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Boyleite

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Formula:
(Zn,Mg)SO
 
4
· 4H
 
2
O
System:MonoclinicHardness:2
Member of:Rozenite Group
Name:Named after Dr. Robert William Boyle (1920– ), Canadian geochemist, Geological Survey of Canada, Ottawa, Canada.


Rozenite Group.

Soluble in water; slowly alters to gunningite in a dry atmosphere.

Classification of Boyleite

IMA status:Approved
Strunz 8th edition ID:6/C.03-50
Nickel-Strunz 10th (pending) edition ID:7.CB.15

7 : SULFATES (selenates, tellurates, chromates, molybdates, wolframates)
C : Sulfates (selenates, etc.) without additional anions, with H2O
B : With only medium-sized cations
Dana 8th edition ID:29.6.6.5

29 : HYDRATED ACID AND NORMAL SULFATES
6 : AXO4·xH2O
Hey's CIM Ref.:25.5.6

25 : Sulphates
5 : Sulphates of Zn and Hg
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Type Occurrence of Boyleite

Type Locality:Porphyry quarry, Kropbach, Münstertal, Black Forest, Baden-Württemberg, Germany
Year of Discovery:1978

Physical Properties of Boyleite

Hardness (Mohs):2

Crystallography of Boyleite

Crystal System:Monoclinic
Cell Parameters:a = 5.94Å, b = 13.6Å, c = 7.95Å
β = 90.4°
Ratio:a:b:c = 0.437 : 1 : 0.585
Unit Cell Volume:V 642.22 ų (Calculated from Unit Cell)

Optical Data of Boyleite

Type:Biaxial (-)
RI values: nα = 1.522 nβ = 1.531 nγ = 1.536
2V:Measured: 70° , Calculated: 72°
Maximum Birefringence:δ = 0.014

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Low
Dispersion:relatively strong

Chemical Properties of Boyleite

Formula:
(Zn,Mg)SO
 
4
· 4H
 
2
O
Essential elements:H, O, S, Zn
All elements listed in formula:H, Mg, O, S, Zn

Relationship of Boyleite to other Species

Member of:Rozenite Group
Other Members of Group:

- +
Aplowite
(Co,Mn,Ni)SO
 
4
· 4H
 
2
O
Ilesite
(Mn,Zn,Fe)SO
 
4
· 4H
 
2
O
Rozenite
FeSO
 
4
· 4H
 
2
O
Starkeyite
MgSO
 
4
· 4H
 
2
O
Related Minerals - Nickel-Strunz Grouping):

- +
7.CB.05Dwornikite
(Ni,Fe)SO
 
4
· H
 
2
O
7.CB.05Gunningite
ZnSO
 
4
· H
 
2
O
7.CB.05Kieserite
MgSO
 
4
· H
 
2
O
7.CB.05Poitevinite
(Cu,Fe,Zn)SO
 
4
· H
 
2
O
7.CB.05Szmikite
MnSO
 
4
· H
 
2
O
7.CB.05Szomolnokite
FeSO
 
4
· H
 
2
O
7.CB.05Cobaltkieserite
CoSO
 
4
· H
 
2
O
7.CB.07Sanderite
MgSO
 
4
· 2H
 
2
O
7.CB.10Bonattite
CuSO
 
4
· 3H
 
2
O
7.CB.15Aplowite
(Co,Mn,Ni)SO
 
4
· 4H
 
2
O
7.CB.15Ilesite
(Mn,Zn,Fe)SO
 
4
· 4H
 
2
O
7.CB.15Rozenite
FeSO
 
4
· 4H
 
2
O
7.CB.15Starkeyite
MgSO
 
4
· 4H
 
2
O
7.CB.15Drobecite
CdSO
 
4
· 4H
 
2
O
7.CB.15Cranswickite
MgSO
 
4
· 4H
 
2
O
7.CB.20Chalcanthite
CuSO
 
4
· 5H
 
2
O
7.CB.20Jôkokuite
MnSO
 
4
· 5H
 
2
O
7.CB.20Pentahydrite
MgSO
 
4
· 5H
 
2
O
7.CB.20Siderotil
FeSO
 
4
· 5H
 
2
O
7.CB.25Bianchite
(Zn,Fe)SO
 
4
· 6H
 
2
O
7.CB.25Chvaleticeite
(Mn,Mg)SO
 
4
· 6H
 
2
O
7.CB.25Ferrohexahydrite
FeSO
 
4
· 6H
 
2
O
7.CB.25Hexahydrite
MgSO
 
4
· 6H
 
2
O
7.CB.25Moorhouseite
(Co,Ni,Mn)SO
 
4
· 6H
 
2
O
7.CB.25Nickelhexahydrite
(Ni,Mg,Fe)SO
 
4
· 6H
 
2
O
7.CB.30Retgersite
NiSO
 
4
· 6H
 
2
O
7.CB.35Bieberite
CoSO
 
4
· 7H
 
2
O
7.CB.35Boothite
CuSO
 
4
· 7H
 
2
O
7.CB.35Mallardite
MnSO
 
4
· 7H
 
2
O
7.CB.35Melanterite
FeSO
 
4
· 7H
 
2
O
7.CB.35Zincmelanterite
(Zn,Cu,Fe)SO
 
4
· 7H
 
2
O
7.CB.35Alpersite
(Mg,Cu)[SO
 
4
] · 7H
 
2
O
7.CB.40Epsomite
MgSO
 
4
· 7H
 
2
O
7.CB.40Goslarite
ZnSO
 
4
· 7H
 
2
O
7.CB.40Morenosite
NiSO
 
4
· 7H
 
2
O
7.CB.45Alunogen
Al
 
2
(SO
 
4
)
 
3
· 17H
 
2
O
7.CB.45Meta-alunogen
Al
 
2
(SO
 
4
)
 
3
· 12H
 
2
O
7.CB.50Aluminocoquimbite
FeAl(SO
 
4
)
 
3
· 9H
 
2
O
7.CB.55Coquimbite
Fe
 
2-x
Al
 
x
(SO
 
4
)
 
3
· 9H
 
2
O, x ~0.5
7.CB.55Paracoquimbite
Fe
 
2
(SO
 
4
)
 
3
· 9H
 
2
O
7.CB.55Rhomboclase
(H
 
5
O
 
2
)Fe
3+
 
(SO
 
4
)
 
2
· 2H
 
2
O
7.CB.60Kornelite
Fe
 
2
(SO
 
4
)
 
3
· 7H
 
2
O
7.CB.65Quenstedtite
Fe
 
2
(SO
 
4
)
 
3
· 10H
 
2
O
7.CB.70Lausenite
Fe
 
2
(SO
 
4
)
 
3
·6H
 
2
O
7.CB.75Lishizhenite
ZnFe
 
2
(SO
 
4
)
 
4
· 14H
 
2
O
7.CB.75Römerite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
· 14H
 
2
O
7.CB.80Ransomite
CuFe
 
2
(SO
 
4
)
 
4
· 6H
 
2
O
7.CB.85Apjohnite
Mn
2+
 
Al
 
2
(SO
 
4
)
 
4
· 22H
 
2
O
7.CB.85Bílinite
Fe
2+
 
Fe
3+
2
(SO
 
4
)
 
4
· 22H
 
2
O
7.CB.85Dietrichite
(Zn,Fe
2+
 
,Mn
2+
 
)Al
 
2
(SO
 
4
)
 
4
· 22H
 
2
O
7.CB.85Halotrichite
FeAl
 
2
(SO
 
4
)
 
4
· 22H
 
2
O
7.CB.85Pickeringite
MgAl
 
2
(SO
 
4
)
 
4
· 22H
 
2
O
7.CB.85Redingtonite
(Fe
2+
 
,Mg,Ni)(Cr,Al)
 
2
(SO
 
4
)
 
4
·22H
 
2
O
7.CB.85Wupatkiite
(Co,Mg,Ni)Al
 
2
(SO
 
4
)
 
4
·22H
 
2
O
7.CB.90Meridianiite
MgSO
 
4
· 11H
 
2
O
Related Minerals - Hey's Index Grouping:

- +
25.5.1Zinkosite
ZnSO
 
4
25.5.2Goslarite
ZnSO
 
4
· 7H
 
2
O
25.5.3Namuwite
(Zn,Cu)
 
4
(SO
 
4
)(OH)
 
6
· 4H
 
2
O
25.5.4Ktenasite
Zn(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 6H
 
2
O
25.5.5Ramsbeckite
(Cu,Zn)
 
15
(SO
 
4
)
 
4
(OH)
 
22
· 6H
 
2
O
25.5.7Serpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
25.5.8Orthoserpierite
Ca(Cu,Zn)
 
4
(SO
 
4
)
 
2
(OH)
 
6
· 3H
 
2
O
25.5.9Zincaluminite
Zn
 
6
Al
 
6
(SO
 
4
)
 
2
(OH)
 
16
· 5H
 
2
O
25.5.10Glaucocerinite
(Zn,Cu)
 
10
Al
 
6
(SO
 
4
)
 
3
(OH)
 
32
· 18H
 
2
O
25.5.11Gunningite
ZnSO
 
4
· H
 
2
O
25.5.12Chaidamuite
ZnFe
3+
 
(SO
 
4
)
 
2
(OH) · 4H
 
2
O
25.5.13Bianchite
(Zn,Fe)SO
 
4
· 6H
 
2
O
25.5.15Zincmelanterite
(Zn,Cu,Fe)SO
 
4
· 7H
 
2
O
25.5.16Zincobotryogen
(Zn,Mg,Mn
2+
 
)Fe
3+
 
(SO
 
4
)
 
2
(OH) · 7H
 
2
O
25.5.17Schuetteite
Hg
2+
3
(SO
 
4
)O
 
2
25.5.18Gianellaite
(Hg
 
2
N)
 
2
SO
 
4

Other Names for Boyleite

Synonyms:
IMA1977-026
Other Languages:
German:Boyleit
Russian:Бойлеит
Spanish:Boyleita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Boyleite

Reference List:

- +
Walenta, K. (1978): Boyleit, ein neues Sulfatmineral von Kropbach im südlichen
Schwarzwald. Chem. Erde. 37, 73–79.

American Mineralogist (1979): 64, 241, 464.

A. J. Blake, P. A. Cooke, P. Hubberstey and C. L. Sampson (2001): Zinc(II) sulfate tetrahydrate. Acta Crystallographica E57, i109-i111.

Internet Links for Boyleite

Search Engines:
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  • Raman and XRD data at RRUFF project
  • American Mineralogist Crystal Structure Database
  • Boyleite details from Handbook of Mineralogy (PDF)
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  • Localities for Boyleite

    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Canada
     
    • Nunavut Territory
      • Baffin Island
        • Nanisivik
    [MinRec 21:533]
    • Québec
      • Montérégie
        • Rouville RCM
          • Mont Saint-Hilaire
    CMMA Micro-News 41-1 (2007) W. Henderson & L. Horvath
    Germany
     
    • Baden-Württemberg
      • Black Forest
        • Münstertal
          • Kropbach
    Chemie der Erde (1978) 37, 73-79
    Greece
     
    • Attikí (Attica; Attika) Prefecture
      • Lavrion (Laurion; Laurium) District
        • Lavrion District Mines
          • Sounion area
            • Sounion Mines
    Lapis, 24, 7/8 (1999)
    Ireland
     
    • Co. Kilkenny
      • Johnstown
    Balassone, G., Rossi, M., Boni, M., Stanley, G., and McDermott, P. (2008): Ore Geology Reviews 33, 168-186.
    Italy
     
    • Sardinia
      • Cagliari Province
        • Villaputzu
    Ciriotti M.E. & Blass.G. (2010): Pot-pourri 2009: identificazioni UKiS AMI. Minerali italiani di interesse. Micro (UK report), 2/2010, 124-127
    Japan
     
    • Kyushu Region
      • Nagasaki Prefecture
        • Tsushima Islands
    Shimada (1982) Sanko-Gakkai Koen-Yoshi, 15.
    Norway
     
    • Rogaland
      • Sauda
    Personal commentary Inge Bryhni, Oslo 1993. ID by XRD and semiquantitative spectrometric analysis.
    Switzerland
     
    • Wallis (Valais)
      • Martigny
        • Mont Chemin
    Stalder, H. A., Wagner, A., Graeser, S. and Stuker, P. (1998): "Mineralienlexikon der Schweiz", Verlag Wepf & Co. (Basel), p. 82
    Mineral and/or Locality
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