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Bobfergusonite

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Formula:
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
System:MonoclinicColour:Green-brown to red-brown
Hardness:4
Member of:Wyllieite Group
Name:
Named by T. Scott Ercit, A. J. Anderson, Petr Cerny, and Frank C. Hawthorne in honor of Robert Bury Ferguson [February 5, 1921-], Professor of Mineralogy, University of Manitoba, Canada.
Isostructural with:Alluaudite Group

Classification of Bobfergusonite

IMA status:Approved 1984
Strunz 8th edition ID:7/A.06-20
Nickel-Strunz 10th (pending) edition ID:8.AC.15

8 : PHOSPHATES, ARSENATES, VANADATES
A : Phosphates, etc. without additional anions, without H2O
C : With medium-sized and large cations
Dana 8th edition ID:38.2.4.5

38 : ANHYDROUS NORMAL PHOSPHATES, ARSENATES, AND VANADATES
2 : (AB)5(XO4)3
Hey's CIM Ref.:19.12.58

19 : Phosphates
12 : Phosphates of Mn
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Type Occurrence of Bobfergusonite

Type Locality:Gottcha Claim (Pegmatite No. 22), Cross Lake, Manitoba, Canada
Place of Conservation of Type Material:Royal Ontario Museum, Ottawa, Canada M42687
Year of Discovery:1984
Geological Setting of type material:Primary mineral in intermediate zone of granitic pegmatite enriched in Mn and F

Physical Properties of Bobfergusonite

Lustre:Sub-Vitreous, Resinous, Greasy
Diaphaneity (Transparency):Translucent
Comment:Bronzy on parting planes.
Colour:Green-brown to red-brown
Streak:Yellow-brown
Hardness (Mohs):4
Tenacity:Brittle
Cleavage:Perfect
Perfect on {010}, {100} good.
Parting:Parting on {100}
Fracture:Irregular/Uneven
Density (measured):3.54(1) g/cm3
Density (calculated):3.57 g/cm3

Crystallography of Bobfergusonite

Crystal System:Monoclinic
Class (H-M):2/m - Prismatic
Space Group:P2/b {P1 1 2/b} {P2/c} {P1 2/c 1}{P2/a}
Cell Parameters:a = 12.773Å, b = 12.486Å, c = 11.038Å
β = 114.35(13)°
Ratio:a:b:c = 1.023 : 1 : 0.884
Unit Cell Volume:V 1,603.78 ų (Calculated from Unit Cell)
Z:4
Morphology:Equant anhedral crystals to 1cm and nodular aggregates.
Comment:P21/n, Can Min 24:605 (1986) structure
X-Ray Powder Diffraction:
d-spacingIntensity
3.05 (100)
2.90 (40)
2.87 (70)
2.82 (40)
2.74 (40)
2.71 (50)
2.51 (50)
2.08 (70)
Comments:ICDD 40-509

Optical Data of Bobfergusonite

Type:Biaxial (+)
RI values: nα = 1.694(1) nβ = 1.698(1) nγ = 1.715(2)
2V:Measured: 46° , Calculated: 52°
Birefringence:0.021
Maximum Birefringence:δ = 0.021

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:High
Dispersion:relatively strong
Optical Extinction:Y || b, X ^ a = + 10°
Pleochroism:Visible
Comments:X=Y= Yellow-orange
Z= Orange
Z>X = Y

Chemical Properties of Bobfergusonite

Formula:
Na
 
2
Mn
 
5
FeAl(PO
 
4
)
 
6
Essential elements:Al, Fe, Mn, Na, O, P
All elements listed in formula:Al, Fe, Mn, Na, O, P
Empirical Formula:
Na
 
2
Mn
2+
5
Fe
3+
 
Al(PO
 
4
)
 
6

Relationship of Bobfergusonite to other Species

Member of:Wyllieite Group
Other Members of Group:

- +
Ferrorosemaryite
◻NaFe
2+
 
Fe
3+
 
Al(PO
 
4
)
 
3
Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
Qingheiite-(Fe2+)
Na
 
2
Fe
2+
 
MgAl(PO
 
4
)
 
3
Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
Related Minerals - Nickel-Strunz Grouping):

- +
8.AC.05Howardevansite
NaCuFe
 
2
(VO
 
4
)
 
3
8.AC.10Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
8.AC.10Arseniopleite
NaCaMn
2+
 
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.10Caryinite
(Na,Pb)(Ca,Na)(Ca,Mn
2+
 
)(Mn
2+
 
,Mg,Fe
3+
 
)
 
2
(AsO
 
4
)
 
3
8.AC.10Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
8.AC.10Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Johillerite
Na(Mg,Zn)
 
3
Cu(AsO
 
4
)
 
3
8.AC.10Maghagendorfite
(□,Na,)(Na,Ca,Fe
2+
 
)Mn(Mg,Fe
2+
 
,Fe
3+
 
)
 
3
(PO
 
4
)
 
3
8.AC.10Nickenichite
Na
 
0.8
Ca
 
0.4
Cu
 
0.4
(Mg,Fe)
 
3
(AsO
 
4
)
 
3
8.AC.10Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
8.AC.10Ferrohagendorfite
NaCaFe
2+
 
Fe
2+
2
(PO
 
4
)
 
3
8.AC.10Bradaczekite
NaCu
 
4
(AsO
 
4
)
 
3
8.AC.10Yazganite
NaFe
3+
2
(Mg,Mn
2+
 
)(AsO
 
4
)
 
3
· H
 
2
O
8.AC.10Groatite
NaCaMn
 
2
(PO
 
4
)(HPO
 
4
)
 
2
8.AC.15Ferrowyllieite
(Na,Ca,Mn)(Fe,Mn)(Fe,Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
8.AC.15Rosemaryite
(Na,Ca,Mn)(Mn,Fe
2+
 
)(Fe
3+
 
,Mg)Al(PO
 
4
)
 
3
8.AC.15Wyllieite
(Na,Ca,Mn)(Mn,Fe)(Fe,Mg)Al(PO
 
4
)
 
3
8.AC.15Ferrorosemaryite
◻NaFe
2+
 
Fe
3+
 
Al(PO
 
4
)
 
3
8.AC.15Qingheiite-(Fe2+)
Na
 
2
Fe
2+
 
MgAl(PO
 
4
)
 
3
8.AC.18Manitobaite
Na
 
16
Mn
2+
 
 
25
Al
 
8
(PO
 
4
)
 
30
8.AC.20Marićite
NaFe
2+
 
(PO
 
4
)
8.AC.25Berzeliite
NaCa
 
2
(Mg,Mn
2+
 
)
 
2
(AsO
 
4
)
 
3
8.AC.25Manganberzeliite
(Ca,Na)
 
3
(Mn
2+
 
,Mg)
 
2
(AsO
 
4
)
 
3
8.AC.25Palenzonaite
(Ca,Na)
 
3
CaMn
2+
2
(VO
 
4
)
 
3
8.AC.25Schäferite
Ca
 
2
NaMg
 
2
(VO
 
4
)
 
3
8.AC.30Brianite
Na
 
2
CaMg(PO
 
4
)
 
2
8.AC.35Vitusite-(Ce)
Na
 
3
(Ce,La,Nd)(PO
 
4
)
 
2
8.AC.40Olgite
(Sr,Ba)(Na,Sr,REE)
 
2
Na(PO
 
4
)
 
2
8.AC.40Bario-olgite
(Ba,Sr)(Na,Sr,REE)
 
2
Na(PO
 
4
)
 
2
·
8.AC.45Strontiowhitlockite
Sr
 
9
Mg(PO
 
4
)
 
6
(HPO
 
4
)
8.AC.45Whitlockite
Ca
 
9
Mg(PO
 
4
)
 
6
(HPO
 
4
)
8.AC.45Merrillite
Ca
 
9
NaMg(PO
 
4
)
 
7
8.AC.45Tuite
Ca
 
3
(PO
 
4
)
 
2
8.AC.45Ferromerrillite
Ca
 
9
NaFe
2+
 
(PO
 
4
)
 
7
8.AC.45Bobdownsite
Ca
 
9
Mg(PO
 
4
)
 
6
(PO
 
3
F)
8.AC.50Chladniite
{Ca}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Fillowite
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Galileiite
{Fe
2+
 
}{Na
 
8
}{Fe
2+
4
Na
 
4
}{Fe
2+
43
}(PO
 
4
)
 
36
8.AC.50Stornesite-(Y)
{(Y, Ca)}{Na
 
6
 
2
}{(Ca,Na)
 
8
}{(Mg,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
8.AC.50Xenophyllite
Na
 
4
Fe
2+
7
(PO
 
4
)
 
6
8.AC.55Harrisonite
Ca(Fe
2+
 
,Mg)
 
6
(PO
 
4
)
 
2
(SiO
 
4
)
 
2
8.AC.60Kosnarite
KZr
 
2
(PO
 
4
)
 
3
8.AC.65Panethite
(Na,Ca)
 
2
(Mg,Fe
2+
 
)
 
2
(PO
 
4
)
 
2
8.AC.70Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
(PO
 
4
)
 
12
8.AC.75Ronneburgite
K
 
2
MnV
 
4
O
 
12
8.AC.80Tillmannsite
(Ag
 
3
Hg)(VO
 
4
,AsO
 
4
)
8.AC.85Filatovite
K(Al,Zn)
 
2
(As,Si)
 
2
O
 
8
Related Minerals - Hey's Index Grouping:

- +
19.12.1Metaswitzerite
Mn
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.2Bermanite
Mn
2+
 
Mn
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.3Natrophilite
NaMn
2+
 
PO
 
4
19.12.4Sidorenkite
Na
 
3
Mn
2+
 
(CO
 
3
)(PO
 
4
)
19.12.5Niahite
(NH
 
4
)(Mn
2+
 
,Mg)(PO
 
4
) · H
 
2
O
19.12.6Robertsite
Ca
 
3
Mn
3+
4
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.7Pararobertsite
Ca
 
2
Mn
3+
3
(PO
 
4
)
 
3
O
 
2
· 3H
 
2
O
19.12.8Sinkankasite
H
 
2
Mn
2+
 
Al(PO
 
4
)
 
2
(OH) · 6H
 
2
O
19.12.9Mangangordonite
Mn
2+
 
Al
 
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.10Heterosite
(Fe
3+
 
,Mn
3+
 
)PO
 
4
19.12.11Purpurite
(Mn
3+
 
,Fe
3+
 
)PO
 
4
19.12.12Wolfeite
(Fe
2+
 
,Mn
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.13Triploidite
(Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)(OH)
19.12.14Lipscombite
(Fe
2+
 
,Mn
2+
 
)Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
19.12.15Frondelite
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.16Rockbridgeite
Fe
2+
 
Fe
3+
4
(PO
 
4
)
 
3
(OH)
 
5
19.12.17Kryzhanovskite
(Fe
3+
 
,Mn
2+
 
)
 
2
(PO
 
4
)
 
2
(OH,H
 
2
O)
 
3
19.12.18Landesite
Mn
2+
3-x
Fe
3+
x
(PO
 
4
)
 
2
(OH)
 
x
· (3-x)H
 
2
O
19.12.19Phosphoferrite
(Fe
2+
 
,Mn
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.20Reddingite
(Mn
2+
 
,Fe
2+
 
)
 
3
(PO
 
4
)
 
2
· 3H
 
2
O
19.12.21Earlshannonite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
19.12.22Hureaulite
(Mn,Fe)
 
5
(PO
 
4
)
 
2
(HPO
 
4
)
 
2
· 4H
 
2
O
19.12.23Switzerite
(Mn,Fe)
 
3
(PO
 
4
)
 
2
· 7H
 
2
O
19.12.24Laueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.25Pseudolaueite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.26Strunzite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 6H
 
2
O
19.12.27Stewartite
Mn
2+
 
Fe
3+
2
(PO
 
4
)
 
2
(OH)
 
2
· 8H
 
2
O
19.12.28Alluaudite
(Na,Ca)Mn
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
,Mg)
 
2
(PO
 
4
)
 
3
19.12.29Ferroalluaudite
(Na,Ca)Fe
2+
 
(Fe
3+
 
,Mn
2+
 
,Fe
2+
 
)
 
2
(PO
 
4
)
 
3
19.12.30Fillowite
{Mn
2+
 
}{Na
 
8
}{Ca
 
4
Na
 
4
}{(Mn
2+
 
,Fe
2+
 
)
 
43
}(PO
 
4
)
 
36
19.12.31Johnsomervilleite
{Ca}{Na
 
6
[ ]
 
2
}{Ca
 
6
Na
 
2
}{(Fe
2+
 
,Mg,Mn
2+
 
)
 
43
}(PO
 
4
)
 
36
19.12.32Wicksite
NaCa
 
2
(Fe
2+
 
,Mn
2+
 
)
 
4
MgFe
3+
 
(PO
 
4
)
 
6
· 2H
 
2
O
19.12.33Dickinsonite-(KMnNa)
{KNa}{Mn
2+
 
◻}{Ca}{Na
 
3
}{Mn
2+
13
}{Al}(PO
 
4
)
 
12
(OH)
 
2
19.12.34Sarcopside
(Fe
2+
 
,Mn
2+
 
,Mg)
 
3
(PO
 
4
)
 
2
19.12.35Ludlamite
(Fe,Mn,Mg)
 
3
(PO
 
4
)
 
2
· 4H
 
2
O
19.12.36Graftonite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
(PO
 
4
)
 
2
19.12.37Wilhelmvierlingite
CaMnFe
3+
 
(PO
 
4
)
 
2
(OH) · 2H
 
2
O
19.12.38Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.39Beusite
(Mn
2+
 
,Fe
2+
 
,Ca,Mg)
 
3
(PO
 
4
)
 
2
19.12.40Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
19.12.41Jahnsite-(CaMnFe)
{Ca}{Mn
2+
 
}{Fe
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.42Jahnsite-(CaMnMn)
{Ca}{Mn
2+
 
}{Mn
2+
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.43Jahnsite-(CaMnMg)
{Ca}{Mn
2+
 
}{(Mg,Fe
2+
 
)
 
2
}{Fe
3+
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.44Keckite
CaMn
2+
 
Fe
3+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
3
(H
 
2
O)
 
7
19.12.45Stanfieldite
Ca
 
7
Ca
 
2
Mg
 
9
(PO
 
4
)
 
12
19.12.46Laubmannite
(Fe
2+
 
,Mn
2+
 
,Ca)
 
3
Fe
3+
6
(PO
 
4
)
 
4
(OH)
 
12
19.12.47Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
(PO
 
4
)
 
6
(OH)
 
4
· 12H
 
2
O
19.12.48Hagendorfite
NaCaMn
2+
 
Fe
2+
2
(PO
 
4
)
 
3
19.12.49Maghagendorfite
(□,Na,)(Na,Ca,Fe
2+
 
)Mn(Mg,Fe
2+
 
,Fe
3+
 
)
 
3
(PO
 
4
)
 
3
19.12.50Varulite
NaCaMn
2+
 
Mn
2+
2
(PO
 
4
)
 
3
19.12.51Griphite
Na
 
4
Li
 
2
Ca
 
6
(Mn
2+
 
,Fe
2+
 
,Mg)
 
19
Al
 
8
(PO
 
4
)
 
24
(F,OH)
 
8
19.12.52Attakolite
(Ca,Sr)Mn(Al,Fe)
 
4
(HPO
 
4
,PO
 
4
)
 
3
(SiO
 
4
,PO
 
4
)(OH)
 
4
19.12.53Arrojadite-(KFe)
{KNa}{Fe
2+
 
◻}{Ca}{Na
 
2
◻}{Fe
2+
13
}{Al}(PO
 
4
)
 
11
(HPO
 
4
)(OH)
 
2
19.12.54Lun'okite
(Mn,Ca)(Mg,Fe,Mn)Al(PO
 
4
)
 
2
OH · 4H
 
2
O
19.12.55Eosphorite
(Mn
2+
 
,Fe
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.56Ernstite
(Mn
2+
 
,Fe
3+
 
)Al(PO
 
4
)(OH,O)
 
2
· H
 
2
O
19.12.57Childrenite
(Fe
2+
 
,Mn
2+
 
)Al(PO
 
4
)(OH)
 
2
· H
 
2
O
19.12.59Qingheiite
NaMn
3+
 
Mg(Al,Fe
3+
 
)(PO
 
4
)
 
3
19.12.60Whiteite-(CaFeMg)
{Ca}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.61Whiteite-(CaMnMg)
{Ca}{Mn
2+
 
}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.62Whiteite-(MnFeMg)
{(Mn
2+
 
,Ca)}{(Fe
2+
 
,Mn
2+
 
)}{Mg
 
2
}{Al
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.63Rittmannite
{(Mn
2+
 
,Ca)}{Mn
2+
 
}{(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
}{(Al,Fe
3+
 
)
 
2
}(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
19.12.64Zanazziite
Ca
 
2
Mg
 
5
Be
 
4
(PO
 
4
)
 
6
(OH)
 
4
· 6H
 
2
O
19.12.65Samuelsonite
(Ca,Ba)Ca
 
8
Fe
2+
2
Mn
2+
2
Al
 
2
(PO
 
4
)
 
10
(OH)
 
2

Other Names for Bobfergusonite

Synonyms:
IMA1984-072IMA1984-072a
Other Languages:
German:Bobfergusonit
Russian:Бобфергусонит
Spanish:Bobfergusonita

Other Information

Fluorescence in UV light:Not fluorescent.
Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Bobfergusonite

Reference List:

- +
American Mineralogist: 73: 190.

Ercit, T.S., Anderson, A.J., Černý, P. & Hawthorne, F.C. (1986): Bobfergusonite, a new phosphate mineral from Cross Lake, Manitoba. Canadian Mineralogist 24, 599-604.

Ercit, T.S., Hawthorne, F.C., Černý, P. (1986): The crystal structure of bobfergusonite. Canadian Mineralogist 24, 605-614.

Internet Links for Bobfergusonite

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  • Localities for Bobfergusonite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Argentina
     
    • San Luis
      • Chacabuco Department
    Can. Min. vol.42 pp.705-716 (2004).
    Canada
     
    • Manitoba
      • Cross Lake
    Handbook of Mineralogy - Anthony, Bideaux, Bladh, Nichols; The Canadian Mineralogist Vol. 36,pp. 367-376 (1998)
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