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Mahnertite

Formula:
NaCu
 
3
(AsO
 
4
)
 
2
Cl · 5H
 
2
O
System:TetragonalLustre:Vitreous
Hardness:2 - 3
Name:Named after Volker Mahnert (b. 1943), zoologist, Director of the Muséum d’Histoire Naturelle, Geneva, Switzerland.


Structurally related to Zdenekite.

Classification of Mahnertite

IMA status:Approved 1994
Strunz 8th edition ID:7/D.25-27
Nickel-Strunz 10th (pending) edition ID:8.DH.45

8 : PHOSPHATES, ARSENATES, VANADATES
D : Phosphates, etc. with additional anions, with H2O
H : With large and medium-sized cations, (OH, etc.):RO4 < 1:1
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Type Occurrence of Mahnertite

Type Locality:Cap Garonne Mine, Pradet, Var, Provence-Alpes-Côte d'Azur, France
Year of Discovery:1995

Physical Properties of Mahnertite

Lustre:Vitreous
Hardness (Mohs):2 - 3

Crystallography of Mahnertite

Crystal System:Tetragonal
Class (H-M):4/mmm (4/m 2/m 2/m) - Ditetragonal Dipyramidal
Space Group:I4/mmm (I4/m 2/m 2/m)
Cell Parameters:a = 10.037Å, c = 23.739Å
Ratio:a:c = 1 : 2.365
Unit Cell Volume:V 2391.5 ų
Z:8
Morphology:Thin pseudotetragonal plates.

Optical Data of Mahnertite

Type:Uniaxial (-)
RI values: nω = 1.686 nε = 1.635
Maximum Birefringence:δ = 0.051

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate

Chemical Properties of Mahnertite

Formula:
NaCu
 
3
(AsO
 
4
)
 
2
Cl · 5H
 
2
O
Essential elements:As, Cl, Cu, H, Na, O
All elements listed in formula:As, Cl, Cu, H, Na, O

Relationship of Mahnertite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
8.DH.05Minyulite
KAl
 
2
[(OH,F)|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.10Leucophosphite
KFe
3+
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Spheniscidite
(NH
 
4
,K)(Fe
3+
 
,Al)
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.10Tinsleyite
KAl
 
2
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.15Jahnsite-(CaMnFe)
CaMn
2+
 
Fe
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Jahnsite-(CaMnMg)
CaMn
2+
 
(Mg,Fe
2+
 
)
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Jahnsite-(CaMnMn)
CaMn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Keckite
(Ca,Mg)(Mn
2+
 
,Zn)
 
2
Fe
3+
3
(PO
 
4
)
 
4
(OH)
 
3
· 2H
 
2
O
8.DH.15Rittmannite
(Mn
2+
 
,Ca)Mn
2+
 
(Fe
2+
 
,Mn
2+
 
,Mg)
 
2
(Al,Fe
3+
 
)
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Whiteite-(CaFeMg)
Ca(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Whiteite-(CaMnMg)
CaMn
2+
 
Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Whiteite-(MnFeMg)
(Mn
2+
 
,Ca)(Fe
2+
 
,Mn
2+
 
)Mg
 
2
Al
 
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Jahnsite-(MnMnMn)
Mn
2+
 
Mn
2+
 
Mn
2+
2
Fe
3+
2
(PO
 
4
)
 
4
](OH)
 
2
· 8H
 
2
O
8.DH.15Kaluginite
(Mn
2+
 
,Ca)MgFe
3+
 
[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.15Jahnsite-(CaFeFe)
CaFeFe
 
2
Fe
 
2
(PO
 
4
)
 
4
(OH)
 
2
·8H
 
2
O
8.DH.15Jahnsite-(NaFeMg)
NaFe
3+
 
Mg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Jahnsite-(NaMnMg)
NaMnMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.15Jahnsite-(CaMgMg)
CaMgMg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.20Manganosegelerite
(Mn
2+
 
,Ca)(Mn
2+
 
,Fe
2+
 
,Mg)Fe
3+
 
(PO
 
4
)
 
2
(OH)
 
2
· 4H
 
2
O
8.DH.20Overite
CaMgAl[OH|(PO
 
4
)
 
2
] · 4H
 
2
O
8.DH.20Segelerite
Ca
 
2
Mg
 
2
Fe
3+
2
(PO
 
4
)
 
4
(OH)
 
2
· 8H
 
2
O
8.DH.20Wilhelmvierlingite
CaMnFe
3+
 
[OH|(PO
 
4
)
 
2
] · 2H
 
2
O
8.DH.20Juonniite
CaMgSc(PO
 
4
)
 
2
(OH)·4H
 
2
O
8.DH.25Calcioferrite
Ca
 
2
Fe
3+
2
[OH|(PO
 
4
)
 
3
] · 7H
 
2
O
8.DH.25Kingsmountite
Ca
 
4
(Fe
2+
 
,Mn
2+
 
)Al
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
· 12H
 
2
O
8.DH.25Montgomeryite
Ca
 
4
MgAl
 
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
· 12H
 
2
O
8.DH.25Zodacite
Ca
 
4
Mn
2+
 
Fe
3+
4
[(OH)
 
2
|(PO
 
4
)
 
3
]
 
2
· 12H
 
2
O
8.DH.30Arseniosiderite
Ca
 
2
Fe
3+
3
[O
 
2
|(AsO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Kolfanite
Ca
 
2
Fe
3+
2
[O
 
2
|(AsO
 
4
)
 
3
] · 2H
 
2
O
8.DH.30Mitridatite
Ca
 
2
Fe
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Pararobertsite
Ca
 
2
Mn
3+
3
[O
 
2
|(PO
 
4
)
 
3
] · 3H
 
2
O
8.DH.30Robertsite
Ca
 
3
Mn
3+
4
[(OH)
 
3
|(PO
 
4
)
 
2
]
 
2
· 3H
 
2
O
8.DH.30Sailaufite
Ca
 
2
Mn
3+
3
[O|CO
 
3
|(AsO
 
4
)
 
2
] · 3H
 
2
O
8.DH.35Mantienneite
KMg
 
2
Al
 
2
Ti[(OH)
 
3
|(PO
 
4
)
 
4
] · 15H
 
2
O
8.DH.35Paulkerrite
K(Mg,Mn
2+
 
)
 
2
(Fe
3+
 
,Al,Ti,Mg)
 
2
Ti(PO
 
4
)
 
4
(OH)
 
3
· 15H
 
2
O
8.DH.35Benyacarite
(H
 
2
O,K)
 
2
(Mn
2+
 
,Fe
2+
 
)
 
2
(Fe
3+
 
,Ti)
 
2
Ti[(O,F)
 
2
|(PO
 
4
)
 
4
] · 14H
 
2
O
8.DH.40Xanthoxenite
Ca
 
4
Fe
3+
2
[OH|(PO
 
4
)
 
2
]
 
2
· 3H
 
2
O
8.DH.50Andyrobertsite
KCdCu
 
5
[H
 
2
AsO4|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.50Calcioandyrobertsite
KCaCu
 
5
[H
 
2
AsO
 
4
|(AsO
 
4
)
 
4
] · 2H
 
2
O
8.DH.55Englishite
K
 
3
Na
 
2
Ca
 
10
Al
 
15
[OH|(PO
 
4
)
 
3
]
 
7
· 26H
 
2
O
8.DH.60Bouazzerite
Bi
 
6
(Mg,Co)
 
11
Fe
3+
14
(AsO
 
4
)
 
18
O
 
12
(OH)
 
4
(H
 
2
O)
 
86

Other Names for Mahnertite

Synonyms:
IMA1994-035
Other Languages:
German:Mahnertit
Russian:Манерит
Spanish:Mahnertita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Mahnertite

Reference List:Sarp, H. (1996), "Mahnertite, (Na,Ca)Cu(AsO4)4Cl.5H2O, a new mineral from the Cap Garonne Mine, Var France", Archs. Sci. Genève 49(2):119-124 (in French, with English abstract).

Wendel,W. & Markl,G. (1999): Lavrion: Mineralogische Klassiker und Raritäten für Sammler. Lapis, 24(7), 34.

Rieck,B. (1999): Seltene Arsenate aus der Kamariza und weitere Neufunde aus Lavrion. Lapis, 24(7), 68

Mineralogical Record: 28: 486.

Pushcharovsky, D. Yu., Zubkova, N.V., Teat, S.J., MacLean, E.J., and Sarp, H. (2004) Crystal structure of mahnertite. European Journal of Mineralogy: 16: 687-692.

Giester, Gerald; Uwe Kolitsch; Peter Leverett; Peter Turner; Peter A. Williams (2007): The crystal structures of lavendulan, sampleite, and a new polymorph of sampleite. European Journal of Mineralogy 19,75-93.

Articles/Blogs about Mahnertite

Internet Links for Mahnertite

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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
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    Localities for Mahnertite

    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    France
     
    • Provence-Alpes-Côte d'Azur
      • Var
        • Pradet
    H. Sarp: Archs. Sci. Genève 49(2):119-124 (1996)
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Agios Konstantinos [St Constantine] (Kamareza; Kamariza)
            • Kamareza Mines
    Lapis, 24(7), 34 (1999); Lapis, 24(7), 68 (1999)
    Mineral and/or Locality
    Google
     
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