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Rappoldite

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Formula:
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
· 2H
 
2
O
System:TriclinicColour:light brown to brown-red
Lustre:VitreousHardness:
Member of:Tsumcorite Group
Name:For its discovery locality


Tsumcorite Group.

Co(II) analogue of Helmutwinklerite.

Classification of Rappoldite

IMA status:Approved 1998
Strunz 8th edition ID:7/C.31-98
Nickel-Strunz 10th (pending) edition ID:8.CG.20

8 : PHOSPHATES, ARSENATES, VANADATES
C : Phosphates without additional anions, with H2O
G : With large and medium-sized cations, RO4:H2O = 1:1
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Type Occurrence of Rappoldite

Type Locality:Rappold Mine, Neustädtel, Schneeberg District, Erzgebirge, Saxony, Germany
General Appearance of Type Material:rosette-like aggregates of prismatic to tabular crystals to 2 mm
Associated Minerals at type locality:
QuartzErythriteCobaltaustiniteArseniosiderite

Physical Properties of Rappoldite

Lustre:Vitreous
Diaphaneity (Transparency):Transparent
Colour:light brown to brown-red
Streak:pale brown-yellow
Hardness (Mohs):
Cleavage:None Observed

Crystallography of Rappoldite

Crystal System:Triclinic

Optical Data of Rappoldite

Type:Biaxial (+)
RI values: nα = 1.850 nβ = 1.870 nγ = 1.900
2V:Measured: 85° , Calculated: 80°
Maximum Birefringence:δ = 0.050

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Very High
Dispersion:r > v distinct

Chemical Properties of Rappoldite

Formula:
Pb(Co,Ni,Zn)
 
2
(AsO
 
4
)
 
2
· 2H
 
2
O
Simplified for copy/paste:Pb(Co,Ni,Zn)2(AsO4)2·2H2O
Essential elements:As, Co, H, O, Pb
All elements listed in formula:As, Co, H, Ni, O, Pb, Zn

Relationship of Rappoldite to other Species

Member of:Tsumcorite Group
Other Members of Group:

- +
Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
· 2(H
 
2
O,OH)
Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
· 2H
 
2
O
Kaliochalcite
KCu
 
2
(SO
 
4
)
 
2
[(OH)(H
 
2
O)]
Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
· 2(OH,H
 
2
O)
Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
(OH,F)
 
2
Natrochalcite
NaCu
 
2
(SO
 
4
)
 
2
(OH) · 2H
 
2
O
Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
Nickeltsumcorite
Pb(Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
· (H
 
2
O,OH)
 
2
Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
· 2(H
 
2
O,OH)
Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Yancowinnaite
PbCuAl(AsO
 
4
)
 
2
OH · H
 
2
O
Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
Related Minerals - Nickel-Strunz Grouping):

- +
8.CG.05Cassidyite
Ca
 
2
(Ni
2+
 
,Mg)(PO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Collinsite
Ca
 
2
(Mg,Fe
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Fairfieldite
Ca
 
2
(Mn
2+
 
,Fe
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Gaitite
Ca
 
2
Zn(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Messelite
Ca
 
2
(Fe
2+
 
,Mn
2+
 
)(PO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Parabrandtite
Ca
 
2
Mn
2+
 
(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Talmessite
Ca
 
2
Mg(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.05Hillite
Ca
 
2
(Zn,Mg)(PO
 
4
)
 
2
· 2 H
 
2
O
8.CG.10Brandtite
Ca
 
2
(Mn
2+
 
,Mg)(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.10Roselite
Ca
 
2
(Co
2+
 
,Mg)(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.10Wendwilsonite
Ca
 
2
Mg(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.10Zincroselite
Ca
 
2
Zn(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.10Rruffite
Ca
 
2
Cu(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.15Ferrilotharmeyerite
Ca(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
8.CG.15Lotharmeyerite
Ca(Zn,Mn
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Mawbyite
Pb(Fe
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
8.CG.15Mounanaite
PbFe
3+
2
(VO
 
4
)
 
2
(OH,F)
 
2
8.CG.15Thometzekite
Pb(Cu,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Tsumcorite
Pb(Zn,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Cobaltlotharmeyerite
Ca(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Cabalzarite
Ca(Mg,Al,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
8.CG.15Krettnichite
(Pb,Sr)(Mn
3+
 
,Co)
 
2
(VO
 
4
)
 
2
· 2(OH,H
 
2
O)
8.CG.15Cobalttsumcorite
Pb(Co,Fe
3+
 
,Ni)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Nickellotharmeyerite
Ca(Ni,Fe
3+
 
,Co)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.15Manganlotharmeyerite
Ca(Mn
3+
 
,Zn)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
8.CG.15Schneebergite
(Bi
3+
 
,Ca)(Co,Ni,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
(OH,H
 
2
O)
 
2
8.CG.15Nickelschneebergite
(Bi
3+
 
,Ca)(Ni,Co,Fe
3+
 
)
 
2
(AsO
 
4
)
 
2
· 2(OH,H
 
2
O)
8.CG.20Gartrellite
Pb(Cu,Fe
3+
 
,Zn)
 
2
(AsO
 
4
,SO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.20Helmutwinklerite
Pb(Zn,Cu)
 
2
(AsO
 
4
)
 
2
· 2H
 
2
O
8.CG.20Zincgartrellite
Pb(Zn,Fe
3+
 
,Cu)
 
2
(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.20Phosphogartrellite
Pb(Cu,Fe
3+
 
)
 
2
(PO
 
4
,AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.20Lukrahnite
Ca(Cu,Zn)(Fe
3+
 
,Zn)(AsO
 
4
)
 
2
· 2(H
 
2
O,OH)
8.CG.25Pottsite
HPbBi(VO
 
4
)
 
2
· 2H
 
2
O
8.CG.35Nickeltalmessite
Ca
 
2
Ni(AsO
 
4
)
 
2
· 2H
 
2
O

Other Names for Rappoldite

Synonyms:
IMA1998-015
Other Languages:
German:Rappoldit
Spanish:Rappoldita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Rappoldite

Reference List:

- +
Effenberger, H., Krause, W., Bernhardt, H.-J. and Martin, M. (2000): On the symmetry of tsumcorite group minerals based on the new species rappoldite and zincgartrellite. Mineralogical Magazine: 64: 1109-1126.

Lapis (2005): 30(7/8): 69.

Internet Links for Rappoldite

Search Engines:
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  • External Links:
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  • Look for Rappoldite on Mineralien Atlas
  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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  • Localities for Rappoldite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Germany
     
    • Saxony
      • Erzgebirge
        • Schneeberg District
          • Neustädtel
    [MinRec 32:418]
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