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Bultfonteinite

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Wessels Mine (Wessel's Mine), Hotazel, Kalahari manganese fields, Northern Cape Province, South Africa

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Formula:
Ca
 
2
[F|HSiO
 
4
] · H
 
2
O
System:TriclinicColour:colourless, pink
Hardness:4½
This page provides mineralogical data about Bultfonteinite.

Classification of Bultfonteinite

IMA status:Valid - first described prior to 1959 (pre-IMA) - "Grandfathered"
Strunz 8th edition ID:8/B.22-40
Nickel-Strunz 10th (pending) edition ID:9.AG.80

9 : SILICATES (Germanates)
A : Nesosilicates
G : Nesosilicates with additional anions; cations in > [6] +- [6] coordination
Dana 8th edition ID:52.4.7.2

52 : NESOSILICATES Insular SiO4 Groups and O,OH,F,H2O
4 : Insular SiO4 Groups and O, OH, F, and H2O with cations in [6] and/or >[6] coordination
Hey's CIM Ref.:17.1.16

17 : Silicates Containing other Anions
1 : Silicates with fluoride (not containing Al)
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Type Occurrence of Bultfonteinite

Type Locality:Bultfontein, Free State Province, South Africa
Year of Discovery:1932

Physical Properties of Bultfonteinite

Colour:colourless, pink
Streak:white
Hardness (Mohs):4½
Cleavage:Distinct/Good

Crystallography of Bultfonteinite

Crystal System:Triclinic
Cell Parameters:a = 10.99Å, b = 8.18Å, c = 5.67Å
α = 93.95°, β = 91.32°, γ = 89.85°
Ratio:a:b:c = 1.344 : 1 : 0.693
Unit Cell Volume:V 508.38 ų (Calculated from Unit Cell)

Optical Data of Bultfonteinite

Type:Biaxial (+)
RI values: nα = 1.587 nβ = 1.590 nγ = 1.597
Maximum Birefringence:δ = 0.010

Chart shows birefringence interference colour range (at 30µm thickness) and does not take into account mineral colouration.
Surface Relief:Moderate
Dispersion:r > v

Chemical Properties of Bultfonteinite

Formula:
Ca
 
2
[F|HSiO
 
4
] · H
 
2
O
Essential elements:Ca, H, O, Si
All elements listed in formula:Ca, F, H, O, Si
Common Impurities:B,Al,Na,P

Relationship of Bultfonteinite to other Species

Related Minerals - Nickel-Strunz Grouping):

- +
9.AG.05Abswurmbachite
CuMn
3+
6
O
 
8
(SiO
 
4
)
9.AG.05Braunite
Mn
2+
 
Mn
3+
6
[O
 
8
|SiO
 
4
]
9.AG.05Neltnerite
CaMn
3+
6
[O
 
8
|SiO
 
4
]
9.AG.05Braunite-II
CaMn
3+
14
SiO
 
24
9.AG.10Långbanite
(Mn
2+
 
,Ca)
 
4
(Mn
3+
 
,Fe
3+
 
)
 
9
Sb
5+
 
[O
 
8
|SiO
 
4
]
 
2
9.AG.15Malayaite
CaSn[O|SiO
 
4
]
9.AG.15Titanite
CaTi[O|SiO
 
4
]
9.AG.15Vanadomalayaite
CaV
4+
 
[O|SiO
 
4
]
9.AG.20Cerite-(Ce)
(Ce,Ca)
 
9
(Fe,Mg)(SiO
 
4
)
 
3
[SiO
 
3
(OH)]
 
4
(OH)
 
3
9.AG.20Cerite-(La)
(La,Ce,Ca)
 
9
(Fe,Ca,Mg)(SiO
 
4
)
 
3
[SiO
 
3
(OH)]
 
4
(OH)
 
3
9.AG.20Aluminocerite-(Ce)
(Ce,La,Ca)
 
9
(Al,Fe
3+
 
)(SiO
 
4
)
 
3
[SiO
 
3
(OH)]
 
4
(OH)
 
3
9.AG.25Trimounsite-(Y)
Y
 
2
Ti
 
2
[O
 
5
|SiO
 
4
]
9.AG.25Yftisite-(Y)
(Y,Dy,Er)
 
4
(Ti,Sn)O(SiO
 
4
)
 
2
(F,OH)
 
6
9.AG.30Sitinakite
KNa
 
2
Ti
 
4
Si
 
2
O
 
13
(OH)·2H
 
2
O
9.AG.35Kittatinnyite
Ca
 
2
Mn
 
2
Mn(SiO
 
4
)
 
2
(OH)
 
4
·9H
 
2
O
9.AG.40aNatisite
Na
 
2
Ti[O|SiO
 
4
]
9.AG.40bParanatisite
Na
 
2
Ti[O|SiO
 
4
]
9.AG.45Törnebohmite-(Ce)
(Ce,La)
 
2
Al(SiO
 
4
)
 
2
OH
9.AG.45Törnebohmite-(La)
(La,Ce)
 
2
Al(SiO
 
4
)
 
2
OH
9.AG.50Kuliokite-(Y)
Y
 
4
Al(SiO
 
4
)
 
2
(OH)
 
2
F
 
5
9.AG.55Chantalite
CaAl
 
2
[(OH)
 
4
|SiO
 
4
]
9.AG.60Mozartite
CaMn
3+
 
[OH|SiO
 
4
]
9.AG.60Vuagnatite
CaAl[OH|SiO
 
4
]
9.AG.65Hatrurite
Ca
 
3
[O|SiO
 
4
]
9.AG.70Jasmundite
Ca
 
11
[O
 
2
|S|(SiO
 
4
)
 
4
]
9.AG.75Afwillite
Ca
 
3
[HSiO
 
4
]
 
2
 · 2H
 
2
O
9.AG.85Zoltaiite
BaV
4+
2
V
3+
12
Si
 
2
O
 
27
9.AG.90Tranquillityite
(Fe
2+
 
,Ca)
 
8
(Zr,Y)
 
2
Ti
 
3
[O
 
4
|SiO
 
4
]
 
3
Related Minerals - Hey's Index Grouping:

- +
17.1.1Hectorite
Na
 
0.3
(Mg,Li)
 
3
Si
 
4
O
 
10
(F,OH)
 
2
17.1.3Agrellite
NaCa
 
2
[F|Si
 
4
O
 
10
]
17.1.4Apophyllite-(NaF)
NaCa
 
4
[F|Si
 
8
O
 
20
] · 8H
 
2
O
17.1.5Apophyllite-(KF)
KCa
 
4
[(F,OH)|Si
 
8
O
 
20
] · 8H
 
2
O
17.1.6Apophyllite-(KOH)
KCa
 
4
[(OH,F)|Si
 
8
O
 
20
] · 8H
 
2
O
17.1.7Hsianghualite
Ca
 
3
Li
 
2
Be
 
3
[F
 
2
|(SiO
 
4
)
 
3
]
17.1.8Leucophanite
NaCaBeSi
 
2
O
 
6
F
17.1.9Norbergite
Mg
 
3
[(F,OH)
 
2
|SiO
 
4
]
17.1.10Chondrodite
(Mg,Fe
2+
 
)
 
5
[(F,OH)
 
2
|(SiO
 
4
)
 
2
]
17.1.11Humite
(Mg,Fe
2+
 
)
 
7
[(F,OH)
 
2
|(SiO
 
4
)
 
3
]
17.1.12Clinohumite
(Mg,Fe
2+
 
)
 
9
[(F,OH)
 
2
|(SiO
 
4
)
 
4
]
17.1.13Canasite
K
 
2
Na
 
4
Ca
 
5
(Si
 
12
O
 
30
(OH,F)
 
4
17.1.14Charoite
(K,Na)
 
5
(Ca,Ba,Sr)
 
8
(Si
 
6
O
 
15
)
 
2
(Si
 
6
O
 
16
)(OH,F)·H
 
2
O
17.1.15Cuspidine
Ca
 
4
[(F,OH)
 
2
|Si
 
2
O
 
7
]
17.1.17Zeophyllite
Ca
 
4
Si
 
3
O
 
8
(OH,F)
 
4
·2H
 
2
O
17.1.18Rowlandite-(Y)
(Y,Fe
3+
 
,Ce)
 
3
[O|(F,OH)|Si
 
2
O
 
7
]
17.1.19Yuksporite
(K,Ba)NaCa
 
2
(Si,Ti)
 
4
O
 
11
(F,OH)·H
 
2
O
17.1.20Yftisite-(Y)
(Y,Dy,Er)
 
4
(Ti,Sn)O(SiO
 
4
)
 
2
(F,OH)
 
6
17.1.21Mosandrite
Na
 
2
Ca
 
4
(Ce,La,Nd)Ti(Si
 
2
O
 
7
)
 
2
OF
 
3
17.1.22Hiortdahlite
(Ca,Na)
 
3
(Zr,Ti)Si
 
2
O
 
7
(O,OH,F)
 
2
17.1.23Burpalite
Na
 
2
CaZr[F
 
2
|Si
 
2
O
 
7
]
17.1.24Seidozerite
Na
 
8
Zr
 
3
Ti
 
3
Mn
2+
2
[O|F|Si
 
2
O
 
7
]
 
4
17.1.25Thorosteenstrupine
CaMnThSi
 
4
O
 
11
(OH)F·6H
 
2
O
17.1.26Zircophyllite
(K,Na)
 
3
(Mn,Fe
2+
 
)
 
7
(Zr,Ti)
 
2
Si
 
8
O
 
24
(O,OH,F)
 
7
17.1.27Jinshajiangite
BaNaTi
 
2
 Fe
2+
4
(Si
 
2
O
 
7
)
 
2
O
 
2
(OH)
 
2
F
17.1.28Rosenbuschite
(Ca,Na)
 
3
(Zr,Ti)[O|F|Si
 
2
O
 
7
]
17.1.29Narsarsukite
Na
 
2
(Ti,Fe)Si
 
4
(O,F)
 
11
17.1.30Sonolite
Mn
2+
9
[(OH,F)
 
2
|(SiO
 
4
)
 
4
]

Other Names for Bultfonteinite

Other Languages:
German:Bultfonteinit
Russian:Бултфонтейнит
Spanish:Bultfonteinita

Other Information

Health Warning:No information on health risks for this material has been entered into the database. You should always treat mineral specimens with care.

References for Bultfonteinite

Reference List:American Mineralogist: 17: 455.

American Mineralogist: 18: 32.

McIver, Edward J. (1963), The structure of bultfonteinite, Ca4Si3O10F2H6: Acta Crystallographica: 16: 551-558.

Internet Links for Bultfonteinite

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    Localities for Bultfonteinite

    Hide Locality List
    The map shows a selection of localities that have latitude and longitude coordinates recorded. Click on the symbol to view information about a locality. The symbol next to localities in the list can be used to jump to that position on the map.
    (TL) indicates type locality. ? indicates mineral may be doubtful at this locality. All other localities listed without reference should be considered as uncertain and unproven until references can be found.
    Australia
     
    • Victoria
    		Aust.Jour. Earth Sci. 46:251 (1999)
    Canada
     
    • Northwest Territories
    Israel
     
    • Negev desert
    		Gross, S. (1977): The Mineralogy of the Hatrurim Formation, Israel. Geological Survey of Israel, Bulletin no. 70, 80 pp.
    Japan
     
    • Honshu Island
      • Chugoku Region
        • Okayama Prefecture
          • Takahashi
            • Bitchu-cho (Bicchu-cho)
    		Mineralogical Record: 27: 303.; Mineralogical Journal Vol. 14 (1989) , No. 7 pp 299-302
    Jordan
     
    • Amman
      • Hashem region
    		Handbook of Mineralogy - Anthony, Bideaux, Bladh, Nichols
    Russia
     
    • Eastern-Siberian Region
      • Prebaikalia (Pribaikal'e)
        • Irkutskaya Oblast'
          • Lake Baikal area
    		Koneva A.A., Uschapovskaya Z.F. (1991) On harkerite and bultfonteinite from skarns of Tazheran alkaline massif, - Geologiya i Geofizika, 2, p.74-78.
    • Northern Caucasus Region
      • Kabardino-Balkarian Republic
    		American Mineralogist, Volume 94, pages 1361–1370, 2009
    South Africa
     
    • Free State Province
    		AM 40 (1955), 900; HB2/1 (1995)
      • Jagersfontein
    		Minerals of South Africa
    • Northern Cape Province
      • Kalahari manganese fields
        • Hotazel
    		[Von Bezing, K. L. et al. (1991) - The Kalahari manganese field : an update, Mineralogical Record, 22 (3), 279-302]
        • Kuruman
          • N'Chwaning Mines
    		[Von Bezing, K. L. et al. (1991) - The Kalahari (Afrique du Sud) manganese field : an update, Mineralogical Record, 22 (3), 279-302.]
    Lapis (2004): 29(9):12; Bonazzi, P., Bindi, L., Medenbach, O., Pagano, R., Lampronti, Menchetti, S. (2007): Olmiite, CaMn[SiO3(OH)](OH), the Mn-dominant analogue of poldervaartite, a new mineral species from Kalahari manganese fields (Republic of South Africa), Mineralogical Magazine, 71, 193-291.
      • Kimberley
    		Minerals of South Africa
    USA
     
    • California
      • Riverside Co.
        • Crestmore
    		[micromounts@yahoogroups.com]
    • New Jersey
      • Sussex Co.
        • Franklin Mining District
          • Franklin
    		Dunn(1995):Pt3:363.
    Mineral and/or Locality
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