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Benyacarite

Big Photo

Hagendorf South Pegmatite (Cornelia Mine; Hagendorf South Open Cut), Hagendorf, Waidhaus, Vohenstrauß, Oberpfälzer Wald, Upper Palatinate, Bavaria, Germany
© Christian Rewitzer

Show Benyacarite Photos (10)
Formula:
(H
 
2
O,K)
 
2
(Mn
2+
 
,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti)
 
2
Ti[(O,F)
 
2
|(PO
 
4
)
 
4
] · 14H
 
2
O
System:OrthorhombicLustre:Vitreous
Hardness:2½ - 3
Name:For Maria Angelica R. de Benyacar (1928-), Comision Nacional de Energia Atomica, Buenos Ares, Argentina, for her contribution to mineralogical studies.


A K-dominant end-member (probably new mineral) was reported by Sejkora et al. (2006).

Compare also paulkerrite and mantienneite.

Classification of Benyacarite

IMA status:Approved
Strunz 8th edition ID:7/D.33-30
Nickel-Strunz 10th (pending) edition ID:8.DH.35

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
Dana 8th edition ID:42.11.21.4

42 : HYDRATED PHOSPHATES, ETC.CONTAINING HYDROXYL OR HALOGEN
11 : (AB)3(XO4)2Zq·xH2O
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Type Occurrence of Benyacarite

Type Locality:El Criollo Mine, Cerro Blanco pegmatite district, Tanti, Punilla Department, Córdoba, Argentina
Year of Discovery:1993

Physical Properties of Benyacarite

Lustre:Vitreous
Hardness (Mohs):2½ - 3

Crystallography of Benyacarite

Crystal System:Orthorhombic
Cell Parameters:a = 10.56Å, b = 20.58Å, c = 12.51Å
Ratio:a:b:c = 0.513 : 1 : 0.608
Unit Cell Volume:V 2,718.73 ų (Calculated from Unit Cell)

Optical Data of Benyacarite

Type:Biaxial (+)
RI values: nα = 1.612 nβ = 1.621 nγ = 1.649
2V:Measured: 60° , Calculated: 60°
Maximum Birefringence:δ = 0.037

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:none

Chemical Properties of Benyacarite

Formula:
(H
 
2
O,K)
 
2
(Mn
2+
 
,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti)
 
2
Ti[(O,F)
 
2
|(PO
 
4
)
 
4
] · 14H
 
2
O
Essential elements:Fe, H, Mn, O, P, Ti
All elements listed in formula:F, Fe, H, K, Mn, O, P, Ti

Relationship of Benyacarite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DH.05Minyulite
KAl
 
2
[(OH,F)|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.10Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.15Jahnsite-(CaMnFe)
CaMn
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMg)
CaMn
2+
 
(Mg,Fe
2+
 
)
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMnMn)
CaMn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Keckite
(Ca,Mg)(Mn
2+
 
,Zn)
 
2
Fe
3+
3
(PO
 
4
)
 
4
(OH)
 
3
 · 2H
 
2
O
8.DH.15Rittmannite
(Mn
2+
 
,Ca)Mn
2+
 
(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
(Al,Fe
3+
 
)
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaFeMg)
Ca(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(CaMnMg)
CaMn
2+
 
Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Whiteite-(MnFeMg)
(Mn
2+
 
,Ca)(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(MnMnMn)
Mn
2+
 
Mn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
](OH)
 
2
 · 8H
 
2
O
8.DH.15Kaluginite
(Mn
2+
 
,Ca)MgFe
3+
 
[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.15Jahnsite-(CaFeFe)
CaFeFe
 
2
Fe
 
2
(PO
 
4
)
 
4
(OH)
 
2
·8H
 
2
O
8.DH.15Jahnsite-(NaFeMg)
NaFe
3+
 
Mg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(NaMnMg)
NaMnMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.15Jahnsite-(CaMgMg)
CaMgMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Manganosegelerite
(Mn
2+
 
,Ca)(Mn
2+
 
,Fe
2+
 
,Mg)Fe
3+
 
(PO
 
4
)
 
2
(OH)
 
2
 · 4H
 
2
O
8.DH.20Overite
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.20Segelerite
Ca
 
2
 Mg
 
2
 Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
 · 8H
 
2
O
8.DH.20Wilhelmvierlingite
CaMnFe
3+
 
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.20Juonniite
CaMgSc(PO
 
4
)
 
2
(OH)·4H
 
2
O
8.DH.25Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
8.DH.25Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.25Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
 · 12H
 
2
O
8.DH.30Arseniosiderite
Ca
 
2
Fe
3+
3
[O
 
2
|(AsO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Kolfanite
Ca
 
2
Fe
3+
2
[O
 
2
|(AsO
 
4
)
 
3
] · 2H
 
2
O
8.DH.30Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Pararobertsite
Ca
 
2
Mn
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Robertsite
Ca
 
3
Mn
3+
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.30Sailaufite
Ca
 
2
Mn
3+
3
[O|CO
 
3
|(AsO
 
4
)
 
2
] · 3H
 
2
O
8.DH.35Mantienneite
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
8.DH.35Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
 · 15H
 
2
O
8.DH.40Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
 · 3H
 
2
O
8.DH.45Mahnertite
NaCu
 
3
(AsO
 
4
)
 
2
Cl · 5H
 
2
O
8.DH.50Andyrobertsite
KCdCu
 
5
[H
 
2
AsO4|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.50Calcioandyrobertsite
KCaCu
 
5
[H
 
2
AsO
 
4
|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.55Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
 · 26H
 
2
O
8.DH.60Bouazzerite
Bi
 
6
(Mg,Co)
 
11
Fe
3+
14
(AsO
 
4
)
 
18
O
 
12
(OH)
 
4
(H
 
2
O)
 
86

Other Names for Benyacarite

Synonyms:
IMA1995-002
Other Languages:
German:Benyacarit
Russian:Бениакарит
Spanish:Benyacarita
Varieties:
Matveevite

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Benyacarite

Reference List:Mineralogical Record: 29: 233-234.

Canadian Mineralogist: 35: 707-712.

Zeitschrift für Kristallographie: 208: 57-71.

Sejkora, J., Škoda, R., Ondruš, P., Beran, P. & Susser, C. (2006): Mineralogy of phosphate accumulations in the Huber stock, Krásno ore district, Slavkovský les area, Czech Republic. Journal of the Czech Geological Society 51, 103-147.

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Internet Links for Benyacarite

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    Localities for Benyacarite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • Córdoba
      • Punilla Department
        • Tanti
          • Cerro Blanco pegmatite district
    		Zeitschr.Krist.(1993) 208, 57-71; Can.Min.(1997) 35, 707-712
    Czech Republic
     
    • Moravia (Mähren; Maehren)
      • Vysočina Region
        • Velké Meziříčí
    		Škoda, R., Staněk, J., Čopjaková, R.: Minerální asociace fosfátových nodulí z granitického pegmatitu od Cyrilova u Velkého Meziříčí, Moldanubikum; část 1 – primární a exsoluční fáze. Acta Mus. Moraviae, Sci. geol., 2007, 92, 59-74.
    Germany
     
    • Bavaria
      • Upper Palatinate
        • Oberpfälzer Wald
          • Vohenstrauß
            • Pleystein
    		Anthony, Bideaux, Bladh, Nichols: Handbook of Mineralogy, Vol. IV
            • Waidhaus
              • Hagendorf
    		Anthony, Bideaux, Bladh, Nichols: Handbook of Mineralogy, Vol. IV
    Portugal
     
    • Guarda District
      • Gouveia
        • Folgosinho
      • Sabugal
    		Christian Rewitzer collection / analysed
    Mineral and/or Locality
    Google
     
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