Natrowalentaite
A valid IMA mineral species
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Formula:
[Fe3+0.5Na0.5(H2O)6][NaAs3+2(Fe3+2.33W6+0.67)(PO4)2O7]
Colour:
Greenish-yellow
Specific Gravity:
2.91
Crystal System:
Orthorhombic
Member of:
Name:
The sodium analogue whose base name is given in honor of Dr. Kurt Walenta (1 December 1927 Prague, Czech Republic - 19 November 2021), Professor of Mineralogy, University of Stuttgart (Germany)
Isostructural with:
Chemically and structurally related to walentaite.
May be treated as FeNaNaWP-analogue of halilsarpite.
May be treated as FeNaNaWP-analogue of halilsarpite.
Unique Identifiers
Mindat ID:
53255
Long-form identifier:
mindat:1:1:53255:0
GUID
(UUID V4):
(UUID V4):
a30c9aa7-7c30-433a-99c5-40f4db220711
IMA Classification of Natrowalentaite
Approved, Pending publication
IMA Formula:
[Fe3+0.5Na0.5(H2O)6][NaAs3+2(Fe3+2.33W6+0.67)(PO4)2O7]
Approval year:
2018
Classification of Natrowalentaite
8.CH.05
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
H : With large and medium-sized cations, RO4:H2O < 1:1
8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
H : With large and medium-sized cations, RO4:H2O < 1:1
Mineral Symbols
As of 2021 there are now IMA–CNMNC approved mineral symbols (abbreviations) for each mineral species, useful for tables and diagrams.
| Symbol | Source | Reference |
|---|---|---|
| Nwal | IMA–CNMNC | Warr, L.N. (2021). IMA–CNMNC approved mineral symbols. Mineralogical Magazine, 85(3), 291-320. doi:10.1180/mgm.2021.43 |
Physical Properties of Natrowalentaite
Colour:
Greenish-yellow
Cleavage:
Perfect
{100}
{100}
Density:
2.91(2) g/cm3 (Measured)
Optical Data of Natrowalentaite
Type:
Biaxial (-)
RI values:
nα = 1.650(3) nβ = 1.728(3) nγ = 1.772(3)
2V:
Measured: 71° (2)
Max Birefringence:
δ = 0.122
Image shows birefringence interference colour range (at 30µm thickness)
and does not take into account mineral colouration.
and does not take into account mineral colouration.
Surface Relief:
High
Pleochroism:
Not Visible
Chemistry of Natrowalentaite
Mindat Formula:
[Fe3+0.5Na0.5(H2O)6][NaAs3+2(Fe3+2.33W6+0.67)(PO4)2O7]
Crystallography of Natrowalentaite
Crystal System:
Orthorhombic
Class (H-M):
mmm (2/m 2/m 2/m) - Dipyramidal
Space Group:
Imma
Setting:
Imma
Cell Parameters:
a = 25.770(3) Å, b = 7.3250(8) Å, c = 10.522(1) Å
Ratio:
a:b:c = 3.518 : 1 : 1.436
Unit Cell V:
1,986.19 ų (Calculated from Unit Cell)
Z:
4
X-Ray Powder Diffraction
Powder Diffraction Data:
| d-spacing | Intensity |
|---|---|
| 12.95 Å | (100) |
| 9.72 Å | (9) |
| 6.72 Å | (14) |
| 4.41 Å | (10) |
| 3.020 Å | (27) |
| 2.940 Å | (15) |
| 2.759 Å | (11) |
| 1.784 Å | (10) |
Geological Environment
Paragenetic Mode(s):
| Paragenetic Mode | Earliest Age (Ga) |
|---|---|
| Stage 7: Great Oxidation Event | <2.4 |
| 47a : [Near-surface hydration of prior minerals] | |
| 47c : [Carbonates, phosphates, borates, nitrates] | |
| 47d : [Arsenates, antimonates, selenates, bismuthinates] |
Type Occurrence of Natrowalentaite
General Appearance of Type Material:
aggregates of extremely thin (1 to 3 μm), bright greenish-yellow blades with lengths up to 200 μm, on natropharmacosiderite.
Place of Conservation of Type Material:
Deposited in the mineralogical collections of the Natural History Museum of Los Angeles County, 900 Exposition Boulevard, Los Angeles, CA 90007, USA, catalogue number 66703.
Synonyms of Natrowalentaite
Relationship of Natrowalentaite to other Species
Member of:
Other Members of this group:
| Walentaite | Fe3+3(P0.84As0.16O4)2(O,OH)6As3+2.56Ca0.42Na0.28Mn2+0.35Fe2+0.30O6.1(OH)0.9(H2O)0.9 | Orth. mmm (2/m 2/m 2/m) : Imma |
Related Minerals - Strunz-mindat Grouping
| 8.CH.05 | Walentaite | Fe3+3(P0.84As0.16O4)2(O,OH)6As3+2.56Ca0.42Na0.28Mn2+0.35Fe2+0.30O6.1(OH)0.9(H2O)0.9 |
| 8.CH.05 | Halilsarpite | [Mg(H2O)6][CaAs3+2(Fe3+2.67Mo6+0.33)(AsO4)2O7] |
| 8.CH.10 | Anapaite | Ca2Fe2+(PO4)2 · 4H2O |
| 8.CH.15 | Picropharmacolite | Ca4Mg(AsO4)2(HAsO4)2 · 11H2O |
| 8.CH.20 | Dittmarite | (NH4)Mg(PO4) · H2O |
| 8.CH.20 | Niahite | (NH4)(Mn2+,Mg)(PO4) · H2O |
| 8.CH.25 | Francoanellite | K3Al5(PO3OH)6(PO4)2 · 12H2O |
| 8.CH.25 | Taranakite | (K,NH4)Al3(PO4)3(OH) · 9H2O |
| 8.CH.30 | Schertelite | (NH4)2MgH2(PO4)2 · 4H2O |
| 8.CH.35 | Hannayite | (NH4)2Mg3H4(PO4)4 · 8H2O |
| 8.CH.40 | Struvite | (NH4)Mg(PO4) · 6H2O |
| 8.CH.40 | Struvite-(K) | KMg(PO4) · 6H2O |
| 8.CH.40 | Hazenite | KNaMg2(PO4)2 · 14H2O |
| 8.CH.45 | Rimkorolgite | (Mg,Mn)5(Ba,Sr,Ca)(PO4)4 · 8H2O |
| 8.CH.50 | Bakhchisaraitsevite | Na2Mg5(PO4)4 · 7H2O |
| 8.CH.55 | Fahleite | CaZn5Fe3+2(AsO4)6 · 14H2O |
| 8.CH.55 | Smolyaninovite | Co3Fe3+2(AsO4)4 · 11H2O |
| 8.CH.60 | Barahonaite-(Al) | (Ca,Cu,Na,Fe3+,Al)12Al2(AsO4)8(OH,Cl)x · nH2O |
| 8.CH.60 | Barahonaite-(Fe) | (Ca,Cu,Na,Fe3+,Al)12Fe3+2(AsO4)8(OH,Cl)x · nH2O |
| 8.CH.70 | Epifanovite | NaCaCu5(PO4)4[AsO2(OH)2] · 7H2O |
| 8.CH.75 | Esdanaite-(Ce) | NaMnCe(PO4)2 · 4H2O |
Other Information
Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Internet Links for Natrowalentaite
mindat.org URL:
https://www.mindat.org/min-53255.html
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References for Natrowalentaite
Localities for Natrowalentaite
symbol to view information about a locality.
The Locality List
- This locality has map coordinates listed.
- This locality has estimated coordinates.
ⓘ - Click for references and further information on this occurrence.
? - Indicates mineral may be doubtful at this locality.
- Good crystals or important locality for species.
- World class for species or very significant.
(TL) - Type Locality for a valid mineral species.
(FRL) - First Recorded Locality for everything else (eg varieties).
All localities listed without proper references should be considered as questionable.
Australia (TL) | |
| Hålenius et al. (2018) |
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