36
]
 
2
 · 30H
 
2
O
Merlinoite
(K,Na)
 
5
(Ca,Ba)
 
2
Al
 
9
Si
 
23
O
 
64
 · 23H
 
2
O
Mesolite
Na
 
2
Ca
 
2
Si
 
9
Al
 
6
O
 
30
 · 8H
 
2
O
Montesommaite
(K,Na)
 
9
Al
 
9
Si
 
23
O
 
64
 · 10H
 
2
O
Mordenite
(Na
 
2
,Ca,K
 
2
)Al
 
2
Si
 
10
O
 
24
 · 7H
 
2
O
Mutinaite
Na
 
3
Ca
 
4
Si
 
85
Al
 
11
O
 
192
 · 60H
 
2
O
Natrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 2H
 
2
O
Natrolite Subgroup
Offretite
KCaMgAl
 
5
Si
 
13
O
 
36
 · 16H
 
2
O or near
Pahasapaite
Li
 
8
(Ca,Li,K)
 
10.5
Be
 
24
(PO
 
4
)
 
24
 · 38H
 
2
O
Paranatrolite
Na
 
2
Al
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Parthéite
CaAl
 
2
Si
 
2
O
 
8
 · 2H
 
2
O
Paulingite
Paulingite-Ca
(Ca,K
 
2
,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-K
(K
 
2
,Ca,Na
 
2
,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Paulingite-Na
(Na
 
2
,K
 
2
,Ca,Ba)
 
5
[Al
 
10
Si
 
35
O
 
90
] · 45H
 
2
O
Perlialite
K
 
9
Na(Ca,Sr)[Al
 
2
Si
 
4
O
 
12
]
 
6
 · 15H
 
2
O
Phillipsite-Ca
(Ca
 
0.5
,K,Na,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
.
 
 12H2O
Phillipsite-K
(K,Na,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
]
.
 
 12H
 
2
O
Phillipsite-Na
(Na,K,Ca
 
0.5
,Ba
 
0.5
)
 
4-7
[Al
 
4-7
Si
 
12-9
O
 
32
] · 12H
 
2
O
Pollucite
(Cs,Na)
 
2
(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Roggianite
Ca
 
2
Be(OH)
 
2
Al
 
2
Si
 
4
O
 
13
 · 2.5H
 
2
O
Scolecite
CaAl
 
2
Si
 
3
O
 
10
 · 3H
 
2
O
Stellerite
Ca[Al
 
2
Si
 
7
O
 
18
] · 7H
 
2
O
Stilbite
Stilbite-Ca
NaCa
 
4
[Al
 
9
Si
 
27
O
 
72
] · nH
 
2
O
Stilbite-Na
(Na,Ca,K)
 
6-7
[Al
 
8
Si
 
28
O
 
72
] · nH
 
2
O
Terranovaite
(Na,Ca)
 
8
(Si
 
68
Al
 
12
)O
 
160
 · 29H
 
2
O
Tetranatrolite
Thomsonite-Ca
NaCa
 
2
Al
 
5
Si
 
5
O
 
20
 · 6H
 
2
O
Thomsonite-Sr
(Sr,Ca)
 
2
Na[Al
 
5
Si
 
5
O
 
20
] · 7H
 
2
O
Tschernichite
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 4-8H
 
2
O
Tschörtnerite
Ca
 
4
(Ca,Sr,K,Ba)
 
3
Cu
 
3
[(OH)
 
2
|Al
 
3
Si
 
3
O
 
12
]
 
4
 · nH
 
2
O
Wairakite
Ca(Al
 
2
Si
 
4
O
 
12
) · 2H
 
2
O
Weinebeneite
CaBe
 
3
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
Willhendersonite
KCa[Al
 
3
Si
 
3
O
 
12
] · 5H
 
2
O
Yugawaralite
CaAl
 
2
Si
 
6
O
 
16
 · 4H
 
2
O

Other Names for Zeolite Group

Synonyms:
GaargotiZeolite
Other Languages:
German:Kuphit
Zeolith
Simplified Chinese:沸石
Spanish:Zeolita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Zeolite Group

Reference List:

- +
Taylor, W.H., Meek, C.A., and Jackson, W.W. (1933) The structures of the fibrous zeolites. Zeitschrift für Kristallographie: 84: 373.

Gottardi, G. & E. Galli (1985), Natural Zeolites, 409 p., Springer-Verlag, Berlin.

Tschernich, R. (1992): Zeolites of the world. Geoscience Press Inc., Phoenix, AZ, USA, 563 pp. [freely downloadable: http://www.mindat.org/books/Zeolites-of-the-World-Updated.pdf]

Coombs, D.S., A. Alberti, T. Armbruster, G. Artioli, C. Colella, E. Galli, J.D. Grice, F. Liebau, J.A. Mandarino, H. Minato, E.H. Nickel, E. Passaglia, D.R. Peacor, S. Quartieri, R. Rinaldi, M. Ross, R.A. Sheppard, E. Tillmans & G. Vezzalini (1997): Recommended nomenclature for zeolite minerals: Report of the Subcommittee on Zeolites of the International Mineralogical Association, Commission on New Minerals and Mineral Names. Canadian Mineralogist 35, 1571-1606. [http://www.mineralogicalassociation.ca/doc/abstracts/ima98/ima98(13).pdf ]

Mineralogical Magazine (1998): 62: 533.

Armbruster, T. & M.E. Gunter (2001), Crystal structures of natural zeolites. in D.L. Bish andD.W. Ming, Eds., Natural zeolites: Occurrence, properties, application Reviews in Mineralogy and Geochemistry: 45: 1-57. Mineralogical Soceity of America and Geochemical Society, Washington, USA.

Baerlocher, Ch., Meier, W.M., & Olson, D.H. (2001), Atlas of zeolite framework types, 5th. edition, 302 p. Elsevier, Amsterdam, Netherlands.

Hay, R.L., and R.A. Sheppard (2001), Occurrence of zeolites in sedimentary rocks: An noverview. In D.L. Bish and D.W. Ming, Editors, Natural zeolites: properties, applications and uses, 45: 217-232. Reviews in Mineralogy and Geochemistry, Mineralogical Society of America, Chantilly, Virginia.

Lee, Y., T. Vogt, J.A. Hriljac, J.B. Parise, J.C. Hanson & S.J. Kimk (2002): Non-framework cation migration and irreversible pressure-induced hydration in a zeolite: Nature: 420: 485-489.

Vieillard, P. (2010): A predictive model for the entropies and heat capacities of zeolites. European Journal of Mineralogy 22, 823-836.


http://www.iza-online.org

http://icnz.lanl.gov/ [Link dead. Jan 2012]

http://www.zeolite-collection.eu/

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