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Fluor-cannilloite

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Formula:
{Ca}{Ca
 
2
}{Mg
 
4
Al}(Al
 
3
Si
 
5
O
 
22
)(F,OH)
 
2
Defined as a an amphibole in the cannilloite group of the Calcium subgroup with Mg>Fe2+ and Al>Fe3+ in the C position and with F as the dominant anion in the W position
System:MonoclinicColour:grey-green
Lustre:VitreousHardness:6
Member of:Cannilloite group > Calcium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Name:In allusion to its composition, with FLUORine dominant over hydroxyl and its relationship to Cannilloite.


Originally, the mineral was named "cannilloite," but the type material was found to be fluorine-dominant (F>OH) and it was renamed as stated.

Note that the "fluor-cannilloites" from Luc Yen, Vietnam, are pargasite (see http://www.mindat.org/mesg-7-198029.html).

Closely related to Pargasite.

Classification of Fluor-cannilloite

IMA status:Approved 1996
Strunz 8th edition ID:8/F.10-105
Nickel-Strunz 10th (pending) edition ID:9.DE.10

9 : SILICATES (Germanates)
D : Inosilicates
E : Inosilicates with 2-periodic double chains, Si4O11; Clinoamphiboles
mindat.org URL:http://www.mindat.org/min-6949.html
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Type Occurrence of Fluor-cannilloite

Type Locality:Pargas (Parainen), Southwestern Finland Region, Finland
General Appearance of Type Material:Fluor-cannilloite is gray-green and semitranslucent with a vitreous luster; it has a grayish white streak and shows
no fluorescence under long-wave or short-wave ultraviolet light. It occurs as isolated anhedral grains and small granular aggregates up to

Physical Properties of Fluor-cannilloite

Lustre:Vitreous
Colour:grey-green
Streak:grey-white
Hardness (Mohs):6
Cleavage:Perfect
on {110}

Crystallography of Fluor-cannilloite

Crystal System:Monoclinic

Optical Data of Fluor-cannilloite

Type:Biaxial (+)
RI values: nα = 1.611 nβ = 1.616 nγ = 1.633
Maximum Birefringence:δ = 0.022

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:relatively strong

Chemical Properties of Fluor-cannilloite

Formula:
{Ca}{Ca
 
2
}{Mg
 
4
Al}(Al
 
3
Si
 
5
O
 
22
)(F,OH)
 
2


Defined as a an amphibole in the cannilloite group of the Calcium subgroup with Mg>Fe2+ and Al>Fe3+ in the C position and with F as the dominant anion in the W position
Essential elements:Al, Ca, F, Mg, O, Si
All elements listed in formula:Al, Ca, F, H, Mg, O, Si

Relationship of Fluor-cannilloite to other Species

Member of:Cannilloite group > Calcium Amphibole Subgroup > w(OH, F, Cl)-dominant Amphibole Group > Amphibole Supergroup
Other Members of Group:

- +
Cannilloite
Ca(Ca
 
2
)(Mg
 
4
Al)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
Ferri-cannilloite
Ca(Ca
 
2
)(Mg
 
4
Fe
3+
 
)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
Ferri-fluoro-cannilloite
(Ca)(Ca
 
2
){Mg
 
4
Fe
3+
 
}(Al
 
3
Si
 
5
O
 
22
)F
 
2
Ferro-cannilloite
Ca(Ca
 
2
)(Fe
2+
4
Al)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
Ferro-ferri-cannilloite
Ca(Ca
 
2
)(Fe
2+
4
Fe
3+
 
)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
Ferro-ferri-fluoro-cannilloite
{Ca}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
3
Si
 
5
O
 
22
)F
 
2
Ferro-fluoro-cannilloite
{Ca}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
3
Si
 
5
O
 
22
)F
 
2
Related Minerals - Nickel-Strunz Grouping):

- +
9.DE.05Anthophyllite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Cummingtonite
☐{Mg
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Clino-holmquistite Group
☐{Li
 
2
}{C
2+
3
C
3+
2
}(Si
 
8
O
 
22
)W
 
2
9.DE.05Grunerite
☐{Fe
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganocummingtonite
☐{Mn
2+
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Manganogrunerite
☐{Mn
2+
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Permanganogrunerite
☐{Mn
2+
2
}{Mn
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.05Ferro-fluoro-pedrizite
{Na}{Li
 
2
}{Fe
 
2
Al
 
2
Li}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.05Ferri-fluoro-leakeite
{Na}{Na
 
2
}{Mg
 
2
Fe
3+
2
Li}(Si
 
8
O
 
22
)F
 
2
9.DE.10Actinolite
☐{Ca
 
2
}{(Mg,Fe
2+
 
)
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferri-tschermakite
☐{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Ferro-Actinolite
☐{Ca
 
2
}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Ferro-hornblende
☐{Ca
 
2
}{Fe
2+
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Ferro-tschermakite
☐{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Joesmithite
{Pb}{Ca
 
2
}{Mg
 
3
Fe
3+
2
}(Be
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Magnesio-hornblende
☐{Ca
 
2
}{Mg
 
4
Al}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.10Tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Tschermakite
☐(Ca
 
2
)(Mg
 
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.10Cannilloite
Ca(Ca
 
2
)(Mg
 
4
Al)(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.10Parvo-manganotremolite
☐{CaMn
2+
 
}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.10Fluoro-tremolite
☐{Ca
 
2
}{Mg
 
5
}(Si
 
8
O
 
22
)F
 
2
9.DE.10Potassic-fluoro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-edenite
{Na}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Ferro-kaersutite
{Na}{Ca
 
2
}{Fe
2+
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Ferro-pargasite
{Na}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Hastingsite
{Na}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Kaersutite
{Na}{Ca
 
2
}{Mg
 
3
AlTi}(Al
 
2
Si
 
6
O
 
22
)O
 
2
9.DE.15Magnesio-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Sadanagaite
{Na}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Fluoro-edenite
{Na}{Ca
 
2
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-ferro-ferri-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Fe
3+
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-sadanagaite
{K}{Ca
 
2
}{Mg
 
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Potassic-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-sadanagaite
{K}{Ca
 
2
}{Fe
2+
3
Al
 
2
}(Al
 
3
Si
 
5
O
 
22
)(OH)
 
2
9.DE.15Magnesio-fluoro-hastingsite
{Na}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.15Potassic- fluoro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Potassic-chloro-hastingsite
{K}{Ca
 
2
}{Fe
2+
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Fluoro-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(F,OH)
 
2
9.DE.15Parvo-mangano-edenite
{Na}{CaMn
2+
 
}{Mg
 
5
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.15Potassic-chloro-pargasite
{K}{Ca
 
2
}{Mg
 
4
Al}(Al
 
2
Si
 
6
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-ferro-chloro-edenite
{K}{Ca
 
2
}{Fe
2+
5
}(AlSi
 
7
O
 
22
)(Cl,OH)
 
2
9.DE.15Potassic-magnesio-hastingsite
{K}{Ca
 
2
}{Mg
 
4
Fe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Potassic-ferro-pargasite
{K}{Ca
 
2
}{Fe
2+
4
Al}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.15Chromio-pargasite
{Na}{Ca
 
2
}{Mg
 
4
Cr
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-taramite
Na(CaNa)(Fe
2+
3
Al
 
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Barroisite
☐{CaNa}{Mg
 
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-barroisite
☐(CaNa)(Fe
2+
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-winchite
☐[CaNa][Fe
2+
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-barroisite
☐(CaNa)(Mg
 
3
Fe
3+
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-taramite
Na(CaNa)(Fe
2+
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Ferro-ferri-katophorite
NaCaNaFe
2+
4
(Fe
3+
 
)[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferro-barroisite
☐{CaNa}{Fe
2+
3
Al
 
2
}(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.20Ferro-richterite
{Na}{CaNa}{Fe
2+
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-winchite
☐{CaNa}{Fe
2+
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Ferro-katophorite
{Na}{CaNa}{Fe
2+
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Ferri-taramite
Na(CaNa)(Mg
 
3
Fe
3+
2
)(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Magnesiotaramite
{Na}{CaNa}{Mg
 
3
AlFe
3+
 
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Winchite
☐{CaNa}{Mg
 
4
Al}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.20Taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)(OH)
 
2
9.DE.20Fluoro-richterite
{Na}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Katophorite
{Na}{CaNa}{Mg
 
4
Al}[(AlSi
 
7
)O
 
22
](OH)
 
2
9.DE.20Potassic-fluoro-richterite
{K}{CaNa}{Mg
 
5
}(Si
 
8
O
 
22
)(F,OH)
 
2
9.DE.20Potassic-richterite
K[CaNa][Mg
 
5
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-ghoseite
☐[Mn
2+
 
Na][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Ferri-winchite
☐[CaNa][Mg
 
4
(Fe
3+
 
,Al)]Si
 
8
O
 
22
(OH)
 
2
9.DE.20Fluoro-taramite
{Na}{CaNa}{Mg
 
3
Al
 
2
}(Al
 
2
Si
 
6
O
 
22
)F
 
2
9.DE.25Arfvedsonite
[Na][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Eckermannite
NaNa
 
2
(Mg
 
4
Al}Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-eckermannite
NaNa
 
2
(Fe
2+
 
,
 
4
Al)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-glaucophane
◻[Na
 
2
][Fe
2+
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Glaucophane
◻[Na
 
2
][Mg
 
3
Al
 
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-mangani-leakeite
[(Na,K)][Na
 
2
][Mg
 
2
Mn
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-arfvedsonite
[Na][Na
 
2
][Mn
2+
4
(Fe
3+
 
)]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-leakeite
[Na][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Magnesio-riebeckite
◻{Na
 
2
}{Mg
 
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-arfvedsonite
{Na}{Na
 
2
}{Mg
 
4
Fe
3+
 
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Riebeckite
◻[Na
 
2
][Fe
2+
3
Fe
3+
2
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Mangano-mangani-ungarettiite
NaNa
 
2
(Mn
2+
2
Mn
3+
3
)(Si
 
8
O
 
22
)O
 
2
9.DE.25Ferro-ferri-nybøite
NaNa
 
2
[(Fe
2+
3
,Mg)Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Clino-ferro-ferri-holmquistite
◻{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Ferri-nybøite
NaNa
 
2
(Mg
 
3
Fe
3+
2
](AlSi
 
7
O
 
22
)(OH)
 
2
9.DE.25Ferro-ferri-leakeite
[Na][Na
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferro-ferri-fluoro-leakeite
Na(Na
 
2
)(Fe
2+
2
Fe
3+
2
Li)(Si
 
8
O
 
22
)(F)
 
2
9.DE.25Sodic-ferri-clinoferroholmquistite
☐{Li
 
2
}{Fe
2+
3
Fe
3+
2
}(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Magnesio-fluoro-arfvedsonite
[Na][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
](F,OH)
 
2
9.DE.25Ferri-pedrizite
[Na][Li
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-ferri-leakeite
[K][Na
 
2
][Mg
 
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-nybøite
NaNa
 
2
(Mg
 
3
Al
 
2
)(AlSi
 
7
O
 
22
)(F,OH)
 
2
9.DE.25Mangani-dellaventuraite
{Na}{Na
 
2
}{MgMn
3+
2
LiTi
4+
 
}Si
 
8
O
 
22
O
 
2
9.DE.25Fluoro-pedrizite
NaLi
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Potassic-arfvedsonite
[(K,Na)][Na
 
2
][Fe
2+
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Ferri-obertiite
Na(Na
 
2
)(Mg
 
3
Fe
3+
 
Ti)(Si
 
8
O
 
22
)O
 
2
9.DE.25Potassic-magnesio-fluoro-arfvedsonite
[(K,Na)][Na
 
2
][Mg
 
4
Fe
3+
 
][Si
 
8
O
 
22
][(F,OH)
 
2
]
9.DE.25Ferro-ferri-pedrizite
[Na][Li
 
2
][Fe
2+
2
Fe
3+
2
Li]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Potassic-magnesio-arfvedsonite
[K][Na
 
2
][Mg
 
4
Fe
3+
 
]Si
 
8
O
 
22
(OH)
 
2
9.DE.25Pedrizite
NaLi
 
2
(LiMg
 
2
Al
 
2
)(Si
 
8
O
 
22
)(OH)
 
2
9.DE.25Ferro-pedrizite
NaLi
 
2
(LiFe
2+
2
Al
 
2
)Si
 
8
O
 
22
(OH)
 
2
9.DE.25Fluoro-leakeite
NaNa
 
2
(Mg
 
2
Al
 
2
Li)(Si
 
8
O
 
22
)F
 
2
9.DE.25Ferro-ferri-obertiite
NaNa
 
2
(Fe
2+
3
Fe
3+
 
Ti)Si
 
8
O
 
22
O
 
2

Other Names for Fluor-cannilloite

Synonyms:
IMA1993-033
Other Languages:
German:Fluorocannilloit
Russian:Фторканнилоит
Spanish:Fluorocannilloita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Fluor-cannilloite

Reference List:

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Hawthorne F.C., Oberti R., Ungaretti L., Grice J.D. (1996): A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from Pargas, Finland American Mineralogist, 81, 995-1002.

Mineralogical Record: 28: 142.

Mineralogical Record: 29: 169-174.

Frank C. Hawthorne, Roberta Oberti, George E. Harlow, Walter V. Maresch, Robert F. Martin, John C. Schumacer, Mark D. Welch (2012): Nomenclature of the amphibole supergroup, American Mineralogist, Volume 97, pages 2031–2048

Internet Links for Fluor-cannilloite

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    • Localities for Fluor-cannilloite

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    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    China
     
    • Yunnan Province
      • Wenshan Autonomous Prefecture
        • Wenshan Co.
    		Kristalldruse shop, Munich, Bavaria, Germany
    Finland
     
    • Southwestern Finland Region
    		Hawthorne, F. C., Oberti, R., Ungaretti, L., Grice, J. D. (1996): A new hyper-calcic amphibole with Ca at the A site: Fluor-cannilloite from Pargas, Finland. American Mineralogist. 81, 995-1002
    Madagascar
     
    • Tuléar Province (Toliara)
      • Anosy Region (Fort Dauphin Region)
        • Amboasary District
    		Lapis 21 (11): p 45. (abstract)
    Vietnam
     
    • Yenbai (Yen Bai) Province
    		http://www.thearkenstone.com/tuc-china2.html; Eugeni Bareche (2007) An Phu, Luc Yen, Vietnam. Revista de Minerales (Barcelona), 2007/2, 26-29.
        • An Phu
    		Eugeni Bareche (2007) An Phu, Luc Yen, Vietnam. Revista de Minerales (Barcelona), 2007/2, 26-29
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