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Trilithionite

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Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
System:
Monoclinic
Colour:
Pink-violet
Member of:

Classification of Trilithionite

Approved
9.EC.20

9 : SILICATES (Germanates)
E : Phyllosilicates
C : Phyllosilicates with mica sheets, composed of tetrahedral and octahedral nets
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Physical Properties of Trilithionite

Colour:
Pink-violet

Crystallography of Trilithionite

Crystal System:
Monoclinic
Class (H-M):
2/m - Prismatic
Space Group:
B2/b
Space Group Setting:
C2/c
Cell Parameters:
a = 9.056Å, b = 5.216Å, c = 20.282Å
β = 99.64°
Ratio:
a:b:c = 1.736 : 1 : 3.888
Unit Cell Volume:
V 944.51 ų (Calculated from Unit Cell)
Morphology:


Comment:
Data from Brigatti et al. (2005) (sample from Chedeville, France; polytype 2M2)

Chemical Properties of Trilithionite

Formula:
K(Li1.5Al1.5)(AlSi3O10)(F,OH)2
Essential elements:
All elements listed in formula:

Relationship of Trilithionite to other Species

Series:
Forms a series with Polylithionite (see here)
Forms a series with Polylithionite (see here)
Member of:
Other Members of Group:
AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2
Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2
AnniteKFe32+(AlSi3O10)(OH)2
Annite-Phlogopite Series
AspidoliteNaMg3(AlSi3O10)(OH)2
BalestraiteKLi2V5+Si4O12
Biotite
BityiteLiCaAl2(AlBeSi2O10)(OH)2
BoromuscoviteKAl2(BSi3O10)(OH)2
Brammallite(Na,H3O)(Al,Mg,Fe)2((Si,Al)4O10)(OH)2
CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2
Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2
ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2
ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2
ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2
EastoniteKMg2Al(Al2Si2O10)(OH)2
EphesiteLiNaAl2(Al2Si2O10)(OH)2
FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2
FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2
Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2
FluoranniteKFe32+(AlSi3O10)(F,OH)2
FluorophlogopiteKMg3(AlSi3O10)(F,OH)2
Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2
Glauconite(K,Na)(Fe3+,Al,Mg)2(Si,Al,Fe3+)4O10)(OH)2
HendricksiteK(Zn,Mg,Mn2+)3(AlSi3O10)(OH)2
IlliteK0.65Al2.0[Al0.65Si3.35O10](OH)2
Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2
Lepidolite
LuanshiweiiteKLiAl1.5□0.5(Si3.5Al0.5)O10(OH,F)2
MargariteCaAl2(Al2Si2O10)(OH)2
Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4
MuscoviteKAl2(AlSi3O10)(OH)2
Muscovite-Celadonite Series
NanpingiteCsAl2(AlSi3O10)(OH,F)2
Natro-glauconite(Na,K)(Fe3+,Al,Mg)2((Si,Al)4O10)(OH)2
NorrishiteKLiMn23+(Si4O10)O2
Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2
OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2
ParagoniteNaAl2(AlSi3O10)(OH)2
Phengite
PhlogopiteKMg3(AlSi3O10)(OH)2
PolylithioniteKLi2Al(Si4O10)(F,OH)2
PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2
RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2
ShirokshiniteKNaMg2(Si4O10)F2
ShirozuliteK(Mn2+,Mg)3(AlSi3O10)(OH)2
SiderophylliteKFe22+Al(Al2Si2O10)(OH)2
SokolovaiteCsLi2Al(Si4O10)F2
Suhailite(NH4)Fe32+(AlSi3O10)(OH)2
TainioliteKLiMg2(Si4O10)F2
TetraferrianniteKFe32+((Fe3+,Al)Si3O10)(OH)2
TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
Tobelite(NH4,K)Al2(AlSi3O10)(OH)2
VoloshiniteRb(LiAl1.51.5)(Al0.5Si3.5)O10F2
Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4
YangzhumingiteKMg2.5(Si4O10)F2
ZinnwalditeKLiFe2+Al(AlSi3O10)(F,OH)2
9.EC.05Minnesotaite(Fe,Mg)3(Si4O10)(OH)2
9.EC.05TalcMg3(Si4O10)(OH)2
9.EC.05Willemseite(Ni,Mg)3(Si4O10)(OH)2
9.EC.10FerripyrophylliteFe23+(Si4O10)(OH)2
9.EC.10PyrophylliteAl2(Si4O10)(OH)2
9.EC.15BoromuscoviteKAl2(BSi3O10)(OH)2
9.EC.15CeladoniteK(Mg,Fe2+)Fe3+(Si4O10)(OH)2
9.EC.15Chernykhite(Ba,Na)(V3+,Al,Mg)2((Si,Al)4O10)(OH)2
9.EC.15Montdorite(K,Na)2(Fe2+,Mn2+,Mg)5(Si4O10)2(OH,F)4
9.EC.15MuscoviteKAl2(AlSi3O10)(OH)2
9.EC.15NanpingiteCsAl2(AlSi3O10)(OH,F)2
9.EC.15ParagoniteNaAl2(AlSi3O10)(OH)2
9.EC.15RoscoeliteK(V3+,Al)2(AlSi3O10)(OH)2
9.EC.15Tobelite(NH4,K)Al2(AlSi3O10)(OH)2
9.EC.15AluminoceladoniteK(Mg,Fe2+)Al(Si4O10)(OH)2
9.EC.15ChromphylliteK(Cr,Al)2(AlSi3O10)(OH,F)2
9.EC.15FerroaluminoceladoniteK(Fe2+,Mg)(Al,Fe3+)(Si4O10)(OH)2
9.EC.15FerroceladoniteK(Fe2+,Mg)(Fe3+,Al)(Si4O10)(OH)2
9.EC.15ChromceladoniteK(Mg,Fe2+)(Cr,Al)(Si4O10)(OH)2
9.EC.15TainioliteKLiMg2(Si4O10)F2
9.EC.15Ganterite(Ba,Na,K)(Al,Mg)2(AlSi3O10)(OH)2
9.EC.20AnniteKFe32+(AlSi3O10)(OH)2
9.EC.20EphesiteLiNaAl2(Al2Si2O10)(OH)2
9.EC.20HendricksiteK(Zn,Mg,Mn2+)3(AlSi3O10)(OH)2
9.EC.20Masutomilite(K,Rb)(Li,Mn3+,Al)3(AlSi3O10)(F,OH)2
9.EC.20NorrishiteKLiMn23+(Si4O10)O2
9.EC.20PhlogopiteKMg3(AlSi3O10)(OH)2
9.EC.20PolylithioniteKLi2Al(Si4O10)(F,OH)2
9.EC.20PreiswerkiteNaMg2Al(Al2Si2O10)(OH)2
9.EC.20SiderophylliteKFe22+Al(Al2Si2O10)(OH)2
9.EC.20TetraferriphlogopiteKMg3(Fe3+Si3O10)(OH,F)2
9.EC.20FluorotetraferriphlogopiteKMg3(Fe3+Si3O10)F2
9.EC.20Wonesite(Na,K)(Mg,Fe,Al)6((Al,Si)4O10)2(OH,F)4
9.EC.20EastoniteKMg2Al(Al2Si2O10)(OH)2
9.EC.20TetraferrianniteKFe32+((Fe3+,Al)Si3O10)(OH)2
9.EC.20FluoranniteKFe32+(AlSi3O10)(F,OH)2
9.EC.20ShirokshiniteKNaMg2(Si4O10)F2
9.EC.20ShirozuliteK(Mn2+,Mg)3(AlSi3O10)(OH)2
9.EC.20SokolovaiteCsLi2Al(Si4O10)F2
9.EC.20AspidoliteNaMg3(AlSi3O10)(OH)2
9.EC.20FluorophlogopiteKMg3(AlSi3O10)(F,OH)2
9.EC.20UM2004-49-SiO:AlCsFHKLi(Cs,K)(Al,Li)2.6((Si,Al)4O10)(F,OH)2
9.EC.20Suhailite(NH4)Fe32+(AlSi3O10)(OH)2
9.EC.20YangzhumingiteKMg2.5(Si4O10)F2
9.EC.20OrloviteKLi2Ti(Si4O10)OF
9.EC.20OxyphlogopiteK(Mg,Ti,Fe)3[(Si,Al)4O10](O,F)2
9.EC.25Brammallite(Na,H3O)(Al,Mg,Fe)2((Si,Al)4O10)(OH)2
9.EC.30MargariteCaAl2(Al2Si2O10)(OH)2
9.EC.35Anandite(Ba,K)(Fe2+,Mg)3((Si,Al,Fe)4O10)(S,OH)2
9.EC.35BityiteLiCaAl2(AlBeSi2O10)(OH)2
9.EC.35ClintoniteCa(Mg,Al)3(Al3SiO10)(OH)2
9.EC.35Kinoshitalite(Ba,K)(Mg,Mn2+,Al)3(Al2Si2O10)(OH)2
9.EC.35Ferrokinoshitalite(Ba,K)(Fe2+,Mg)3(Al2Si2O10)(OH,F)2
9.EC.35Oxykinoshitalite(Ba,K)(Mg,Ti,Fe3+,Fe2+)3((Si,Al)4O10)(O,OH,F)2
9.EC.35FluorokinoshitaliteBaMg3(Al2Si2O10)F2
9.EC.40Beidellite(Na,Ca0.5)0.3Al2((Si,Al)4O10)(OH)2 · nH2O
9.EC.40Kurumsakite(Zn,Ni,Cu)8Al8V25+Si5O35 · 27H2O (?)
9.EC.40Montmorillonite(Na,Ca)0.33(Al,Mg)2(Si4O10)(OH)2 · nH2O
9.EC.40NontroniteNa0.3Fe2((Si,Al)4O10)(OH)2 · nH2O
9.EC.40VolkonskoiteCa0.3(Cr,Mg,Fe)2((Si,Al)4O10)(OH)2 · 4H2O
9.EC.40Yakhontovite(Ca,Na)0.5(Cu,Fe,Mg)2(Si4O10)(OH)2 · 3H2O
9.EC.45HectoriteNa0.3(Mg,Li)3(Si4O10)(F,OH)2
9.EC.45SaponiteCa0.25(Mg,Fe)3((Si,Al)4O10)(OH)2 · nH2O
9.EC.45SauconiteNa0.3Zn3((Si,Al)4O10)(OH)2 · 4H2O
9.EC.45SpadaiteMgSiO2(OH)2 · H2O (?)
9.EC.45Stevensite(Ca,Na)xMg3-x(Si4O10)(OH)2
9.EC.45SwineforditeLi(Al,Li,Mg)4((Si,Al)4O10)2(OH,F)4 · nH2O
9.EC.45ZincsiliteZn3(Si4O10)(OH)2 · 4H2O
9.EC.45FerrosaponiteCa0.3(Fe2+,Mg,Fe3+)3((Si,Al)4O10)(OH)2 · 4H2O
9.EC.50Vermiculite(Mg,Fe,Al)3((Al,Si)4O10)(OH)2 · 4H2O
9.EC.55Baileychlore(Zn,Fe,Al,Mg)6((Si,Al)4O10)(OH)8
9.EC.55Chamosite(Fe2+,Mg)5Al(AlSi3O10)(OH)8
9.EC.55Clinochlore(Mg,Fe2+)5Al(AlSi3O10)(OH)8
9.EC.55Cookeite(Al2Li)Al2(AlSi3O10)(OH)8
9.EC.55FranklinfurnaceiteCa2Fe3+Mn32+Mn3+(Zn2Si2O10)(OH)8
9.EC.55Gonyerite(Mn2+,Mg)5Fe3+(Fe3+Si3O10)(OH)8
9.EC.55Nimite(Ni,Mg,Al)6((Si,Al)4O10)(OH)8
9.EC.55Orthochamosite(Fe2+,Mg,Fe3+)5Al(AlSi3O10)(OH,O)8
9.EC.55PennantiteMn52+Al(AlSi3O10)(OH)8
9.EC.55Sudoite(Mg,Fe2+)2Al3(AlSi3O10)(OH)8
9.EC.55DonbassiteAl4.33(AlSi3O10)(OH)8
9.EC.55GlagoleviteNa(Mg,Al)6(AlSi3O10)(OH,O)8
9.EC.55BorocookeiteLi1+3xAl4-x(BSi3O10)(OH)8
9.EC.60AliettiteCa0.2Mg6((Si,Al)8O20)(OH)4 · 4H2O
9.EC.60Corrensite(Mg,Fe)9((Si,Al)8O20)(OH)10 · nH2O
9.EC.60DozyiteMg7Al2(Al2Si4O15)(OH)12
9.EC.60HydrobiotiteK(Mg,Fe2+)6((Si,Al)8O20)(OH)4 · nH2O
9.EC.60Karpinskite(Ni,Mg)2Si2O5(OH)2 (?)
9.EC.60KulkeiteMg8Al(AlSi7O20)(OH)10
9.EC.60LunijianlaiteLi0.7Al6.2(AlSi7O20)(OH,O)10
9.EC.60Rectorite(Na,Ca)Al4((Si,Al)8O20)(OH)4 · 2H2O
9.EC.60Saliotite(Li,Na)Al3(AlSi3O10)(OH)5
9.EC.60TosuditeNa0.5(Al,Mg)6((Si,Al)8O18)(OH)12 · 5H2O
9.EC.60BrinrobertsiteNa0.3Al4(Si4O10)2(OH)4 · 3.5 H2O
9.EC.65Macaulayite(Fe,Al)24Si4O43(OH)2
9.EC.70BurckhardtitePb2(Fe3+Te6+)[AlSi3O8]O6
9.EC.75Ferrisurite(Pb,Ca)2.4Fe23+(Si4O10)(CO3)1.7(OH)3 · nH2O
9.EC.75Surite(Pb,Ca)3(Al,Fe2+,Mg)2((Si,Al)4O10)(CO3)2(OH)2
9.EC.75Niksergievite(Ba,Ca)2Al3(AlSi3O10)(CO3)(OH)6 · nH2O
9.EC.80KegelitePb8Al4(Si8O20)(SO4)2(CO3)4(OH)8

Other Names for Trilithionite

Name in Other Languages:

Other Information

Health Risks:
No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Trilithionite

Reference List:
Canadian Mineralogist (1998): 36: 905-912.

Brigatti, M. F., Caprilli E., Malferrari D., Medici L. and Poppi L. (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2. European Journal of Mineralogy: 17(3): 475-481.

Internet Links for Trilithionite

Localities for Trilithionite

map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
(TL) indicates type locality for a valid mineral species. (FRL) indicates first recorded locality for everything else. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
Australia
 
  • Western Australia
    • Coolgardie Shire
      • Nepean
Peter Keller Collection
Brazil
 
  • Minas Gerais
    • Doce valley
      • Conselheiro Pena
Wilson, W E (2012) Famous Mimeral localities: The Jonas Mine, Itatiaia, Minas Gerais, Brazil. Mineralogical Record 43:289-317.
Canada
 
  • British Columbia
    • Revelstoke Mining Division
      • Revelstoke
RRUFF Database Specimen No. RO60004
  • Manitoba
    • Red Cross Lake
Cerny et al. 2012; Černý, O., Teertstra, D.K., Chapman, R., Selway, J.B., Hawthorne, F.C., Ferreira, K., Chackowsky, L.E., Wang, X.J. & and Meintzer, R.E. (2012)
China
 
  • Henan Province
    • Sanmenxia Prefecture
      • Lushi Co.
        • Guanpo
          • Guanpo pegmatite field
Fan G., Li G., Shen G., Xu J., Dai J. (2013): Luanshiweiite: A New Member of Lepidolite Series. Acta Mineralogica Sinica, 33, 713-721.
  • Jiangxi Province
    • Yichun Prefecture
      • Yifeng Co.
Ganfu Shen and Jinsha Xu (2006): Acta Petrologica et Mineralogica 25(6), 463-472
  • Xinjiang Autonomous Region
    • Yili Hasake Autonomous Prefecture (Ili Kazakh Autonomous Prefecture)
      • Aletai Prefecture (Altay Prefecture)
        • Fuyun Co. (Koktokay Co.)
          • Koktokay pegmatite field (Keketuohai pegmatite field)
            • Altay Mine
Wang, R.C., Hu, H., Zhang, A.C., Fontan, F., de Parseval, P., and Jiang, S.Y. (2007): Contributions to Mineralogy and Petrology 153, 355-367.
Czech Republic
 
  • Bohemia (Böhmen; Boehmen)
    • South Bohemia Region
      • Český Krumlov
Welser, P. et al.: Lithný pegmatit Nová Ves. Minerál, Special volume, 2007, roč. 15.
    • Ústí Region
      • Krušné Hory Mts (Erzgebirge)
        • Krupka (Graupen)
          • Knöttel area (Knötel; Knödel; Knödlberg)
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
  • Moravia (Mähren; Maehren)
    • Vysočina Region
      • Hrotovice
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
      • Velké Meziříčí
Novák, M., Staněk, J.: Lepidolitový pegmatit od Dobré Vody u Velkého Meziříčí, západní Morava. Acta Musei Moraviae, Scientiae geologicae, 1999, roč. 84, s. 3 - 44.
      • Žďár nad Sázavou
Novák, M., Houzar, S., Pfeiferová, A.: Přehled mineralogie, petrografie a historie klasické lokality lepidolitového pegmatitu v Rožné u Bystřice nad Pernštejnem, západní Morava. Acta Musei Moraviae, Sci. geol., 83:3-48.
P. Pauliš (2001): Nejzajímavější naleziště Moravy a Slezska. Kuttna, Kutná Hora.
P. Pauliš (2001): Nejzajímavější naleziště Moravy a Slezska. Kuttna, Kutná Hora.
Finland
 
  • Western and Inner Finland Region
    • Orivesi
      • Eräjärvi area
Sandström, F. & Lahti, S.I. (2009): Viitaniemipegmatiten i Eräjärvi, Orivesi, Finland. Litiofilen 26 (1): 11-38
France
 
  • Limousin
    • Haute-Vienne
      • Ambazac
Brigatti, M. F., Caprilli E., Malferrari D., Medici L. and Poppi L. (2005) Crystal structure and chemistry of trilithionite-2M2 and polylithionite-2M2. European Journal of Mineralogy: 17(3): 475-481.
Germany
 
  • Saxony
    • Oberlausitz
      • Weißenberg
        • Döbschütz
          • Arnsdorf-Melaune Quarry
T. Witzke & T. Giesler (2001): Neufunde aus Sachsen (VII): Bazzit, Bertrandit, Euxenit-(Y), Powellit und andere aus dem Königshainer Granit in der Lausitz.- Lapis 26 (1), 43-48
Germany & Czech Republic
 
  • Saxony & Ústí Region (Bohemia; Böhmen; Boehmen)
    • Erzgebirge; Krusné Hory Mts
Rieder, M., Huka, M., Kučerová, D., Minařík, L., Obermajer, J., and Povondra, P. (1970): Contributions to Mineralogy and Petrology 27, 131-158.
Japan
 
  • Honshu Island
    • Kanto Region
      • Ibaraki Prefecture
        • Hitachiohta City
Kataoka & Uehara (2000) Koubutsu-Gakkai Kou'en-Youshi, 101.
  • Kyushu Region
    • Fukuoka Prefecture
www.petrovrareminerals.com/articles02.html
Mozambique
 
University of Arizona Mineral Museum 13619
Portugal
 
  • Castelo Branco District
    • Covilhã
      • Barco
B. Charoy et al. , Eur.Journ. Mineral. , 1995, 7, pp. 335-352.
Spain
 
  • Madrid
Tanago, J. G., Lozano, P. L., Larios, A. , La Iglesia, A. (2012) Stokesite crystals from La Cabrera, Madrid, Spain. Mineralogical Record 43:499-508
Ukraine
 
  • Zhytomyr Oblast' (Zhitomir Oblast')
Lyckberg, P., Chornousenko, V. & Wilson, W. E. (2009): Volodarsk-Volynski, Zhitomir Oblast, Ukraine. Mineralogical Record, 40, 473-506.
USA
 
  • Colorado
    • Fremont Co.
RRUFF Database Specimen No. RO50486
    • Gunnison Co.
      • Quartz Creek Pegmatite District
University of Arizona Mineral Museum 5528
Mineral and/or Locality  
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