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Graeserite

Formula:
(Fe
3+
 
,Ti)
 
4
Ti
 
3
AsO
 
13
(OH)
System:MonoclinicColour:Black
Lustre:MetallicHardness:
Name:For Prof. Dr. Stefan Graeser (1935-), in recognition of his extensive research on the oxides and sulfosalts of arsenic in the Binntal region of Switzerland.


The Fe3+ dominant analog of Tomichite and the As3+ dominant analog of Derbylite.

Classification of Graeserite

IMA status:Approved
Strunz 8th edition ID:4/C.23-15
Nickel-Strunz 10th (pending) edition ID:4.JB.55

4 : OXIDES (Hydroxides, V[5,6] vanadates, arsenites, antimonites, bismuthites, sulfites, selenites, tellurites, iodates)
J : Arsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodates
B : Arsenites, antimonites, bismuthites; with additional anions, without H2O
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Type Occurrence of Graeserite

Type Locality:Gorb, Lercheltini (Lärcheltini) area, Binn Valley, Wallis (Valais), Switzerland
Geological Setting of type material:In hydrothermal veins in a two-mica paragneiss.

Occurrences of Graeserite

Geological Setting:Metamorphosed Precambrian calc-silicate gneissic rock in the footwall of a Zn-Fe-Mn orebody (Sterling Hill, NJ).

Physical Properties of Graeserite

Lustre:Metallic
Diaphaneity (Transparency):Opaque
Colour:Black
Streak:Black
Hardness (Mohs):
Fracture:Conchoidal

Crystallography of Graeserite

Crystal System:Monoclinic

Chemical Properties of Graeserite

Formula:
(Fe
3+
 
,Ti)
 
4
Ti
 
3
AsO
 
13
(OH)
Essential elements:As, Fe, H, O, Ti
All elements listed in formula:As, Fe, H, O, Ti

Relationship of Graeserite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
4.JB.05Fetiasite
(Fe
3+
 
,Fe
2+
 
,Ti)
 
3
[O
 
2
|As
 
2
O
 
5
]
4.JB.10Manganarsite
Mn
 
3
[(OH)
 
4
|As
 
2
O
 
4
]
4.JB.15Magnussonite
Mn
 
10
As
 
6
O
 
18
(OH,Cl)
 
2
4.JB.15UM1984-09-AsO:ClHMn
Mn
 
10
As
 
6
O
 
18
(OH)Cl
4.JB.20Armangite
Mn
2+
26
[CO
 
3
|(HAsO
 
3
)
 
4
|(AsO
 
3
)
 
14
]
4.JB.25Nanlingite
NaCa
 
6
(Mg,Fe,Li)
 
12
(AsO
 
3
)
 
2
[Fe(AsO
 
3
)
 
6
]F
 
14
·
4.JB.30Asbecasite
Ca
 
3
(Ti,Sn
4+
 
)Be
 
2
[(AsO
 
3
)
 
3
|SiO
 
4
]
 
2
4.JB.35Stenhuggarite
CaFeSbO(AsO
 
3
)
 
2
4.JB.40Trigonite
Pb
 
3
Mn
2+
 
[HAsO
 
3
|(AsO
 
3
)
 
2
]
4.JB.45Finnemanite
Pb
 
5
[Cl|(AsO
 
3
)
 
3
]
4.JB.50Gebhardite
Pb
 
8
[O|Cl
 
6
|(As
 
2
O
 
5
)
 
2
]
4.JB.55Derbylite
(Fe,Fe,Ti)
 
7
SbO
 
13
(OH)
4.JB.55Tomichite
(V,Fe)
 
4
Ti
 
3
AsO
 
13
OH
4.JB.60Hemloite
(As,Sb)
 
2
(Ti,V,Fe,Al)
 
12
O
 
23
(OH)
4.JB.65Freedite
Pb
 
15
(Cu,Fe
2+
 
)
 
3
[O
 
7
|Cl
 
10
|(AsO
 
3
)
 
4
]
4.JB.70Georgiadèsite
Pb
 
16
[(OH)
 
6
|Cl
 
14
|(AsO
 
4
)
 
4
]
4.JB.75Ekatite
(Fe
3+
 
,Fe
2+
 
,Zn)
 
12
(OH)
 
6
(AsO
 
3
)
 
6
[AsO
 
3
,HOSiO
 
3
]
 
2

Other Names for Graeserite

Synonyms:
IMA1996-010
Other Languages:
German:Graeserit
Spanish:Graeserita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.
Industrial Uses:None

References for Graeserite

Reference List:Krezemnicki, M.S. and Reusser, E. (1998) Graeserite, Fe3+4Ti3As3+O13(OH) a new mineral species of the derbylite group from from the Mount Leone Nappe, Binntal Region, Western Alps, Switzerland. Canadian Mineralogist: 36: 1083-1088.

Schweizerische mineralogische und petrographische Mitteilungen: 78: 1-9.

Verbeek, E., Orosz, J., and Nikischer, T. (2006) Mineral News: 22(9): 8-9.

Internet Links for Graeserite

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  • Look for Graeserite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Search for Graeserite in the Natural History Museum (London) online catalogue
  • Graeserite details from Handbook of Mineralogy (PDF)
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    Localities for Graeserite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Switzerland
     
    • Wallis (Valais)
      • Binn Valley
        • Lercheltini (Lärcheltini) area
    M.S. Krzemnicki & E. Reusser (1998): Graeserite, Fe4Ti3AsO13(OH), a new mineral species of the derbylite group from the Monte Leone nappe, Binntal, Western Alps, Switzerland.- Canadian Mineralogist 36, 1083-1088.
    USA
     
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Ogdensburg
            • Sterling Hill
    Verbeek, E. et al (2006) Mineral News: 22(9): 8-9.
    Mineral and/or Locality
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