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Erionite-Ca

Formula:
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
System:HexagonalColour:White
Lustre:VitreousHardness:3½ - 4
Name:From the Greek for wool, in allusion to its white, fibrous, wool-like appearance. The Ca-dominant member of the erionite series.


A zeolite difficult to distinguish from offrétite.

Classification of Erionite-Ca

IMA status:Approved
Strunz 8th edition ID:8/J.26-94
Nickel-Strunz 10th (pending) edition ID:9.GD.20

9 : SILICATES (Germanates)
G : Tektosilicates with zeolitic H2O; zeolite family
D : Chains of 6-membered rings – tabular zeolites
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Type Occurrence of Erionite-Ca

Type Locality:Maze (Mazé), Niigata Prefecture, Chubu Region, Honshu Island, Japan

Physical Properties of Erionite-Ca

Lustre:Vitreous
Colour:White
Streak:White
Hardness (Mohs):3½ - 4

Crystallography of Erionite-Ca

Crystal System:Hexagonal
Class (H-M):6/mmm (6/m 2/m 2/m) - Dihexagonal Dipyramidal
Space Group:P63/mmc {P63/m 2/m 2/c}
Cell Parameters:a = 13.15Å, c = 15.05Å
Ratio:a:c = 1 : 1.144
Unit Cell Volume:V 2,253.82 ų (Calculated from Unit Cell)

Optical Data of Erionite-Ca

Type:Uniaxial (+)
RI values: nω = 1.471 nε = 1.474
Maximum Birefringence:δ = 0.003

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Erionite-Ca

Formula:
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
Essential elements:Al, Ca, H, O, Si
All elements listed in formula:Al, Ca, H, K, Na, O, Si

Relationship of Erionite-Ca to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.GD.05Gmelinite-Ca
(Ca,Na
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
9.GD.05Gmelinite-K
(K
 
2
,Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
9.GD.05Gmelinite-Na
(Na
 
2
,Ca)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
9.GD.10Willhendersonite
KCa[Al
 
3
Si
 
3
O
 
12
] · 5H
 
2
O
9.GD.10Chabazite-Ca
(Ca,K
 
2
,Na
 
2
)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
9.GD.10Chabazite-K
(K
 
2
,Ca,Na
 
2
,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
9.GD.10Chabazite-Na
(Na
 
2
,K
 
2
,Ca,Sr,Mg)
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
9.GD.10Chabazite-Sr
Sr
 
2
[Al
 
2
Si
 
4
O
 
12
]
 
2
· 12H
 
2
O
9.GD.15Lévyne-Ca
(Ca,Na
 
2
,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
9.GD.15Lévyne-Na
(Na
 
2
,Ca,K
 
2
)[Al
 
2
Si
 
4
O
 
12
] · 6H
 
2
O
9.GD.20Bellbergite
(K,Ba,Sr)
 
2
Sr
 
2
Ca
 
2
(Ca,Na)
 
4
[Al
 
3
Si
 
3
O
 
12
]
 
6
· 30H
 
2
O
9.GD.20Erionite-K
(K
 
2
,Ca,Na
 
2
)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
9.GD.20Erionite-Na
(Na
 
2
,K
 
2
,Ca)
 
2
[Al
 
4
Si
 
14
O
 
36
] · 15H
 
2
O
9.GD.25Offretite
KCaMgAl
 
5
Si
 
13
O
 
36
·16H
 
2
O or near
9.GD.25Wenkite
(Ba,K)
 
4
(Ca,Na)
 
6
[(SO
 
4
)
 
3
|(Si,Al)
 
20
O
 
39
(OH)
 
2
] · 0.5H
 
2
O
9.GD.30Faujasite-Ca
(Ca,Na
 
2
,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
9.GD.30Faujasite-Mg
(Mg,Na
 
2
,Ca)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
9.GD.30Faujasite-Na
(Na
 
2
,Ca,Mg)
 
3.5
[Al
 
7
Si
 
17
O
 
48
] · 32H
 
2
O
9.GD.35Maricopaite
Pb
 
7
Ca
 
2
(Si,Al)
 
48
O
 
100
·32H
 
2
O
9.GD.35Mordenite
(Na
 
2
,Ca,K
 
2
)Al
 
2
Si
 
10
O
 
24
·7H
 
2
O
9.GD.40Dachiardite-Ca
(Ca,Na
 
2
,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
·25H
 
2
O
9.GD.40Dachiardite-Na
(Na
 
2
,Ca,K
 
2
)
 
5
Al
 
10
Si
 
38
O
 
96
·25H
 
2
O
9.GD.45Epistilbite
CaAl
 
2
Si
 
6
O
 
16
·5H
 
2
O
9.GD.50Ferrierite-K
(K
 
2
,Na
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
]·18H
 
2
O
9.GD.50Ferrierite-Mg
(Mg,Na
 
2
,K
 
2
,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
]·18H
 
2
O
9.GD.50Ferrierite-Na
(Na
 
2
,K
 
2
,Mg,Ca)
 
3-5
Mg[Al
 
5-7
Si
 
27.5-31
O
 
72
]·18H
 
2
O
9.GD.55Bikitaite
LiAlSi
 
2
O
 
6
·H
 
2
O

Other Names for Erionite-Ca

Other Languages:
Russian:Эрионит-Ca

Other Information

Health Warning:Carcinogenic upon inhalation of its dust, due to its fibrous structure (Ref.: IARC Monography 42:225-239, 1987)

References for Erionite-Ca

Reference List:Sheppard, R.A. and Gude, A.J. (1969b) Chemical composition and physical properties of the related zeolites offretite and erionite. American Mineralogist: 54: 875-886.

Gualtieri, A., G. Artioli, E. Passaglia, S. Bigi, A. Viani, and J.C. Hanson (1998): Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite American Mineralogist: 83, 590-606.

Passaglia, E., G. Artioli, and A. Gualtieri (1998): Crystal chemistry of the zeolites erionite and offretite American Mineralogist: 83, 577-589.

Internet Links for Erionite-Ca

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    Localities for Erionite-Ca

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Czech Republic
     
    • Bohemia (Böhmen; Boehmen)
      • Ústí Region
        • Ústí nad Labem (Aussig)
    Rychlý, R., Langrová, A., Had, J.: Chemicstry of cowlesite from Zezice, Bohemia. Scripta Fac. Sci. Nat. Univ. Masaryk. Brun, Geol., 1996, vol. 26, p. 43 - 44.
    France
     
    • Auvergne
      • Haute-Loire
        • Yssingeaux
          • Araules
    Gualtieri A, et al. (1998) Crystal structure-crystal chemistry relationships in the zeolites erionite and offretite. American Mineralogist 83: 509-606
    Germany
     
    • Rhineland-Palatinate
      • Eifel Mts
        • Mayen
          • Ettringen
            • Bellerberg volcano
              • Ettringer Bellerberg Mt. (Bellberg Mt.; Bellenberg Mt.; Billenberg Mt.; Boilenberg Mt.)
    Blass, G., Graf, H.W., Neue Mineralienfunde aus der Vulkaneifel, Mineralien-Welt 12/1, 17-25, 2001
    Japan
     
    • Honshu Island
      • Chubu Region
        • Niigata Prefecture
    Am. Mineral. 52, 1785; Can. Mineral. 35, 1571.
    USA
     
    • North Dakota
      • Dunn Co.
    JAMES MacPHERSON (Associated Press Writer) "North Dakota Gravel Sparks Fears." 5 April 2008
    JAMES MacPHERSON (Associated Press Writer) "North Dakota Gravel Sparks Fears." 5 April 2008
    JAMES MacPHERSON (Associated Press Writer) "North Dakota Gravel Sparks Fears." 5 April 2008
    • Oregon
      • Tillamook Co.
    Micro Probe Volume IX Number 3
    Mineral and/or Locality
    Google
     
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