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Zhonghuacerite-(Ce)

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Bayan Obo (Bayun-Obo; Baiyunebo) deposit, Bayan Obo, Darhan Muminggan United Banner (Da'erhan Maoming'an Lianheqi), Baotou League (Baotou Prefecture), Inner Mongolia Autonomous Region, China

Show Zhonghuacerite-(Ce) Photos (2)



Formula:
Ba
 
2
Ce(CO
 
3
)
 
3
F
System:TrigonalColour:Yellow
Lustre:Vitreous, ResinousHardness:4½
Name:From Chinese for "a cerium mineral from China."


Bastnäsite Group.

Probably not valid, type material may be either Huanghoite-(Ce) or Kukharenkoite-(Ce). Formula and the revised monoclinic cell parameters seen in e.g. webmineral.com (from Dana 8?) suggest identity with kukharenkoite-(Ce).

Originally reported from West Mine, Bayan Obo (Bayun-Obo; Baiyunebo) deposit, Darhan Muminggan United Banner, Baotou League, Nei Mongol Autonomous Region (Inner Mongolia), China.

Classification of Zhonghuacerite-(Ce)

IMA status:Published without Approval
Explanation of status:The so called zhonghuacerite-(Ce) was never submitted to the IMA CNMMN hence it was never approved. It entered the mineralogical literature via a review in the New Minerals section of Am. Min. 67, 1078. The description was published in Chinese and reviewer was not aware that the mineral was not approved by IMA. The mineral was listed in the Glossary of Mineral Species (Fleischer 1983 and Fleisher and Mandarino 1995).

Zhonghuacerite was published in 1981 without having been submitted to the CNMMN. The name was changed by the CNMMN in 1987 to zhonghuacerite-(Ce) as part of the update of mineral names with Levinson modifiers.

Thus we have a strange situation that we seem to have a CNMMN-approved name for a non-approved mineral.
Strunz 8th edition ID:5/C.07-160
Nickel-Strunz 10th (pending) edition ID:5.BD.10

5 : CARBONATES (NITRATES)
B : Carbonates with additional anions, without H2O
D : With rare earth elements (REE)
Dana 8th edition ID:16a.1.8.1

16a : ANHYDROUS CARBONATES CONTAINING HYDROXYL OR HALOGEN
1 : (AB)(XO3)Zq
Hey's CIM Ref.:12.1.20

12 : Carbonates with other anions
1 : Carbonates with halides
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Physical Properties of Zhonghuacerite-(Ce)

Lustre:Vitreous, Resinous
Diaphaneity (Transparency):Transparent
Colour:Yellow
Hardness (Mohs):4½

Crystallography of Zhonghuacerite-(Ce)

Crystal System:Trigonal
Cell Parameters:a = 5.07Å, b = 5.07Å, c = 9.82Å
α = 90°, β = 90°, γ = 120°
Ratio:a:b:c = 1 : 1 : 1.937
Unit Cell Volume:V 218.60 ų (Calculated from Unit Cell)
Z:1

Optical Data of Zhonghuacerite-(Ce)

Type:Uniaxial (-)
RI values: nω = 1.745 nε = 1.565
Maximum Birefringence:δ = 0.180

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Zhonghuacerite-(Ce)

Formula:
Ba
 
2
Ce(CO
 
3
)
 
3
F
Essential elements:Ba, C, Ce, F, O
All elements listed in formula:Ba, C, Ce, F, O

Relationship of Zhonghuacerite-(Ce) to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
5.BD.05Cordylite-(Ce)
NaBaCe
 
2
(CO
 
3
)
 
4
F
5.BD.05Lukechangite-(Ce)
Na
 
3
Ce
 
2
(CO
 
3
)
 
4
F
5.BD.10Kukharenkoite-(Ce)
Ba
 
2
Ce(CO
 
3
)
 
3
F
5.BD.10Kukharenkoite-(La)
Ba
 
2
(La,Ce,Th)(CO
 
3
)
 
3
F
5.BD.15Cebaite-(Ce)
Ba
 
3
Ce
 
2
(CO
 
3
)
 
5
F
 
2
5.BD.15Cebaite-(Nd)
Ba
 
3
(Nd,Ce)
 
2
(CO
 
3
)
 
5
F
 
2
5.BD.18Arisite-(Ce)
NaCe
 
2
(CO
 
3
)
 
3-x
F
 
2x+1
5.BD.18Arisite-(La)
NaLa
 
2
(CO
 
3
)
 
3-x
F
 
2x+1
5.BD.20aBastnäsite-(Ce)
(Ce,La)(CO
 
3
)F
5.BD.20aBastnäsite-(La)
(La,Ce)(CO
 
3
)F
5.BD.20aBastnäsite-(Y)
(Y,Ce)(CO
 
3
)F
5.BD.20aHydroxylbastnäsite-(Ce)
(Ce,La)(CO
 
3
)(OH,F)
5.BD.20aHydroxylbastnäsite-(Nd)
(Nd,Ce,La)(CO
 
3
)(OH,F)
5.BD.20aHydroxylbastnäsite-(La)
(La,Ce)(CO
 
3
)(F,OH)
5.BD.20bParisite-(Ce)
Ca(Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
5.BD.20bParisite-(Nd)
Ca(Nd,Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
5.BD.20dRöntgenite-(Ce)
Ca
 
2
(Ce,La)
 
3
(CO
 
3
)
 
5
F
 
3
5.BD.20cSynchysite-(Ce)
Ca(Ce,La)(CO
 
3
)
 
2
F
5.BD.20cSynchysite-(Nd)
Ca(Nd,Y,Gd)(CO
 
3
)
 
2
F
5.BD.20cSynchysite-(Y)
Ca(Y,Ce)(CO
 
3
)
 
2
F
5.BD.20aThorbastnäsite
Th(Ca,Ce)(CO
 
3
)
 
2
F
 
2
 · 3H
 
2
O
5.BD.20aBastnäsite-(Nd)
(Nd,Ce,La)(CO
 
3
)F
5.BD.25Horváthite-(Y)
NaY(CO
 
3
)F
 
2
5.BD.25Qaqarssukite-(Ce)
Ba(Ce,REE)(CO
 
3
)
 
2
F
5.BD.35Huanghoite-(Ce)
BaCe(CO
 
3
)
 
2
F
Related Minerals - Hey's Index Grouping:

- +
12.1.1Northupite
Na
 
3
Mg(CO
 
3
)
 
2
Cl
12.1.2Barentsite
Na
 
7
AlH
 
2
(CO
 
3
)
 
4
F
 
4
12.1.3Rouvilleite
Na
 
3
(Ca,Mn,Fe)
 
2
(CO
 
3
)
 
3
F
12.1.4Chlormagaluminite
(Mg,Fe
2+
 
)
 
4
Al
 
2
(Cl
 
2
,CO
 
3
)(OH)
 
12
 · 2H
 
2
O
12.1.5Defernite
Ca
 
6
(CO
 
3
)
 
2-x
(SiO
 
4
)
 
x
(OH)
 
7
(Cl,OH)
 
1-2x
 (x=0.5)
12.1.6Brenkite
Ca
 
2
(CO
 
3
)F
 
2
12.1.7Stenonite
(Sr,Ba,Na)
 
2
Al(CO
 
3
)F
 
5
12.1.8Bastnäsite-(Ce)
(Ce,La)(CO
 
3
)F
12.1.9Bastnäsite-(La)
(La,Ce)(CO
 
3
)F
12.1.10Bastnäsite-(Y)
(Y,Ce)(CO
 
3
)F
12.1.11Parisite-(Ce)
Ca(Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
12.1.12Parisite-(Nd)
Ca(Nd,Ce,La)
 
2
(CO
 
3
)
 
3
F
 
2
12.1.13Synchysite-(Ce)
Ca(Ce,La)(CO
 
3
)
 
2
F
12.1.14Synchysite-(Y)
Ca(Y,Ce)(CO
 
3
)
 
2
F
12.1.15Synchysite-(Nd)
Ca(Nd,Y,Gd)(CO
 
3
)
 
2
F
12.1.16Röntgenite-(Ce)
Ca
 
2
(Ce,La)
 
3
(CO
 
3
)
 
5
F
 
3
12.1.17Cordylite-(Ce)
NaBaCe
 
2
(CO
 
3
)
 
4
F
12.1.19Huanghoite-(Ce)
BaCe(CO
 
3
)
 
2
F
12.1.21Cebaite-(Ce)
Ba
 
3
Ce
 
2
(CO
 
3
)
 
5
F
 
2
12.1.22Thorbastnäsite
Th(Ca,Ce)(CO
 
3
)
 
2
F
 
2
 · 3H
 
2
O
12.1.23Phosgenite
Pb
 
2
CO
 
3
Cl
 
2
12.1.24Barstowite
Pb
 
4
Cl
 
6
(CO
 
3
) · H
 
2
O
12.1.25Albrechtschraufite
Ca
 
4
Mg(UO
 
2
)
 
2
(CO
 
3
)
 
6
F
 
2
 · 17 H
 
2
O
12.1.26Kettnerite
CaBiCO
 
3
OF

Other Names for Zhonghuacerite-(Ce)

Other Languages:
Russian:Жоньхуацерит-(Се)

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Zhonghuacerite-(Ce)

Reference List:

- +
Zhang Peishan and Tao Kejie (1981): Zhonghuacerite Ba2Ce(CO3)3F - A new mineral. Scientia Geologica Sinica 1981(2), 195-196 (in Chinese with English abstract).

Zhang Peishan, Tao Kejie, and Li Fanghua (1981): Zhonghuacerite - A new rare earth mineral. Acta Mineralogica Sinica 1(2), 65-74 (in Chinese with English abstract). - American Mineralogist (1982) 67, 1078 (abstract).

Zaitsev et al. (1996): European Journal of Mineralogy 8, 1327-1336.

Internet Links for Zhonghuacerite-(Ce)

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    • Localities for Zhonghuacerite-(Ce)

    Hide Locality List
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    China
     
    • Inner Mongolia Autonomous Region
      • Baotou League (Baotou Prefecture)
        • Darhan Muminggan United Banner (Da'erhan Maoming'an Lianheqi)
          • Bayan Obo
            • Bayan Obo (Bayun-Obo; Baiyunebo) deposit
    		Zhang Peishan, Tao Kejie, and Li Fanghua (1981): Acta Mineralogica Sinica 1(2), 65-74.
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